528018 Carton steel - Wikipedia
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Carbon steel
Carbon steel is a steel with carbon content up to 2.1% by weight. The definition of carbon steel from the American Iron
and Steel Institute (AISD states:
Steel is considered to be carbon steel when:
+ no minimum content is specified or required for chromium, cobalt, molybdenum, nickel, niobium, titanium,
tungsten, vanadium or zirconium, or any other element fo be added to obtain a desired alloying effect;
+ the specified minimum for copper does not exceed 0.40 percent;
+ or the maximum content specified for any of the folowing elements does not exceed the percentages noted
manganese 1.65, silicon 0.60, copper 0.60."
The term "carbon steel" may also be used in reference to steel which is not stainless steel; in this use carbon steel may
include alloy steels.
As the carbon percentage content rises, steel has the ability to become harder and stronger through heat treating;
however, it becomes less ductile. Regardless of the heat treatment, a higher carbon content reduces weldability. In carbon
steels, the higher carbon content lowers the melting point 21
Contents
Type
Mild or low-carbon steel
High-tensile steel
Higher-carbon steels
AISI Classification
Low-carbon steel
Medium-carbon steel
High-carbon steel
Ultra-high-carbon stee!
Heat treatment
9
Forging temperature of steel
See also
Case harde
References
Bibliography
Type
Mild or low-carbon steel
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Mild steel (iron containing a small percentage of carbon, strong and tough but not readily tempered), also known as plain=
carbon steel and low-carbon steel, is now the most common form of steel because its price is relatively low while it
provides material properties that are acceptable for many applications. Mild steel contains approximately 0.05-0.25%
carbont*! making it malleable and ductile. Mild steel has a relatively low tensile strength, but itis cheap and easy to form;
surface hardness can be increased through carburizing
In applications where large cross-sections are used to minimize deflection, failure by yield is not a risk so low-carbon
steels are the best choice, for example as structural steel. The density of mild steel is approximately 7.85 g/cm?
(7850 kg/m? or 0.284 Ib/in’)!) and the Young's modulus is 200 GPa (29,000 ksi).!1
Low-carbon steels suffer from yield-point runout where the material has two yield points. The first yield point (or upper
yield point) is higher than the second and the yield drops dramatically after the upper yield point. Ifa low-carbon steel is
only stressed to some point between the upper and lower yield point then the surface develop Liider bands." Low-carbon
steels contain less carbon than other steels and are easier to cold-form, making them easier to handle.
High-tensile steel
High-tensile steels are low-carbon, or steels at the lower end of the medium-carbon range, which have additional alloying
ingredients in order to inerease their strength, wear properties or specifically tensile strength. These alloying ingredients
include chromium, molybdenum, silicon, manganese, nickel and vanadium. Impurities such as phosphorus or sulphur
have their maximum allowable content restricted.
= A tx steel
= 4140 steel
* 4145 steel
= 4340 steel
+ 300M steel
= EN25 steel 214% nickel-chror
= EN26 stee!
im-molybdenum steel
Higher-carbon steels
Carbon steels which can successfully undergo heat-treatment have a carbon content in the range of 0.30-1.70% by weight.
Trace impurities of various other elements can have a significant effect on the quality of the resulting steel. Trace amounts
of sulfur in particular make the steel red-short, that is, brittle and crumbly at working temperatures. Low-alloy carbon
steel, such as 36 grade, contains about 0.05% sulfur and melts around 1,426-1,538 °C (2,599-2,800 °F) ®) Manganese is
often added to improve the hardenability of low-carbon steels. These additions turn the material into a low-alloy steel by
some definitions, but AISI’s definition of carbon steel allows up to 1.65% manganese by weight.
AISI Classification
Carbon steel is broken down into four classes based on carbon content:!”
Low-carbon steel
0.05 to 0.30% carbon content.
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Medium-carbon steel
Approximately 0.3-0.8% carbon content.{"! Balances ductility and strength and has good wear resistance; used for large
parts, forging and automotive components.)
High-carbon steel
1
Approximately 0.8~2.0% carbon content." Very strong, used for springs, edged tools, and high-strength wires.
Ultra-high-carbon steel
Approximately 3.25~4.0% carbon content.!"l Steels that ean be tempered to great hardness. Used for special purposes like
(non-industrial-purpose) knives, axles or punches. Most steels with more than 2.5% carbon content are made using
powder metallurgy.
Heat treatment
‘The purpose of heat treating carbon steel is to change the mechanical
properties of steel, usually ductility, hardness, yield strength, or impact
resistance. Note that the electrical and thermal conductivity are only slightly
altered. As with most strengthening techniques for steel, Young's modulus
(elasticity) is unaffected. All treatments of steel trade ductility for increased
strength and vice versa, Iron has a higher solubility for carbon in the austenite
phase; therefore all heat treatments, except spheroidizing and process " ‘oan
annealing, start by heating the steel to a temperature at which the austenitic ,
phase can exist. The steel is then quenched (heat drawn out) at a moderate to ‘tn
low rate allowing carbon to diffuse out of the austenite forming iron-earbide —-55-carion phase diagram
(cementite) to precipitate leaving ferrite, or at a high rate, trapping the carbon showing the temperature and
within the iron thus forming martensite. The rate at which the steel is cooled ranges for certain types of
t treatments.
through the eutectoid temperature (about 727°C) affects the rate at which
carbon diffuses out of austenite and forms cementite. Generally speaking,
cooling swiftly will leave iron carbide finely dispersed and produce a fine
grained pearlite and cooling slowly will give a coarser pearlite. Cooling a hypoeutectoid steel (less than 0.77 wt% C) results
in a lamellar-pearlitic structure of iron carbide layers with a-ferrite (nearly pure iron) between. If it is hypereutectoid steel
(more than 0.77 wt% C) then the structure is full pearlite with small grains (larger than the pearlite lamella) of cementite
formed on the grain boundaries. A eutectoid stee! (0.77% carbon) will have a pearlite structure throughout the grains with
no cementite at the boundaries. The relative amounts of constituents are found using the lever rule. The following is alist
of the types of heat treatments possible:
+ Spheroidizing: Spheroidite forms when carbon stee|is heated to approximately 700 *C for over 30 hours.
Spheroidite can form at lower temperatures but the time needed drastically increases, as this is a diflusion-controlled
process. The results a siructure of rods or spheres of cementite within primary structure (ferrite or pearl,
depending on which side of the eutectoid you are on). The purpose is to soften higher carbon steels and allow more
formabilty. This is the softest and most ductile form of steel. The image to the right shows where spheroidizing
usually occurs."2)
+ Full annealing: Carbon steel is heated to approximately 40 °C above Ac3? or Acm? for 1 hour; this ensures all the
ferrite transforms into austenite (although cementite might stl exist i the carbon content is greater than the
eulectoid). The steel must then be cooled slowly, in the realm of 20 °C (36 *F) per hour. Usually itis just furnace
Cooled, where the furnace is tured off wth the steel stil inside. This results in'a coarse pearitic structure, which
means the "bands" of pearlte are thick") Fully annealed steel is soft and ductile, with no internal stresses, which is
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often necessary for cost-effective forming. Only spheroidized steel is softer and more ductile ("41
+ Process annealing: A process used to relieve stress in a cold-worked carbon stee! with less than 0.3% C. The steol
is usually heated to 550-650 °C for 1 hour, but sometimes temperalures as high as 700 °C. The image rightward
shows the area whore process annealing occurs
+ Isothermal annealing: Itis a process in which hypooutectoid steel is heated above the upper critical temperature.
This temperature is maintained for a time and then reduced to below the lower critical temperature and is again
maintained. itis then cooled to room temperature. This method eliminates any temperature gradient.
+ Normalizing: Carbon steel is heated to approximately 55 °C above Ac3 or Acm for 1 hour; this ensures the steel
completely transforms to austenite. The steel is then air-cooled, which is a cooling rate of approximately 38 °C
(100"F) per minute, This results ina fine pearllic structure, and a more-uniform structure. Normalized steel has a
higher strength than annealed steel ithas a relatively high strength and hardness."
+ Quenching: Carbon steel with atleast 0.4 wi% C is heated to normalizing temperatures and then rapidly cooled
(quenched) in water, brine, or oll tothe crtcal temperature. The ertical temperature is dependent on the carbon
content, but as a general rule is lower as the carbon content increases. This results in a martensitic structure; a form
of stool that possesses a super-saturated carbon content in a deformed body.centored cubic (BCC) crystalline
structure, properly termed body-centered tetragonal (BCT), with much internal stress. Thus quenched steel is
extremely hard but bite, usually too bri for practical purposes. Thess intemal stresses may cause stress cracks
on the surface. Quenched steel is approximately three to four (with more carbon) fold harder than normalized
steal")
+ Martempering (Marquenching): Martempering is not actualy a tempering procedure, hence the term
“marquenching". It is a form of isothermal heat treatment applied after an initial quench, typically in a molten salt bath,
ata temperature just above the "martensite start temperature", At this temperature, residual stresses within the
material are relieved and some bainite may be formed from the retained austenite which did not have time to
transform into anything else. In industry, this is a process used to control the ductility and hardness of a material. With
longer marquenching, the ductility increases with a minimal loss in strength; the steel is held inthis solution until the
inner and outer temperatures of the part equalize. Then the steel is cooled al a moderate speed to keep the
temperature gradient minimal. Not only does this process reduce internal stresses and siress cracks, butt also
increases the impact resistance.!"7
+ Tempering: This is the most common heat treatment encountered, because the final properties can be precisely
determined by the temperature and time of the tempering. Tempering involves reheating quenched steel to a
temperature below the eutectoid temperature then cooling. The elevated temperature allows very small amounts of
spheroidite to form, which restores duciity, but reduces hardness. Actual temperatures and times are carefully
chosen for each composition 8)
+ Austempering: The austempering process is the same as martempering, except the quench is interrupted and the
Steel is held in the molten salt bath at temperatures between 205°C and 840°C, and then cooled at a moderate rate
The resulting steel, called bainte, produces an acicular microstructure in the steel that has great strength (but less
than martensite), greater ductility, higher impact resistance, and less distortion than martensite steel. The
disadvantage of austempering sit can be used only on a few steels, and it requires a special salt bath !"]
Case hardening
Case hardening processes harden only the exterior of the steel part, creating a hard, wear resistant skin (the “case") but
preserving a tough and ductile interior. Carbon steels are not very hardenable meaning they can not be hardened
throughout thick sections. Alloy steels have a better hardenability, so they can through-hardened and do not require case
hardening. This property of carbon steel can be beneficial, because it gives the surface good wear characteristics but leaves
the core tough.
Forging temperature of steel
(20)
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Steel Type Maximum forging temperature (F /*C) | Burning temperature (°F /°C)
1.5% carbon 1920 / 1049 2080 / 1140
41.4% carbon 1980 / 1082 2140/1171
0.9% carbon 2050/1121 2230/1224
0.5% carbon 2280/1249 2460 / 1949
0.2% carbon 2410/1324 2680/1474
3.0% nickel steel 2280/1249 2500/1971
3.0% nickel-chromium steel 2280 / 1249 2500 1971
5.0% nickel case-hardening) steel | 2320/1271 2640/1449
Chromium-vanadium steel 2280/1249 2460 / 1949
High-speed steel 2370/1299 2520 1985
Stainless stee! 2340/1282 2520 / 1985
‘Austenitic chromium-rickel steel | 2370/1299 2590 / 1420
Silico-manganese spring steel 2280/1249 2460 / 1350
See also
= Cold working
= Hot working
= Welding
= Forging
References
1. "Classification of Carbon and Low-Alloy Steels” (htt:/www.keytometals,com/Articles/Art62.htm)
2. Knowles, Peter Reginald (1987), Design of structural steelwork (ntips://books.google.com/books?id=UBWX-3CBygcC.
‘&pg=PA1) (2nd od.), Taylor & Francis, p. 1, ISBN 978-0-903384-59-9.
3. Engineering fundamentals page on low-carbon steel (hitp://efunda.comimaterials/alloys/alloy_homel../carbon_steelsi!
‘ow_carbon.cim)
4. Elert, Glenn, Density of Stee! (http: ypertextbook. convfacts/2004/KarenSutherland shtml), retrieved 23 April 2009.
5. Modulus of Elasticity, Strength Propertios of Metals ron and Stee! (hitp:/www.engineersedge.comimanufacturing_s
peciproperties_of_matals_strength htm), rotrioved 23 April 2009
6. Degarmo, p. 377.
7. “Low-carbon steets” (hito:/www.efunda.com/materials/alloys/carbon_steels/low_carbon.cfm). efunda. Retrieved
2012-05-25,
8. Ameristeel article on carbon steo! (htp:/www.ameristeel.com/products/msds/docs/carbon_steel.paf) Archived (https!
web archive. org/web/20061018015022/http:/imww.ameristeel.com/products/msds/docs/carbon_steel.pdf) 18 October
2006 al the Wayback Machine
9, Nishimura, Naoya; Murase, Katsuhiko; ito, Toshihiro; Watanabe, Takeru; Nowak, Roma
spall damage induced by low-velocity repeated impact". Central European Journal of Engin
doi 10.2478/513531-012-0013-5 (hitps://dol.org/10.2478%2Fs13531-012-0013-5).4
10. Engineering fundamentals page on medium-carbon steel (hitp:/mww.efunda.comimaterials/alloysicarbon_steels/medi
um_carbon.cfm)
Itrasonic detection of
jeering. 2 (4): 650-655,
hipster. wikipedia orghwikiCaroon_stec! 56528018 Carton steel - Wikipedia
‘11. Engineering fundamentals page on high-carbon steel (http:/www.efunda.com/materials/alloys/carbon_steels/high_car
bon.cfm)
12. Smith, p. 388
13, Alvarenga HD, Van de Putte T, Van Steenberge N, Sietsma J, Terryn H (Apr 2009). "Influence of Carbide Morphology
and Microstructure on the Kinetics of Superficial Decarburization of C-Mn Steels", Metal Mater Trans A.
doi:10.1007/511661-014-2600+y (hitps:l/doi.org/10.1007%2Fs11661-014-2600-y).
14, Smith, p. 386
16, Smith, pp. 386-387
16. Smith, pp. 373-377
17. Smith, pp. 389-390
18, Smith, pp. 387-388
19. Smith, p. 391
20. Brady, George S.; Clauser, Henry R.; Vaccari A., John (1997). Materials Handbook (14th ed.). New York, NY:
McGraw-Hill. ISBN 0-07-007084-9
Bibliography
= Degarmo, E. Paul; Black, J T.; Kohser, Ronald A. (2003), Materials and Processes in Manufacturing (9th ed.), Wiley,
ISBN 0-471-65653-4
= Oberg, E.; et al. (1996), Machinery’s Handbook (25th ed.), Industrial Press Inc, ISBN 0-8311-2599-3.
= Smith, William F.; Hashemi, Javad (2006), Foundations of Materials Science and Engineering (ath ed.), McGraw-Hill,
ISBN 0-07-295358-6,
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