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To cite this article: Christopher Kendrick & Nicholas Walliman (2007) Removing Unwanted Heat in
Lightweight Buildings Using Phase Change Materials in Building Components: Simulation Modelling
for PCM Plasterboard, Architectural Science Review, 50:3, 265-273
Download by: [University of Manitoba Libraries] Date: 16 September 2017, At: 01:06
Architectural Science Review
www.earthscan.co.uk/journals/asre doi:10.3763/asre.2007.5032 Volume 50.3, pp 265-273
Oxford Institute for Sustainable Development-Technology Group, School of the Built Environment, Oxford Brookes
University, Gipsy Lane, Headington, Oxford OX3 0PB, England
†Corresponding author: Tel: 44 (0)1865 483 644; Fax: 44 (0)1865 483 298; Email: nwalliman@brookes.ac.uk
Abstract: Phase change materials (PCMs) can store much larger amounts of thermal energy per unit mass than conventional building
materials and can be used to add thermal stability to lightweight construction without adding physical mass. This paper reviews how
PCMs could be incorporated in building materials, particularly in passive applications. A simulation study using IES Virtual Environment
package ‘Apache’ was carried out on PCM impregnated plasterboard, investigating various fusion temperatures of the PCM during
night, day, and week-long test durations in hot weather conditions. Different ventilation rates and alternative conductivity values of the
gypsum in the plasterboard were tested. It was shown that use of PCMs has significant advantages for both commercial and residential
building applications, provided sufficient night ventilation is allowed.
Keywords: Building components, Building materials, Fusion temperature, Lightweight construction, PCM impregnated plasterboard, Phase
change materials (PCM), Plasterboard, Simulation, Thermal comfort, Thermal energy, Thermal insulation, Thermal simulation, Ventilation, Virtual
environments
Introduction
The UK government is actively encouraging higher speeds and temperatures. There is a tension between the drive to construct
standards of construction using off-site construction techniques more efficient structures with minimum environmental impact
(Prescott, 2005). In addition, the Part L Building Regulation and the tendency to add more mass (in practice concrete) for
requirements on energy efficiency and carbon, demand increasingly thermal storage.
stringent energy performance for new construction (Building Phase change materials (PCMs) can store much larger amounts of
Regulations, 2006). These factors have led to a significant shift away thermal energy per unit mass than conventional building materials
from conventional brick and block building techniques towards by storing energy as latent rather than sensible heat. Compared to
lightweight timber and steel frame construction, because it is a the amount of mass required for energy storage in a block or brick
competitive solution for new pre-fabricated building elements and building, the amount of PCMs needed is minimal. Similarly, the
tends to be more cost effective to achieve compliance with thermal energy needed to produce the PCMs would only be a fraction of
performance demands. the energy needed to produce blocks, bricks or concrete with the
However, a move to lightweight construction raises concerns same heat storage capacity (Anderson & Shires, 2002).
over internal comfort conditions due to lack of thermal storage PCMs can be used for cooling a building in three conventional
properties, resulting in rapid swings of internal temperature. This ways:
concern is exacerbated by projected climate change because of • Passive cooling: Cooling through the direct heat exchange of
global warming. Recent studies have indicated that hotter, drier indoor air with PCMs incorporated into the existing building
summers are likely. Without optimised design of new buildings, materials such as plasterboards, floorboards and furniture
many of the benefits accruing from reduced heating consumption • Assisted passive cooling: Passive cooling with an active
may be lost as air conditioning units are fitted to reduce internal component (for example, a fan) that accelerates heat exchange by
266 Architectural Science Review Volume 50, Number 3, September 2007
increasing the air movement across the surface of the PCM applications, can be incorporated into a variety of building products,
• Active cooling: Using electricity or absorption cooling to reduce including wallboards and insulation foams. At an experimental
the temperature and/or change the phase of the PCM stage, conventional, resistive insulation has been converted to
As active cooling, and to a lesser extent supportive passive cooling, capacitive or dynamic insulation by addition of PCM, thus adding
require the use of additional energy (refrigeration and fans) it is thermal storage and consequent time lags where previously none was
likely that the simplest, most cost-effective and environmentally possible. Experiments have been carried out with perlite-based loft
sound means of using PCM is in a purely passive way. Although insulation, in which perlite is impregnated with hydrated calcium
more research is needed to investigate if this is in fact so, the main chloride and contained between layers of conventional insulation
focus of this paper is on the use of PCMs for passive cooling. (Petrie, Childs, Christian & Childs, 1997). Ceiling tiles is another
possible PCM application that has been tested using monitored
PCMs in Building Applications test cells (University of Brighton Thermal Storage Research Group,
2006). The same group has also undertaken work on a 5mm thick
PCM can be impregnated into building materials such as interior wall lining material containing PCM.
plasterboard, either directly or as impregnated pellets. Various Recently, wall/ceiling board (plasterboard), concrete blocks
materials have been investigated (see Table 1). Paraffin wax, and wall/floor tiles containing micro-encapsulated PCM have
because of its cheapness and ready availability, combined with been produced commercially (Azom.com News, 2006; Hittle,
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its flexibly adjustable phase change temperature is seen as a 2002). The phase change temperature close to the desired mean
particularly promising material for use in building components temperature of the room aims to provide effective thermal storage
(Amar, Kudhair & Farid, 2004; Chen, Nelson & Polanski, 1982; for both cooling and heating applications. The large surface
Demirbas, 2006). area available for heat transfer should enable effective use of this
Another method of incorporating PCM into conventional distributed thermal mass.
construction components is micro-encapsulation (Hawlander, Plasterboard is the most common lining material used in
Uddin & Khin, 2002; Hawlander, Uddin & Zhu, 2002; Schossig, lightweight timber and steel framed construction and could thus
Henning, Gschwander & Haussmann, 2005). Schossig P., Henning, make the biggest contribution to controlling overheating if replaced
H., Gschwander, S., & Haussmann, T. (2005) describe simulation with PCM variants. In order to test the effectiveness of PCM
and testing of PCM plasterboard-lined rooms, and finds notable plasterboard linings in reducing unwanted heat in buildings, an
decreases in peak temperature in both when compared with effective method of simulation was devised, and a series of tests
conventionally finished rooms. However, it is noted that the main carried out described below. The main difference from most
difficulty is night cooling, and mechanical ventilation is used at previous work is that real weather conditions are used rather than
four air changes per hour to cool the PCM. Micro-encapsulated fixed conditions.
PCM has the appearance of beads or powder, depending upon
size. The PCM is contained within small polymer spheres (for Modelling PCM Impregnated Plasterboard
example ‘Thermocules’, 10 micron diameter acrylic spheres which
contain paraffin wax), increasing the area to volume ratio available Dynamic thermal simulation is a powerful tool for assessing
for heat transfer in PCM applications. This effectively overcomes the thermal comfort and energy use of buildings throughout
the problems experienced by most encapsulation systems caused the year. However, none of the commercially available software
by reduced heat flux through the solid-liquid interface as it moves allows incorporation of PCM as part of the standard routine, so
away from the heat transfer surface. In addition, a wall thickness additional modelling was required to assess their use in buildings.
of approximately 1 micron reduces thermal resistance of the The essential feature of PCMs is that they absorb energy as latent
encapsulant to negligible proportions. This technique has been a rather than sensible heat over a small range of temperatures around
significant breakthrough, as it enables easy integration of organic their melting point (fusion temperature), and hence exhibit no
PCM into building components (for example, plaster, plasterboard sensible temperature rise over this range. The amount of heat
and concrete) whilst avoiding odour and handling problems. absorbed in this way is termed the latent heat of crystallization, and
Micro-encapsulated PCM, already used in some specialized varies with the material under consideration, as does the melting
clothing such as ski wear and in some electronics cooling point. The absorbed heat is released back into the space when
Table 1: Some existing PCMs that may be useful for Passive Cooling Applications.
Table 1: Some existing PCMs that may be useful for Passive Cooling Applications.
Material Phase Type of material Environmental performance
Change
Temperature
CristopiaAC00
Cristopia AC00 0¡C Water and Crystallising Agent ¥ Safe and non-toxic
(sealed plastic nodule) ¥ Low energy
Cristopia PCM-13A
Cristopia PCM-13A
13¡C Trimethylolethane (sealed plastic ¥ Safe and non-toxic
nodule) ¥ Low energy
Cristopia PCM-20 20¡C Organic Fatty Acids (sealed ¥ Natural by-product
Cristopia PCM-20 plastic nodule) ¥ Safe and non-toxic
¥ low energy
CristopiaPCM27
Cristopia PCM-27 27¡C Calcium and Potassium Chloride ¥ Corrosive, hence needs to be enclosed
Solution (sealed plastic nodule) ¥ Low energy
Various
Various 22-35¡C Paraffin Waxes ¥ By-product of the petroleum industry
manufacturers
manufacturers ¥ Low energy
Christopher Kendrick and Nicholas Walliman Phase Change Materials for Removing Unwanted Heat in Lightweight Buildings 267
temperatures drop below the melting point. This process may be point is reached and thence the temperature will remain fixed
considered fully reversible for the purposes of simulation. for some period after that. This can be modelled by describing
The PCMs were modelled using the conditioned cavity method, a cooling scenario for spaces adjacent to the wallboard. In
whereby a cavity is maintained at a setpoint behind the PCM reality, these spaces are the wall cavities and space between joists.
material related to the melting point of the material chosen. As Normally these would be modelled by an air gap in the wall and
the temperature rises above the melting point, energy will be ceiling construction. Here the wall and ceiling constructions
passed into the conditioned space, the amount of energy being have been divided into two constructions describing either side
monitored until all the theoretical latent heat of the material can of the air gaps.
be accounted for. At this point, conditioning will be switched To make the model as simple to describe as possible, the wall
off, allowing the temperature of the material to rise in the cavity spaces are double height: two being described: one wraps
normal manner. The process is reversed for solidification, the from the eastern face of the building and one the western face.
conditioning being maintained until all latent heat contained in The glazing is described by separate window spaces, again double
the material is released back into the space, assuming temperature height. The glazing effectively consists of an external and internal
differentials allow. Energy consumed in conditioning the space is window that are aligned and separated by a gap of 100mm. The
not considered in the assessment of energy use for the building, external windows are standard double-glazing and internal single
but is used purely to simulate the phase change behaviour of clear glazing. The combined effect of the two windows having
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Office Environment
A single room open plan office building of lightweight
construction was modelled. The building is rectangular in plan
with an east-west axis. North and south faces were glazed to 30%
of their areas. Walls were timber framed with brick cladding,
and the roof was modelled as ‘flat’ but of conventional sloping
roof materials. All external surfaces were insulated to Building
Regulation Part L (2002) standards.
Casual gains:
Office equipment: 8.89W/m2 from 9am to 6pm
People: 90/60W sensible/latent, 1 person
per 12.5m2 from 9am to 6pm
Lighting: 7.33W/m2 from 8am to 8pm
Figure 3: Geometric detail: ceiling rooms.
Air exchanges: Figure 3: Geometric detail: ceiling rooms.
Room infiltration: 1 air change per hour (ac/h) continuously
Night ventilation: 3 ac/h from 6pm to 6am
All windows open at 10% by area from 9am to 6pm once air
temperature exceeds 22°C.
Cavities:
Infiltration: 1 ac/h continuously
Table
ble 3: Summary 3: Summary
of Resultant of (DRT)
Comfort Resultant Comfortbetween
temperatures (DRT)0900
temperatures
and 1800 for theTable 4: Summary
different of overall effect of the use of various night
between 0900 and 1800 for the different fusion temperatures
ion temperatures compared with the standard plasterboard case (no PCM). ventilation rates.
compared with the standard plasterboard case (no PCM). Table 4: Summary of overall effect of the use of various night ventilation rates.
Fusion Temperature % hours below % hours above 24¡C Air changes per % hours below % hours above % hours above
¡C 20¡C hour (Ac/h) admin! 20¡C
5/8/07 8:16 PM 24¡C 25¡C
21 6 24 0 Formatted2 Table 58 32
22 8 29 3 4 44 10
23 10 27 10 14 32 6
No PCM 11 32 0, no PCM 2 66 58
are achieved at lower fusion temperatures, 22°C giving the better comfort range: this appears to give the best compromise between
overall cooling performance. cool morning temperatures and hot afternoons. A PCM melting
The nature of the performance at the different temperatures is temperature of 22°C will be used for the majority of subsequent
illustrated in Figure 5. This shows the temperature fluctuation investigations. However, even at an optimum temperature it would
on a hot day. appear necessary to incorporate an additional cooling strategy to
A PCM melting at 21°C shows the greatest ability to reduce air improve cooling significantly.
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temperatures but will soon absorb all its fusion energy, allowing The working week 11-15th August proved to be significantly
subsequent temperatures to rise quickly due to the lightweight hotter than other weeks in August. Indeed, for the PCM at 22°C,
nature of the construction when neither melting nor crystallization this week accounted for 70% of the overheated hours. Remaining
is occurring. studies will concentrate on this week.
At 22°C, fusion temperature the response is slower with less
reduction in temperatures within the room. This slower response Study 2: Night Ventilation
means that full melting is delayed by an extra couple of hours A common technique for low energy cooling buildings of high
when compared with the lower fusion temperature PCM and room thermal mass is the introduction of cold night air to induce heat
temperatures begin to drop in late afternoon. Full melting of the flow out of structure and into the air stream that is subsequently
PCM occurs at the end of the working day and temperatures rise extracted from the building. Night ventilation may be employed
in the early evening. naturally or through mechanical means. A short study was
The 23°C case shows an even slower response and higher conducted into the effect of this strategy on comfort performance.
temperatures. However, in this case, the PCM does not fully melt Ventilation rates of 3 and 10 air changes per hour (ac/h) were
and the temperatures drop more progressively. incorporated between 6am and 6pm, see Table 4.
It is also worth noting that at the start of the day, only the lower Most significant is the reduction in the prevalence of very high
temperature PCM behaves differently to the standard board. This temperatures as indicated by the number of hours over 25°C.
is an indication that the lower temperature PCM has not fully Even when the PCM is crystalline at the start of the working day,
given up its heat of fusion: the adjacent surfaces are thus at 21°C the gains on a very hot day exceed those that can be absorbed by
which prevents the space from becoming too cold at the start of the PCM. Whilst the PCM is at its fusion temperature, on a very
the day. hot day (high temperature and gains) it cannot accommodate
In conclusion, the best overall performance might be expected a temperature difference between itself and the air of under
to be achieved with a PCM operating around the mid-point of the 2°C (corresponding
28 to an air temperature of 24°C) which
Hourly Variation in DRT during one hot day (11/08) for various fusion
temperatures
28
Dry Resultant Temperature (oC)
26
24
21oC
22 22oC
20 23oC
18 No PCM
16 outside
14
12
0 3 6 9 12 15 18 21 24
Hour Of Day
DRT
The 0 ac/h case (as Study 1) illustrates the problem 22
as standard plasterboard.
Cooling Load for 11-15/08 for standard wallboard and PCM impregnated
In the 3ac/h case, the night ventilation extracts
all the heat of fusion from the PCM such that it
120
has its full potential for absorbing excess heat. It PCM21
has fully melted at around 6pm by which time it is 100 PCM22
80
outside air can be introduced to assist the removal
of this heat. 60
The 10ac/h case is similar to the 3ac/h case.
40
However, the heat is removed more quickly and
the high air change means that the environment 20
more closely matches the outside temperature,
0
producing an environment that is too cold in the 22 23 24
early-occupied hours. Clearly, the incorporation of Cooling Set Point
night ventilation is advantageous to the performance
of the PCM, only requiring a low air change. Over Figure 7: Cooling loads for different wallboards.
Figure 7: Cooling loads for different wallboards.
ventilation may be prevented by employing a control
mechanism. 35
Study 3: Additional Artificial Cooling temperature (PCM22). In this case, the instantaneous peak load
To achieve optimal comfort within an office environment, as was halved and the cumulative load cut to less than 20% of its
the previous studies indicate, it may be necessary to incorporate base value.
some additional mechanical cooling. In Study 2, it was found Cooling to lower temperatures will not reduce the equipment
that whilst achieving significant improvement in comfort on very sizing but will still give considerable benefits in energy saving (38-
hot days (measured according to the time in the 20-24°C range) 54% in the simulated cases). These results are for a hot week in
may be difficult, the cooling load appeared much reduced. Thus, which the PCM finds it more difficult to control the air temperature.
whilst an air-conditioning plant may still be required, this plant It is probable that milder days will produce even greater savings as
may be smaller and use less energy. no additional cooling will be necessary on such days.
A set of simulations were performed with air-conditioning
set-points of 22, 23 and 24°C on PCMs operating at 21 and Study 4: Effect of Latent Heat of Fusion on Performance
22°C together with standard plasterboard. According to the All the above studies have used a latent heat of 320kJ/m2.
modelling, it was found that PCMs operating at the same This is based on 19% PCM in gypsum plasterboard. PCM
temperature as the cooling setpoint are unlikely to be successful as percentages of up to 25% of this material have been achieved,
the air-conditioning ends up competing with the cooling system. equivalent to 420kJ/m2. In addition, other materials will exhibit
However, if in reality, PCMs are installed in the ceiling only then other properties including different heats of fusion. It is clear
this may be successful due to the stratification of temperatures from previous studies that heat of fusion does have an effect on
within the room. the performance: we have seen that the value used is one which 36
Accordingly, a range of cooling setpoints and PCM fusion whilst being sufficient in mild summer weather is stretched in
temperatures were used and compared against the same setpoints more severe conditions. The heat of fusion is of the right order
when the surfaces did not incorporate PCMs. to be appropriate to this application but how flexible is this
The results, as summarised in Figure 6, indicated that the energy level?
greatest benefit in reducing mechanical cooling loads is clearly A short parametric study of the effect of different heats of
achieved by cooling to 24°C the case with a PCM of 22°C fusion fusion on DRT was conducted using half and double that used in
272 Architectural Science Review Volume 50, Number 3, September 2007
previous studies, measured over the occupied period Comfort Temperature for Living Room Model: With and Without PCM
within a hot week. It was found that the main effect
of different heats of fusion is to reduce the very high 30
DRT (oC)
22
to be kept below 26°C. This heat is sufficient to
20
prevent full melting of the PCM to occur on any
18
of the simulated days. However, it does not bring 16
all hours within the comfort band, an indication 14
that the heat cannot be absorbed into the PCM as 0 24 48 72 96 120 144 168
quickly as desirable. Hour Of Week : Mon 11/08 - Sun 17/08
Pcm/Gypsum Board Figure 8: Effect of PCM on temperature profile for residential conditions.
In all the above studies, the thermal conductivity Figure 8: Effect of PCM on temperature profile for residential conditions.
Downloaded by [University of Manitoba Libraries] at 01:06 16 September 2017
The main limit to performance is the heat transfer between the Chen, J., Nelson, R., & Polanski, P. (1982). Pelletization and roll
air in the space and the surface of the material containing PCM. encapsulation of phase change materials. Proceedings of the 6th Annual
This could be enhanced by creating air movement with fans Thermal and Chemical Storage Contractors’ Review Meeting. Silver
PCM is effective for residential buildings, reducing peak Spring, Maryland: MCC Associates, 177-184.
temperatures by 4-5°C, and hours over 24°C by 90%. Thermal Demirbas, M.F. (2006). Thermal energy storage and phase change
stability of lightweight buildings is also increased, reducing materials: An overview. Energy Sources, Part B: Energy, Economics,
temperature swings from around 10°C to 4°C in the case studied. and Planning, 1(1), 85-95.
However, the resulting higher overnight internal temperatures (3- Hawes, D., Banu, D., & Feldman, D. (1992). Stability of phase change
4°C) may not be desirable for bedrooms. It may be that use of PCM materials in concrete. Solar Energy Materials and Solar Cells, 27(2),
building materials be restricted to rooms used during the daytime 103-188.
and early evening, allowing lighter construction to be retained for Hawes, D., Feldman, D., & Banu D. (1993). Latent heat storage in
bedrooms where it appears to be advantageous. building materials. Energy and Buildings 20, 77-86.
Overall, it can be concluded that the use of PCM impregnated Hawlander, M., Uddin, M., & Khin, M. (2002). Microencapsulated phase
plasterboard has significant advantages for both commercial change materials. Proceedings of the 9th Asia Pacific Confederation
and residential building applications, provided sufficient night of Chemical Engineers Congress and Chemeca. Christchurch, New
ventilation is allowed. Although the most likely market is initially Zealand: University of Canterbury [CD-ROM].
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for commercial buildings, where use of PCM can improve thermal Hawlander, M., Uddin, M., & Zhu, H. (2002). Encapsulated phase change
comfort levels and obviate or reduce the need for air-conditioning, materials for thermal energy storage: Experiments and simulation.
with the increasing use of lightweight construction for homes, International Journal of Energy Research, 26(2), 159-171.
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Acknowledgements Viewed 1st February 2007.
The authors would like to thank the following for their assistance: Kruse, M., & Uwe, F. (2002). Latentwärmespeicher in Baustoffen (Latent
Steffie Broer, ESD; Kees Stap, Ecofys UK; Paul Tickner, Cristopia UK; Heat Storage in Building Materials). Karlsruhe: Gesellschaft für
Evangelos Kounavis, Kajima Construction Europe; Andrew Thorne, Wissenschaftlich-Technische Information mbH.
Building Research Establishment; and Funding from the Energy Efficiency Petrie, T., Childs, P., Christian, J., & Childs, K. (1997). Thermal
Best Practice Programme. behaviour of mixtures of Perlite and phase change materials in a
simulated climate. Insulation Materials: Testing and Applications:
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