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Designation: D 1066 – 06
1. Scope 3. Terminology
1.1 This practice covers the sampling of saturated and 3.1 Definitions:
superheated steam. It is applicable to steam produced in fossil 3.1.1 For definitions of terms used in this practice, refer to
fired and nuclear boilers or by any other process means that is definitions given in Practice D 1129.
at a pressure sufficiently above atmospheric to establish the 3.2 Definitions of Terms Specific to This Standard:
flow of a representative sample. It is also applicable to steam at 3.2.1 isokinetic sampling (representative sampling)—a con-
lower and subatmospheric pressures for which means must be dition wherein the sample entering the port (tip) of the
provided to establish representative flow. sampling nozzle has the same as the velocity vector (velocity
1.2 For information on specialized sampling equipment, and direction) as the stream being sampled. Isokinetic sam-
tests or methods of analysis, reference should be made to the pling ensures a representative sample of dissolved chemicals,
Annual Book of ASTM Standards, Vols 11.01 and 11.02, solids, particles, chemicals absorbed on solid particles, and in
relating to water. the case of saturated and wet steam, water droplets are
1.3 The values stated in SI units are to be regarded as the obtained.
standard. The values given in parentheses are for information 3.2.2 sample cooler—a small heat exchanger designed to
only. provide cooling/condensing of small process sampling streams
1.4 This standard does not purport to address all of the of water or steam.
safety concerns, if any, associated with its use. It is the 3.2.3 sampling—the withdrawal of a representative portion
responsibility of the user of this standard to establish appro- of the steam flowing in the boiler drum lead or pipeline by
priate safety and health practices and determine the applica- means of a sampling nozzle and the delivery of this portion of
bility of regulatory limitations prior to use. steam in a representative manner for analysis.
3.2.4 saturated steam—a vapor whose temperature corre-
2. Referenced Documents sponds to the boiling water temperature at the particular
2.1 ASTM Standards: 2 existing pressure.
A 269 Specification for Seamless and Welded Austenitic 3.2.5 superheated steam—a vapor whose temperature is
Stainless Steel Tubing for General Service above the boiling water temperature at the particular existing
A 335/A 335M Specification for Seamless Ferritic Alloy- pressure.
Steel Pipe for High-Temperature Service
D 1129 Terminology Relating to Water 4. Summary of Practice
D 1192 Guide for Equipment for Sampling Water and 4.1 This practice describes the apparatus, design concepts
Steam in Closed Conduits3 and procedures to be used in extracting and transporting
D 3370 Practices for Sampling Water from Closed Conduits samples of saturated and superheated steam. Extraction nozzle
D 5540 Practice for Flow Control and Temperature Control selection and application, line sizing, condensing requirements
for On-Line Water Sampling and Analysis and optimization of flow rates are all described. Condensed
steam samples should be handled in accordance with Practices
D 3370 and D 5540, and Guide D 1192.
1
This practice is under the jurisdiction of ASTM Committee D19 on Water, and
is the direct responsibility of Subcommittee D19.03 on Sampling Water and 5. Significance and Use
Water-Formed Deposits, Analysis of Water for Power Generation and Process Use, 5.1 It is essential to sample steam representatively in order
On-Line Water Analysis, and Surveillance of Water.
Current edition approved Dec. 15, 2006. Published January 2007. Originally to determine the amount of all impurities (dissolved chemicals,
approved in 1949. Last previous edition approved in 2001 as D 1066 – 97 (2001). solid particles, chemicals absorbed on solid particles, water
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
3
Withdrawn.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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droplets) in it (1).4 An accurate measure of the purity of steam reaching the sample station. Partially or fully condensed
provides information, which may be used to determine whether samples usually have a velocity too low to prevent excessive
the purity of the steam is within necessary limits to prevent deposition and the sample becomes nonrepresentative of the
damage or deterioration (corrosion, solid particle erosion, source. Detailed design of the sample line to control vapor and
flow-accelerated corrosion, and deposit buildup) of down- liquid velocity can minimize this interference but cooling of
stream equipment, such as turbines. Impurities in the steam saturated steam samples at the source is recommended to
may be derived from boiler water carryover, inefficient steam assure a representative sample. See Practices D 3370 and
separators, natural salt solubility in the steam and other factors. D 5540 for further information on factors that affect liquid
The most commonly specified and analyzed parameters are sample transport.
sodium, silica, iron, copper, and cation conductivity. 6.2 Superheated Steam—Most contaminants can be dis-
solved in superheated steam. However, as steam pressure and
6. Interferences temperature are reduced the solubility of many contaminants is
6.1 Saturated Steam— Sampling of steam presents difficult decreased and the contaminants precipitate and deposit on the
extraction and transport problems that affect the representative- inner surfaces of the sample line (4). This condition has been
ness of the sample. found to be prevalent only in regions of dry wall tube where the
6.1.1 Isokinetic sampling requires that the velocity vector temperature of the tube wall exceeds the saturation temperature
(velocity and direction) of the fluid entering the sample nozzle of the steam.
port (tip) be the same as the stream being sampled at the 6.2.1 Interference also occurs when the transport tube tem-
location of the sample nozzle. When the sample is not extracted perature is at or below the saturation temperature. The steam
isokinetically the contaminants in the steam are not properly loses superheat and dissolved contaminants deposit on the tube
represented in the sample. The effects of non-isokinetic sam- wall. The sample is no longer representative. Superheated
pling are illustrated in Fig. 1 and can make the sample steam samples shall be cooled or desuperheated in the sample
unrepresentative. The sample should be removed at a position nozzle or immediately after extraction to ensure a representa-
away from the pipe wall, located at a point of average velocity tive sample. Cooling the sample within the sample nozzle may
which can be calculated for both laminar and turbulent flows. cause thermal fatigue. All necessary precautions should be
6.1.2 Traditionally, saturated steam samples with initial taken. See 7.1.3.4 and 7.2.4.
steam velocities above 11 m/s (36 ft/s) were considered to
7. Materials and Apparatus
provide adequate turbulent flow to ensure transport of most
particulates and ionic components. More recent studies (2,3) 7.1 Extracting the Sample:
found that because many sample lines are long and uninsu- 7.1.1 Saturated Steam—Since saturated steam is normally
lated, steam samples are frequently fully condensed prior to sampled as a two-phase fluid, made up of steam and small
droplets of water, isokinetic sampling shall be employed. Since
steam velocities vary with boiler load it normally is not
4
The boldface numbers given in parentheses refer to a list of references at the practical to sample isokinetically throughout the load range.
end of this standard. Normally, the load of interest is full load or a guaranteed
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REFERENCES
(1) Jonas, O., Mathur, R. K., Rice, J.K., Coulter, E.E., and Freeman, R., Proceedings of the American Power Conference, Vol. XXVI, 1964.
“Development of a Steam Sampling System,” Electric Power Research (6) Cobb, R.V., and Coulter, E.E., “The Prevention of Errors in Steam
Institute, December 1991, EPRI TR-100196. Purity Measurement caused by Deposition of Impurities in Sampling
(2) Coulter, E., “Sampling Steam and Water in Thermal Power Plants,” Lines,” Proceedings of the American Society for Testing and Materi-
Electric Utility Workshop, University of Illinois, March 1988. als, Vol 61, 1961, pp 1386–1395.
(3) Rommelfaenger, E., “Design Criteria for Steam Sample Lines,”
(7) Jonas, O. and Mancini, J., “Sampling Savvy,” Power Engineering,
presented at EPRI Fourth International Conference on Cycle Chem-
May 2005.
istry in Fossil Plants, September 1994.
(4) Stringer, J., “Steamside Oxidation and Exfoliation,” McMaster Uni- (8) “Steam and Water Sampling, Conditioning, and Analysis in the Power
versity, May 4–5, 1983. Cycle,” ASME Performance Test Code (PTC) 19.11, 1997.
(5) Goldstein, P. and Simmons, F.B., “An Experimental Investigation of (9) Steel Products Manual: Stainless and Heat Resisting Steels, American
Factors Which Influence the Accuracy of Steam Sampling-Series II,” Iron and Steel Institute, December 1974.
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