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201100140
Abstract
An artificial neural network (ANN) and a genetic algorithm parameters (anode support thickness, anode support poros-
(GA) are employed to model and optimize cell parameters ity, electrolyte thickness, and functional layer cathode thick-
to improve the performance of singular, intermediate-tem- ness) are determined by using the GA under different condi-
perature, solid oxide fuel cells (IT-SOFCs). The ANN model tions. The results show that these optimum cell parameters
uses a feed-forward neural network with an error back-pro- deliver the highest maximum power density under different
pagation algorithm. The ANN is trained using experimental constraints on the anode support thickness, porosity, and
data as a black-box without using physical models. The electrolyte thickness.
developed model is able to predict the performance of the
SOFC. An optimization algorithm is utilized to select the Keywords: Artificial Neural Network, Genetic Algorithm,
optimal SOFC parameters. The optimal values of four cell Modeling, Optimization, SOFC
FUEL CELLS 12, 2012, No. 1, 11–23 © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 11
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
ORIGINAL RESEARCH PAPER
These are based on data obtained from experimental mea- relationships is then optimized by considering the uncertain-
surements or physical models. In addition, GAs are used to ties presented in Ref. [16].
select optimal points in a design space according to the prin- A hybrid system combining SOFCs and gas turbines
cipals of natural selection and genetics. They are powerful (SOFC/GT) is optimized by the GA with and without CO2-
tools for solving a variety of optimization problems with dis- capture in Ref. [17]. In this research, the electrical efficiency is
continuous, non-differentiable, or highly nonlinear objective selected as the objective function, and the airflow, fuel flows
functions. (main and supplementary), cell voltage in the stacks, air tem-
The application of ANNs in SOFC modeling is used to pre- perature at the stack inlet, reformer duty, and pressure ratio
dict the performance of the physical model, as it was are the decision parameters.
employed in Refs. [8] and [9]. In both studies, multi-layer The genetic programming and RBF neural network
feed-forward networks are trained with a back-propagation approach are used to model and simulate the static and
algorithm to learn the performance parameters of the SOFC. dynamic behavior of the SOFC stack presented in Ref. [18]. A
The simulation results show good agreement with the physi- physical model is used to generate the training data and test
cal models. However, the cell parameters of the SOFCs are data in this research [18]. The results of the genetic program-
not considered as inputs or outputs to the ANN models. ming show significant improvement compared to those of the
Entchev and Yang [10] used real data from a 5 kW system RBF neural network. The cell parameters and their optimiza-
to model the SOFC performance of residential micro-genera- tion are not considered.
tion installations by means of an ANN. Real data about the The porous electrodes of an anode-supported proton-con-
SOFC’s start-up, steady-state, and shut-down operations ducting SOFC are optimized by a GA with a physical model
were applied to train the ANN. The input parameters to the in Ref. [19]. The porosity and particle diameter distributions
ANN included the temperatures of the stack, burner combus- of the electrodes are designed for the maximum performance,
tion, air inlet components, and relevant mass flow rates for but the characteristics of the materials and layers of the SOFC
the stack and burner components. The output parameters used in this study are completely different with those pre-
were the stack current and voltage. The most efficient net- sented in the current paper.
work is chosen after testing several network architectures. The market demands fuel cells with high output and good
A radial basis function (RBF) ANN based on GAs is pro- durability. Performance of SOFCs is the most important fac-
posed as a GA-RBF model to simulate SOFC performance tor in the development plan. Anode-supported SOFCs are
[11–13]. Wu et al. used two datasets of current density and one of the promising fuel cell configurations with high per-
cell voltage in 3 and 9 bars from another model as training formance. These SOFCs as planar single cells generally con-
data at 800 and 1,000 °C [11, 12]. The RBF neural network has sist of five layers: an anode support layer (ASL), an anode
an input layer with two nodes, a nonlinear hidden layer with functional layer (AFL), an electrolyte layer, a cathode func-
three nodes and a linear output layer with one node. A com- tional layer (CFL), and a cathode current collector layer
parison between their predictions and the experimental data (CCCL). The anode layer is often made of nickel and yttria-
is shown along with the precision of their successful predic- stabilized zirconia (Ni/YSZ), and YSZ is used as the electro-
tions in Ref. [11, 12]. A hybrid experimental model, consisting lyte material. A composite cathode material is produced from
of an improved RBF neural network model and a pressure- strontium-doped lanthanum manganite and YSZ (LSM/
incremental model, is presented in Ref. [13]. This model can YSZ). The geometrical and physical properties of these layers
predict the stack voltage at any current density at different play major roles in both the performance and the strength of
temperatures and partial pressures of hydrogen, oxygen, and a single cell of the SOFC. Research on these multilayer struc-
water. tures of better performance are reported in Refs. [20–23].
In Ref. [14], the performances of single cells of an SOFC In this paper, a statistical, data-driven approach is used to
are modeled by the ANN using experimental data in the optimize the performance of a single cell of an SOFC using a
steady state condition, and the ANN is trained with a back- hybrid architecture employing both an ANN and a GA. The
propagation algorithm. Different ANN architectures are used optimal parameters of the single cell (i.e., anode support
to model and investigate the cell’s operating conditions, thickness, anode support porosity, electrolyte thickness, and
including current density, cell temperature, oxidant composi- functional layer cathode thickness) are successfully deter-
tion, and fuel composition. The cell geometrical parameters, mined for a singular, intermediate-temperature, anode-sup-
such as electrolyte thickness, anode thickness, and anode po- ported SOFC under different constraint conditions.
rosity are also considered. The ANN model is shown to be
predicting the cell voltage with relatively high accuracy.
A hybrid model with mathematical and ANN relation- 2 Modeling and Optimization Methodology
ships for optimal concurrent SOFC system design is intro-
duced in Ref. [15]. In this optimal design procedure, the tem- For modeling a single cell of SOFC and optimization of the
perature and the partial pressure of hydrogen input to the performance on cell parameters, a hybrid method of using
SOFC stack are calculated as design variables. A new para- artificial intelligence techniques is employed. Firstly, an ANN
metric design approach with neural network and fuzzy-logic is developed to model the relation between the SOFC param-
12 © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 12, 2012, No. 1, 11–23
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
FUEL CELLS 12, 2012, No. 1, 11–23 www.fuelcells.wiley-vch.de © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 13
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
Fig. 3 Comparison of I–V curves for standard cell by ANN model and experimental data from [23].
14 © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 12, 2012, No. 1, 11–23
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
MPD Max: IV
Fig. 4 Comparison of I–V curves for anode support thickness changes at 800 °C by ANN model and experimental data from [23].
FUEL CELLS 12, 2012, No. 1, 11–23 www.fuelcells.wiley-vch.de © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 15
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
ORIGINAL RESEARCH PAPER
Fig. 5 Comparison of I–V curves for anode support porosity changes at 800 °C by ANN model and experimental data from [23].
Fig. 6 Comparison of I–V curves for electrolyte thickness changes at 800 °C by ANN model and experimental data from [23].
Figure 5 presents the cell voltage versus current density In Figure 6, it can be seen that the cell voltage versus cur-
curves of the ANN predictions and the experimental data at rent density curves with electrolyte thickness dependence
800 °C as the anode support porosity is varied from 32 to 76% modeled by the ANN compares well with the experimental
and the RMSE and SEP of the model are 0.0161 and 2.426%, data at 800 °C. The electrolyte thickness ranges from 4 to 20.
respectively. The ANN results describing the changes in performance
with electrolyte thickness are in good agreement with the
16 © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 12, 2012, No. 1, 11–23
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
Fig. 8 Comparison of I–V curves for optimized cell by ANN modeling and experimental data from [23].
experimental data with an RMSE of 0.0075 and an SEP of In Figure 8, voltage–current density curves are plotted for
1.1733%. the optimal cell from the ANN model and compared with
Figure 7 shows I–V curves of the cells at 800 °C from the experimental data at temperatures of 600, 700, and 800 °C.
ANN and experimental data as the functional layer cathode The RMSE is 0.0108, and the SEP is 1.5841%.
thickness changes from 6 to 105. The RMSE is 0.0166, and the The ANN can model the SOFC performance with accepta-
SEP is 2.6767%. ble accuracy. The results clearly show the ability of the ANN
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Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
ORIGINAL RESEARCH PAPER
model as an efficient tool for predicting the effect of the cell (i.e., anode support thickness, anode support porosity, elec-
parameters on its performance. trolyte thickness, and functional layer cathode thickness). Fig-
ures 9–12 show the effects of the changes of the cell parame-
ters on its performance. The cell parameters are studied in an
4 Results and Discussion OVAT approach. The values of constant parameters are men-
tioned in the caption of each figure.
In this section, the results of using the ANN model for spe-
Figure 9 shows the cell performance at 800 °C as the anode
cific ranges of SOFC parameters are discussed. Then, the opti-
support thickness changes from 0.25 to 2.50 mm. The ANN
mized outputs from the GA are compared with the other
model predicted the performances of cells with anode thick-
published experimental and analytical results.
nesses of 0.25, 0.75, 1.25, 1.75, and 2.50 mm. It can be seen that
higher ASL thickness reduces the cell performance.
4.1 Parametric Study
Figure 10 presents the cell voltage versus current density
The ANN model can simulate the cell voltage versus cur- curves at 800 °C as the anode support porosity varies from 35
rent density curves for different values of the cell parameters to 75%. The maximum performance is predicted at 65%.
Fig. 9 I–V curves for anode support thickness changes at 800 °C by ANN model prediction (ASL porosity = 48%; electrolyte thickness = 8 lm; CFL thick-
ness = 20 lm).
Fig. 10 I–V curves for anode support porosity changes at 800 °C by ANN model prediction (ASL thickness = 1.0 mm; electrolyte thickness = 8 lm; CFL
thickness = 20 lm).
18 © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 12, 2012, No. 1, 11–23
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
Fig. 11 I–V curves for electrolyte thickness changes at 800 °C by ANN model prediction (ASL porosity = 48%; ASL thickness = 1.0 mm; CFL thick-
ness = 20 lm).
Fig. 12 I–V curves for functional layer cathode thickness changes by ANN model prediction (ASL porosity = 48%; ASL thickness = 1.0 lm; electrolyte
thickness = 8 lm).
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Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
Table 3 Optimized cell parameters by ANN and GA, and the other methods from [20–23], the optimized values are highlighted.
ORIGINAL RESEARCH PAPER
Methods: ANN and GA Experimental [20] Modeling [21] Modeling [22] Experimental [23]
ASL thickness (mm) 0.5–1.5 1.500a) 1.000a) 1.000a) 0.5
ASL porosity (%) 50–76 n/a 50a) 48a) 57
AFL thickness (lm) 20a) 5–10a) 20a) 10–20 20a)
Electrolyte thickness 4–8 5–10a) 10a) 8a) 8
(lm)
CFL thickness (lm) 6–39 30 15 20–40 20
CCCL thickness (lm) 50a) 50–60 85 200–300 50a)
Performance 1.1–2.2 W cm–2 at 800 °C ~1.50 A cm–2 at 800 °C, ~0.70 W cm–2 at 700 °C Average current density: ~1.8 W cm–2 at 800 °C
700 mV 0.41 A cm–2 at 700 °C
a)
Constant values.
n/a: not available.
Fig. 13 I–V curves predicted by the ANN model for optimized sets of parameters, [ASL thickness (mm); ASL porosity (%); electrolyte thickness (lm); CFL
thickness (lm)], obtained by the GA (see cell No. 1–3 in Table 4 for lower and upper bounds of GA search space).
the specifications of single cells shown in the literature thickness [20–23]. These constraints are applied to the GA
require at least 1 or 1.5 mm ASL thickness, less than 50 or optimization to obtain the results shown in Table 4 and the
57% ASL porosity, and more than 8 or 10 lm electrolyte simulated I–V curves by ANN model in Figures 14 and 15.
20 © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim www.fuelcells.wiley-vch.de FUEL CELLS 12, 2012, No. 1, 11–23
Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
Fig. 15 I–V curves predicted by the ANN model for optimized sets of parameters, [ASL thickness (mm); ASL porosity (%); electrolyte thickness (lm); CFL
thickness (lm)], obtained by the GA (see cell No. 8–10 in Table 4 for lower and upper bounds of GA search space).
The changes to the CFL thickness show that this parameter is the GA optimization predict that the optimal CFL thickness is
dependent on the values of the other parameters in Table 4, close to that of the optimal cell from Zhao and Virkar’s work
while the other three parameters (ASL thickness, porosity, [23] under the same conditions. Also, it can be seen in Table 4
and electrolyte thickness) tend to extremal points (minimum, that the optimal CFL thickness is in very good agreement
maximum, and minimum values, respectively). The results of with those brought in Ref. [20] under similar conditions.
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Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
5 Conclusion Subscripts
ORIGINAL RESEARCH PAPER
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Bozorgmehri, Hamedi: Modeling and Optimization of Anode-Supported Solid Oxide Fuel Cells
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