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4
Atomic Theory of Matter
i.e., solid sodium
mixed with chlorine
• Postulates of Dalton’s Atomic Theory gas forms a new
substance, salt, with
4.) A chemical reaction consists of the totally different
rearrangements of the atoms present in the properties from the
starting materials.
reacting substances to give new chemical
combinations present in the substances formed by
the reaction (new chemical with different
properties).
2 Na (s) + Cl2 (g) 2 NaCl (s)
Once again, later
5.) Atoms are not created, destroyed, or broken found indivisible
into smaller particles by any chemical reaction. to be untrue.
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Atomic Theory of Matter
Nucleus
( +)
-
e
7
Atomic Theory of Matter
8
Atomic Theory of Matter
– In 1909, U.S. physicist, Robert Millikan obtained the
charge on the electron (1.602 x 10-19 C).
-
Na+ Z=11 11p, 10e- Cl Z=17 17p, 18e-
code for
Note: #e- > #p; both: proton
therefore, negatively charged species 15
Atomic Theory of Matter
– Isotopes are atoms whose nuclei have the same
atomic number (Z) but different mass numbers (A);
that is, the nuclei have the same number of protons
but different numbers of neutrons thereby causing
them to have different masses.
– Chlorine, for example, exists as two isotopes:
chlorine-35 and chlorine-37.
37 Frac abund = 24.229%
35
17 Cl Frac abund = 75.771%
Mass = 34.97 amu 17 Cl Mass = 36.97 amu
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anomalies
The Periodic Table
Periods and Groups
24
Metals, Nonmetals, and Metalloids – generally,
left of staircase are metals, touching staircase
are metalloids, right of staircase are nonmetals.
This is important for determining bond type,
using proper terminology, and making decisions.
Metallic character
Metallic character
nonmetals
metals
25
Chemical Formulas; Molecular and
Ionic Substances
The chemical formula of a substance is a
notation using atomic symbols with subscripts
to convey the relative proportions of atoms of
the different elements in a substance.
– aluminum oxide, Al2O3 2Al:3O ratio
Na+ Cl-
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Chemical Formulas; Molecular
and Ionic Substances
Ionic substances
– The formula of an ionic compound is written by giving
the smallest possible whole-number ratio of different
ions in the substance.
– The formula unit of the substance is the group of
atoms or ions explicitly symbolized by its formula.
Covalent bond (share e-) Ionic bond (transfer e-/
attraction charged particles
Na2SO4 ionic substance; formula unit; ionic and covalent bonds in SO42-
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CO2 molecular substance; molecule; covalent bonds
Ions in Aqueous Solution
Many (not all) ionic compounds (ionic
bond/m-nm) dissociate into independent
ions when dissolved in water
varies
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Rules for naming monatomic ions
– Monatomic cations are named after the element. For
example, Al3+ is called the aluminum ion.
– If there is more than one cation of an element (charge),
a Roman numeral in parentheses denoting the charge
on the ion is used. This often occurs with transition
elements.
Na+ sodium ion Ca2+ calcium ion
Fe2+ iron (II) ion Fe3+ iron (III) ion
Older name: higher ox state (charge) – ic, / lower, -ous
Fe3+ ferric ion Fe2+ ferrous ion Cu2+ cupric ion
Cu+ cuprous ion Hg2+ mercuric ion Hg22+ mercurous ion
also done with Pb4+, Pb2+ ; Sn4+, Sn2+ ; As5+, As3+ ; Sb5+, Sb3+.
phosphate
SnSO4 tin (II) sulfate or stannous sulfate
Na2SO3 sodium sulfite
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Chemical Substances; Formulas and
Names
Naming simple compounds
– Chemical compounds are classified as organic or
inorganic.
47
Chemical Formulas; Molecular and
Ionic Substances
Organic compounds
– An important class of molecular substances that contain
carbon is the organic compounds.
48
Classifying Compounds
Organic vs. Inorganic
• in the 18th century, compounds from living
things were called organic; compounds from
the nonliving environment were called
inorganic
• organic compounds easily decomposed and
could not be made in 18th century lab
• inorganic compounds very difficult to
decompose, but able to be synthesized
49
Modern Classifying Compounds
Organic vs. Inorganic
• today we commonly make organic compounds
in the lab and find them all around us
• organic compounds are mainly made of C and
H, sometimes with O, N, P, S, and trace
amounts of other elements
• the main element that is the focus of organic
chemistry is carbon
50
Carbon Bonding
• carbon atoms bond almost exclusively covalently
– compounds with ionic bonding C are generally
inorganic
• when C bonds, it forms 4 covalent bonds
– 4 single, 1 double + 2 singles, 2 double, or 1 triple + 1 single
51
Examples of Carbon Compounds
52
Classifying Organic Compounds
• there are two main
categories of organic
compounds, hydrocarbons
and functionalized
hydrocarbons
• hydrocarbons contain
only C and H
• most fuels are mixtures of
hydrocarbons
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Classifying Hydrocarbons
• hydrocarbons containing only single bonds
are called alkanes
• hydrocarbons containing one or more C=C
double bonds are called alkenes
• hydrocarbons containing one or more CC
triple bonds are called alkynes
• hydrocarbons containing C6 “benzene” ring
are called aromatic
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55
Naming Straight Chain Hydrocarbons
• consists of a base name to indicate the number of
carbons in the chain, with a suffix to indicate the
class and position of multiple bonds
– suffix –ane for alkane, –ene for alkene, –yne for alkyne
56
Functionalized Hydrocarbons
• functional groups are non-carbon groups that
are on the molecule
• substitute one or more functional groups
replacing H’s on the hydrocarbon chain
• generally, the chemical reactions of the
compound are determined by the kinds of
functional groups on the molecule
57
Functional Groups
58
Chemical Reactions: Equations
Writing chemical equations
– A chemical equation is the symbolic representation of a
chemical reaction in terms of chemical formulas.
– For example, the burning of sodium and chlorine to
produce sodium chloride is written
2Na Cl 2 2NaCl
Reactants (consumed) Products (produced)
2Na(s ) Cl 2 ( g ) 2NaCl(s )
We write above the arrow any conditions for the reaction such as
pressure, catalyst, heat, etc. A reaction gives a recipe for the amount
of reactants needed to produce the amount of products. Species with
no coefficient have an understood coefficient of 1. 60
Chemical Reactions: Equations
Writing chemical equations
– The law of conservation of mass dictates that the
total number of atoms of each element on both sides of
a chemical equation must match. The equation is then
said to be balanced.
CH 4 2 O 2 CO 2 2 H 2O
We must have the same number of atoms on both sides for a reaction to be considered
balanced and obeying the law of conservation of mass. To balance a reaction:
1. First, balance the atoms for elements that occur in only one substance on each side of the
reaction. In this problem, O is involved with two substances on the product side;
therefore, I will wait on balancing O until later. C & H are only in one species on both
sides so I will balance them first. C needs no changes because there are one on each
side, but H needs a 2 in front of H2O to balance the 4H on the reactants side.
2. Now that we have changed the coefficient of one of the O on the product side, it is easier
to balance the O. We determine that we need a 2 coefficient on the O2 to balance the O
on both sides at 4. Now the equation is balanced with 1C, 4O, and 4H on both sides.61
Chemical Reactions: Equations
Caution: For formulas that have subscripts, you
must account for all atoms especially when
dealing with parentheses for polyatomic species.
For example,
[
2 As2S 3 O2 As2O 3 3 SO 2 ]
2 As2S3 9 O2 2 As2O3 6 SO 2