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For an example I'll use a common 18650 li-ion cell. When fully charged these carry
a potential of 4.2-4.25V and when discharged 3V. This is true of any cell that
hasn't shut down whether it's new or old and tired. So what is the difference
between a new cell and an old cell? Internally a battery consists of an
electrolyte/electrode interface where the potential is generated by chemical
reactions. As the reactions progress forward and are reversed during charging, the
interface slowly degrades. This degradation results in not only a loss of capacity
but also an increase in what is known as the batteries internal resistance.
High battery internal resistance is a BAD THING for a number of reasons. First, it
makes the battery output voltage drop when the battery is being used. As soon as
you take the battery out of the circuit to measure its voltage, the voltage rises
and it seems OK again. Secondly, high internal resistance saps output power from
the battery's already diminished capacity. This sapped power winds up as HEAT in
the battery and can cause ugly issues and further degradation.
Measuring the battery's internal resistance is simple. All you need is a 4 ohm 5W
power resistor or similar and a multimeter. Five common 1W 1 Ohm resistors in
series would work. If you aren't measuring an 18650, choose a load resistance that
will load the cell but not overload it. Capacity/3 should be ok.
Ri = (V1-V2)*R/V2
Example: cell measures 4.2V unloaded, 4.0V when connected to a 4 ohm resistor has
an internal resistance of 200 mOhms (0.2 ohms)
A new high quality 18650 battery will have an internal resistance under 100mOhms.
So, feel free to test a few batteries you have around and post what you find!!