KEMENTERIAN RISET, TEKNOLOGI DAN PENDIDIKAN TINGGI

UNIVERSITAS BRAWIJAYA
FAKULTAS TEKNIK
PROGRAM STUDI TEKNIK KIMIA
Jl. Mayjen Haryono 167, Malang 65145, Indonesia
Telp. : +62-341-587710, pswd : 1333, 1139, 1245, 1229; Fax : +62-341-574140
website : http://teknikkimia.ub.ac.id E-mail : teknikkimia@ub.ac.id

Dosen : Dr. Uswatun Hasanah

Ujian : Akhir Semester
Rama Oktavian S.T., M.Sc.
Mata Kuliah : Kimia Fisika
Tanggal : 22 Juni 2016
Kelas A/B : Kelas B
Waktu : 90 menit
Semester : Genap 2015/2016
Sifat : Buka Catatan 1 lembar A4
Prodi : Teknik Kimia

Total points: 120 pts

1. (10 pts) This problem deals with 1st law thermodynamics concept
A gas (assume as ideal gas) is enclosed within a chamber that is fitted with a frictionless piston. The piston is then
pushed in, thereby compressing the gas, what will happen to the state of that gas according to the 1 st law of
thermodynamics? Is that possible when there is no heat flows in the chamber, the temperature of that gas
increases? Please explain for your yes or no answer!

2. This problem deals with state and path function

Consider the cyclic process below representing a heat engine.

If there is 1.00 mol of ideal gas (Cp = 7/2R and Cv = 5/2R), the temperature at each point in the
cycle is as follows:
Temp at A Temp at B Temp at C Temp at D
487 K 975 K 487 K 244 K
a. (5 pts) Write the sign “+”, “-“, or “0” for the value of ΔU, q, and w in each process and overall process
(AB, BC, CD, DA, and overall)
b. (15 pts) Calculate enthalpy change, internal energy change, heat and work produced and absorbed for
each process and overall process.

3. This problem deals with reversible work

A mass of 1000 kg is placed on a 1m x 1m plate which acts as a piston over a 1m x 1m x 1m volume of perfect
gas at 298 K. The gas is originally in equilibrium with the external pressure of 1 atm (101325 Pa).
a. (15 pts) How much will the piston descend if the temperature is kept constant? The gravitational acceleration is
g = 9.80 ms-2
b. (15 pts) Calculate the work performed on the gas, and the heat absorbed by the gas in the process.
c. (5 pts) Is this compression a reversible process (in the thermodynamics sense)? Please give a reason for your
yes or no answer
 KEMENTERIAN RISET, TEKNOLOGI DAN PENDIDIKAN TINGGI
UNIVERSITAS BRAWIJAYA
FAKULTAS TEKNIK
PROGRAM STUDI TEKNIK KIMIA
Jl. Mayjen Haryono 167, Malang 65145, Indonesia
Telp. : +62-341-587710, pswd : 1333, 1139, 1245, 1229; Fax : +62-341-574140
website : http://teknikkimia.ub.ac.id E-mail : teknikkimia@ub.ac.id

4. This problem deals with Thermocemistry calculation

(20 pts) Given the data at 25 °C :

Ti (s) + 2Cl2 (g) TiCl4 (l) Standard Molar Enthalpy of formation= -804.2 KJ/mol
Ti (s) + 2Cl2 (g)TiCl4 (g) Standard Molar Enthalpy of formation= -763.2 KJ/mol
For the reaction:

a. Calculate H f for TiCl4(l) at 25 °C

0

b. Calculate H 0 for this reaction at 135.8 °C, the boiling point of TiCl4(l)

5. This problem deals with phase diagram of single and binary compound
a. (15 pts) Prior to the discovery that freon-12 (CF2Cl2) was harmful to Earth’s ozone layer, it was frequently
used as the dispersing agent in spray cans for hair spray, etc. Its enthalpy of vaporization at its normal boiling
point of –29.2°C is 20.25 kJ mol-1. Estimate the pressure that a can of hair spray using freon-12 had to withstand
at 40°C (the temperature of a can that has been standing in sunlight). Assume that ΔvapH is a constant over the
temperature range involved. (Hint: Use Clausius-Clapeyron equation)

b. (20 pts) At 100°C benzene has a vapor pressure of 180.9 kPa, and toluene has a vapor pressure of 74.4 kPa.
Assuming that these substances form ideal binary solutions with each other, calculate the composition of the
solution that will boil at 1 bar at 100°C and the vapor composition. Sketch the p-x,y diagram for this system and
show the composition of the solution along its vapor composition.
 KEMENTERIAN RISET, TEKNOLOGI DAN PENDIDIKAN TINGGI
UNIVERSITAS BRAWIJAYA
FAKULTAS TEKNIK
PROGRAM STUDI TEKNIK KIMIA
Jl. Mayjen Haryono 167, Malang 65145, Indonesia
Telp. : +62-341-587710, pswd : 1333, 1139, 1245, 1229; Fax : +62-341-574140
website : http://teknikkimia.ub.ac.id E-mail : teknikkimia@ub.ac.id
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