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International Journal of Engineering and Creative Science, Vol. 1, No.

1, 2018
www.ijecs.net

Effect of Fly Ash as an Additive on CI Engine


Fuelled with Water Emulsified Diesel

S. M. Chaudhari1, V. W. Khond2
1,2
Assistant Professor Department of Mechanical Engineering, G. H. Raisoni College of Engg. Nagpur-440019

Abstract – Diesel engines exhausting gaseous emission and particulate matter have long been regarded as one of the
major air pollution sources, particularly in metropolitan areas, and have been a source of serious public concern for a
long time. There has been numerous research in the field of reduction of these pollutants since diesel engines came to
major use. Major emissions from a diesel engine are NOx, SOx, CO and particulate matter (PM).amongst these pollutants
CO and Sox and some quantity of particulate matters are reduced by some after treatment devices. Also NOx emissions are
reduced by selective catalytic reduction, exhaust gas recirculation.

In this work, the experiment was carried out on twin cylinder diesel engine fuelled with water emulsified diesel and
fly ash as an additive. The test is carried out at constant speed and varying the load condition and investigate the
performance and emission characteristics of the engine. Brake specific fuel consumption is increased by 3.33% and 5.43%.
and NOX emission is reduced by 11.87% and 15% respectively, when addition of 5% and 10% water in diesel. Also with
the addition of 3% and 6% fly-ash in 5% and 10% water diesel emulsion. Brake specific fuel consumption is increased by
6.27%, 7.91%, 5.79% and 8.21%, also Co emission was increases by 22.33%, 12.5%, 36.36% and 22.22% respectively
when results comparing with diesel. The Brake thermal efficiency was increased by 4.39% when addition of 10% water in
diesel and also with addition of 3% and 6% fly-ash in 10% water diesel emulsion there is 3.97% and 1.11%. Brake thermal
efficiency increases as compare to diesel.

Keywords- Twin cylinder diesel engine, fly ash, NOx, brake thermal efficiency

I- INTRODUCTION soot. There are various ways to treat these pollutants.


Two major ways are –treatment inside the cylinder and
after treatment or treatment outside the cylinder. In this
Internal combustion engines generate undesirable project an emulsion is prepared which replaces the diesel
emissions during the combustion process. The pollutants fuel meant for the engine, and the emission and
that are exhausted from the internal combustion engines performance parameters are studied [1].
affect the atmosphere and cause problems such as global Water acts as a diluents, which lowers the combustion
warming, smog, acid rain, respiratory hazards etc. These temperature and suppresses NOx formation. The water
emissions are mostly due to nonstoichiometric emulsification decrease overall particulate emissions.
combustion, dissociation of nitrogen and impurities in Diesel water emulsification may require additional
the fuel and air .Major emissions include Nitrogen cetane enhancing additives. NOx can roughly be lowered
Oxides (NOx), unburnt Hydrocarbons (HC), oxides of on one- percent reduction for every percent of water
Carbon, oxides of Sulphur and other carbon particles or added to the fuel, depending on engine design and

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service profile [3]. The advantage of an emulsion fuel difference between water and diesel. Water contents
are reduction in the emission of nitrogen oxides and ranging from 5% to 45% have been studied.
particulate matters, which both are health hazardous and C. Alan Canfied [4] has worked on effects of diesel
reduction in fuel consumption due to better burning water emulsion on diesel engine and NOx emissions.
efficiency. An important aspect is that diesel emulsion Results also lead to conclude that NOx reduction from
can be used without engine modification. The fuel injection timing delay and improved injector design,
combustion efficiency is improved when water is as demonstrated in, is also probably due to a reduced
emulsified with diesel. This is a consequence of the flame temperature. A trend to lower exhaust temperature
micro emulsions, which facilitate atomization of the fuel and lower NOx emissions with increased timing delay,
[4]. which corresponds to the trend for water added to the
Some metal-based additives are reported to be effective fuel. In general, it was concluded from the reported data
in lowering diesel emissions. They may reduce diesel that fuel—water mixtures are an effective option to
emissions by two ways [5]. First, the metals either react reducing NOx emissions from diesel engines without
with water to produce hydroxyl radicals, which enhance requiring modifications to the engine, if a lower full load
soot oxidation, or react directly with carbon atoms in the is acceptable. By installing larger fuel injectors, the
soot, thereby lowering the oxidation temperature. When diesel engine can attain the original load level.
these additives are used after combustion in the engine, Omar Badran et al. [5] have worked on Impact of
the metal acts as a nucleus for soot deposition. Usually, Emulsified Water/Diesel Mixture on Engine
the additive is added as a metal-organic compound, and Performance and Environment. Emulsified diesel fuels
it is emitted in the particulate phase as oxide, on soot of 0, 10, 15, 20, 25 and 30 water/Diesel ratios by
particles or forming new nanometre-sized particles by volume, were used in a single cylinder, direct injection
homogeneous nucleation of the additive. Diesel engine, operating between 1000-1600 rpm. The
In this project, the addition of water in diesel and this average increase in the brake thermal efficiency for 30%
emulsified fuel inject in CI Engine and reduce the water emulsion is approximately 5% over the use of
emission characteristics of the engine. And also addition diesel for the engine speed ranges studied. The
of fly-ash in emulsified fuel and improves the particulate matter and NOx emissions decrease as the
performance and reduces the emission characteristics of percentage of water in the emulsion increased to 30%.
the engine. Because fly-ash contain various types of K. Kannan et al. [6] have worked on NOx and HC
metal additives. So fly-ash use as combustion improver emission control using single cylinder engine. This paper
and emission reduction additives to increase the reports on the effects of water emulsified diesel fuel
efficiency and decrease the NOx emission of the CI combustion on the brake thermal efficiency, brake
Engine. specific fuel consumption and NOx and unburnt
hydrocarbon emissions in a diesel engine. Experiments
II-LITERATURE REVIEW were conducted on a single cylinder four stroke cycle
direct injection diesel engine running at a constant speed
The addition of water to diesel fuel has been proven to with a fuel injection pressure of 200 bars. Tests were
significantly reduce NOx and PM emissions. These done using commercial diesel fuel and emulsified diesel
benefits have been observed both with and without fuel with 10% and 20% water by volume.
modifications to the test engine. It was discovered that R. Venkatesh Babu and Dr. S.Sendilvelan, [7]
the effectiveness in lowering the peak combustion investigate the effect of addition of water-fuel
temperature is dependent on the engine timing and emulsions in diesel engines is a notable reduction in
decreases as engine timing is advanced. Greater NOx emissions. The added water acts as a diluents,
reductions in both PM and NOx can also be attained with which lowers the combustion temperature and
the combined use of emulsions and after treatment suppresses NOx formation. The water emulsification
technologies such as PM traps and oxidation catalysts. decrease overall particulate emissions. Diesel water
Anna Lif et al. [3] have worked on reduction of water emulsification may require additional cetane enhancing
and PM in diesel engines. The water content affects the additives. NOx can roughly be lowered on one- percent
combustion under on two accounts. The first is the reduction of for every percent of water added to the
reduced peak temperature in the cylinder, resulting in a fuel, depending on engine design and service profile.
lower levels of NOx formation. The second is the micro This reduction is achieved by lowering the peak
explosion phenomenon, which is due to the volatility combustion temperature in the engine cylinders.

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The various types of metal additives use in a Diesel V.W.Khond and Swapnil M.Kondawar [13] investigated
Engine and investigate the that, Fly-ash contains silicon dioxide, aluminum oxide,
Performance and emission characteristics of the engine iron or calcium oxide and carbon content. Ash also
V. Arul Mozhi Selvan. et al. [8] an experimental contains smaller amount of magnesium oxide, sodium
investigation is carried out to establish the performance oxide and potassium oxide. Fly ash is typically finer than
and emission characteristics of a compression ignition Portland cement and lime. Fly ash consists of silt-sized
engine while using cerium oxide nanoparticles as particles which are generally spherical, typically ranging
additive in neat diesel and diesel-biodiesel-ethanol in size between 10 and 100 micron (Figure 1)
blends. The cerium oxide acts as an oxygen donating
catalyst and provides oxygen for the oxidation of CO or
absorbs oxygen for the reduction of NOx. The
activation energy of cerium oxide acts to burn off
carbon deposits within the engine cylinder at the wall
temperature and prevents the deposition of non-polar
compounds on the cylinder wall results reduction in HC
emissions. The tests revealed that cerium oxide
nanoparticles can be used as additive in diesel and
diesel-biodiesel-ethanol blend to improve complete
combustion of the fuel and reduce the exhaust
emissions significantly.
G.R.Kannan et. al [9] have found that the biodiesel Fig 1: Fly ash particles at 2,000x magnification, SEM
fuelled engines emit less carbon monoxide, total
hydrocarbon, and particulate matter (PM) as compared Table 1 : Metal Content in Fly-Ash
to diesel but there is a slight increase in nitric oxide
(NO) emission. Reduction of NO can be attained while Contents Percentage
using biodiesel can be achieved by improving the diesel Si02 70.70%
engine design and combustion chamber [10]. The
reduction rates achieved have not been adequate to meet Al203 20.70%
the emission standards. Further reduction in emission Fe203 3.90%
and improvement in engine efficiency can be achieved
by use of fuel additives. Metal based additives have been CaO 1.13%
employed as combustion catalyst to promote the K20 1.09%
combustion and to reduce fuel consumption and
Ti02 0.92%
emission for hydrocarbon fuels.
Kelso [11], investigated the effect of platinum based MgO 0.77%
additive on diesel engine. These metal additive acts as a
Na20 0.26%
fuel borne catalyst and increase the combustion rate. and
the result revealed that the use of platinum based P205 0.15%
additive improved BSFC and reduced CO and UHC
MnO 0.05%
emission. It was found that Metal based additives have
been employed as combustion catalyst to promote the
combustion and to reduce fuel consumption and
emission for hydrocarbon fuels. They investigate the effect of water emulsified diesel
Yang HH, Miyamoto N. et al. [12] has experimentally fuel inject in a CI Engine and improve the performance
studied the reduction of emission while using metal characteristics and reduce the emission characteristics
based additive may be either due to the fact that the also they have add various types of metal based additive
metal react with water vapour to produce hydroxyl in a Diesel and investigate the performance and emission
radicals or serve as an oxidation catalyst thereby characteristics of the CI Engine.
reducing the oxidation temperature that results in So according to their investigation we add Fly-
increased particle burnout. Due to this phenomenon the Ash in a water diesel emulsified fuel because Fly-Ash
rate of combustion increases. contains various type of metal additives and emulsified
fuel is fuelled with Twin cylinder Diesel Engine test rig
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and investigate the performance and emission


characteristics of the CI Engine.

III-EXPERIMENTATION AND MEASUREMENTS

In experimentation and measurements first prepare the


fuel sample and check the properties of fuel sample. This
emulsified fuel is fuelled with Twin cylinder Diesel
Engine test rig and investigate the performance and
emission characteristics of the CI Engine and compare
this result to the Diesel Engine fuelled with pure Diesel. Fig 3 :Surfactant Span 80
Magnetic Stirrer
Preparation of emulsion
An emulsion can be defined as a mixture of two liquids This is used to thoroughly mix the mixture and form the
in which one is present in droplets of macroscopic or emulsion. It consists of a motor which is used to rotate
ultramicroscopic size, distributed throughout the other. the blades which is dipped in the mixture. There is speed
Emulsions are made from the constituents spontaneously control knob to optimize the speed of the motor.
or by a mechanical way. In spontaneous emulsions, the
mixing is easy and spontaneous. (Britannica) But if they
don’t mix properly then a third chemical called a
surfactant is used to bind the molecules of the
constituent liquids. Then a magnetic stirrer is used to
mix the liquids thoroughly. After mixing them for some
time, emulsion is formed.
To help save time in emulsifier selection, ICI introduced
in the late 1940's a systematic scheme of centering down
on the relatively few emulsifiers suitable for any given
application. This is called the HLB System - the letters
HLB standing for "Hydrophile-Lipophile Balance.
Briefly, the HLB System enables you to assign a
number to the ingredient or combination of ingredients
Fig 3: Magnetic Stirrer
you want to emulsify, and then to choose an emulsifier
or blend of emulsifiers having this same number. At So according to HLB value, Sorbitan monooleate,
least, this is the principle of the system. In practice, NF, (Span 80) and Polysorbate 80, NF, (Tween 80) these
unfortunately, the task is never simple. But the HLB two surfactants are selected and prepare the fuel sample.
System does provide a useful guide -a series of beacons
to steer you through channels where virtually no other Table: Properties of Fuel sample
markers exist. Fuel Sample Calorific Density Viscosity
Value (kg/m3) (cSt)
(kJ/kg)

Diesel 49500 831 2.41

Diesel + 5%Water 47133 838 6.58

Diesel + 5%Water + 47314 841 7.2


3%flyashl

Diesel + 5%Water + 47468 844 7.63


6%flyashl

Diesel + 10%Water 44791 845 12.88

Diesel + 10%Water 44815 847 12.92


+ 3%flyashl
Fig 2 :Surfactant Tween 80
Diesel + 10%Water 44954 850 12.98
+ 6%flyashl

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Experimental Setup

Fig : Schematic diagram of Experimental Setup

Table: Engine specification

Engine Kirloskar Twin Cylinder Diesel


Type Vertical four stroke, C.I. Engine
Bore 87.5 mm
Stroke 110 mm
Cubic capacity 1.323 litre Figure 4-2: Variation of Brake Specific Fuel
Normal compression Consumption and Brake Mean Effective Pressure
17.5:1
ratio
Fuel tank capacity 11 lts. It is seen from the Figure that the Brake
Governor Centrifugal Mechanical Type Specific Fuel Consumption of the Engine increases when
Speed 1500 rpm emulsion is used, it depends on the concentration of
Water in the emulsion and also the Fly-ash content in the
Cooling Water cooling
Water-Diesel emulsion.
Mode of starting By hand cranking
The Brake specific fuel consumption is
B.M.E.P. at full load
6.33 Kg/Cm2 increased by 3.33% when addition of 5% water in diesel
and 1500 rpm
and also with the variation of addition of 3% and 6% fly-
ash in 5% water diesel emulsion there is 6.27% and
IV-RESULTS AND DISCUSSIONS
7.91% Brake specific fuel consumption increases as
compare to diesel.
Performance characteristics
The Brake specific fuel consumption is
In the performance characteristics, investigate the
increased by 5.43% when addition of 10% water in
variation of Brake Specific Fuel Consumption and Brake
diesel and also with the variation of addition of 3% and
Mean Effective Pressure and also the variation of Brake
6% fly-ash in 10% water diesel emulsion there is 5.79%
Thermal Efficiency and Brake Mean Effective Pressure.
and 8.21% Brake specific fuel consumption increases as
Comparison graphs were plotted to see what are the
compare to diesel.
advantages and disadvantages of using the emulsion over
diesel.
4. 2.2 Brake Thermal Efficiency
Brake specific fuel consumption

Brake specific fuel consumption of an engine is


defined as the amount of fuel used in kg per brake power
per second. This is an important performance parameter
as it determines the mileage of the vehicle. In practical
purposes this very important aspect a consumer looks
for, as it determines whether the product is value for
money or not.

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Figure 4-4: Variation Brake Thermal Efficiency and


Brake Mean Effective Pressure

Brake thermal efficiency of a vehicle is a very important


performance parameter. It increases with increase in
load. It can be seen that it increases linearly for diesel.
Whereas for the emulsions, it increases initially till a
load and then decreases. But it can be observed that
Brake thermal efficiency for emulsions are always
higher than that of diesel except at very high loads. So
emulsions prove out to be better fuels when Brake Fig 4-6: Variation of NOX (Oxides of Nitrogen)
thermal efficiency is concerned. emissionand Brake Mean Effective Pressure
The Brake thermal efficiency is increased by
1.55% when addition of 5% water in diesel and also with
the variation of addition of 3% and 6% fly-ash in 5% The NOX emission is decreased by 11.87% when
water diesel emulsion there is 1.88% and 3.91% Brake addition of 5% water in diesel and also with the variation
thermal efficiency decreases as compare to diesel. of addition of 3% and 6% fly-ash in 5% water diesel
The Brake thermal efficiency is increased by emulsion there is 10% and 7.5% NOX emission
4.39% when addition of 10% water in diesel and also decreases as compare to diesel.
with the variation of addition of 3% and 6% fly-ash in
10% water diesel emulsion there is 3.97% and 1.11% The NOX emission is decreased by 15% when
addition of 10% water in diesel and also with the
Brake thermal efficiency increases as compare to diesel.
variation of addition of 3% and 6% fly-ash in 10% water
diesel emulsion there is 13.75% and 11.87% NO X
4.3 Emission Characteristics
In the emission characteristics, investigate the emission decreases as compare to diesel.
variation of NOX (Oxides of Nitrogen) emission and
4.3.2 CO (Carbon Monoxide) emission
Brake Mean Effective Pressure, CO (Carbon Monoxide)
emission and Brake Mean Effective Pressure,
Hydrocarbon emission and Brake Mean Effective
Pressure,CO2 (Carbon Dioxide) emission and Brake
Mean Effective Pressure and also the variation Smoke
Opacity emission and Brake Mean Effective Pressure.
Comparison graphs were plotted to see what are the
advantages and disadvantages of using the emulsion over
diesel.

4.3.1 NOX (Oxides of Nitrogen) emission

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Figure 4-10: Variation of Hydrocarbon emission and


Brake Mean Effective Pressure
Figure 4-8: Variation of CO (Carbon Monoxide)
emission and Brake Mean Effective Pressure Exhaust gases leaving the combustion chamber
of a CI engine contains up to 100 ppm of hydrocarbon.
These consist of small non equilibrium which is formed
Carbon monoxide is emitted as a result of incomplete
when large fuel molecules break up during the
combustion of carbon and oxygen under high
combustion reaction. It is often convenient to treat these
temperature inside the cylinder. With increase in load
molecules as if they contained carbon atom. It is seen
CO emission increases for all the fuels used. It has been
that HC emissions increases up to a certain load then
observed that emission of CO increases with increase in
decreases for diesel. For the emulsions it shows
volume of water in the emulsion. This happens because
increasing trend as the load increases. Under lower load
with increase in water the temperature inside the
conditions emission in case of diesel is more than that of
cylinder decreases slowing down the combustion of
emulsions but at higher load conditions the emulsions
carbon, as a result of which incomplete combustion
give more HC (Hydrocarbon) emissions than diesel.
occurs.
The CO emission is increased by 30% when The Hydrocarbon emission is decreased by
addition of 5% water in diesel and also with the variation 28.57% when addition of 5% water in diesel and also
of addition of 3% and 6% fly-ash in 5% water diesel with the variation of addition of 3% and 6% fly-ash in
emulsion there is 22.22% and 12.5% CO emission 5% water diesel emulsion there is 31.42% and 34.28%
increases as compare to diesel. Hydrocarbon emission decreases as compare to diesel.
The CO emission is increased by 46.15% when addition
of 10% water in diesel and also with the variation of The Hydrocarbon emission is decreased by
addition of 3% and 6% fly-ash in 10% water diesel 40% when addition of 10% water in diesel and also with
emulsion there is 36.36% and 22.22% CO emission the variation of addition of 3% and 6% fly-ash in 10%
increases as compare to diesel. water diesel emulsion there is 42.85% and 44.28%
4.3.3 Hydrocarbon emission Hydrocarbon emission decreases as compare to diesel.

4.3.4 CO2 (Carbon dioxide) emission

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Figure 4-12: Variation of CO2 (Carbon dioxide)


emissionand Brake Mean Effective Pressure Figure 4s-14: Variation of Smoke Opacity emission and
Brake Mean Effective Pressure

Carbon dioxide comes as exhaust as a result of complete Smoke opacity is increases with increase in Brake Mean
combustion of carbon particles in the fuel and the Effective Pressure. The smoke decreases with diesel and
combustion of CO inside the cylinder. For diesel it water emulsion when comparing with diesel. Also the
increases linearly with increase in load. For the addition of Fly-ash in diesel decreases the smoke further.
emulsions too it increases linearly with some variations The use of emulsified fuel improve better combustion is
at some loads. CO2 emission increases when we add the cause for the smoke reduction.
water to diesel. With increase in the percentage of water
in diesel CO2 emission increases. The Smoke Opacity emission is decreased by 6.25%
The CO2 emission is decreased by 0.46% when when addition of 5% water in diesel and also with the
addition of 5% water in diesel and also with the variation variation of addition of 3% and 6% fly-ash in 5% water
of addition of 3% and 6% fly-ash in 5% water diesel diesel emulsion there is 6.25% and 12.5% Smoke
emulsion there is 0.69% and 1.15% CO2 emission Opacity emission decreases as compare to diesel.
decreases as compare to diesel.
The CO2 emission is decreased by 0.69% when The Smoke Opacity emission is decreased by 12.25%
addition of 10% water in diesel and also with the when addition of 10% water in diesel and also with the
variation of addition of 3% and 6% fly-ash in 10% water variation of addition of 3% and 6% fly-ash in 10% water
diesel emulsion there is 0.92% and 1.36% CO2 emission diesel emulsion there is 18.75% and 18.75% Smoke
decreases as compare to diesel. Opacity emission decreases as compare to diesel.

V-CONCLUSION

1. The brake specific fuel consumption of the


4.3.5 Smoke Opacity emission
engine increases for emulsion than diesel at all
brake mean effective pressure. it depends on the
concentration of water in the emulsion. The
brake specific fuel consumption is also
increases with increase the percentage of fly-
ash.
2. It can be observed that brake thermal efficiency
for water diesel emulsions are always higher
than that of diesel except at very high loads. So
emulsions prove out to be better fuels when
thermal efficiency is concerned. And addition
of fly-ash also increases the thermal efficiency.
3. With increase in brake mean effective pressure
NOx emission increases for diesel as well as
other fuels. It has been observed that using
diesel water emulsion as fuel greatly reduces
the NOx emissions as compared to diesel.

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4. The addition of metal additive decreases the HC charging from a heavy-duty diesel engine”, Environ int
emission when comparing with diesel. The use 1998;24(4):389-403.
of metal additive promotes complete [13] V.W.Khond and Swapnil M.Kondawar, “Fly Ash
combustion is cause for the hydrocarbon Utilization Technologies and use as Thermal
emission reduction. Composite Insulation”, Vol. 2, Issue III/April:12,
5. Carbon monoxide and carbon dioxide emissions Indian Streams Research Journal.
increase with increase in water percentage in
the fuel. This is due to the fact that most of the
hydrocarbons are burnt at lower loads.
6. Smoke opacity is increases with increase in
brake mean effective pressure. The smoke
decreases with diesel and water emulsion when
comparing with diesel. Also the addition of fly-
ash in diesel decreases the smoke further.

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