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FUSED ALUMINA

Prices for fused alumina, particularly BFA, have dramatically increased over
recent months, due to supply problems and shipping costs, as well as the
costly nature of fused alumina production itself . Courtesy Washington Mills.

Uphill struggle
A melting pot of supply related factors heralds an uncertain future for the
global fused alumina market

by Rachel Backus, Assistant Editor


lthough the main end-user however, in all of fused alumina’s wants to be presented on the Chinese

A market for fused alumina,


abrasives, is steady, supply of
fused alumina worldwide is
market applications, there are
alternative raw minerals, so the future
of fused alumina appears to depend on
market and end user markets. In China,
Treibacher Schleifmittel only produces
BFA, a commodity product. This is
short. This includes supply from major whether its benefits are not outweighed produced partly for the domestic market
producer, China, where a shortage of by its availability and cost. and partly for export. All Chinese tax
brown fused alumina (BFA) in particular increases have been passed on to the
is having a knock-on effect on fused Supply overview customers.”
alumina prices. China’s capacity, which accounts for However, while China’s capacity is
However, the crisis doesn’t end there. half of the world’s supply, has been increasing, there still appears to be
Rising electricity costs, environmental increasing in recent years, while fused problems with supply from China.
regulations and a shortage of container alumina production in the rest of the Furthermore, the quality of Chinese
ships from Asia is compounding the world has decreased. Many western products seems to be less reliable than
problem. Could this spell a murky producers are now venturing in China that of the western producers.
future for fused alumina, or a potential (see accompanying table for main producers). A non-Chinese BFA producer added:
opportunity for western producers? Hans-Georg Leitner, sales manager for “Material from China is becoming
Stable market applications and Germany minerals for abrasives division increasingly expensive and also the
possible new applications suggest a at Treibacher Schleifmittel told IMIM: “In quality of what is available is often
continued demand for fused alumina, early 2007, Treibacher Schleifmittel unreliable. Now customers want to
painting a somewhat brighter picture; took over another plant in China, as it reduce risks by increasing purchases

32 December 2007
FUSED ALUMINA

products. These grains are also used for


from local European producers even if Fused fundamentals
shot blasting purpose and as polishing
that means paying more”. Fused alumina – formed in electric arc
media; refractory grade WFA is used as
Industry consultant, William furnaces – comes in various forms, the
raw material for high alumina refractories.
McCracken, formerly with Harbison- most common of which are white (WFA)
Walker Refractories Co. and F&S Alloys and brown (BFA). Fused alumina is a
Other fused aluminas
and Minerals commented: “With the granular material with a high density,
Pink and red fused aluminas are
low porosity, low permeability and high
steadily-increasing pressure being put produced by the addition of chromium
refractoriness. In general, fused alumina
on all mineral raw materials in China, it oxide to WFA, which increases the
has a melting point of approximately
is proper to anticipate that there will be 2,500°C and a Mohs hardness of 9. toughness of the finished product.
supply problems with such a bauxite- Additionally, pink and black forms Pink fused alumina contains less than
related important key material as BFA”. are produced by a small number of 2% chromium oxide and has a Knoop
Leitner continued: “There is a general companies. hardness of 2,150 compared to 1,950 for
direction towards higher quality products WFA. Small amounts of titanium oxide
and applications; therefore Treibacher BFA are also added to increase toughness.
Schleifmittel opened a new R+D BFA is both the most common form of Pink fused alumina (PFA) has medium
fused alumina, making up around two- sized sharp or blocky grains, which make
centre at the end of 2004. Treibacher
thirds of all output, and probably one it suitable for precision broad surface and
Schleifmittel’s main capacities are still in
of the most widely used abrasives. To tool room grinding of hard alloy steels.
Europe. Treibacher Schleifmittel Europe
make BFA, the electric arc furnace is Red fused alumina has a higher
produces higher quality products than chromium oxide content of around 3%
charged with bauxite, as well as additives
its Chinese counterpart for the world with small quantities of silicon oxide,
to increase the amount of alumina. It is
market.” ferrous oxide, sodium oxide, calcium
used in a wide variety of applications but
Anne Williams, manager of marketing oxide and magnesium oxide. This fused
mainly in bonded abrasives, particularly
services at Washington Mills, told IM
IM: grinding wheels for high tensile alumina has blocky, sharp edged, friable
“In response to this turbulent and materials, and coated abrasives such grains and is tougher than pink grades
unpredictable environment, customers as paper, discs and belts for wood and
find value in the quality and certainty metalworking. Production
of supply from a North American “safe Grains of abrasive BFA may be z during fusion, bauxite or alumina is
haven” producer like Washington Mills. calcined before use to increase hardness, transformed at temperatures of above
These trends of a rapidly developing or to set ceramic coatings applied to 2,000°C into a liquid state by electric
China are likely to continue and intensify improve the roughened surface and arc furnaces
in the future. This suggests that today’s increase the adhesion of the bonding z cooling of the fused alumina ingots
media to the grain. China produces over takes more than one week
lean manufacturers will want to rely
more on vertically integrated domestic
50% of the world’s capacity of BFA. z following fusion and cooling, the
ingots are ground
suppliers that can provide stability to
WFA z the classification in sieving towers,
their critical manufacturing processes.” arranged in cascade order
WFA is the purer (higher grade) form,
China’s supply problems are, according which consequently is used most readily z sedimentation tanks for classification
to Washington Mills: “The most in refractories. WFA is made from z additional refining steps to further
significant recent development in the Bayer process alumina and is a friable improve the properties of the grain
global fused alumina market”. This product. Like BFA, WFA is used in the z final sieving inspection before
problem has increased the cost and manufacturing of grinding wheels (both packaging
reduced the availability of BFA and vitrified and resin bonded) and coated z weighing and packaging

Fused alumina production capacity, 1995, 2000 and 2003 (‘000 tpa) RAW

FUSION IN ELECTRIC
ARC FURNACE
1995 2000 2003
COOLING; REMOVAL
Australia 100 50 50 FROM MOULD
Austria 60 60 60
CRUSHING
Brazil 100 50 50
China 400 450 600 GRINDING

France 45 40 40
SIEVING
Germany 150 80 80
India 20 40 40 HEAT TREATMENT
(BFA; SEMI-FRIABLE)
Japan 55 50 25
SIZING
Ukraine 90 90 80
USA & Canada 220 220 88
PACKAGING
Others 150 80 80
WAREHOUSE,
Total 1,390 1,190 1,110 DESPATCH

December 2007 33
FUSED ALUMINA

Major fused alumina producers (>50,000 tpa) good quality bauxite feedstock for fused
alumina production.
Company Plant location Products Capacity Chinese fused alumina supply
WFA, BFA and brown semi-friable problems are mainly owing to:
Rio Tinto Alcan Gardanne, France
fused alumina
Boksitogorsky Glinozem z increased Chinese domestic demand
(Rusal)
Boksitogorsky, Russia WFA 110,000 tpa z tighter Chinese environmental
controls that restrict the supply
Newell, USA BFA
C-E Minerals of alumina as plants are closed or
Puerto Ordaz, Venezuela WFA operate less frequently
(Imerys)
Xiuwen and Zhanjiang, China BFA z increased Chinese power costs and
availability
China Qisha Group Co. Qingzhen, China WFA, BFA 100,000 tpa
z efforts to divert scarce bauxite and
Elfusa Geral de power resources in China to other
Sao João da Boa Vista, Brazil BFA, WFA, PFA 120,000 tpa
Eletrofusao Ltda more strategic industries
Henan Mianchi Great
Mianchi, China WFA, BFA 50,000 tpa z increased cost of domestic Chinese
Wall Corundum transportation
Motim Electrocorundum
Mosanmagyaróvár, Hungary
WFA for refractories, abrasives and
50,000 tpa
z increased sea freight cost and scarcity
Ltd ceramics of bulk ocean vessels
Nanchuan Jingshan
Nanchuan, China BFA 50,000 tpa
Fused Alumina Traders have reported that moves
Japan Abrasives Co., Sakai to control production have intensified
WFA
City, Japan lately. Chalco, China’s leading producer
S-G Abrasivos Ltda BFA, WFA 30,000 tpa of aluminium, is pursuing an aggressive
Saint-Gobain strategy of purchasing raw bauxite from
S-G Abrasives, Huntsville, USA BFA, WFA
mining areas and individual mines
Chippawa, Canada WFA, WFA, Al-Zr nationwide. The Shanxi government
S-G Abrasives, Kolo, Poland BFA 10,000 tpa permanently closed all shaft and round
kilns in June 2007, and some of these
Taiyuan Twin Towers were demolished shortly after, thus
Taiyuan, China BFA 60,000 tpa
Aluminium Oxide
reducing production capacity of calcined
Villach, Austria (headquarters) bauxite. Moreover, many rotary kilns
Bonded abrasives (BFA, WFA, PFA, are producing at low output levels.
Domodossola, Italy
semi-friable fused alumina and Another industry source added:
Ruse, Slovenia special fused alumina) “The Chinese government wants to
Laufenburg, Germany Coated abrasives (BFA, WFA, PFA, control all minerals and completely stop
semi-friable fused alumina and exportation eventually. They have set
Sokolov, Czech Republic special fused alumina) specific bauxite export reduction targets
Refractories (BFA)
Treibacher Schleifmittel Niagara Falls, USA already and that theoretically ought to
Ceramics (WFA) 300,000 tonnes
AG (Imerys) Andersonville, USA help BFA producers but the reverse
Dust collector fines (BFA, WFA,
is true as the bauxite will all go to the
Guiyang, China PFA, semi-friable fused alumina
and special fused alumina) aluminium metal producers.”
Kaili, China Blasting media (BFA, WFA) One Chinese producer stated: “They
Zschornewitz, Germany Specialised applications ((BFA, [overseas consumers] are not going to be
WFA, PFA and semi-friable fused able to get bauxite from China.”
Puerto Ordaz, Venezuela alumina) This may encourage and provide
Salto, Brazil justification for bauxite operations
outside China to start up and/or export
Niagara Falls, Canada 120,000 tpa
in order to produce more BFA in the
(including
Washington Mills Electro 50,000 tpa countries surviving furnaces.
BFA, WFA.
Minerals Corp. Niagara Falls, USA capacity BFA
tilt furnace in Prices skyrocket
Canada) Prices for fused alumina, particularly
Zaporozhsky Abrazivny BFA, have dramatically increased
Zaporozhye, Ukraine BFA and silicon carbide 90,000 tpa over recent months, owing to supply
Combine
problems and shipping costs, as well
Zunyi Jingshan Brown
Zunyi, China BFA 50,000 tpa as the costly nature of fused alumina
Fused Alumina
production itself.

December 2007 35
FUSED ALUMINA

Leitner stated: “Fused alumina is


a very complex product. Treibacher
Schleifmittel has not witnessed many
changes over the last three years, but
prices are generally increasing due to
raw material availability and costs as
well as environmental costs. Prices are
increasing in double digits: the cost of
energy is increasing and raw materials
are in short supply. With regards to
freight, there is a shortage of containers
from Asia to Europe, which is causing
freight costs to increase dramatically.”
Additionally, producing fused
alumina with an electric arc furnace
itself is a very energy intensive process,
requiring 2,000 kWh of electricity per
tonne of product (at standard industry China’s supply problems have increased the cost and reduced the availability of BFA and good
price, the cost of electricity comprises quality bauxite. Courtesy Washington Mills.
approximately 12% of the product’s
market value). developed world back into the market, the Olympics as China battles with the
Leitner continued: “Treibacher thereby subduing prices. pollution problem and I would not be
Schleifmittel and other producers Prices for WFA, which is favoured by surprised at all of drastic measures are
are also experiencing problems with producers in the developed world, will brought in like shutting down large
exchange rates for the Japanese yen and continue to be largely under the control parts of the industry in provinces like
the US dollar.” of producers. With stable Bayer process Shanxi, Ningxia and Gansu a couple
Williams stated: “Washington Mills alumina prices, production costs are of months before the Olympics to
does not expect to see prices come unlikely to increase significantly in the reduce the pollution in Beijing over that
down in the near future and we expect medium term, and will remain stable. period.”
demand to flatten in North America. Chinese BFA producers are
We do, however, expect the demand for forecasting that prices for the refractory Market applications
exports to continue to grow as a result of BFA could increase by $200/tonne to The main use of fused aluminas is in
a weaker US dollar.” reach $800/tonne before the end of the manufacture of abrasives, although
The large differential between 2007, before stabilising. Prices for BFA it is also used in refractories (bricks and
Chinese and USA/European prices led jumped by as much as 35% during July/ monolithics), as well as having some
to a decline in the production of crude August 2007, and have not stabilised more specialist uses, such as in floor
BFA in the USA and Europe, and to since, probably due to higher coal, cast tiles.
the introduction of a 134% antidumping iron and bauxite prices.
duty in the USA on processed BFA Sources within China have reported Abrasives
in late 2003. The duty and a growing that prices have also risen due to Abrasives account for about 60% of
shortage of alumina in China resulted in agreements reached between the the demand for all types of fused
a relative equalisation of prices, which country’s largest producers. In July, alumina. In comparison to other abrasive
settled at $700-$900/tonne FEPA 8-220, producers gathered in Zhengzhou, to materials, fused alumina has a higher
European/USA; and $580-$600/tonne strike an agreement to allow ex-works Young’s modulus rating than either
FEPA 8-220, FOB China in October prices of abrasive grade BFA finished aluminium nitride or boron nitride, but
2007. grits to rise significantly to RMB4,000/ is weaker than silicon carbide. Fused
Chinese producers dominate the tonne ($533/tonne). Since then, it is alumina containing 99% Al2O3 is harder
production of non-metallurgical understood that producers have had at than less pure grades, but not as tough.
aluminas, especially BFA. The supply least three more meetings to set higher As it is more friable than BFA, WFA
of low cost Chinese fused alumina has, prices. is preferable where a faster, cooler cut is
over a period of years, forced producers Commenting on Chinese electricity required. WFA is used for the precision
in the USA and western Europe out price increases, and forecasting future grinding of alloys, high speed and heat-
of the market. With reduced world problems, Mike Sanderson, purchasing treated steels. Abrasive grade WFA
production capacity and buoyant director of Vesuvius Advanced Ceramics contains 99.53% Al2O3, 0.33% Na2O,
demand, the price of both refractory Co. told IM
IM: “BFA is a nightmare 0.10% Fe2O3, 0.04% SiO2 and 0.03% C.
and abrasive grade BFA is forecast to following the electricity increases in Its Knoop hardness is 1,950 compared
continue rising. This may, however, Henan province…In my opinion I can with 1,850 for BFA, and it melts at
bring some of the producers in the see a problem when we get closer to 2,050˚C (2,000˚C).

December 2007 37
FUSED ALUMINA

Applications and compositions of alumina abrasives In general terms, abrasives are


irreplaceable in industrial applications.
Type Composition Market Applications A leading producer commented:
“Despite efforts made by industry
BFA Al2O3 (96.6%), TiO2 (2.6%) Coated Belts, non woven wheel pads
SiO2 (0.6%) to create synthetic and non-mineral
based abrasives with some success,
Grinding wheels, sharpening sticks,
Bonded the abrasives industry that today is
hones, tumbling media
served by BFA has been pared down to
Metalworking, surface preparation, essential applications and most of the
Blasting
cleaning, deburring erosion of these applications by form
Polishing Set-up wheels to fit manufacturing and other abrasive
products have ceased”.
Lapping Creating parallelism, flatness
Cleaning, stuccoing, removing shell
Investment casting Refractories
material
Compound/buffing Satin finishing, liquid compound Refractory BFA’s chief characteristics
are high hardness, good toughness and
Non-slip Floors, ramps, stairs, walkways, paint sharp shape in size. Refractory WFA
Stone trade Designing, lettering has higher hardness and slightly lower
toughness compared with BFA. Among
Brakeshoes/clutches Linings
its properties as a high-grade refractory
WFA Al2O3 (99.08-99.5%) Wheels, grinding high alloy heat are high purity, acid and alkali resistance,
Bonded
sensitive steels
good thermal stability.
Blasting Miniature, metals The general trend in the refractories
Compound/buffing Automotive market is towards higher purity refractory
raw materials, which prolong life, thus
Polishing Non-woven pads
reducing replacement frequency. In such
Lapping Compounds a squeezed market, a longer life span is
becoming increasingly important to keep
Investment casting Stuccoing
operation costs at a minimum.
Brakeshoes Friction modifier Leitner stated: “The refractory
Non-slip Floors, floor tiles industry is booming, so there will be no
big revolution there. There is a trend
Alumina-zirconia AZ (75% Al2O3 23% ZrO2) Blasting Metal finishing, surface preparation
in the refractory towards higher quality
Investment casting Removing shell material refractory raw materials. This trend could
possibly suggest that in the future, WFA
Stone trade Blasting, granite finishing, engraving
could take over from BFA as a refractory
Organic grinding wheels, cold pressed
ZF (75% Al2O3, 23% ZrO2) Bonded raw material. Whatever the outcome,
snagging
Treibacher Schleifmittel will follow the
Tumbling Deburring
rest of the market.”
Organic grinding wheels for steel
ZS (75% Al2O3, 23% ZrO2) Bonded
conditioning
Other uses
NZ (60% Al2O3, 39% ZrO2) Coated Belts, discs, jumbo rolls, cutsheets BFA is becoming more popular in
Source: Saint-Gobain abrasive blasting as a replacement for
silica sand on environmental grounds.
Overall, the market alumina abrasives for aluminas because less grinding and Leitner commented: “Fused alumina
is stable, despite the number of factors fewer grinding tools are needed – have could be an interesting raw material
suggesting its decline. There have, been and will be developed as demand for new applications. There are three
however, been some minor fluctuations: for high performance abrasives increases. main applications for fused alumina:
substitution by other abrasives in However, it is thought that BFA abrasives, refractories and blasting. A
cathode ray tube polishing has led abrasive manufacture in China will growing fourth application is for wear
to some decline in demand for fused gradually increase in China due to resistance in floor tiles. However, I
aluminas. its lower production costs. China’s would not forecast any big changes in
Furthermore, falling prices for higher advantage has been attributed to the the main applications of fused alumina.
performance abrasives have increased lower cost power, materials and labour, There are some specific new niche
their competitiveness with BFA, and and less restrictive environmental market possibilities arising from heat
new products, such as the diamond regulation. However, as China’s resistance quality of fused alumina.
and cubic boron nitride super abrasives domestic demand increases, exports are Treibacher Schleifmittel will look for
– viewed as a potential replacement likely to decrease. new applications.”

38 December 2007

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