Professional Documents
Culture Documents
Transport Phenomena
Space lattice, crystal structure of ionic, covalent and metallic materials. Crystallographic directions and
planes. Points defects, dislocations and twin, grain-boundaries, Structure of silicates and polymers. Solid
solution and intermetallic compounds. Binary phase diagrams of important ferrous and non-ferrous alloys
and related microstructures. Elements of ternary diagrams.
1. K.M.Ralls, T.H.Courtney and J.Wulff, Introduction to Materials Science and Engineering, Wiley Eastern,
1978.
2. V.Raghavan, Physical Metallurgy Principles and Practice, Pretice-Hall (India), 1983.
3. J.F.Schackelford, Introduction to Materials Science for Engineers, 2nd Ed., Macmillan, 1988.
4. V. Raghavan, Materials Science and Engineering: A first course, 3rd ed. Printice-Hall of India, 1990.
S.S. Rao, Optimisation � Theory and applications, Wiley Eastern Ltd., 1978.
R.L. Fox, Optimization Method for Engineering Design, Addison Wesley, 1970.
JM. Kupfer Schmind and J.G. Ecker, Introduction to Operations Research, John Wiley & Sons, 1988.
Fracture Mechanics and Failure Analysis
Fracture criteria, Introduction to linear elastic fracture mechanics, Analysis of simple crack problems.
Nucleation and propagation of cracks. Correlation between microstructure and fracture behaviour in
different materials. Mechanisms of fracture. Evaluation of fracture toughness. Crack behaviour in elastic
plastic materials. Effect of strain rate, environments temperature, irradiation etc. on fracture behaviour of
materials. Conventional approach to fatigue crack growth in reactive environments, static or cyclic loading.
Applications of fracture mechanics to materials selection, alloy design, design of structures and failure
analysis.
T.L. Anderson, Fracture Mechanics: Fundamentals and Applications, CRC Press, Inc., 1995
S.T. Rolfe and J.M. Barsom, Fracture and Fatigue Control in Structures, Butterworth-Heinemann, 1999
S.R. Lampman, (Technical Ed.), ASM Handbook: Fatigue and Fracture, ASM International, 1996
David Broek, Elementary Engineering Fracture Mechanics, Scjtoff & Noordhoff, 1978.
Case Histories in Failure Analysis, ASM, Ohio, 1979.
Brian Lawn, Fracture of Brittle Solids, Cambridge University Press, 1993.
Computational Methods for Metal Forming Analysis
Description of generalized stress / strain behaviour. Principal quantities; Mohrs circle; Elastic vs. plastic
deformation. Theories of yielding; Analysis of metal forming processes by ideal work, upper bound and
slab methods. Analytical modeling approach for simulating axi-symmetric deep drawing process. Concept
of formability and forming limit strains. Applications of computational methods for metal forming analysis.
Application of FE based programs for metal forming analysis. Experimental measurements of loads and
strains during tensile and formability testing of variety of materials (low carbon steel, aluminum and
stainless steel). Development of a computation model for tensile test simulation and its validation.
Simulation of tensile and metal forming tests using computational programs based on finite element
methods. Comparison of computed results with the experimentally measured data. Simulation and
validation of industrial metal formed components.
R.H. Wagoner and L. Chenot, Metal Forming Analysis, Cambridge University Press, 2001.
W.F. Hosford and R.M. Caddell, Metal Forming: Mechanics and Metallurgy, 2nd Ed., Prentice-Hall, 1993.
G.W. Rowe, C.E.N. Sturgess, P. Hartley and I. Pillinger, Finite Element Plasticity and Metal Forming
Analysis, Cambridge University Press, 1991.
C.R. Calladine, Plasticity for Engineers, Ellis Horwood, 1995.
Mechanical Behavior of Thin Films
Elasticity basics: Stress and strain tensors, tensor transformations, Mohr†™s circle representation of stress
and strain, constitutive equations. Origin of stresses in thin films: thermoelastic mismatch between film and
substrate, lattice mismatch in heteroepitaxial films, recrystallization, phase transformation, incorporation
of atoms and chemical reactions. Application of the above for designing structures with low stresses.
Experimental techniques for measuring stresses/strains in thin films: Substrate curvature; Stoney†™s
equation, methods for curvature measurement, X-ray diffraction, nanoindentation, bulge test, 4-point bend
test, and microtensile test. Models for high stresses, strain-hardening rates and Bauschinger effect in thin
films, influence of grain size, film thickness and interfaces.
1. Thin film materials: stress, defect formation and surface evolution. L. B. Freund, S. Suresh, Cambridge
University Press, 2003
2. Materials Science of Thin Films. M. Ohring, Academic Press, 1992.
3. Mechanical Metallurgy. G. E. Dieter, McGraw-Hill, 1986.
Materials & Processes for Semiconductor Devices
Pre-requisite: MM 474 and MM 372 Elemental and compound semiconductor materials, structural,
electronic and optical properties. Theory of basic processing techniques: crystal growth, diffusion,
oxidation, ion implantation, rapid thermal processing, epitaxy, chemical vapour deposition, and physical
vapour deposition, metallization, the physics and chemistry of nonequilibrium plasmas. Emphasizes plasma
etching.The interrelationship between material properties, fabrication techniques and device performance.
S. Cambell, The Science & Engineering of Microelectronic Fabrication, Oxford, 1996.
S.K. Ghandi, VLSI Fabrication Principles, 2nd Edition, Wiley 1994.
Pierret/Neudeck, Modular Series and Solid State Devices, Vols. 1-5, Addison-Wesley, 1984.
J.L. Vossen and W. Kern, Thin Film Processes, Academic Press, 1978.
S.P. Mauraka and M.C. Peckerar, Electronic Materials Science and Technology, Academic Press, 1989.
Diffusion and Kinetics
Introduction. Ficks laws of diffusion. Analytical and numerical solutions. Diffusion in semi-infinite, finite
and composite media. Chemical Kinetics. Order of reactions. Homogeneous reactions. Heterogeneous
reactions Adsorption, gas-solid reactions. Examples: Carburisation, Diffusion in semiconductors, Diffusion
through a stagnant gas film, Diffusion in thin films and multilayers, reactions in CVD processes, oxidation,
reduction, decomposition etc. Atomistic models of diffusion. Random walk model. Diffusion mechanisms.
Kirkendall effect. Homogeneous and heterogeneous nucleation. Grain growth and coarsening. TTT
diagrams. Precipitation. Spinoidal decomposition. Diffusion in ionic solids. Diffusion along surfaces and
interfaces. Sintering of particles.
J. Crank, Mathematics of Diffusion, Oxford University Press, 2nd Ed., 1979.
J.M. Smith, Chemical Engineering Kinetics, McGraw-Hill, 3rd Ed., 1981.
P. Shewmon, Diffusion in Solids, Minerals, Metals & Materials Soc., 1989.
R.J. Borg and G.J. Dienes, Introduction to Solid State Diffusion, Academic Press, 1997.
R.W. Balluffi, S.M. Allen and W.C. Carter, Kinetics of Materials, John Wiley, 2003.
Plastic Deformation and Microstructure Evolution
Molecular theory of deformation kinetics. Rate theory of plastic deformation. Micormechanistic approach
for deformation behaviour of single crystals and polycrystals. Low temperature deformation of metals and
other crystalline colids. Dynamic strain aging, creep, internal stress. Deformation of intermetallic
compounds. Substructural evolution at large strains. Recovery, recrystallization and grain growth during
high temperature deformation. Formation cells boundaries, slip in a cell structure and composite model of
time dependent flow.
R.W. Cahn, P.Haasen and E.J. Kramer(eds), Materials Science and Technology, Vol6,
Plastic DEformation and Fracture of materials, H. Mughrab i(vol.ed.), VCH,1993.
G. Krasus(ed.), Deformation, Processing and Structure, ASM, 1984.
S. Krausz and H. Eyring, Deformation kinetics, JohnWiley and Sons, 1975. T.N. Baer(Ed.,),
Yield, flow and fracture of Polycrystals, Applied Science Publishers Ltd., 1983.
R.J. Arsenault(Ed.) PLastic Deformation of Materials: Treatise on Materials Science and Technology,
Vol.6, Academic Press, 1975.
X-Ray Diffraction and Electron Microscopy
Introduction: to X-rays, filters. Atomic Scattering factors and structure factor. Intensity Calculations.
Reciprocal Lattice. Ewald spehre construction. Techniques for structure determination. Point groups. Space
groups. Systematic absences due to symmetry elements. Wyckoff Notation. Fourier series methods. Phase
prolem. Patterson Function. Heavy atom methods. Anamolous scattering. Finite size effects. Intensity
distribution in reciprocal space. Particle size determination for polycrystalline samples. Introduction to
electron microscopy, electrons and their interactions with the specimen, electron diffraction. TEM-
construction, contrast mechanisms and some applications. Analytical microscopy. SEM.
L.C. Azaroff, Elements of X-ray Crystallography, McGraw Hill, NY, 1968.
F.D. Bloss, Crystallography and Crystal Chemistry, Holt, Rinehart and Winston, NY, 1971.
G. Thomas and M.T.Goringe, Transmission Electron Microscopy of Materials, John Wiley, 1979.
M.V. Heimendahl, Electron Microscopy of Materials - An Introduction, Academic Press, 1980.
Topics in Phase Transformations
Gibbs free energy composition diagrams, Analysis and synthesis of phase diagrams. Solid-solid mucleation
theory. Interface and diffusion and kinetics of phase separation. Order-disorder transformations.
Crystallography of martensitic transformation. Transformations of rapidly solidified alloys and glasses.
Phase stability in advanced ceramics. High pressure phase transformations. Phase transformations in Steels.
H.I. Aaronson(ed.) Lectures on the theory of Phase transformation, The Metallurgical Society(AIME),
Warrendale, Pennysylvania, 1975.
J.W. Christian, " Theory of Transformations in Metals and Alloys", Pergamon Press, 1965.
P.Haasen(Ed.), Phase Transformations in Materials, VCH Publishers Inc, New York,1991.
T.J. Gray and V.D. Frechette, "Kinetics of REactions in Ionic Crystals", Plenum Press, 1969.
A.G. Khachaturyan," Thoery of Structural Transformations in Solids", Wiley Interscience Publishers,1983.
A.M. Alper, "Phase Diagrams:Material Science and Technology", Vol6, Academic Press, 1978.
Materials for Corrosion Prevention at High Temperatures
Choice of materials based on their mechanical strength, creep, fatigue and toughness. Microstructural
stability and corrosion resistance. General properties and application of various steels, ODS alloys, rapidly
solidified materials, single crystals, intermetallics, refractories and composite materials. Need for protective
coatings at high temperature, Diffusion coatings, PVD and CVD coatings, ion-plating ion sputtering,
electron beam coatings, laser glazing and laser alloying.
E. Bullock et al, Research and Development of High Temperature Materials for Industry, Elsevier Sci.,
1989.
O. Van Der Biest, Analysis of High Temperature Materials, Appl. Sci. Pub., 1986.
E. Lang, Editor, Coatings for High Temperature Applications, Appl. Sci. Pub., 1983.
Nanomaterials for Advanced Electrochemical Energy Storage and Conversion
302225 Brief introduction to nanomaterials 302225 Overview of the basic characteristic differences
between nanomaterials and more conventional materials 302225 Brief overview of the electrochemical
interfaces at the nano-level (in more general terms) 302225 Overview of the various types and architectures
of nanomaterials with relevance to applications in energy storage/conversion devices (including carbon
nanostructures, oxide nanostructures, metallic nanostructures, polymer nanostructures, nanocomposites,
various 0D, 1D, 2D, 3D nano-architectures) 302225 Introduction to the working principles and importance
of advanced electrochemical energy storage and conversion devices (Li-ion batteries, supercapacitors, fuel
1 cells)302225 Materials characteristics/properties required for use as electrode and electrolyte materials
(covering aspects right from effects of crystal structures, crystallographic orientations, effects of different
dimensions at different scales, overview of the effects of nanoscaled dimensions, dimensional/structural
stability during operation, surface areas/properties, issues related to diffusivity, relevant mechanical and
physical properties including electrical conductivity)302225 Advantages of nanomaterials with respect to
such characteristics as well as special beneficial aspects of nanostructured materials (improvements in the
relevant material properties and concomitantly performance in terms of energy densities, power/rate
capabilities, cycle life, design considerations, safety aspects and other relevant details)302225 Problems
associated with the synthesis of nanomaterials and their use in electrochemical energy storage/conversion
devices and ways to overcome such limitations302225 Nanomaterials presently in use in the energy
storage/conversion devices302225 Potential nanomaterials and nanostructures deemed to further enhance
the functionalities significantly302225 Current state and necessities for continuing fundamental research
on fabricating/designing nanomaterials for such applications.
Text/References: Since this is an advanced level course that not only deals with the basics but also
elaborates cutting edge research developments, in addition to some text books mentioned here (relevant to
the basics), a significant portion will be covered from various research reports, articles and review papers.
Few review articles are mentioned below, and copies of more research/review articles relevant to the more
specific sections to be covered in the course will be handed over to the students during the course. Text
books: 1) Nanostructured materials for electrochemical energy production and storage; by Leite, Edson
Roberto (Ed.); New York: Springer (2009) (available in Institute library) 2) Fundamental studies connected
with electrochemical energy storage; by E.Buck; Washington, DC: NASA (1975) (available in Institute
library) 2 3) Lithium Ion Batteries302227Fundamentals and Performance;by W. Wakihara, and O.
Yamamoto (eds);Kodansha-Wiley-VCH, Weinheim (1998) 4) Electrochemical Supercapacitors; by B. E.
Conway; Kluwer Academic/Plenum; New York (1999) 5) Fuel cells: from fundamentals to applications;
by Supramaniam Srinivasan; Springer Science + Business Media; New York (2006)Journal (review)
articles (Institute has online access to all): 1) A. S. Arico, P. Bruce, B. Scrosati, J. M. Tarascon, W. V.
Schalkwijk; Nanostructured materials for advanced energy conversion and storage devices. Nature
Materials 4 (2005) 366-377 2) J. M. Tarascon, M. Armand; Issues and challenges facing rechargeable
lithium batteries. Nature 414 (2001) 359-367 3) C. Arbizzani, M. Mastragostino, S. Soavi; New trends in
electrochemical supercapacitors. Journal of Power Sources 100 (2001)164302226170 4) E. Frackowiak, F.
Beguin; Carbon materials for the electrochemical storage of energy in Capacitors. Carbon 39 (2001)
937302226950 5) S. Srinivasan, R. Mosdale, P. Stevens, C. Yang; Fuel cells: reaching the era of clean and
efficient power generation in the twenty-first century. Annu. Rev. Energy Environ. 24 (1999)
281302226238.
MM 673 - Concepts in Materials Science
Network structure of various oxide glasses, Stevel�s parameters and kinetic criterion of glass formation.
Role of oxides in glass composition. Melting, refining and forming of oxide glasses. Viscoelastic behaviour
and mechanical properties. Thermal, dielectric and optical properties of glasses. Coloured and
photosensitive glasses; glass fibre technology. Glass-ceramics, glasses for electronic applications.
Preparation of metallic glasses by rapid solidification. Synthesis of amorphous alloys by mechanical
alloying. Properties and applications of amorphous alloys. Microcrystalline and nanocrystalline materials.
H. Scholze, �Glass: Nature, structure and Properties� Springer-verlag, N.Y, 1991. J. Zarzycki, �Glasses
and the Vitreous State�, Cambridge Univ. Press, Cambridge 1991. S.J. Schneider Jr., �Ceramics and
Glasses� Engineered Materials Handbook, Vol.4, ASM Int. Ohio 1991. F.H. Froes and S.J. Savage (Eds.)
�Processing of structural Metals by Rapid Solidification�, ASM Pub., Ohio 1987. H.H. Liebermann (Ed),
�Rapidly Solidified Alloys�, Marcel Dekker Inc., N.Y., 1993. C. Arzt and L. Schulte (Eds), �New
Materials by Mechanical Alloying Techniques�, Deutsche Gesellschaft fur Metalkunde (DGM) Germany,
1989.
MME691-Topics in Phase Transformations
Gibbs free energy composition diagrams, Analysis and synthesis of phase diagrams. Solid-solid mucleation
theory. Interface and diffusion and kinetics of phase separation. Order-disorder transformations.
Crystallography of martensitic transformation. Transformations of rapidly solidified alloys and glasses.
Phase stability in advanced ceramics. High pressure phase transformations. Phase transformations in Steels.
H.I. Aaronson(ed.) Lectures on the theory of Phase transformation, The Metallurgical Society(AIME),
Warrendale, Pennysylvania, 1975. J.W. Christian, " Theory of Transformations in Metals and Alloys",
Pergamon Press, 1965. P.Haasen(Ed.), Phase Transformations in Materials, VCH Publishers Inc, New
York,1991. T.J. Gray and V.D. Frechette, "Kinetics of REactions in Ionic Crystals", Plenum Press, 1969.
A.G. Khachaturyan," Thoery of Structural Transformations in Solids", Wiley Interscience Publishers,1983.
A.M. Alper, "Phase Diagrams:Material Science and Technology", Vol6, Academic Press, 1978.
MME695-High Temperature Corrosion
Low temperature vs high temperature corrosion. Introduction to oxidation, thermodynamics of gas/metal
reaction, stability of oxides/sulphides. Ellingham diagrams; oxidation kinetics 302226 linear, parabolic,
cubic, logarithmic rate laws, Wagner302222s theory of oxidation. Types of oxidation: general oxidation,
selective oxidation, internal oxidation, breakaway and catastrophic oxidation; defects in oxides (p&n type),
Wagner Hauffe Rules, Kroger Vink notations; oxidation vs sulphidation, hot-corrosion, oxidation of
important metals and alloys; Use of electron-optical techniques in assessing oxidation damage and
understanding oxidation mechanism. Practical examples of high temperature oxidation 302226 power
plants, gas turbines, petrochemical plants etc.
Per Kofstad, High Temperature Corrosion, Elsevier Applied Science, 1988.U.R. Evans, Corrosion and
Oxidation of Metals, Arnold Publ., London, 1981.N. Birks and G.H. Meier, Introduction to Oxidation of
Metals, Edward Arnold, London, 1983.A.S. Khanna, Introduction to High Temperature Oxidation and
Corrosion, ASM International, Materials Park, Ohio, 2002.
MME699-Corrosion Laboratory
Metallographic sample preparation and microstructural examination using optical microscope of steels,
brasses, aluminum alloys, titanium alloys. Potential and pH measurements; weight loss measurements;
determination of electrochemical kinetic parameters (Tafel extrapolation), passivity and pitting studies;
illustration of role of inhibitors, galvanic corrosion, intergranualr corrosion tests: ASTM A 262 A and EPR
techniques; Demonstration of stress corrosion cracking tests : U-bend, slow strains rate and constant load
tests. High temperature oxidation kinetics of Cu, steel & SS at 500oC; characterization of oxide layers using
optical, SEM/EDS (surface morphology & cross-section); study of bimetallic diffusion couples. Surface
preparation and application of paint coatings; characterization: thickness, impact, hardness, adhesion and
corrosion performance evaluation using salt spray, UV-weatherometer and EIS. References:
MME703-Materials Science for Corrosion Engineers
Classification of materials, Bonding in materials and crystal structure, Phase diagrams : General concepts
in binary diagrams, Fe-Cr, Fe-Ni-Cr classification of alloys, ferrous and non-ferrous alloys, Heat treatment:
concept of hardening, annealing, quenching, tempering, Thermomechanical treatment etc., surface
hardening treatment. Solidification and its effect. Mechanical behaviour of materials; Stress strain concept
of deformation; true stress true strain dislocations, Frank-read source, elastic and plastic behaviour, role of
defects in mechanical properties, treatment of various mechanical tests such as hardness, impact, tensile
tests with theoretical principles. Strengthening mechanism, solid solution strengthening, precipitate
strengthening, work hardening etc. Fatigue of materials: Types and mechanism of creep, Development of
creep resistant materials, low and high cycle fatigue and mechanism of fatigue. Fracture of materials:
Griffith’ s theory and fracture mechanics, fracture toughness, Analysis of fractographs in relation to mode
of fracture.
L.H. Van Vlack, Elements of Materials Science and Engineering, 6th Ed., Addison-Wesley, 1989.S.H.
Avner, Introduction to Physical Metallurgy, 2nd Ed., McGraw-Hill, 1974.
MME706-Control of Erosion and Wear in Corrosive Environment
Principles of friction and wear. Mechanism of adhesive and abrasive, corrosion and erosive wear. Rebinder
effect Fretting and fatigue, fundamentals of erosion and erosion-corrosion and corrosion resistance,
requirements for high temperature coatings, principles of CVD, PVD, plasma spraying, carburizing, and
nitriding, ion implantation, laser surface alloying, life prediction of coated surface, economic consideration
and future coatings requirements.
Friction, Lubrication and Wear technology, ASM Metals Handbook, Vol 18, 9th edition, Ohio,
1992.Hutchings, I.M., Tribology-Friction & Wear of Engineering Materials, Edward Arnold 226 Great
Britain, 1992.
MME708-Cathodic Protection Engineering
Fundamentals of cathodic protection, types of cathodic protection systems and anodes. Surveys, design of
anode ground beds. Life time calculations, rectifier selection. Stray current corrosion problems and its
prevention. Coating for various cathodic protection system and their assessment.
Applegafe Z.M, Cathodic Protection , McGrowHill, New York, 1960. Morgan, Cathodic Protection, ,
NACE, Houston, 1987.
MME709-Surface Engineering of Engineering Materials
Significance, design of surface layers based on mathematical modeling, rational application of surface
layers, significance of the surface, the surface ? physico-chemical concepts, interphase surface ? a physical
surface, surface energy, surface phenomenon, the superficial surface structure, potential properties,
stereometric-physico-chemical parameters, residual stresses, adsorption, tribological properties, types of
friction, the role of surface in the friction process, electrochemical nature of surface layers ? electrical
structure of surface layer, corrosion resistance, anti corrosion properties, structure of metallic coatings,
adhesion, hardness, ductility (elasticity), service properties, anti corrosion properties, porosity, bulging,
permeability, prevention ? coatings and formation of technological surface layers, techniques of formation
(mechanical, thermo-mechanical, thermal, thermo-mechanical, electrochemical and chemical), electron
beam technology, Laser technology, implantation techniques (ion implantation), glow discharge methods
and CVD technology, vacuum deposition by physical techniques (PVD) for surface modification.
1.011T. Burakowski and Wierzchon, Surface Engg. of Metals Principles, Equipments, Technologies, CRC
Press, Boca Raton London New York, Washington, 1999.2.011Bockris, JOM, Reddy, A.K.N., Modern
Electrochemistry, Plenum/Rosetta Edition, New York, 2000.3.011Fontana M.G., Corrosion Engineering,
3rd ed., McGraw Hill, New York, 1986.
MME710-Fracture Mechanics and Non Destructive Evaluation
Deformation, Defects & Fracture, Detection & Characterization of Defects using, NDT Techniques,
Introduction to LEFM & EPFM, Micro-structural Aspects of Fracture Toughness, Environmental Assisted
Cracking, Determination of Toughness Parameters, Quantitative NDE & Analysis of Engg. Failures,
Fitness for Purpose and Life Extension.
1.011T.L. Anderson, Fracture Mechanics: Fundamentals and Applications, CRC Press, Inc. USA,
1995.2.011D. Hull, Fractography, Cambridge Univ. Press, U.K. 1999.3.011Rechard W. Hertzberg,
Deformation & Fracture Mechanics of Engineering Materials, John Wiley & Sons, USA, 1989. 4.011NDE
and Quality Control Metals Handbook, Published by ASM, Metals Park, Ohio, vol. 17, 1989.
MME712-Advances in Design and Control of Corrosion
Design of field and laboratory experiments, Galvanic, Pitting and Crevice corrosion, Intergranular
corrosion, Stress corrosion cracking and Corrosion fatigue. Application of optical, scanning electron and
transmission electron microscopes, X-ray diffraction, EPMA, Auger and Photo electron spectroscopy.
Influence of composition and microstructure and their control and materials selection. Design involving
Geometry, Fabrication such as welding, piping system and plant layout for corrosion prevention. Treatment
of water for recirculating systems. Cathodic Protection: principle, classification - sacrificial and impressed
current, types of anodes, soil surveys, life estimation of anodes, rectifiers-selection criteria, stray current
corrosion, monitoring of CP - pipelines and offshore structures. Anodic protection : Principles and
applications Failure analysis : Principles and detailed methodology, case studies from various industrial
failures.
C.R. Pludek, Design and Corrosion control, Macmillan, London, 1977. S.K. Couburn, Corrosion Source
book, ed. NACE and ASM Metals Park Ohio, 1984. Corrosion Vol. 13, Metals Hand book 9th edition,
Ohio: 1987. Failure Analysis and Prevention, Vol. 11, Metals Handbook, 9th edition, Ohio 1986.
MME713-Aqueous Corrosion and its Control
Importance and cost of corrosion, thermodynamics of corrosion, passivation, Pourbaix diagram, mixed
potential theory of corrosion and its application to understand the influence of oxidizers, effect of velocity
of the medium, galvanic corrosion: area relationship in both active and passive states of metals.
Computation of corrosion rateDifferent forms of corrosion and their control viz., uniform corrosion,
galvanic corrosion, selective leaching, crevice corrosion, filliform corrosion, pitting corrosion,
intergranular corrosion, erosion corrosion, fretting damage, stress corrosion cracking, corrosion fatigue,
hydrogen embrittlement and microbes induced corrosion.Corrosion testing procedures, inhibitors, cathodic
protection, anodic protection, materials selection.
Corrosion Engineering, 3rd Ed., Mars G. Fontana, * McGraw-Hill, Singapore, 1987.* Corrosion and its
Control, 3rd Ed., H.H. Uhlig and R.W. Revie, John Wiley, Singapore, 1991.* Stress corrosion cracking
302226 Theory and Practice, V S Raja and T Shoji (eds), Woodhaed Publishing Limited, Oxford, 2011,*
Corrosion Failures: Theory, Case Studies and Solutions, K.E. Perumal and V.S. Raja; John Wiley & Sons,
USA 2.
MME714-Fracture and Failure Analysis of Composites
MME717-Electrochemical Materials Science
1. The scope of electrochemistry in development of advanced materials and devices. i) Structure of metals,
single crystal surfaces, metal & semiconductor band structure ii) Electrochemical cell, Electrode potential,
Standard electrode potential, Thermodynamics of electrochemical reaction, Nernst equation, Reference
electrode, Pourbiax diagram, electrochemical efficiency. 2. The electrode-solution interface Ideally
polarizable electrodes ; The Gouy– Chapman theory, The Helmholtz capacity; The potential of zero charge;
The semiconductor-electrolyte interface; Potential profile and band bending; Thermodynamics of
electrode-electrolyte interface; 3. Electrochemical kinetics: Polarization, Butler – Volmer equation, Tafel
equation, Linear polarization, Mass transport effect. 4. Electrochemical processing of Materials: Scope,
state-of-the-art and opportunity. Overview of electrochemical processing methods. i) Electrodeposition,
principles & mechanism, nucleation and growth, Microstructure Control of Plated Films, Additives,
Electrodeposition of alloy, Electrodeposition of metal and semiconductor nanostructures, electrodeposition
into template. Electroless deposition. UPD, EPD, Applications in semiconductor and magnetic recording
industry and corrosion protection. ii) Electrochemical Atomic Layer Epitaxy (ECALE) iii) Electrochemical
dissolution: principle of electrochemical dissolution of metals, formation and properties of anodic Porous
Alumina, AAT synthesis of nanowires and nanotubes, Anodization of semiconductors, nanoporous metals
and semiconductor electrodes, porous Si, TiO2 & ZnO2 iv) Aqueous Processing of Metals: Electrowinning
and Electrorefining 5. Electrochechemical devices: Principle and operation of energy storage and
conversion devices. Efficiency of electrochemical devises, factors affecting efficiency of electrochemical
devices, Electrochemical capacitor, principle and operations; Fuel cell, types of fuel cell, Battery, Dye
sensitized solar cell, Materials requirement for electrochemical devices, Electrochemical sensors and
actuators, detection principles, sensitivity, factors affecting sensitivity, examples and biosensors.
Electrocatalyst.
1. Fundamentals of Electrochemistry, 2nd Edition Vladimir S. Bagotsky (Editor), John A. Wiley & Sons.
2. Electrochemistry for Materials Science; Walfried Plieth; 2008 Elsevier Science 3. Nanostructured
Materials in Electrochemistry, Ali Eftekhari, 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
MME718-Laser Processing and Nanostructures
Fundamentals of Laser, Continuous and pulsed Laser concept, Laser safety and best practices,
Fundamentals of Laser Material Interactions, Introduction to Nanotechnology, Nanomaterials,
Semiconducting and metallic nanoparticles, Synthesis/fabrication techniques of Nanomaterials, Laser
induced synthesis of nanoparticles, Laser fabrication of Nanostructures for energy and bio applications.
1)Fundamentals of Photonics (by Saleh and Teich, Wiley Interscience, 2nd edition, 2007); 2)Laser
Electronics (by J T Verdeyen, Prentice Hall, 3rd Edition, 1995) 3)Nanophotonics (by P N Prasad,Wiley
Interscience, 2004)
MME719-Introduction to Ab-initio Methods in Materials Modelling
Pair potentials, Variational principles, Born-Oppenheimer Approximation, Hartree Approximation,
Hartree-Fock Approximation, Introduction to Molecular Dynamics, Introduction to Density Functional
Theory, Case studies.
1) Electronic Structure and the properties of Solids: The Physics of the Chemical Bond-Walter A Harrison
(Dover Publications, Inc.) 1989
2) Electronic Structure: Basic Theory and Practical Methods-Richard M. Martin (Cambridge University
Press) 2004 3)Plane Waves, Pseudopotentials, and the LAPW method-David J. Singh and Lars
Nordstorm (Springer) 2nd edition.
MME720-Organic Semiconductors and Devices
Introduction; Fundamental of organic semiconductors (Bonding, Conjugation, Hybridization, Electronic
structure); Charge injection and transportOptical phenomenon (light emission/absorption) and their
processingFilm deposition techniquesStructure-property relationshipsPatterning, Printing,
EncapsulationElectro-optical devices (Organic Light emitting diodes, thin film transistors, photovoltiacs,
memory, sensors)
1)Hagen Klauk, 302223Organic Electronics: Materials, Manufacturing and Applications302224, Wiley-
VCH, 20062)Wolfgang Bruetting, 302221Physics of Organic Semiconductors302222, Wiley-VCH, 2005
MME721-Fatigue, Creep and Superplasticity
Materials response to cyclic loading, Types of fluctuating cycles, Fatigue parameters, Fatigue testing, S-N
curve, Low cycle and high cycle fatigue, Manson-Coffin law, Basquin model, Fatigue crack nucleation and
crack growth, Fatigue damage accumulation theory, Effect of metallurgical variables. Case studies on
fatigue of structural materials and some medical implants. Thermal activation processes, Creep, Creep
testing, Creep curves, Factors affecting creep deformation, Creep mechanisms, Deformation mechanism
maps, Stress rupture, Case studies on creep of superalloys and other high temperature materials,
Superplasticity, Grain boundary sliding, Cavity nucleation and growth, High strain rate superplasticity,
Superplastic forming.
1)T.H. Courtney, Mechanical behavior of materials, 2nd edition (2005), Waveland Press Inc., USA. 2)M.A.
Meyers and K.K. Chawla, Mechanical behavior of materials, 2nd edition (2009) Cambridge University
press, UK. 3)S. Suresh, Fatigue of materials, 2nd edition (1998) Cambridge University press, UK. 4)ASM
handbook, Mechanical testing and evaluation, Volume 8 (2000). 5)D. Caillard, J.L. Martin, Thermally
activated mechanisms in crystal plasticity, 1st edition Volume 8 (Pergamon materials series) (2003)
Elsevier science Ltd., UK. 6)J.P. Poirier, Creep of crystals: High temperature deformation processes in
metals, ceramics and minerals, (1985/Reprint-2005) Cambridge University press, UK (&USA). 7)K.A.
Padmanabhan, G.J. Davies, Superplasticity: Mechanical and structural aspects, environmental effects,
fundamentals and applications (materials research and engineering) (1980) Springer-Verlag, NY, USA.
8)T.G. Nieh, J. Wadsworth, O.D. Sherby, Superplasticity in Metals and Ceramics, (1997/2005) Cambridge
University press, UK. 9)Selected scientific publications/review articles.
MME725-Tribology of Materials
This course will start with analytical solutions of contact stresses and deformations at surfaces and delve
on various wear mechanisms: adhesive, abrasive, fatigue, impact, chemical and fretting wear.
Macromechanical vs micromechanical tribology processes will be contrasted and ways of quantifying wear
will be discussed. Use of coatings as a way to reduce wear will be discussed in detail with respect to
deposition processes and coating structures, characterization of coatings and selection. Engineering design
for wear, effect of microstructure and wear induced microstructural change will be discussed in detail for
metals, polymers, ceramics and composites. Case studies will be used to highlight critical design criteria
for wear.
Raymond G. Bayer: Engineering Design for Wear, CRC Press, 2004, 2nd edition. Bharat Bhushan:
Introduction to Tribology, Wiley, 2013, 2nd edition. Kenneth Holmberg, Allan Matthews: Coatings
Tribology, Elsevier, 2009, 1st edition.
MME726-Corrosion Management and Modeling
General management approach for effective and economical corrosion control: Basis of corrosion
management, tools of corrosion management, organizational policies and their implementation. Importance
of design, application and implementation of effective corrosion control methodologies, corrosion
monitoring, maintenance and inspection and their importance in corrosion management. Risk based design
and inspection for industrial components. Role of failure analysis and its importance in corrosion
management by using its input in better design and control policies. Modeling tools, mathematics for
modeling, finite element approach. Illustrations in modeling corrosion life prediction. Corrosion modeling
to predict the effectiveness of corrosion control measures. Prediction of current and potential distributions
under different conditions and strategies. Application of corrosion modeling in: oil and gas applications,
cathodic protection design, inhibitors applications, stress corrosion cracking and corrosion fatigue,
electrochemical corrosion, and coatings of components and structures to predict their performance. Design
of corrosion in concrete. Prediction of components life against high temperature corrosion: Fick’ s Law
and its application.
Guidance for corrosion management in oil and gas production and processing, Energy Institute, London,
2008. · Practical Corrosion Management, IDC Technologies, Australia, United States · External corrosion
management Inspection project, A report by the Offshore Division of HSE’ s Hazardous Installations
Directorate · Modeling of Aqueous Corrosion, A. Anderko, OLI Systems Inc., 108 American Road, Morris
Plains, NJ 07950, USA, Elsevier B.V. 2010. · Corrosion Modeling in Research Opportunities in Corrosion
Science and Engineering, National Academic Press 2011.
MME727-Corrosion in Oil & Gas, Refineries & Petrochemical Industry
Definition of highly aggressive environment, sour and sweet environments, materials requirements for
offshore structures, refineries, petrochemical plants, X-40 to X120 steels for pipelines, high corrosion
resistant materials such as superaustenitic, superferritic, Duplex stainless steels and special superalloys,
design of corrosion resistant storage tanks, tank linings and cathodic protection, transportation of crude and
gas, underground cross country pipelines, phenomena of corrosion in crude gas pipelines, complex
combination of pH, water cut, oil, carbon dioxide and H2S, external corrosion prevention by coatings and
cathodic protection, methods of corrosion monitoring of pipelines, PSP surveys, Pearson surveys,
intelligent pigging, ultrasonic and other NDT methods, SCADA system. Corrosion of offshore structures,
corrosion problems during deep well drilling, inhibitor dosing to water injection pipelines. Corrosion
problems in refineries and petrochemical industries: review of typical environments of various units such
as, hydrodesulphurization unit, distillation columns, fluid catalytic cracking units, reformers. Naphthenic
acid corrosion, sulphidation and sulphidic corrosion, carbon dusting. Storage tanks corrosion and
prevention.
Metallurgy and Corrosion Control in Oil and Gas Production, Robert Heidersbach, Wiley 1st Edn., 2011. ·
Corrosion and Materials in the Oil and Gas Industries, Reza Javaherdashti (Editor), Chikezie Nwaoha
(Editor), Henry Tan (Editor) CRC Press 2013. · Corrosion in the Petrochemical Industry, Linda Garverick
(Ed.), ASM International, 1994.
MME728-Topics in Corrosion Research
Passivity and localized corrosion Experimental techniques for Corrosion research Mechanisms of SCC and
hydrogen embrittlement and concepts in materials development against such failures and life prediction
Presentation of recent papers in corrosion research by students Advanced concepts in coatings development
and evaluation Advanced materials for high temperature applications, selection criteria based upon
mechanical properties. Materials for gas turbines, supercritical power plants Advanced concepts in coating
failure, practical approaches to determine life of coatings, failure mechanisms and remedial measures.
Corrosion mechanisms, Florian Mansfeld (Ed), New York: Marcel Dekker, 1987 · Corrosion mechanisms
in theory and practice, P. Marcus and J. Oudar (Eds), New York: Marcel Dekker, 1995 · Electrochemical
techniques in corrosion science and engineering. Kelly, Robert G (Ed), New York: Marcel Dekker, 2003. ·
Stress corrosion cracking – Theory and Practice, V S Raja and T Shoji (Eds); Woodhead Publishing
Limited, Oxford, 2011.
MME729-Characterization of Materials for Corrosion Control
Corrosion fundamentals and characterization techniques, Electrochemical techniques for
corrosionmonitoring, Electrochemical polarization techniques, Electrochemical noise, Electrochemical
Impedancespectroscopy, Gravimetric techniques, Electrical resistance techniques, Sensors for corrosion
monitoring,Cathodic protection monitoring, Localized corrosion monitoring methods 302226 SECM,
SVET, drop cell, SCCmeasurement techniques, Surface analytical techniques.
CB21 6AH, England, 2008.302267 Practical Non-destructive Testing, Baldev Raj, T. Jayakumar and M.
Thavasimuthu, NarosaPublications, New Delhi, 1997.302267 Non-destructive Evaluation and Quality
Control, ASM Handbook, Vol. 17, Ohio, 1989.
MME730-Topics in Mechanical Behaviour of Materials
Metallographic sample preparation and microstructural examination using optical microscope of steels,
brasses, aluminum alloys, titanium alloys. Potential and pH measurements; weight loss measurements;
determination of electrochemical kinetic parameters (Tafel extrapolation), passivity and pitting studies;
illustration of role of inhibitors, galvanic corrosion, intergranualr corrosion tests: ASTM A 262 A and EPR
techniques; Demonstration of stress corrosion cracking tests : U-bend, slow strains rate and constant load
tests. High temperature oxidation kinetics of Cu, steel & SS at 500oC; characterization of oxide layers using
optical, SEM/EDS (surface morphology & cross-section); study of bimetallic diffusion couples. Surface
preparation and application of paint coatings; characterization: thickness, impact, hardness, adhesion and
corrosion performance evaluation using salt spray, UV-weatherometer and EIS.
Electrochemical techniques in corrosion science and engineering, R. G. Kelly, J. R. Scully, D. Shoesmith,
R. G. Buchheit, Marcel Dekker, New York, 2003. · Electrochemical techniques for corrosion engineering,
R. Baboian, NACE, Houston, 1986. · Introduction to high temperature oxidation and corrosion, A.S.
Khanna, ASM International, 2002. · High Performance Coatings, A.S.Khanna (editor), Woodhead
Publication, 2008.
MME731-Experiments in Advanced Materials Processing (Lab)
Induction melting and electroslag remelting, Formability tests, Rolling of metals, Powder processing,
Solgel processing, Thin film deposition, Evaluation of castings and moulding sand.
K.Tien and J.F. Elliott (Eds.), Metallurgical Treatises, Metall. Soc. AIME, 1981. · G.E. Dieter, Mechanical
Metallurgy, McGraw-Hill, 3rd Ed., 1988. · G.A. Higgerson, Experiments in Materials Technology,
Affiliated East-West Press, 1973.
MME732-Structural Characterization of Materials
Optical microscopy – different modes of microscopy, image analysis Scanning electron microscopy –
secondary electron and backscattered electron imaging, EDS/EPMA X-ray diffraction – indexing of XRD
patterns, Intensity calculations, particle size effects, lattice parameter determination.
B. D. Cullity and S. R. Stock, Elements of X-ray Diffraction, Prentice Hall; 3 ed., 2001 R. Egerton, Physical
Principles of Electron Microscopy: An Introduction to TEM, SEM, and AEM, Springer, 1st ed. 2005 R.
Haynes, Optical Microscopy of Materials, Springer, 1984
MME 733-Mechanical Characterization of Materials
Axial (tension and compression) testing of materials. Torsion test. Bend test (bulk and thin films). Hardness
(Macro, Micro and Nano – Indentation). Scratch and wear test. Fracture (Impact test). Fatigue test. Creep
and superplasticity.
Reference/Textbook W.F. Hosford, Mechanical Behavior of Materials, Cambridge University Press, 2005.
MME 734-Electrical Characterization of Materials
Conductivity measurements (bulk and thin films) – 2 and 4 probe measurements in metals, semiconductors
and insulators. Hall effect, mobility, carrier concentration measurements. AC measurements – impedance
and dielectric. Various sources – grain, grain boundary, space charge, electron. Activation energy. Optical
measurements – band gap in semiconductors. Absorption measurements, photoconductivity,
photoluminescence for defects. Ellipsometry. Work function measurement – UPS, metal-semiconductor
contacts, Kelvin probe. IR and Raman spectroscopy. Ferro-electric and ferro-magnetic measurements.
Peter Stallinga, Electrical Characterization of Organic Electronic Materials and Devices, Wiley, NJ, 2009
Laszlo Solymar, Donald Walsh, Electrical Properties of Materials, Oxford University Press, 8th Ed., 2010
MME 735-Material Chracterization at High Temperatures
Importance of High temperature measurements-relevance to Materials Processing, Basic principles of
measurements at high temperature: Temperature measurement (thermocouples, optical pyrometers), gas
flow and composition, importance of gas cleaning, detection of trace constituents (e.g. oxygen sensing),
means to attain high temperature, requirement of special atmosphere, choice of crucible/sample container,
Thermal analysis: DTA, DSC, TGA, dilatometry, Measurement of Thermodynamic parameters:EMF
measurement, equilibration with gas mixtures, iso-piestic method, special methods, Concept of “ capacity”
of a slag: e.g. sulphide, phosphate, carbonate, alkali, etc., Thermophysical measurements:density, viscosity,
interfacial tension, thermal conductivity, Particle characterisation: pycnometry, BET analysis, porosimetry,
Case studies.
1. Treatise in Process Metallurgy (3 vol.s): Ed. S. Seetharaman, Elsevier Publications, 2013. 2. O.
Kubachewski & C. B. Alcock, Metallurgical Thermochemistry:, Pergamon Press, 1979. 3. T. Allen, Particle
Size Measurement:, Springer, 1990.
MME737-Physical Metallurgy
Crystal structures of metals and alloys, Defects – vacancies, dislocations, stacking faults, twins, grain
boundaries, Interstitial and substitutional solid solutions, Solidification – Homogenous and heterogeneous
nucleation, Precipitation – JMA growth kinetics, Recovery, recrystallization and grain growth, Case
studies – Age hardenable Al-Cu alloys, Phase transformations in Fe-C etc.
Reza Abbaschian, Lara Abbaschian, Robert E Reed-Hill, Physical Metallurgy Principles, Fourth Edition,
Wadsworth Publishing Co Inc, 2008
MME738-Physics of Materials
Crystal Structures and Reciprocal Lattice, Free-electron model – electron gas, Fermi-Dirac distribution,
Fermi surface, Band theory of solids – Bloch Theorem , Brillouin zone, Kronig Penney model, Band gap
and Bragg reflection, effective mass, holes, Conductivity of metals Semiconductors – Intrinsic and
extrinsic semiconductors, carrier concentration, electrical conductivity and mobility, Hall effect, direct and
indirect band gap. Dielectric and optical properties – absorption and optical properties of semiconductors,
Dielectric constant, polarizability, sources of polarizaility- dipolar, ionic, electronic. Complex dielectric
constant, dielectric losses,
1. Ali Omar, Elementary Solid State Physics, Pearson Education; First edition (1999)
2. A. J. Dekker, Solid State Physics, Macmillan Publishers India (2000)
MME739-Semiconductor Photoelectrochemistry and Photocatalysis
Semiconductor Surfaces and Solid-Solid Junctions, Solid-Liquid Interface, Theory of Electron and Hole
Transfer, Charge Transfer Processes at Semiconductor-Liquid Interfaces, Photoreactions at Semiconductor
Particles, Electron Transfer Processes Between Excited Molecules and Semiconductor Electrodes,
Semiconductor electrodes and their interaction with light, Kinetic aspects in photoelectrochemical solar
cells, Materials engineering: General considerations, Choosing a photoelectrode, Photostorage of solar
energy in colloidal semiconductor systems, Redox catalysis in photochemical and photoelectrochemical
solar energy conversion systems, Effect of organized assemblies on electron transfer reactions and charge
separation processes, Photocatalytic reactions of organic compounds. Hydrogen generation from organics
and degration of wastes, Heterogenous photocatalysis: overview on the water splitting, CO2 reduction and
dinitrogen reduction.
1. Semiconductor electrochemistry, Rudiger Memming, Wiley publishers, Germany, 2008
2. Photoelectrochemisry, photocatalysis and photoreactors, Mario Schiavello, Springer Science, Germany,
1987
3. Semiconductor photoelectrochemistry, Yuri Pleskov & Yuri Gurevich, Consultants Bureau, NewYork,
1986.
MME740-Silicon Manufacturing Technology Laboratory
Four probe resistivity of silicon, edge effects and possible errors. . Hall measurement: determine dopant
concentration of various silicon samples. . Minoritycharge carrier life time measurement of bulk carriers.
• Photo Luminiscent (PL) mapping of charge carrier life times in wafers and ingots. • Optical defect
visualisation using etching techniques. • Crystal growth from melt – I (effect of pull rate) • Crystal growth
from melt – II (effect of temperature profile). • . Crystal growth from melt – III (impurity effects). • .
Zone refining. • Cleavage of single crystal and determination of cleavage surface morphology, orientation.
• Measurement of average size of the grains and their SDF for the polycrystalline Silicon sample • Safety
and precautions standards measurements of the working lab.
Dieter k. Schroder, SEMICONDUCTOR MATERIAL AND DEVICE CHARACTERIZATION, A. John
Wiley & Sons, Inc., publication, 2006.
MME741-Introduction to Silicon Manufacturing Technology
Thermodynamics essentials- (2-3L) Gibb’ s phase rule, chemical potential of a gas, chemical potential of
saturated vapor pressure of liquids and solids, dilute solutions, many component solutions, activity and
activity coefficients, law of mass action, phase diagrams, general equation for solidus and liquidus lines.
Precursor Manufacturing- (5-7L) production methodologies of MG-Si, trichloro silane (TCS),
dichlorosilane, silicon tetra chloride, and silane. Thermodynamic properties, surface tension, viscosity and
thermal conductivity of these precursors. Corrosion rates of materials of constructions. Health hazards and
safety precautions for gases: handling, storage, distribution, uses, exhaust and effluent control, monitoring
and safety systems. Polysilicon preparation (semiconductor grade)- (5-7L) TCS based process, Bell jar
reactor design and operation, silicon rod based deposition, wire (Re-W, W-Ta, Zr-Nb, Ti-Zr, or carbon
added Molybdenum wires >0.5 mm US Patent 7732012B2) based deposition, advantages and disadvantages
of the two methods, general practices of reactor gas recovery, capital and operating costs, feed stock
considerations, free space reactors, fluidized bed reactors (FBR). • Multicrystalline silicon manufacturing-
(3-4L) Directional Solid System (DSS) method for multicrystalline ingots. • Silicon crystal growth- (10-
12L) Melt growth theory, heat balance, dislocations and point defects, crystal growth mechanisms. Mass
transport of impurities: equilibrium distribution coefficient of impurities, effective distribution coefficient
as a function of pull velocity v and /D ( solid – liquid interface width, D is diffusion coefff.),
microscopic variation in doping, convective instability, macroscopic distribution of impurities.
Constitutional supercooling: reasons, conditions to avoid. Practical aspects of CZ growth- crystal pullers,
melting methods, crucibles, dislocation free growth. Growth forms and habits, diameter control, doping
techniques, variation in radial resistivity, effect of orientation. O2 and C in Si: techniques to control O2 and
C. Semi continuous and continuous CZ: schematic, Magnetic CZ, square ingot growth. Float zone (FZ)
technique Metrology: Course seminars/assignments, applications, charactrerizations • Tutorial
simulations- (12 L) 1-D simulation of CZ growth using MATLAB, problems related to the syllabus.
Junctions: p-n junction in equilibrium, forward and reverse biased p-n junction, I_V
characteristics, break down, transient and switching behavior, Junction geometry and
capacitance, Rectifier, zener and tunnel diodes, BJT, I-V Characteristics, switching
behavior, small signal model, JFET and MOSFET devices # Low dimensional
Semiconductors: Quantum well structures, quantum wires and quantum dots, Exciton
absorption, saturation and carrier transport in quantum well structures # Quantum
Devices: LEDs, Charge and optical confinements, Device response, drive circuits,
Stimulated emission as a basis of lasers, Cavity and modes, Diode lasers, DFB and DBR
lasers, VCSEL lasers, quantum well lasers, quantum cascade laser, Single photon
generators, quantum well modulators and switches, p-n junction solar cells, Junction
photodiodes- PIN APD , Single photon detectors, CCDs and optical imaging,
superconductivity, cooper pair, Josephson junction, SQUID, Magnetic storage devices,
electron spin and spintronics.
Physics of semiconductor devices- S. M. Sze Physics of optoelectrnic devices- S. L.
Chuang Optoelectronics- J. Wilson and J. F. B. Hawkes- Prentice hall of India.
EP 432 - Physics of Nanostructures and nanoscale Devices
Electrons in semiconductor hetero-structures: band offsets, effective mass;
semiconductor hetero-junctions, 2-DEG systems, quantum wires and quantum dots;
Transmission in nanostructures: tunneling in planar barrier, resonant tunnel diodes,
Landauer formula, transport in quantum waveguide structures; single electron
tunneling and Coulomb blockade. Electron transport in devices: Schottky diodes, p-n
junction diodes, short diodes; bipolar and field-effect transistors, MOSFETS, effect of
size reduction, short channels; scaling down to nanosizes, FINFETS; issues with
nanoscale devices.
Sapoval S and Herman C, Physics of Semiconductors, Springer International Edition,
2006. Ferry D K and Goodnick S M, Transport in Nanostructures, Cambridge University
Press, 1997. Datta S, Electronic Transport in Mesoscopic Systems, Cambridge
University Press, 1995. Davies J H, Physics of low Dimensional Semiconductors,
Cambridge University Press, 1998. Colinge J P and Colinge C, Physics of Semiconductor
Devices, Springer International, 2007. Neamen D A, Semiconductor Physics and
Devices, TataMcGraw-Hill, 3rd Edition, 2003. Singh Jasprit, Semiconductor Devices,
Basic Principles, John Wiley & Sons Inc, 2001. Sze S M, Semiconductor Devices, Wiley-
India, 2008. Hess K, Advanced Theory of Semiconductor Devices, IEEE Press, Prentice-
Hall of India, 2000.
EP 411 - Analytical Techniques in Physics
The students will be expected to undertsand the basic principle of working and also
carry out analysis of samples in a few simple cases, with the following techniques.
Atomic absorption and emission. X-ray diffraction and fluorescence. NMR, ESR, ESCA
and Auger. Absorption in visible and infrared. Raman Scattering, Photo-acoustic
detection Nitrogen and tunable dye lasers, Electron microscopy.
EP 425 - Introduction to Nanoscience and Nanotechnology
Structure and bonding in Nanoparticles: Electronic structures in Bulk and
Nanoclusters. Magic clusters; Magic number, Geometric structures, electronic
structures. Theoretical modeling of nanoparticles: Fullerenes, Carbon Nanotubes and
Graphenes. Free electrons in Bulk and Nanoparticles. Size and Dimensionality effects:
Eelectronic energy bands in semiconductors; electron energy states in quantum
confined systems. quantum wires, quantum dots; excitons in semiconductor particles
and its size dependence. Absorption and Luminisence in nanoparticles. Electron
transport and size scaling in nanoparticles. Size dependence of properties:
Introduction to Mie theory with applications to nanoparticles; surface plasmons in
noble metal nanoparticles, Magnetic nanoparticles, Superparamagnets. Mechanical
properties and size scaling. Nanoparticles in Colloids.
Poole C P and Owens F J, Introduction to Nanotechnology, Wiley-Interscience 2003.
Cao G, Nanostructures and Nanomaterials: Synthesis, properties and applications,
Imperial College Press 2004. Reich S, Thomsen C and Maultzsch J, Carbon Nanotubes
– Basic concepts and physical properties, Wiley-VCH 2004. Bohren C F and Huffman D
R, Absorption and scattering of light by small particles, Wiley Interscience Paperback
series, 1998. Gaponenko S V, Optical properties of semiconductor Nanocrystals,
Cambridge University Press, 1998.
PH 803 - Computer Programming and Numerical Methods
Basics in computing : Basic organization of computer and its functional units; Exposure
to Unix operating system. Fortran 90 programming language : Conditional statements;
Looping; Logical expression and case statement; Arrays; Modular programming using
functions and subroutines; Format specifications and processing strings and
characters; Processing files in Fortran 90 ; Dynamic memory allocation and pointers.
Numerical methods: Statistical description of data: Mean, Variance and Skewness.
Solution of algebraic and transcendental equation : bisection method, the method of
false position, Newton Raphson method. Interpolation. Integration of functions :
Trapezoidal rule, Simpson`s 1/3 method; Least squares fit; Sorting; Matrices : Matrix
inversion and evaluation of determinant by elimination method. Solution of ordinary
differential equation : Runge-Kutta method, Predictor-corrector method. Random
Numbers and Monte Carlo Integration. Elementary Graphics : Using gnuplot and xmgr
packages to visualize data.
V. Rajaraman, Computer Programming in Fortran 90 and 95, Prentice Hall India, 1997.
S. J. Chapman, Introduction to Fortran 90 and 95, McGraw Hill, Int. Ed., 1998 . S. E.
Koonin and D. C. Meredith, Computational Physics, Addison-Wesley, 1990. W. Cheney
and D. Kincaid, Numerical Mathematics and Computing, 4th Ed, Brooks/Cole, 1999.
PH 416 - Soft Matter Physics
Basic phenomenology, Liquid crystals, polymers, membranes, surfactants, colloids,
gels. Phase transitions, Landau theory, order parameter (conserved and
nonconserved), nucleation and spinodal decomposition. Nematic liquid crystals, Mean
field theory for isotropicnematic transition, LandaudeGennes theory, Effect of spatial
gradients, Onsager’ s theory for isotropicnematic transition. Polymers, random walk,
gaussian chain, excluded volume, Flory theory, Deforming polymer chains,
Temperature effects, Field theories and RG approach, solutions, melts, dynamics –
Rouse and Zimm. Membranes and interfaces – Free energy and shape transitions. Flow
and deformation of soft matter, mechanical properties and molecular models, colloids
– rheology and dimensional analysis, viscoelasticity and response functions. Optional:
• Elastic soft matter, Fundamentals, Kuhn theory of rubber elasticity, polymer gels.
Physics of jamming, Supercooled liquids, and search for a transition, Jamming phase
diagram for glasses, foams, and granular matter.
M. Doi, Soft Matter Physics, Oxford University Press, 2013 • P.M. Chaikin & T.C.
Lubensky, Principles of Condensed Matter Physics, Cambridge University Press, 2000
• M. Rubinstein & R.H. Colby, Polymer Physics, Oxford University Press, 2003 • P.G. de
Gennes & J. Prost, The Physics of Liquid Crystals, Oxford University Press, 1995 • M.
Doi & S.F. Edwards, The Theory of Polymer Dynamics, Oxford University Press, 1988 •
P.G. de Gennes, Scaling Concepts in Polymer Physics, Cornell University Press, 1979 •
W.B. Russel, D.A. Saville, W.R. Schowalter, Colloidal Dispersions, Cambridge University
Press, 1989.
PH 432 - Condensed Matter Physics
Crystal structures, reciprocal lattice, X-ray and electron diffraction. Lattice vibrations,
Einstein and Debye models, phonons. Drude and Summerfeld models. Block theorem,
Empty lattice and nearly free electron model, tight-binding model, Density of states
and Fermi surfaces. Semi classical model of electron dynamics. Concept of Effective
mass.
N. Ashcroft and N.D. Mermin, Solid state physics C. Kittel, Introduction to solid state
physics, 7th ed., John Wiley 1997. J.R. Christman, Fundamentals of Solid State Physics.
John Wiley 1988 Holf Finehart and Winston, 1972.
PH 522 - Theoretical Condensed Matter Physics
Elementary theory of groups and their representation, application solid state physics.
Electronic state in solids. Hartree and Hartree-Fock approximation. Free electron,
exchange, pseudopotential theory. Cohesive energy of simple metals. Energy bands
and their symmetries. Magnetism: Heisenberg exchange and magnetic ordering,
magnetic resonance and relaxation. Superconductivity: Microscopic theory,
Josephson effect, flux quantization.
W. Harrison, Solid State Theory Tata McGraw Hill. N. Ashcroft and N.D. Mermin, Solid
State Physics, Holt, Rinehart and Winston, 1972. J. Ziman, Principles in the Theory of
Solids, Cambridge.
PH 810 - Advanced Simulation Techniques in Physics
Basic Numerical Methods and Classical Simulations : Review of differentiation,
integration (quadrature), and finding roots. Integration of ordinary differential
equations. Monte Carlo simulations, applications to classical spin systems. Classical
Molecular Dynamics. Quantum Simulations : Time-independent Schrodinger equation
in one dimension (radial or linear equations). Scattering from a spherical potential;
Born Approximation; Bound State solutions. Single particle time-dependent
Schrodinger equations. Hartree-Fock Theory : restricted and unrestricted theory
applied to atoms. Schrodinger equation in a basis: Matrix operations, variational
properties; applications of basis functions for atomic, molecular, solid-state and
nuclear calculations. Mini-projects on different fields of physics, e.g., Thermal
simulations of matter using Car-Parrinello molecular dynamics; Many-Interacting-
Particle Problems on Hubbard and Anderson model for electrons using Lanczos
method (exact diagonalisation) for the lowest states; Quantum Monte Carlo methods;
Computational methods for Lattice field theories; Microscopic mean-field theories
(Hartree-Fock, Bogoliubov and relativistic mean-field); methods in nuclear many-body
problems.
S. J. Chapman, Introduction to Fortran 90 and 95,McGraw Hill, Int. Ed. 1998. S. E.
Koonin and D. C. Meredith, Computational Physics, Addison-Wesley, 1990. Tao Pang,
An Introduction to Computationl Physics, Cambridge Univ Press, 1997. R. H. Landau
and M. J. P. Mejia, Computational Physics, John Wiley, 1997. J. M. Thijssen,
Computational Physics, Cambridge Univ Press, 1999. K. H. Hoffmann and M. Schreiber,
Computational Physics, Springer, 1996.
NT 401 - Introduction to Nanotechnology
Basic Solid State Physics-Crystal structures, size dependence of properties,
semiconductors, energy bands, excitons Measurement of properties-particle size,
TEM, SEM, STM, AFM, Spectroscopy and magnetic resonance Properties of individual
nanoparticles – Metal nanocrystals, magic numbers and theoretical modeling,
geometric structure, electronic structure, reactivity, magnetic clusters,
semiconducting nanoparticles, molecular clusters, carbon nanoparticles, synthesis
and characterization Bulk nanocrystals- synthesis methods thin film deposition,
multilayers, magnetic nanoparticles, spin valve, giant and colossal magnetoresistance,
ferrofluids Quantum wells, wires and dots – Basic quantum mechanics, Preparation of
quantum nanostructures, size and dimensionality effects, single electron tunneling,
applications- IR detectors, quantum dot lasers Self Assembly and Catalysis – self
assembly process, monolayers, surface area of nanoparticles, colloids, porous
materials Organic compounds and polymers-forming and characterization, size
effects, supramolecules, micelles Biological materials –biological building blocks, DNA
double nanowire, genetic code, biological nanostructures (proteins, miscelles and
vescilles), multilayer films, MEMS, NEMS – design, fabrication and applications.
1. Charles P Poole Jr. and Frank J Owens, Introduction to Nanotechnology, Wiley
(2003)
2. Hari Singh Nalwa (Editor), Nanostructured Materials & Nanotechnology Concise
Edition, Academic 2001
3. William A Goddard, Donald W Brenner, Sergey Edward Lyshevski, Goddard III,
Handbook of Nanoscience, Engineering, and Technology CRC Press, 2003
4. N. Peyghambrain., S.W. Koch and A. Mysyrowicz, Introduction to Semiconductor
Optics, Prentice Hall, 1993.
5. S.V. Gaponenko., Optical Properties of Semiconductor Nanocrystals, Cambridge
Univeristy Press, 1998.
6. David Sellmyer and R Skomski Ed., Advanced magnetic nanostructures, Springer,
2006 1997.
7. Gabriel O Shonaike, Suresh G Advani, Advanced Polymeric Materials CRC Press
2003.