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INTRODUCTION:
aA+bB→cC
the reaction rate is often found to have the form:
rA = -d[A]/dt = k[A]n[B]m
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In this experiment we will be determining the rate of reaction
constant of the Saponification reaction
Saponification:
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Mechanism:
3) Deprotonation
Batch Reactor:
The batch reactor is the generic term for a type of vessel widely used
in the process industries. Its name is something of a misnomer since
vessels of this type are used for a variety of process operations such
as solids dissolution, product mixing, chemical reactions, batch
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distillation, crystallization, liquid/liquid extraction and
polymerization. In some cases, they are not referred to as reactors
but have a name which reflects the role they perform (such as
crystallizer, or bioreactor).
Advantages:
1. High conversion per unit volume for one pass
2. Flexibility of operation-same reactor can produce one product one
time and a different product the next
3.Easy to clean
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Disadvantages:
1. High operating cost.
2. Variable product quality in comparison to a continuous operation.
THEORY:
Chemical kinetics deal with rates and mechanisms of chemical
reaction without the disguising influence of energy and mass
transfer.
It quantitatively describes the course of reaction with time as a
function of reaction conditions (concentration, pressure,
temperature)
Unfortunately, in most cases the status of current research
does not enable us to predict the elementary steps (reaction
mechanism) of particular reaction a priori. Consequently,
kinetic analyses almost always require experiment.
Reaction rates must frequently be represented by means of
simplified models which do not exactly correspond to the
chemical processes taking place, based on the fit between
model and experiment the kinetic should decide whether the
simplifications involved are truly permissible.
𝑑𝐶𝐴
-𝑟𝐴 = =K𝐶𝐴 2
𝑑𝑡
𝑑𝐶𝐴
=K𝐶𝐴 2
𝑑𝑡
Rearranging we get:
𝑑𝐶𝑖
=Kdt-
𝐶𝐴 2
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Taking integral:
𝐶
𝑡
𝑑𝐶𝑖
∫ = 𝑘 ∫ 𝑑𝑡
𝐶𝐴 2 0
𝐶𝐴0
−2
∫ 𝐶𝐴 𝑑𝐶𝐴 = Kt
Finally, we get:
1 1
= Kt +
𝐶𝐴0 𝐶𝐴
EQUIPMENT:
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-Tools:
-Chemical Substances:
3. Distilled water.
Procedure:
Experiment A
Getting the (Conductivity vs Concentration) Calibration
1. Prepare different concentrations of sodium hydroxide (0.005 ,
0.02 ,0.03 , 0.04 , 0.05)M
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2. Measure thermal conductivity by using conductivity meter for
each concentration.
3. Plot CA(x) against K(y) and get an equation that represents the
relationship between the two parameters.
Experiment B
1. Prepare two solutions of NAOH and ethyl acetate by the same
quantity and concentration (0.05 M).
2. Put the solutions in the reactor at the same time and turn on the
stirrer.
3. Start the stop watch.
4. Record the conductivity every 5 minutes for 40 minutes.
5. Plot 1/CA(y) against t(x).
Experiment A
Results:
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Graph:
Concentration vs Conductivity
4.5
4
3.5
3
Conductivity
2.5
2
1.5
1
0.5
0
0 5 10 y15= -0.0892x + 3.542 20 25
Concentration R² = 0.8898
Experiment B
Preparing a 0.05M solution for each of NaoH and ethyl acetate:
NaOH:
W = Mwt*V*M
MWT = 40 g/gmol
V = 0.5 L
M = 0.05
W = 40 * 0.5 * 0.05 = 0.5 g
Ethyl acetate:
Mwt = 88 g/gmol
V = 0.5
M = 0.05
W = 88 * 0.5 * 0.05 = 1.1 g
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Results:
Graph:
1/CA vs Time
140
120
100
80 y = 1.6365x + 64.272
1/CA
R² = 0.9285
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40 Slope = K
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0
0 5 10 15 20 25 30 35 40 45
Time
-Slope = 𝐾 = 1.636515
*Using the equation from the first graph we can calculate the corresponding value of CA
-K=205.97CA – 0.017 1.636515=205.97CA – 0.017 CA= 0.008028
-Intercept = 1/CA0 = 64.27161
CA0−CAF 0.0187−0.00819
-Conversion XA = * 100 = * 100 = 56.2%
CA0 0.0187
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CONCLUSION:
From the results and graphs obtained from experiment A we
conclude that the relation between (K) and (CA) is directly
proportional, higher concentrations give us higher conductivity rates.
RECOMMENDATIONS:
There were few recommendations in order to overcome the possible
errors. Firstly, the chemical preparation of the solution of NaOH and
Ethyl Acetate should be done carefully so that no disrupted results can
occur. Secondly, the Batch must be cleaned before and after the
usage to prevent contaminations.
Due to time limitations and scarce resources, Experiment A results were
taken directly from the lab manual , also Experiment B were not given
enough time to reach a steady-state.
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REFERENCES
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