Professional Documents
Culture Documents
CALYPSO WORKS.
A L U M I N I U M
A N D I T S A L L O Y S
THEIR PROPERTIES, T H E R M A L T R E A T M E N T
AND INDUSTRIAL APPLICATION
BY
C. G R A R D
LIEUTENANT-COLONEL D'ARTILLERIE
TRANSLATED BY
C. M . P H I L L I P S
(NATURAL SCIENCES TRIPOS, CAMBRIDGE)
AND
H. W. L. P H I L L I P S , B.A.(CANTAB,), A.I.C.
(LATE SCHOLAR OF ST. JOHN'S COLLEGE, CAMBRIDGE)
C O N S T A B L E & COMPANY L T D
io & 12 ORANGE STREET LEICESTER SQUARE WC 2
TRANSLATORS1 NOTE
FOR carrying out the numerous tests required for this work,
we have utilised the following Government laboratories:—
Le Laboratoire d'Essais du Conservatoire national des Arts
et Metiers (chemical analyses, mechanical tests).
Le Laboratoire d'Essais de la Monnaie et des MMailles
(chemical analyses).
Le Laboratoire de la Section technique de FArtillerie
(chemical analysis).
Le Laboratoire de l'Aeronautique de Ch&lais-Meudon
(mechanical tests and micrography).
The results, from which important deductions have been
made, possess, therefore, the greatest reliability.
We must also thank the following private laboratories:—
Les Laboratoires de la Soci6te Lorraine-Dietrich (heat
treatments and mechanical tests),
Les Laboratoires de l'Usine Citroen (mechanical tests and
micrography),
for the readiness with which they have placed their staflE and
laboratory material at the disposal of the A6ronautique. By
their assistance tests were multiplied, inconsistencies removed,
and the delays, incidental to the carrying out of this work,
minimised.
Thanks also to the courtesy of the Society de Commentry-
Fourchambault, M. Ghevenard, engineer to the Company,
has investigated, by means of the differential dilatometer of
which he is the inventor, the critical points of certain alloys,
whose thermal treatment (quenching and reannealing) is of
vital importance.
INTRODUCTION
BOOK I
ALUMINIUM
BOOK II
ALLOYS OF ALUMINIUM
_, PAOE
CLASSIFICATION 67
PART? III—LIGHT ALLOYS OF ALUMINIUM FOB CASTING
PUBPOSES 71
PART IV—LIGHT ALLOYS OF GREAT STRENGTH . . . 87
CHAPTKB
I. (a) VARIATION IN MECHANICAL PROPERTIES WITH AMOUNT OP
COLD WORK . . . . . . . . 89
(6) VARIATION m MECHANICAL PROPERTIES WITH ANNEALING
TEMPERATURE . . . . . . . . 91
II. QUISNCHING 96
Efect of Quenching Temperature . . . . . 95
Kate of Cooling . . . . . . . .101
Agoing after Quenching . . . . . . .103
III. VARIATION IN MECHANICAL PROPERTIES WITH TEMPERATURE
OF BEANNEAL AFTER QUENCHINa 110
IV. RESULTS or CUPPING TESTS AFTER VARYING TEERMAX TREAT-
MENT 114
V. HAKDNESS TESTS AT HIGH TEMPERATURES . . . .116
APPENDICES
APPENDIX
I. ANALYTICAL METHODS 147
II- EXTBACTS I'ROM THE FRENCH AERONAUTICAL SPECIFICATIONS
FOR Al/UMINIUM AND LlGHT ALLOYS 03? GitEAT STRENGTH . 151
HI. REPORT OF TESTS CARRIED OUT AT THE CONSERVATOIRE DES
ABTS ET METIERS ON THE COLD WORKING OF ALUMINIUM . 155
IV. REPORT OF THK TESTS CARRIED OUT AT THE CONSERVATOIRE DES
ABTS ET METIERS ON ANNEALING THIN SHEET ALUMINIUM
AFTBR. COLD WORK 158
V. BEPOBT OF TESTS CARRIED OUT AT THE CONSERVATOIRE DES
ABTS ET METIERS ON THE ANNEALING or THICK (10 in.)
SHBBT ALUMINIUM AFTER COLD WORK . . . .167
VI. PAPEB SUBMITTKD TO THE ACADEMIE DES SCIENCES BY LT.-COL.
GRARD, ON THE THERMAL TREATMENT OF LIGHT ALLOYS OF
GREAT STRENGTH . . . . . . . .174
LIST OF PLATES
Calypso Works Frontispiece
BOOK I
ALUMINIUM
PART I—PRODUCTION A
. OSTD METALLURGY
PLATE TO FACE PAGE
I Norwegian Nitrides and Aluminium Company . . . . 1 3
Photograph 1. Works at Eydehavn near Arendal
„ 2. Works at Tyssedal on the Hardanger Fjord
II. Saint Jean de Maurienne . . . . . . . 1 3
Photograph 1. Cylindrical dam
„ 2. Aqueduct across the Arc
III. Engine-room at Calypso . . . . . . . 1 3
PART II—PROPERTIES or ALUMINIUM
I AND II. Micrography of Aluminium . . . . . . 57
Photograph 1. Aluminium ingot, chill cast (K. J. Anderson)
„ 2. Aluminium ingot, sand cast (R. J. Anderson)
„ 3. Aluminium, cold worked (50 %)
„ 4. Aluminium, cold worked (100 %)
„ 5. Aluminium, cold worked (300 %)
„ C. Aluminium, cold worked (300 %) and subsequently
annealed at 350° for 10 minutes
„ 7. Aluminium annealod at 595° for 60 minutes (R. J.
Anderson)
„ 8. Aluminium annealed at 595° for 4 hours (R. J.
Anderson)
BOOK I I
ALLOYS OF ALUMINIUM
PART III—CASTING ALLOYS
III AND III A. Micrography of casting alloys . . . . . 8 6
Photograph 1. Copper 4 %, aluminium 96 %
„ 2. Copper 8 %, aluminium 92 %
„ .3. Copper 12 %, aluminium 88 %
4. Copper 3 %, zinc 12 %, aluminium 85 %
„ 3. Copper 11 %, tin 3 %, nickel 1 %, aluminium 85 %
xv
xvi ALUMINIUM AND ITS ALLOYS
PLATE TO FACE PAGE
PABT V—CUPRO-ALUMINIUMS
I. Micrography of cupro-almninium, Type I, forged and annealed 143
Photograph 1. As forged. x 60
„ 2. As forged. X225
„ 3. Forged and subsequntly annealed at 300°.
X60
„ 4. Forged and subsequently annealed at 300°.
X225
IB. Micrography of cupro-alummium, Type I, showing eutectic
structure . . . . ' . . . . .143
Photograph A. Etched with alcoholic FeCl3. X 500
(Portevin)
„ B. Etched with alcoholic FeCl3. X 870
(Portevin)
„ C. Etched with alcoholic FeCl3, showing cellular
and lamellar formations. x500 (Por-
tevin)
„ D. Etched with alcoholic FeCl3, showing eutectic
+ 7. Hypereutectoid alloy. X200
(Portevin)
II. Micrography of cupro-aluminium, Type I, forged and subse-
quently annealed. . . . . . . .143
Photograph 5. Forged and subsequently annealed at 700°.
X60
„ G. Forged and subsequently annealed at 700°.
X225
„ 7. Forged and subsequently annealed at 900°.
X60
„ 8. Forged and subsequently annealed at 000°.
X225
III. Micrography of cupro-aluminium, Type I, forged and subse-
quently quenched . . . . . . .143
Photograph 9. Forged and subsequently quenchod from
500°. xCO
„ 10. Forged and subsequently quenched from
500°. X225
„ 11. Forged and subsequently quenched1 from
600°. x 60
„ 12. Forged and subsequently quenched from
600°. X225
IV. Micrography of cupro-aluminium, Type I, forged and eubso-
quently quenched (Breuil) . . . . . .143
Photograph 13. Forged and subsequently quenchod from
700°. x (50
„ 14. Forged and subsequently quenched from
700°. x 225
„ 15. Forged and subsequently quenched from
800°. x 60
„ 16. Forged and subsequently quenchod from
800°. X 225
LIST OF PLATES xvii
PLATE TO PACE PAGE
V. Micrography of cupro-aluminiura, Type I, forged and subse-
quently quenched (Breuil) . . . . . .143
Photograph 17. Forged and subsequently quenched from
900°. X 60
„ 18. Forged and subsequently quenched from
900°. X225
VI. Micrography of cupro-alumiraium, Type I, forged, quenched,
and reannealed . . . . . . . . 144
Photograph 19. Forged, quenched from 900°, reannealed at
300°. x 60
„ 20. Forged, quenched from 900°, reannealed at
300°. X 225
„ 21. Forged, quenched from 900°, reannealed at
600°. x 60
„ 22. Forged, quenched from 900°, reannealed at
600°. x 225
VII. Micrography of cupro-aluminium, Type I, forged, quenched,
and reannealed . . . . . . . .144
Photograph 23. Forged, quenched from 900°, reannealed at
700°. X 60
„ 24. Forged, quenched from 900°, reannealed at
700°. X 225
„ 25. Forged, quenched from 900°, reannealed at
800°. X 60
„ 26. Forged, quenched from 900°, reannealed at
800°. x225
VIII. Micrography of cupro-aluminium, Type I, cast and annealed . 144
Photograph 27. As cast. x 60
„ 28. As cast. x225
„ 29. Cast and annealed at 800°. X 00
„ 30. Cast and annealed at 800°. X 225
IX. Micrography of cupro-aluminium, Type I, cast and annealed . 144
Photograph 31. Cast and annealed at 900°. X 60
32. Cast and annealed at 900°. X 225
X. Micrography of cupro-aluminium, Type I, cast and quenehed 144
Photograph 33. Cast and quenched from 500°. X 60
„ 34. Cast and quenched from 600°. x 00
„ 35. Cast and quenched from 700°. X 00
„ 36. Cast and quenched from 800°. x 60
„ 37. Cast and quenched from 900°. x 00
XI. Micrography of cupro-aluminium, Type II, forged and an-
nealed . . . . . . . . . 144
Photograph 38. As forged. x 00
39. As forged. x225
„ 40. Forged and subsequently annealed at 800°.
X60
„ 41. Forged and subsequently annealed at 800°.
X225
h
xviii ALUMINIUM AND I T S AXLOYS
BOOK I
ALUMINIUM
BOOK II
ALLOYS OF ALTJMINIUM
T-i - PA.GE
iL.q_u.ili"briuin diagram of copper -aluminium alloys (Curry) . . 69
PART III—CASTING ALLOYS
*>• Hardbiess of aluminium at high temperatures (500 kg. load) . 73
"archness of aluminium-copper alloy (i % Cu) at high tempera-
"tixxes (50Oand 1000 kg.) 77
** * -Ha,r<fLness of aluminium-copper alloy (8 % Cu) at high tempera-
t u r e s (SOOand 1000 kg.) 77
KarcLness of alximiniurn-copper alloy (12 % Cu) at high tempera-
t u r e s (5 00 and 1000 kg.) 79
*i4. V a r i a t i o n in hardness with copper content (load 500 kg.) Tem-
peratures 0°, L00°, 200°, 300°, 350°, 4=00° . . . . 79
-*•*. H a r d n e s s of aluminium-zinc-copper alloy (12 % Zn, 3 % Cu) at
hxgfci temperatures (500 and 1000 kg. load) . . . . 81
• M#. H a r d n e s s of aluminium-copper-tin-nickel alloy (11 % Cu, 3 % Sn,
1 % iNi) at high temperatures (500 and 1000 kg. load) . . 83
•**. M o l t i n g -point cuive for zinc-aiurninium alloys . . . . 83
PART TV—LIOHT AXX.OYS OP GBEA.T STRENGTH
*^H. Teixsile test piece (thick sheet) 89
*M. T e n s i l e test piece (thin sheet) 89-
1 f). "Vttiriation. in mechanical properties (tensile and shock) of duralumin
w i t h cold wort. Metal previously annealed at 450° and cooled
i n air. Test pieces cut longitudinally to direction of rolling . 90
•* I« Variation in mechanical properties (tensile and shock) of duralumin
wifch cold work. Metal previously annealed at 450° and cooled
i n air. Test pieces cut transversely to direction of rolling . . 91
4 2. Var-iation in mechanical properties (tensile, hardness, and shock) of
duralumin, with annealing temperature. Metal subjected to
50 % cold work, annealed, and cooled very slowly. Longitudinal
•best pieces . . . . . . . . . . 9£
4!i~ Variation in mechanical properties (tensile and shock) of
cL-uralumin, -with annealing temperature. Metal subjected to
GO % cold Tffork, annealed, and cooled in air. Longitudinal test
pieces . . . . . . . . . . 93
•4 !•- Variation in mechanical properties (tensile, hardness, and shock)
of doiralumin, -with annealing temperature. Metal subjected to
f>0 % cold work, annealed, and cooled very slowly. Transverse
•test pieces . . . . . . . . . . 93
<#S- Variation in mechanical properties (tensile and shock) of
clujalumin, with annealing temperature. Metal subjected to
45O % cold Trork, annealed, and cooled in air. Transverse test
jpieces . . . . . . . . . . 94
xxii ALUMINIUM AND I T S A L L O Y S
FIGURE PAGE
46. Duralumin compared with pure aluminium, using dilatometer . 96
47. Variation in mechanical properties of duralumin, with time after
quenching (from 300°). . . . . . . . 9 7
48. Variation in mechanical properties of duralumin with time after
quenching (from 350°) 98
49. Variation in mechanical properties of duralumin with time after
quenching (from 400°) 99
50. Variation in mechanical properties of duralumin with time after
quenching (from 450°) 99
51. Variation in mechanical properties of duralumin with time after
quenching (from 500°) 100
52. Variation in mechanical properties of duralumin with time after •-
quenching (from 550°) 100
53. Variation in mechanical properties of duralumin with quenching
temperature (after 8 days) . . . . . . .101
54. Variation in mechanical properties of duralumin with time after
quenching from 475° (during first 48 hours) - . . .103
55. Variation in mechanical properties of duralumin with time after
quenching from 475° (during first 8 days) , . . .104
56. Variation in mechanical properties of duralumin with annealing
temperature. Metal quenched from 475°, reannealed, and cooled
very slowly. . . . . „ . . . .110
57. Variation in mechanical properties of duralumin with annealing
temperature. Metal quenched from 475°, reannealed, and cooled
in air . . . . . . „ . . .111
58. Variation in mechanical properties of duralumin with annealing
temperature. Metal quenched from 475% reannealed, and
quenched in water . . . . . . . .112
59. Duralumin. Chipping tests. Variation in breaking load and depth
of impression with annealing temperature. Anneal followed by
cooling at various rates . . . . . . .114
60. High temperature hardness tests (500 kg.) on duralumin quenched
from 475° 116
PART V—CUPRO-ALUMINIUMS
61. Tensile test piece (round bars) . . . . . . .120
62. Aluminium bronze, Type I, critical points . . . .121
63. Aluminium bronze, Type I, allowed to cool in furnace . .122
64. Aluminium bronze, Type I, Blow cooling . . . . . 122
65. Aluminium bronze, Type I, temperature not exceeding Ac3 . 122
66. Variation in mechanical properties (tensile and impact) with an-
nealing temperature. Cast aluminium bronze, Typ« I (Cu 90 %,
A110%) . . .123
LIST OF ILLUSTRATIONS I N T E X T
FIGTOBE
67. Variation in mechanical properties (tensile and impact) with an-
nealing temperature. Forged aluminium bronze, Type I .124
68. Variation in mechanical properties (tensile and impact) with
quenching temperature. Cast aluminium bronze, Type I .125
69. Variation in mechanical properties (tensile and impact) with
quenching temperature. Forged aluminium bronze, Type I . 126
70. Variation in mechanical properties (tensile and impact) with
temperature of reanneal after quenching from 700°. Forged
aluminium bronze, Type I . . . . . . . 127
71. Variation in mechanical properties (tensile and impact) with.
temperature of reanneal after quenching from 800°. Forged
aluminium bronze, Type I . . . . . . . 128
72. Variation in mechanical properties (tensile and impact) with
temperature of reanneal after quenching from 900°. Forged
aluminium bronze, Type I . . . . . . . 120
726. High-temperature hardness tests (500 kg.) on aluminium bronze,
Type I, as cast, worked, and heat treated . . . .131
73. Aluminium.bronze, Type II, critical points . . . . 132
74. Aluminium bronze, Type II . . . . . .132
75. Variation in mechanical properties (tensile and impact) with
annealing temperature. Forged aluminium bronze, Type II
(Cu 89 %, Mn 1 %, Al 10 %) 133
76. Variation in mechanical properties (tensile and impact) with
quenching temperature. Forged aluminium bronze, Type II . 134
77. Variation in mechanical properties (tensile and impact) with.
temperature of reanneal after quenching from 800°. Forged
aluminium bronze, Type II . . . . . . . 135
78. Variation in mechanical properties (tensile and impact) with
temperature of reanneal after quenching from 900°. Forged
aluminium bronze, Type II . . . . . . .135
78b. High-temperature hardness tests (500 kg.) on aluminium bronze,
Type II. Quenched from 900°, reannealed at 600°. . .136
79. Aluminium bronze, Type III, critical points (dilatometer) . . 137
80. Aluminium bronze, Type III, critical points, temperature time
curve . » • • • • • • • • 138
81. Variation in mechanical properties (tensile and impact) with
annealing temperature. Forged aluminium bronze, Type III
(Cu81%,Ni4%,Fe4%,Alll%) 138
82. Variation in mechanical properties (tensile and impact) with.
quenching temperature. FoTged aluminium bronze, Type III 139
83. Variation in mechanical properties (tensile and impact) with
temperature of reanneal after quenching from 900°. Forged
aluminium bronze, Type III .,..•,.....,,..•., . . . . 140
836. High-temperature hardnejf.-tests (500 kg.) on aTtooinium bronze,
Type IK A l ^ 9 0 t o °
A l u m i n i u m a n d i t s A l l o y s
PART I
PRODUCTION OF ALUMINIUM
CHAPTER I
METALLURGY OF ALUMINIUM
ALUMINIUM is prepared by the electrolysis of alumina dissolved
in fused cryolite. The electric energy is derived from water-
power. The essential materials for the process are therefore
(i) Alumina,
(ii) Cryolite.
ALUMINA.
Alumina is prepared from bauxite [(Al, Fe) 2 O 8 2H a O] or
from certain clays [Al 2 O 3 .2SiO 2 ].
(a) From Bauxite.
Bauxite is a clay-like substance, whitish when silica is pre-
dominant, or reddish when oxide of iron is largely present. I t
is found in great quantity in France, in the neighbourhood of
the village of Baux, near Aries (hence the name, bauxite),
and more commonly in the Departments of Bouches-du-
Rhone, Gard, Ariege, H6rault, and Var. I t is found in Calabria,
Iceland, Styria, Carniola, and in the United States of America
in Georgia, Arkansas, Alabama, and Teimessee.
Commercial bauxite has the following composition :—*
Alumina (A12O8) . 57 % A premium of -20 t o -40 francs
per kilo (roughly Id. t o 2d. per
lb.) was, in 1909, paid for each
per cent over 60 %.
Silica (SiOa) . . 3 % If below 2 %, a premium of -20
fr. per kg. (roughly Id. per lb.)
was paid per -1 %.
• Lodin, "Annales des Mines," Nov., 1909.
3
4 ALUMINIUM AND ITS ALLOYS
Iron Oxide (Fe2O 3) . 1 4 % For each per cent above this
value, up to the maximum
allowed, 17 %, -20 fr. per kg.
(roughly Id. per lb.) was de-
ducted. Some works allow as
much as 25 % Fe 2 O 3 .
White bauxites are chiefly used for the production of
aluminium sulphate and the alums. Red bauxites form the
raw material for the preparation of alumina, and therefore of
aluminium. Intermediate or refractory bauxites, fused in an
electric furnace, give artificial corundum.
Bauxite is treated either by Deville's method or by t h a t of
Bayer, the latter being almost exclusively employed. A third
method depends upon the production of aluminium nitride.
This is obtained by heating bauxite in air to 1800°-1900° in
an electric furnace. It is then decomposed in an autoclave in
presence of soda solution, giving (i) ammonia, used as a manure
in the form of its sulphate, (ii) sodium aluminate, from which
commercially pure alumina can be obtained.
(b) From Clay.
Clays are treated either by the Cowles-Kayser or by the
Moldentrauer process, yielding alumina from which aluminium
is prepared by electrolysis.
CRYOLITE.
Cryolite, which is so called on account of its high fusibility,
is a double fluoride of aluminium and sodium of the formula
Al 2 F 6 .6NaF. I t is obtained from Western Greenland, where
it occurs in beds up to one metre thick, but the high price of
this material has led to the manufacture of synthetic cryolite,
using calcium fluoride (fluor-spar), which is found in con-
siderable quantities.
ELECTBIC FURNACES.
The furnace consists of a vat, containing electrodes (anodes),
and a conducting hearth (the cathode) sloping towards tho
tapping hole. Aluminium, formed by electrolysis of the
alumina, collects on the floor of the v a t ; oxygen is liberated
at the anode, which it attacks, forming carbon monoxide
and finally carbon dioxide.
The current is used at a potential difference of 8 to 10
volts, and at a density of 1-5 to 3 amps, per square centimetre
of electrode. The furnace is regulated by raising or lowering
the electrodes, or by varying the quantity of alumina. When
METALLURGY OF ALUMINIUM
the latter is present in small quantities, the fluorides decom-
pose, and the voltage (normally 8-10 volts) rises. This is
indicated by the change in intensity of a lamp. I n this case
sodium is formed at the cathode, and has deleterious effects
on the quality of the metal.
METHOD OP TAPPING ALUMINIUM.
Since aluminium is very easily oxidised, it cannot be sub-
jected to a final refining process, but must possess, at this early
stage, its commercial purity. I t is therefore essential t o avoid
oxidation during the manufacturing process, and the cryolite,
1000-
975
950-
925-
900-
0 5 10 15 20
F I G . 1 . — M e l t i n g - p o i n t C u r v e of M i x t u r e s of A l 2 F f l . C N a F a n d A 1 2 O 3 . (Pryn.)
WORLD'S PRODUCTION
I. BAUXITE.
T H E French Minister of Commerce gives the following par-
ticulars concerning the world's production of bauxite :—*
U.S.A. France Great Britain Italy
U.S.A.
Scale 210,228 tons
Italy
10,000
Tons O France
6842
Gt.
Britain
6056
304,410 tons
F I G . 2.—Distribution of Bauxite.
* Vol. I , " R a p p o r t g6n6ral sur l'industrie fran^aise, sa situation, son
avenir," based on the work of sections of the "Comite" consultatif des Arts
et^Manufactures " and of t h e "Direction des Etudes techniques," April, 1919,
(Director: M. Guillet).
10 ALUMINIUM AND ITS ALLOYS
Sixty-five per cent of the French production was exported,
half of which (i.e. 32 %) was sent directly or indirectly to
Germany, approximately 15 % to Great Britain, and a certain
proportion to the United States, which is rapidly falling off, as
the new beds are developed in that country, in Tennessee and
North Carolina.
Of the 7365 tons (7483 tonnes) of alumina exported, 80 %
goes to supply the Swiss factories.
The Report of the French Minister of Commerce (loc. cit.)
shows the influence of the war on the production of bauxite.
ka) France.
Bauxite for Bauxite for
Aluminium other purposes Total
Tonnes Ton Tonnes Tons Tonnes Tons
1915 37,894 37,296 48,628 47,860 86,522 85,156
1916 68,866 67,779 37,334 36,743 106,200 104,520
1917 101,748 100,150 19,168 18,865 120,916 119,015
The diminution in production is clearly due to t h e large falling
off of exports.
(b) United States.
1915 . 293,253 tons (297,961 tonnes) of bauxite.
1916 . 418,640 „ (425,359 „ )
1917 . 559,750 „ (568,690 „ )
(c) Great Britain.
1915 . 11,726 tons (11,914 tonnes) of bauxite.
1917 . 14,714 „ (14,950 „ )
The whole of this amount was imported from the French beds
at Var. The discovery of beds in British Guiana, where there
are large waterfalls, will probably affect the British production
very considerably.
(d) Italy.
Position unchanged.
(e) Germany.
Germany has been unable to import French bauxite, and
has, therefore, since the war, begun to work the beds at Frank-
fort-on-Main.
(f) Austria-Hungary.
Austria-Hungary has supplied the needs of Germany during
the war. Just when war was declared, very important beds
io
d
M E D I T E / I R A N I A N
SCALC OF MILES
S £ A {0 0 ^0 20 ^0 40
Reduction Works
Preparation of Alumina - - _ - - - - - _
SAINT-JEAN—CYLINDRICAL DAM.
ENGINE-ROOM AT CALYPSO.
WORLD'S PRODUCTION IS
ALUMINA W O K K S .
The alumina works are situated near the bauxite beds in
Herault, Var, and Bouches-du-Rhone, at Gardanne and L a
Barasse (Bouches-du-Rhone) and at Salindres (Gard).
(b) Great Britain.
Output about 6000 tons.
There are two companies :—
(i) The British Aluminium Company (Scotland a n d Norway),
(ii) The Aluminium Corporation (works a t Dolgarrog, North
Wales).
(c) Italy.
Output 1500-2000 tons.
(d) Switzerland.
Output 12,000-13,000 tons, from works a t Neuhausen
(canton of Schaffhausen) and at Chippis and Martigny (canton
of Valais). I t is noticeable t h a t in Switzerland there are no
works for the preparation of alumina from bauxite, hence the
materials required for the manufacture of aluminium, alumina
and cryolite are imported.
(e) Norway.
The Norwegian output has been:—
1913 . . approximately 1000 tons
1917 . . „ 7000 „
1918 . . „ 6000 „
Its possible production may be about 15,000-16,000 tons.
Alumina is imported mainly from the works at Menessis
(Somme) and Salzaete (Belgium), belonging to L'Aluminium
fran?aise, which have been damaged during the war.
(f) United States and Canada.
The output of the United States and of Canada in recent
years has been about 30,000 t o n s ; it is capable of great
development, b u t it is difficult to give precise details on the
subject.
The " Rapport sur Flndustrie fran£aise " of the Minister
of Commerce gives, as a probable figure for 1917, 70,000 tons,
which might rise to 80,000 with further increase in prospect.
The two large American companies are t h e Aluminium
Company of America, and the Northern Aluminium Company
14 ALUMINIUM AND ITS ALLOYS
of Canada, having their main works at Niagara Falls, at
Massena, at Quebec a n d a t Sehawinigan Falls respectively.
(g) Germany and Austria.
I t is really difficult to give precise returns on the capacity
for production of these two countries. I t has been given as
approximately 10,000 tons, though it is not possible actually
to verify this figure.
I n conclusion, the following table of actual world's production
may be given, omitting all more or less hypothetical specula-
tions :—
United States and Canada . . 70,000 tons (?)
France . . . . . 15,000 „
Switzerland . 12,000 „
Great Britain 6,000 „
Norway . . . . 6,000 „
Italy . 2,000 „
Germany and Austria . . 10,000 „ (?)
P R O P E R T I E S OF ALUMINIUM
CHAPTER I
PHYSICAL PROPERTIES
MECHANICAL PROPERTIES
A. T E N S I L E PROPERTIES
Thin Series
Dimensions of test pieces.
TYPE IA. (Length 100 m m .
Between shoulders j Breadth 20 mm.
(Thickness 0-5 m m .
Area of cross section 10 sq. mm.*
Gauge length (for measuring elongation)= \/66-61$
= 3 0 mm.
TYPE I B . [Length 100 m m .
Between shoulders < Breadth 20 m m .
[Thickness 1 mm.
Area of cross section 20 sq. mm.
Gauge l e n g t h = V 6 6 : 6 7 i = 3 6 m m .
TYPE I C . (Length 100 m m .
Between shoulders -J Breadth 20 mm.
(Thickness 1-5 m m .
Area of cross section 30 sq. mm.
Gauge l e n g t h = v / 6 6 * 6 7 s = 4 5 mm.
* These values are only approximate. In each case the breadth and
thickness were measured, to the nearest -01 mm., and the exact cross section
calculated from these figures.
20 ALUMINIUM AND ITS ALLOYS
ID. [Length 100 mm.
Between shoulders \ Breadth 20 mm.
[Thickness 2 mm.
Area of cross section 40 sq. mm.
Gauge length= ^
Thick Series
TYPE II. [Length 100 mm.
Between shoulders J Breadth 15 mm.
[Thickness 10 mm.
Area of cross section 150 sq. mm.
Gauge l e n g t h = ^66-678= 100 mm.
TESTING LABORATORIES.
The experiments on the variation of mechanical properties
with cold work (thin series) and the cupping tests (both in t h e
worked and annealed states) were carried out at the " Chalais
M e u d o n " Laboratory. The experiments on the effect of
annealing a t different temperatures after cold work were
carried out at the Conservatoire des Arts et Metiers. Reports
of the latter, experiments are given in the appendices.
SECOND METHOD.
A slab 40 mm. thick, at an initial temperature of 450°, is
reduced to a uniform thickness of 8 mm. by hot rolling.
Annealed Metal. The sheet, 8 mm. thick, is reduced to the
required thickness by cold rolling, with intermediate annealing
at 350° every 2 mm. reduction, and is finally annealed a t 350°.
Cold-Worked Metal. Assuming that 100 % cold work is
desired, the sheet, 8 mm. thick, is reduced by cold rolling,
with intermediate annealing every 2 mm. reduction, to double
the final thickness required. I t is then annealed a t 350°, and
cold rolled so as to reduce the section by one-half. A similar
process is employed for the other degrees of cold work in-
vestigated.
A comparative study of the cold working of thin sheets
was carried out by both these methods, whereas in the study
of the cold working of thick sheets, and in the study of annealing
alone, the second method only was employed. Although the
second method is more uniform and more sound, it has not
given results superior to those of the first.
As will be seen below, it seems as if, up to a certain limit,
large amounts of cold work need not be avoided in manufacture,
provided that this is only an intermediate stage, and is followed
by a re-softening anneal.
ANALYSIS
Cold work 0 %
Thickness 0-5 mm. 1 mm. 1-5 mm. 2 mm.
Iron . 0-93 % 0-82% 0-98 % 0-95 %
Silicon . 0-56 0-52 0-56 0-45
Cold: work 50 %
Iron . 0-88 0-84 0-97 0-93
Silicon . . 0-25 0-26 0-39 0-41
Alumina . . 0-36 0-30 0-26 0-34
Cold work 100 %
Iron . 0-81 0-83 0-70 0-81
Silicon . 0-32 0-38 0-23 0-23
Alumina . . 0-24 0-29 0-26 0-24
Cold iwork 300 %
Iron . 0-88 0-77 0-85 0-72
Silicon . 0-31 0-46 0-56 0-46
Alumina . • 0-17 016 0-24 0-22
MECHANICAL P R O P E R T I E S 23
NUMBER OF T E S T S .
For each degree of cold work, two sheets were used for the
tensile tests, and in each sheet three test pieces were cut
longitudinally and three transversely.
THIN SERIES
(Sheet 1 m m . t h i c k )
R E S U L T S O F T E S T S .
10
THIN SERIES
(Test Pieces 0.5 mm. thick)
Temperature
FIG. 7.—Variation in Mechanical Properties on Annealing at
different T e m p e r a t u r e s after 50 % Cold W o r k .
F I G . 6. T E S T S O K T B A N S Y E R S E T E S T P I E C E S .
THIN SERIES
(Test Pieces 0'5mm. thick)
the other, 2-0 mm. thick, Type Id. Each of these series
includes metal in three degrees of cold work, 50, 100, and
300 %.
30 ALUMINIUM A M ) ITS ALLOYS
INVESTIGATION OF THE DURATION OF TIME NECESSABY FOB
COMPLETE ANNEAL AT VABIOTJS TEMPEBATUBES.
Preliminary tests have been carried out with a view to
determining the minimum time necessary to give the properties
characterising each temperature.*
THIN SERIES
(Test Pieces OSmm.thick)
Kg. per
11
\ \ % Elongation
40 16 \ > •10
\\ S v
\ \ / ^ ^
v
\
35 14 \
\
V\
\
\
\
30 12
\ | \ ^ Tensile —
\ Strength
\
25 10 \
ton
\\
3 8
£
O 20
LJ I\
15 6 // \ N^^ Elastic.
J ~"Umii~
10 4 /
0 0
100 200 300 400 500 6 0 0 °C
Temperature
FIG. 9.—Variation in Mechanical Properties on Annealing
at different Temperatures after 300 % Cold Work.
-•1 1
•10
(iii) R e g i o n of Complete A n n e a l ; 3 5 0 - 4 5 0 ° .
T h i s i s t h e r e g i o n i n w h i c h t h e e x t e n t of a n n e a l r e m a i n s
a p p r o x i m a t e l y c o n s t a n t ; t h a t is t o s a y , i n w h i c h t h e p r o p e r t i e s
o f t h e m e t a l a r e a l m o s t t h e s a m e a f t e r a n n e a l i n g a t a n y t e m p e r a -
t u r e w i t h i n t h i s r a n g e .
MECHANICAL P R O P E R T I E S
350° t o 450° is, therefore, the optimum annealing range of
temperature.
(iv) Region of Falling-off of Elongation ; 450-500°.
I n t h i s region there is a decrease in the Elongation, without
any appreciable change in the Tensile Strength a n d Elastic
Limit.
THIN SERIES
(Test Pieces 2mm.thick)
I 8 Kg per
mm2
(i) T h e s o f t e n i n g i s t h e m o r e a b r u p t a s t h e o r i g i n a l cold
work increases.
(ii) T h e t e m p e r a t u r e of c o m p l e t e a n n e a l ( c h a r a c t e r i s e d b y
m a x i m u m elongation) becomes lower as t h e cold work increases.
ALUMINIUM AND ITS ALLOYS
Temperature of Maximum
Amount of Original Cold Work Elongation
50 % . 425°
100 % 400°
300 % 350°
(iii) The values of the properties in the completely annealed
state increase with the amount of original cold work, up to
300 %.
Amount of Tensile Strength Elastic Limit
Cold Work Kg./nam. * Tons/in.2 Kg. /mm 2 Tons/in.2 Elongation
THICK SERIES
Kg
per
mm 2
40 10
Elongation
9
35
8
O 30
a 7
"00
c
25
UJ 6
£
20 5 Q.
tn
c
3
10 Elastic
2
Limit
A s i n t h e c a s e of t h e t h i n series, t h e s a m e r e g i o n s a r e n o t i c e -
able, a n d a comparison of t h e t w o figures leads to the same
c o n c l u s i o n s a s t o t h e effect of initial c o l d w o r k o n t h e results
obtained after a subsequent anneal.
36 ALUMINIUM AND ITS ALLOYS
HARDNESS T E S T S .
(a) Brinell Tests on thick sheets.
These were carried out under a load of 500 kg. and 1000 kg.
respectively, using a ball 10 mm. in diameter. The results are
shown in Fig. 15.
THICK SERIES
(Test Pieces 10mm. thick)
THICK SERIES
42 Brine//
41
40
Shock
39 Resistanc
38
37
36
3
g34
3 3;
I 31
| 30
29
28
27
26
25
24
23
22
21
50 100 150 20O 250 300%
Cold Work
F I G . 15.—Variation in Mechanical Properties (Hardness
a n d S h o c k ) w i t h Cold W o r k .
under 500 kg. and 1000 kg. These hardness curves under
500 a n d 1000 kg. deviate v e r y little from each other, and the
divergences, for which experimental errors are partly re-
sponsible, need n o comment.
38 ALUMINIUM AND ITS ALLOYS
Annealed aluminium possesses a Brinell Hardness of 23
under 500 or 1000 kg., corresponding with a Tensile Strength
of approximately 10 kg. per sq. mm. (6-35 tons per sq. in.).
I n the case of t h e thick series, the maximum hardness, as also
the maximum Tensile Strength, occurs at 200 % cold work.
SHOCK T E S T S .
These were carried out on test bars, 5 5 x 10X10 mm., with
a Mesnager notch of 2 mm. depth, using a 30 kg. m. charpy
pendulum of t h e Conservatoire des Arts et Metiers.
The results are also shown in Fig. 15. If the Shock Resistance
curves (longitudinal and transverse) of Fig. 15 be compared
with the Elongation curves of Figs. 5 and 6, it will be seen t h a t
t h e y are of identical shape.
At 50 % cold work, the Shock Resistance reaches almost its
minimum value. I n the annealed state, the Shock Resistance
varies between 8 and 8-5 kilogramme-metres per sq. cm.,
without any appreciable difference between test pieces cut
longitudinally or transversely. This difference, however,
becomes more marked as the cold work increases.
Minimum Shock Resistance, 300 % cold work (longitudinal)
5 kg. m. per sq. cm.
Minimum Shock Resistance, 300 % cold work (transverse)
3 kg. m. per sq. cm.
MECHANICAL PROPERTIES 39
THICK SERIES
(Test Pieces 10mm. thick)
37
H A K D N E S S .
The hardness curves under 1000 kg. a n d 500 kg. are shown
in the figures. These curves diverge little ; t h e y are practically-
i d e n t i c a l i n t h e r e g i o n of c o l d w o r k , a n d d i v e r g e c h i e f l y i n the
r e g i o n of a n n e a l , w h e r e t h e h a r d n e s s u n d e r 1 0 0 0 k g . i s s l i g h t l y
greater than that under 500 kg. The object in obtaining
ALUMINIUM AND I T S ALLOYS
these curves is not so much to compare the actual hardness
numbers under 500 and 1000 kg., as t o gain some indication
of the trend of these values under two different loads. The
advantage of this is evident; for instance, in the case of high
temperature tests, where the determination of hardness under
THICK SERIES
(Test Pieces 1 Omm. thick)
40 1000 Kg
39
38
37
36
35
34 Shock
S3
Resistance
Kg.m
£3 per
| 31 Shock
Resistance
| 3 0 10
28 9
I 8
7
27
[6
26
5
25
4
24
23
22
21
201 500 600°C
200
100 300 " 400
Temperature
FIG. 17.—Variation in Mechanical Properties (Hardness and
Shock) on Annealing after 300 % Cold Work.
C. CtrpprsrG T E S T S
c a r r i e d o u t , w e r e t h o s e c o m p r i s i n g t h e t h i n series ; 0-5 m m . ,
1-0 m m . , 1-5 m m . , a n d 2-0 m m . i n t h i c k n e s s r e s p e c t i v e l y .
F i g . 19 shows for e a c h t h i c k n e s s t h e v a r i a t i o n of t h e D e p t h
of I m p r e s s i o n a n d B r e a k i n g L o a d w i t h cold w o r k .
THIN SERIES
1000
Breaking
Load
Load (2 mmj
16
15-
14
13
12
*o
X
-M
Q.
5
Q
lnad(0'5
300%
WO % Cold
'50 % Work
0%
2 190
Q.
JC 6 180 / Load
fa J
o
170 /
160 /
T h e y s h o w , f u r t h e r , t h a t t h e final r e s u l t s ( D e p t h o f I m p r e s s i o n
a n d B r e a k i n g L o a d ) are higher as t h e initial cold work is
greater.
The following table summarises the results:—
F i g s . 24:, 2 5 , a n d 2 6 g i v e t h e r e s u l t s f o r T y p e Id ( 2 - 0 m m .
t h i c k ) . T h e y s h o w t h a t for s h e e t 2-0 m m . t h i c k , a s i n t h e
c a s e of s h e e t 0-5 m m . t h i c k , t h e D e p t h of I m p r e s s i o n a n d
Breaking L o a d reach their m a x i m u m values in approximately
the same temperature range, but slightly extended (3rJ5°-4:50o)y
THIN SERIES
14
13 Breaking
Load Depth of
12
j f Impression
Kg
200
o /
*S5 9 r v**^" Breaking
0)
8 190 ^S S Load
I /
180 V
a.
Q
170 > ^
160
150
0 100 200 300 400 560 60
Temperature
FIG. 22.—Cupping Tests: Variation in Breaking Load and
Depth of Impression on Annealing after 100 % Cold Work.
D. FINAL SUMMARY
THIN SERIES
15 Breaking (Test Pieces O'Smm. thick)
Load
14
13 Depth of
12 Impression
Breaking
Load
(i) I n f l u e n c e of c o l d w o r k ,
(ii) I n f l u e n c e of a n n e a l i n g a f t e r c o l d w o r k ,
12
I"
o 10
900
'55
I Breaking
I * 850 Load
I 800
Q 5
700
100 200 300 400 500 600 C
Temperature
F I G . 2 4 . — C u p p i n g T e s t s : Variation i n Breaking L o a d a n d
D e p t h of I m p r e s s i o n o n Annealing after 6 0 % Cold Work.
T h e u t i l i s a t i o n of large a m o u n t s of c o l d w o r k , 2 0 0 a n d 3 0 0 % ,
possesses certain decided advantages. I t increases generally
t h e v a l u e of t h e m e c h a n i c a l properties o b t a i n e d after a c o m -
plete anneal, a n d possesses a n indubitable economic advantage
in dispensing with useless intermediate anneals.
MECHANICAL P R O P E R T I E S
(b) Final Cold Work,
Cold work is far from advisable, particularly in aeronautical
work. I t hardly seems t o constitute a stable state, and should
especially be avoided in material subjected to constant vibration.
We are therefore of t h e opinion t h a t aluminium should be
used in the annealed condition, certainly as regards aero-
nautical work; the increased strength, which results from
cold work, as described in this chapter, should be attained
by other means, such as increase of thickness, or the employ-
ment of alloys.
THIN SERIES
(Test Pieces 2mm. thick)
16 Kg Depth of
1000 Impression
15 Breaking
Load
14
13 950
12
£
E 900 Breaking
c 10 Load
o
'5>
</>
o 850
a. 8
Z. 7
o
-c 6 800
a.
<D el
750
700
100 200 300 400 500 600°C
Temperature
FIG. 25.—Cupping Tests : Variation in Depth of Impression
and Breaking Load on Annealing after 100 % Cold Work.
(ii) ANNEALING.
W e h a v e pointed o u t t h e existence of regions of cold work,
softening, complete anneal, a n d of falling off of ductility.
Only one region, t h a t of complete anneal, produces a techni-
50 ALUMINIUM AND ITS ALLOYS
cally finished product.* This fixes an optimum mean annealing
temperature of 400°, and gives, in the metal, after a suitable
initial cold work (200 %-300 % ) , the following properties :—
Elongation % =40
Tensile Strength == 11 kg. per sq. mm. (6-98 tons per sq. in.).
Elastic Limit =5 „ „ (3-17 „ „ ).
Shock Resistance=8-5 kg. m. per sq. cm.
Brinell Number = 2 3
THIN SERIES
(Test Pieces 2mm.
16
Breaking
15 Load
14 Kg
Breaking
13
Load
12
£
£ 900
c 10
o
8 9
CD
| s 850
e^- 7
O
-C
800
5
a
750
700
100 200 300 400 500 600°C
Temperature
F I G . 2 6 . — C u p p i n g T e s t s : V a r i a t i o n i n D e p t h of I m p r e s s i o n
a n d B r e a k i n g L o a d o n A n n e a l i n g after 300 % Cold W o r k .
* A n i n t e r m e d i a t e s t a t e , producing in aluminium a Tensile S t r e n g t h
higher t h a n t h a t possessed h y t h e annealed metal, m a y be studied. As we
h a v e seen, t h i s c a n n o t b e a c h i e v e d b y a s l i g h t cold w o r k i n g , w h i c h d e p r i v e s
t h e m e t a l of a p o r t i o n of i t s E l o n g a t i o n , b u t o n l y b y s u b m i t t i n g i t t o a n
anneal in t h e softening r e g i o n — a n incomplete anneal. B u t t h e i m p r o v e m e n t
i n t h e T e n s i l e S t r e n g t h , a m o u n t i n g t o s o m e t o n s p e r sq. in., is o n l y r e a l i s e d
a t t h e e x p e n s e of t h e E l o n g a t i o n , a n d of t h e r e g u l a r i t y of t h e r e s u l t s . T h e
g r e a t s l o p e of t h e c u r v e s for T e n s i l e S t r e n g t h , a n d E l o n g a t i o n % , i n t h i s
s o f t e n i n g z o n e s h o w s t h a t a v e r y slight v a r i a t i o n of t e m p e r a t u r e h a s a n
e n o r m o u s influence on t h e properties—hence t h e irregularity.
MECHANICAL P R O P E R T I E S 51
Erichsen
Number
11
10
(Depth .of /
lmpression)Q
(mm.) *
8
7
0-5 V0 1-5 2*0 2*5 mm.
Thickness
FIG. 27.—Variation in Depth of Impression with Thickness.
Annealed Aluminium Sheet.
Erichsen
Number
8
(Depth of
Impression) 7
(mm.)
6
10 15 20- 25 30 35 40 45 50 55 60 65
Time (minutes)
FIG. 29.
a n n e a l ; a slight v a r i a t i o n , t h e r e f o r e , in t h e l e n g t h of t i m e ,
difficult t o aToid in w o r k s p r a c t i c e , m a y l e a d t o l a r g e irregu-
larities.
F i n a l a n n e a l s , w h i c h m u s t "be c a r r i e d o u t v e r y precisely, i n
o r d e r to o h t a i n r e g u l a r i t y I n t h e finished p r o d u c t , a r e c o n d u c t e d
a t t h e t e m p e r a t u r e specified a b o v e (i.e. 375°-425°) for t h e
m i n i m u m l e n g t h of t i m e possible, w h i c h is e a s i l y d e t e r m i n e d
for t h e p a r t i c u l a r t e m p e r a t u r e e m p l o y e d .
CHAPTER IV
MICROGRAPHY OF ALUMINIUM
PHOTOGRAPH 1. PHOTOGRAPH 2.
ALUMINIUM INGOT. CHILL CAST. ALUMINIUM INGOT. SAND CAST.
X40. X 50.
(Robert J. Anderson.) (Robert J. Anderson.)
PHOTOGRAPH 3. I°HOTOGRAPH 4.
ALUMINIUM. COLD WORKED (50 %) ALUMINIUM. COLD WORKED (100 %).
XlOO. XlOO.
To face pa^e 57
PLATE II.
w m m m
m m m
PHOTOGRAPH 7. PHOTOGRAPH 8.
ALUMINIUM. ANNKALED AT 595° FOR ALUMINIUM. ANNEALED AT 505° FOR
()0 MfNUTES, 4 HOURS.
X 50. X50.
(Robert J. Anderson.) (Robert J. Anderson.)
To face page 57
MICROGEAPHY OF ALUMINIUM 57
acid (HF), as suggested by Brislee, employing a mixture of one
part of fuming hydrofluoric acid and eight parts of water.
The section is plunged into this liquid, and the blackening of
the surface is removed by immersing for some seconds in con-
centrated nitric acid. Hydrogen fluoride vapour may equally
well be employed for etching. To give good results, the hydro-
fluoric acid should be chemically pure, and should be preserved
and used in vessels coated with paraffin.
RESULTS.
Micrographs of aluminium are given in Plates I and I I .
Photographs 1 and 2, taken from the work of R. J . Anderson,
refer to chill and sand castings.
The first shows the dendritic structure, well known in cast
metals. The second shows crystals of aluminium surrounded
by segregations.
Photographs 3, 4, and 5 refer to aluminium cold worked to
50,100, and 300 % respectively. The flow lines in the direction
of rolling are evident.
Photographs 6, 7, and 8 show the effect of annealing after
cold work. Photograph 6 shows the result of annealing,
at 350° for 10 minutes, aluminium previously cold worked
to 300 %. The lines of flow due to cold work have not dis-
appeared, but underneath these striations, still visible, a fine
cellular network, characteristic of annealed metal, can be seen.
The striations due to cold work only disappear on heating
either for a longer period or to a higher temperature. Photo-
graphs 7 and 8 show the characteristics of a metal whose
Elongation has diminished as a result of over-annealing.
The thermal and mechanical treatment of aluminium can
thus be controlled, up to a certain limit, by micrographic
examination, as can also the purity of the metal and the
absence of dross.
CHAPTER V
PRESERVATION OF ALUMINIUM
E F F E C T OF ATMOSPHEBIC AGENCIES
The effect of atmospheric agencies can' be summarised as
follows:—
AIR.
Sheets of aluminium were protected from the rain, and
exposed to the atmosphere by Heyn and Bauer, and after two
hundred days had not changed in appearance.
Ditte explains this apparent unchangeability by the fact that
a very thin film of alumina is formed, which protects the rest
of the metal from all change.
WATER.
Aluminium is attacked by distilled water, hydrated alumina
being deposited. According to Ditte, this thin layer of alumina
protects the aluminium from further oxidation.
A I R AND W A T E R .
Air and ordinary water, acting alternately, have less effect
t h a n water alone.
A I R AND SALT W A T E R .
The views of Ditte upon this subject are as follows :—
" Whenever aluminium is in contact with the atmosphere,
salt water, sea water, or brackish water, the metal becomes
PRESERVATION OF ALUMINIUM 59
coated with a more or less compact layer of alumina, possibly
mixed with other soluble salts.
After the aluminium has been removed from the liquid, the
change will continue to take place, if the metal has not been
entirely freed from this coating and has not been sufficiently
washed so as to remove from it all traces of alkali.
Wherever the external surface of the metal has allowed a
trace of the sea salt to penetrate, the action will slowly con-
tinue, proceeding the more rapidly as the oxidised substance
is more hygroscopic, and permits the possible chemical re-
actions to take place more easily."
I n these results, the molecular state of the metal (anneal,
degree of cold work, etc.) has not been taken into account.
Then the following questions arise :—
Are these changes solely due to chemical actions, oxidations,
tending to change the composition of the metal %
Are they due to disintegrations, depending upon the mole-
cular state of the aluminium ?
Are they due to the ill-effects of cold work, giving rise to a
sort of spontaneous anneal, accompanied by disintegrations
and cracks ?
We have particularly studied this phenomenon in the
brasses, whose preservation was irretrievably endangered, if,
after cold working, a certain minimum anneal (350°) had not
been previously carried out.
Cartridge cases and artillery shells suffered very largely
from this fault before the remedy, just described, was applied.
I n other words, is the disintegration of aluminium connected
with chemical causes or mechanical causes or does it not
depend on these two causes together ?
The following literature, referring to different cases of
alteration, will enable us to see, up to a certain point, what are
the respective parts played by these two types of phenomena.
Ducru* observed the alterations of aluminium for the first
time about 1894 in the case of wires of this metal, used as
telegraph wires in the Congo or Dahomey from the coast to
the interior. I n a month, the wire, which had a Tensile Strength
of 23 kg. per sq. mm. (14-6 tons per sq. in.), had become grey,
and changed to an extremely weak substance. Chemical
analysis showed no oxidation. Hence there was no change of
a chemical nature.
* See 2nd Report, 1911, of the meeting of the French and Belgian members
of the International Association for testing materials, March 25th, 1911.
Burdin, Angers.
60 ALUMINIUM AND ITS ALLOYS
The same phenomena were observed in the case of a sheet
of aluminium at Havre, exposed alternately to air and sea
water ; in this instance, at the end of three months, there was
superficial oxidation.
This changed layer was removed by planing so as t o leave
only the sound portion. Tests on this showed t h a t the Tensile
Strength had fallen from 22 to 4 kg. per sq. mm. (14 to 2-54
tons per sq. in.). At all events, there was an initial cold work
clearly indicated.
I n 1897, Ducru observed the alteration of aluminium in
utensils made b y pressing. This alteration took place on the
bottom of the utensil in the following manner :—
There was a diminution in the metallic lustre of the alu-
minium, and the appearance of a grey colour, becoming more
pronounced. The altered portion possessed no strength, while
analysis showed only 4 to 5 % of the metal to be changed to
alumina.
Similar observations were made about 1911, on utensils,
1 mm. in thickness, made by pressing, and intended for domestic
and culinary purposes. The same changes were apparent, and
the bottom of the vessel could be pierced by simple pressure
of the finger. Analysis showed that 2-7 %, 3-7 %, and 3-5 %,
according to the sample, was changed to alumina, and Ducru
drew the following conclusions :—
" I n conclusion, t h e alteration of aluminium appears, at
least in certain cases, t o have one peculiar characteristic,
namely, t h a t it is not an oxidation effect, for t h a t seems to
affect only a small portion of the metal, and it is, on the other
hand, accompanied by a diminution in mechanical strength,
which causes serious trouble."
Then, if the phenomena be investigated more closely, it is
evident that the unfortunate incidents mentioned have occurred
in the case of excessively cold-worked aluminium—wires,
sheets, or pressed utensils.
The external agencies play the part of accelerators, assisting
the breakdown of equilibrium, which, in their absence, would
probably only have been delayed.
We have, ourselves, verified these disintegrations due to
cold work. We have not carried out experiments on alu-
minium, b u t the investigations we have made on the cold
working of brass lead us t o infer that the working of aluminium
cannot be irrelevant to these disintegrations.
From the micrographic standpoint, worked aluminium,
similarly to worked brass, assumes a striated appearance,
PRESERVATION OF ALUMINIUM 61
showing crystalline deformation in the direction of the mechani-
cal work—a condition in which instability is probable.
For aeronautical use, where security is essential, the need
for an anneal is clearly proved,—a conclusion supported by
the arguments already given. For strengths higher than that
of annealed aluminium, resource must be had to its alloys.
For purposes in which safety is not of prime consideration,
and in which the high strength obtained by the working of
aluminium is desirable, the problem takes on another aspect.
The practical durability of cold-worked aluminium will be
a predominant factor to be considered in solving the problem
of the practical and economical uses of which it is capable
(for wires and cables for electrical conductors).
CHAPTER V I
SOLDERING OF ALUMINIUM
ALLOYS OF ALUMINIUM
CLASSIFICATION OF ALLOYS
3 % tin.
1 % nickel.
According to the classification adopted (see page xi), we
h a v e to consider
(1) Light alloys of aluminium for casting purposes.
(2) Light alloys of aluminium of great strength (Tensile
Strength greater than 35 kg. per sq. mm. (22-22 tons
per sq. in.)).
A typical light alloy of these two classes has a density less
t h a n 3-5, and in the majority of light alloys, as we shall see,
t h e density is less than 3.
(3) Heavy alloys of which aluminium is a constituent,
comprising especially the "cupro-aluminiums," t h a t
is to say, alloys of copper and aluminium containing
1-20 % of aluminium with less than 1 % of other im-
purities.
Copper being the principal constituent, an alloy of copper con-
taining 10 % of aluminium, for example, would be represented
"by t h e symbol CuAl 10 and the special cupro-aluminium alloy con-
t a i n i n g 9 % of aluminium and 1 % of manganese by CuAloMnx.
These alloys are often known as aluminium bronzes, though
t h e name aluminium bronze should be restricted to alloys of
copper and tin containing aluminium, such as the aluminium
Ibronze for bearings whose symbolic notation is CuSn 44 Al a .
68 ALUMINIUM AND ITS ALLOYS
Moreover, in the nomenclature of alloys, we shall invariably
put first the principal metal, followed by the other metals
which are present as added constituents. Thus the name—
" aluminium-zinc alloys "—refers to those rich in aluminium
and which therefore come under the heading of light alloys,
while the name " zinc-aluminium alloys " refers to those rich
in zinc, which are not, therefore, classed as light alloys, but
as heavy alloys. These heavy alloys are only of value in
aeronautical construction if some special properties compensate
for their weight.
After dealing with the alloys of the three groups of which
we have made a special investigation, we shall summarise
shortly, in a special section, the properties of the principal
alloys in the group which have been studied by previous
investigators. Before discussing, in the following chapters,
the investigations on these alloys, we think it advisable to
recall the important part played by copper in the alloys of
aluminium. Since the majority of the alloys of these three
groups are affected by this constituent, it seems suitable to
consider it separately, before entering into a detailed study
of each.
EQUILIBRIUM DIAGRAM OF COPPER-ALUMINIUM ALLOYS.
The diagram was first established by H. Le Chatelier, then
by Campbell and Mathews, Carpenter and Edwards, Gwyer,
and Curry. There are few differences between these various
diagrams.
We give Curry's diagram (Fig. 30), and the results of the
micrographic examination may be summarised as follows:—
Three regions may be distinguished:—
First Region, Alloys rich in copper (100 %~8(> % by weight
of copper).
I n the region extending from 100 %-92 % of copper, the
alloy consists of a solid solution, known as a, while from 92 % -
86 % of copper the solid solutions a and y are present.
The latter region can be f urther divided into two, namely:—
/ solution a
92 %-88 % copper +
' eutectic ( a + y )
/ solution y
88 %-86 % copper +
'eutectic ( a + y )
CLASSIFICATION O F ALLOYS 69
At 88 % of copper, therefore, the alloy consists of t h e eutectic
( a + y ) , formerly called /?. This use of the name j8 is incorrect,
since the constituent j3 corresponds with austenite in steels—
we shall not employ it. The solution a would correspond, in
steels, with a iron, t h e solution y with cementite, and t h e
eutectic ( a + y ) with pearlite.
noo
IOOO \
900
800
700
600
500
0 % (Atomic)
90 80 70 60 50 4 0 3 0 2 0 10 0%(by weight)
F I G . 3 0 . — C o p p e r - A l u m i n i u m D i a g r a m (after Curry).
80
2 70
JD
£ 60;
Z 50
1 40
CO 3 0 :
20
10
I n o r d e r t o a v o i d c o l l a p s e , t h o s e p a r t s s u b j e c t e d t o stresH
s h o u l d p o s s e s s , t h r o u g h o u t t h e w h o l e r a n g e of t e m p e r a t u r e
experienced during working, certain m i n i m u m properties.
74 ALUMINIUM AND ITS ALLOYS
As regards hardness, this can be expressed approximately b y
a Brinell number of about 30 under a load of 500 kg.
This number is greater than that of aluminium in the cold,
and necessitates an original hardness of 50 to 60.
Tests have been carried out on a certain number of alloys
in order to examine these properties at high temperatures.
Fig. 306 shows the hardness of aluminium at different
temperatures, and enables us to see how the hardness is in-
creased by the addition of various constituents.
(5) A Maximum Thermal Conductivity and Specific Heat.
A high conductivity prevents local heating, which rapidly
causes deterioration, and renders the article useless.
Alloys of aluminium possess great advantages in this respect.
We know that the conductivity of aluminium is 36, t h a t of
silver being 100 and of copper 75-11—it is third as regards
thermal conductivity. This fact is of very great importance ;
it renders the employment of aluminium alloys for pistons very
successful.
On the other hand, the specific heat of aluminium is very
high, which reduces the rise in temperature. This property,
added to the high thermal conductivity, causes aluminium
pistons to become far less heated in use than pistons of cast
iron.
The temperature reached is lower t h a n t h a t of decomposition
of the lubricating oils, so that carbonaceous deposits, similar t o
those produced on cast-iron pistons, are not formed on pistons
of alloys of aluminium—for this reason fouling and seizing
do not occur.
After this short discussion we will consider individually the
alloys which we have investigated or met with in practice.
ALLOYS OF ALUMINIUM FOR CASTING PURPOSES.
The following alloys have been considered :—
(a) Binary aluminium-copper alloys—the study of tho p a r t
of the equilibrium diagram of the aluminium-coppor
alloys extending from 100 % to 88 % of aluminium.
(6) Ternary alloys—aluminium-copper-zinc.
(c) Quaternary alloys—aluminium-copper-tin-nickel.
T Y P E I (4 % COPPER)
TYPE II (8 % COPPER)
Analysis
Aluminium, alumina . . . 9Q-07
Copper . . . . . 8 «65
Iron 0-84
Silicon 0-44
D e n s i t y : 2-92
Mechanical Properties (as cast).
The average mechanical properties may be summarised as
follows:—
LIGHT ALLOYS OP ALUMINIUM 77
150
14T)
130
120
110
100
00
80
70
60
CO 5 0
40
30
iodd
20 Kg.
10
150
140
130
120
no
£100
"21
CD
Analysis
Aluminium, alumina . . ~ 86-24
Copper 12*65
Iron 0-88
Silicon 0-43
D e n s i t y : 2-95.
Mechanical Properties (as cast).
The average mechanical properties may be summarised as
follows:—
(a) Tests on Sand Castings.
Tensile Strength = 1 3 kg. per sq. mm. (8-25 tons per sq. in.)
% Elongation =0-8
Shock Resistance = 0 - 2 kg. m. per sq. cm.
(b) Tests on Chill Cast Bars.
Tensile Strength = 13-6 kg. per sq. mm. (8-64 tons per sq. in.)
% Elongation =1
The Elastic Limit is approximately the same as the Tensile
Strength.
The results of t h e hardness tests at high temperatures are
summarised in Fig. 33.
The variations in t h e hardness at high temperatures with the
copper content are shown in Fig. 34.
Allowing, with a view to avoiding the possibility of collapse,
a minimum Brinell hardness of 30, it is evident that the alloy
L I G H T ALLOYS OF ALUMINIUM 79
150
140
130
120
110
I 100
*E 90
I 80
= 70
£ 60
CD 50
40
30
20
10
50 100 150 200 250 300 350 400°C
Temperature
FIG. 33.—Hardness of Copper-Aluminium Alloy, containing 12 %
Copper, at High Temperatures under 500 and 1000 Kg. load.
80T
70
Ordinary
Temperature• 100°0
60
200°C
£ 50
£
Z 40
300aC
£
CD 3 0
20
10
0 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2
% Copper
FIG. 34.—Variation in Hardness under 500 Kg. load, with Copper
content at Temperatures 0°, 100°, 200°, 300°, 350°, and 400° C.
80 ALUMINIUM AND ITS ALLOYS
containing 4 % copper can be used for the range of temperature
0-275°,
the alloy having 8 % copper over the range 0-310 ,
and the alloy having 12 % copper over the range 0-320°.
I t must be noted t h a t cold working cannot be employed to
increase the hardness, since its effect must be nullified by the
rise in temperature.
(b) TERNARY ALLOYS—ALUMINIUM-COPPER-ZINC (12-13 %
ZINC, 3 % COPPER).
Analysis
Aluminium, alumina . . . 83*75
Copper 3-10
Zinc 11*60
Lead 0-22
Iron 0-88
Silicon 0-55
Density: 2-94.
Analysis
Aluminium, alumina . 84-93
Copper . 10-14
Tin 3-20
Nickel . . . . . 0-86
Iron . . . . . 0-48
Silicon . . . . . 0-27
Density : 2-98
1 50T
140
130
120
110
£ loo
| 90
1 60 ^ \
| 60 X
CO 50
40
30
20
10
Q
0 50 TOO 150 200 250 300 350 400°C
Temperature
"FIG. 35.—Hardness of Zinc-Copper-Aluminium
pp Alloy,
y, con-
taining 12 % Zinc, 3 % Copper, at High Temperatures
under 500 and 1000 Kg. load.
Mechanical Properties (as cast).
The average mechanical properties may be summarised as
follows:—
(a) Tests on Sand Castings.
Tensile Strength
g = 13 kg. per sq[. mm. (8 -25 tons per sq. in.)
E gl i
% Elongation =1
Shock Resistance =0*3 kg. m. per sq. cm.
(b) Tests on Chill Cast Bars.
Tensile Strength = 12-6 kg. per sq.mm.(8-00 tons per sq. in.)
% Elongation =0-5
82 ALUMINIUM AND ITS ALLOYS
The Elastic Limit is approximately the same as the Tensile
Strength.
The results of the Hardness tests at high temperatures are
summarised in Fig. 36.
90
£ 80
2 70
c 60
CO
50
40 Kg.
30
20
10
50 TOO 150 200 250 300 350 400 °C
Temperature
FIG. 36.—Hardness of Copper-Tin-Nickel-Alumimum Alloy, con
taining 11 % Copper, 3 % Tin, and 1 % Nickel, at High
Temperatures under 500 and 1000 Kg. load.
100 80 60
700i
600
500
400
300
200
20 40 60 80 100-%Al
FIG. 37.—Melting-point Curve of Zinc-Aluminium Alloys.
84 ALUMINIUM AND ITS ALLOYS
of temperature. The Brinell number for this alloy falls from
85 under a load of 500 kg. at the normal temperature, to 56
under the same load at 100°.
Cadmium is sometimes added to alloys of aluminium and
zinc (1-40 % zinc) (patented by Bayliss and Clark, England)
in the proportions of 0*001 to 10 respectively, an addition
which confers great malleability, and facilitates working and
stamping.
At other times, 0-5 % to 1 % of copper is added, or even
2 %, forming for aluminium-zinc alloys the soldering metal of
the following composition:—
Aluminium • 88 %
Zinc .
Copper • 2%
(b) Zinc-Aluminium Alloys. Investigations on the alloys
rich in zinc have been carried out by L6on Guillet and Victor
Bernard.*
The following alloys, among others, were studied:—
(1) Binary zinc-aluminium alloys containing 1, 2, 3, or 5 %
of aluminium.
(2) Ternary zinc-aluminium-copper alloys containing 2 % of
aluminium and 2, 4, 6, or 8 % of copper; 4 % of alu-
minium and 2, 4, 6, or 8 % copper; 8 % of aluminium
and 4 % of copper (German type of alloy).
The following results were obtained:—
(1) The cast alloys are of no value, the Elongation and
Shock Resistance being approximately zero.
(2) The rolled alloys have low elongations and almost no
Shock Resistance.
Extruded alloys generally have considerably increased
elongations. This extrusion gave the following properties for
the alloy containing 8 % of copper and 4 % of aluminium:—
Tensile Strength = 3 0 to 31 kg. per sq. mm. (19-05-19-68 tons
per sq. in.)
% Elongation =27-29
Shock Resistance=2 kg. m. per sq. cm.
This is the most interesting of the zinc-aluminium alloys, but
its Shock Resistance is very low.
* " Revue de Metallurgies Sept.-Oct., 1918.
LIGHT ALLOYS OF ALUMINIUM 85
(2) ALUMINIUM-TIN ALLOYS.
The alloy, containing 3 % of tin, having a density 3-25,
should be mentioned, as it is very suitable for casting.
Tin is frequently added in foundry practice, in order to facili-
tate the casting of alloys.
(3) ALLOYS o r ALUMINIUM AND MAGNESIUM.
I t is clear t h a t these alloys, from the point of view of light-
ness, are more important the more magnesium (density : 1-75)
they contain.
(a) Aluminium-Magnesium Alloys. Magnalium, which con-
tains 5-25 % of magnesium, has, for an average content of
magnesium, a density of about 2-80 in the cast state.
MECHANICAL PROPERTIES OF ALUMINIUM-MAGNESIUM ALLOYS.
Jean Escard, in the work just quoted, gives the following
values for alloys containing 2 % and 10 % of magnesium :—
Tensile Strength 2 Elonga
agutSium rea men Kff./mm.2 Tons/in. L 1OH
fir»n
Sand cast 12-6 8-00 3°
2% - Cast and rapidly cooled . 20-1 12-76 2
Cast and quenched 28-1 17-84 1
Sand cast 15 9-52 2-4
10 % • Cast and rapidly cooled . 23-6 14-99 3-4
Cast and quenched 43 27-30 4-2
The effect of quenching on alloys containing magnesium is
marked, but we shall discuss this more fully in connection with
the alloys of the second group (light alloys of great strength).
A very small quantity of magnesium (0-5 to 1 %) is sufficient
to increase the hardness after quenching in a most remark-
able manner; the presence of 30 % to 50 % of magnesium
renders the alloy hard and brittle.
(b) Magnesium-Aluminium Alloys. The magnesium-alu-
minium alloys, t h a t is to say, alloys rich in magnesium, have
been worked out by the Germans during the war, and the
Zeppelin L 49, brought down at Bourbonne, possessed several
parts made of similar alloys. The alloy would be of the type
" Elecktron," known before the war, whose density is 1-8,
and whose conductivity is of the same order as t h a t of zinc;
it contains 90-92 % of magnesium.
These alloys are very difficult to roll, and generally contain
numerous holes and flaws.
86 ALUMINIUM AND ITS ALLOYS
The alloy containing 90 % of magnesium and 10 % of
aluminium possesses the following properties, as cast:—
Elastic Limit = 8 kg. per sq. mm. (5-08 tons per sq. in.)
Tensile Strength = 1 1 kg. per sq. mm. (6-98 tons per sq. in.)
% Elongation =1
Shock Resistance=zero
Their most striking property is lightness, and they should
not he overlooked by aviation authorities, who should take an
interest in perfecting their manufacture.
PHOTOGRAPH 1. PHOTOGRAPH 2.
Copper, 4 % ; Aluminium, 96 %. Copper, 8 %; Aluminium, 02 %.
PHOTOGRAPH 3.
Copper, 12 % ; Aluminium, 88 %.
To face i>.ijj
PLATE IIIA.
PHOTOGRAPH 4.
Copper, 3 %; Zinc, 12 % ;
Aluminium, 85 %.
To lace i SO
PART IV
L I G H T A L L O Y S OF G R E A T STRENGTH
r10t
FIG. 39.—Tensile Test Piece (thin sheet).
DURALUMIN
(Longitudinal)
Kg.m 6:
per
20 30
% Cold Work
F I G . 40.—Variation in Mechanical Properties (Tensile and
Impact) with Cold Work. Metal previously annealed
a t 450° and cooled in air.
15
Elastic Limit
id 10 o.
</>
o
Kg.m6 '12
p e r
cm2 5
4 8\ N % Elongation
3
2
Shock^""-'^'^...
1 Resistance
0
10 20 30 40 50
%Co\6 Work
FIG. 41.—Variation in Mechanical Properties (Tensile and
Impact) with Cold Work. Metal previously annealed
at 450° and cooled in air.
w o r k b e y o n d t h i s p o i n t l e a d s t o a c r a c k i n g of t h e s h e e t s .
Moreover, a stronger plant is required t h a n t h a t usually
e m p l o y e d for working this a l l o y — a point which does n o t
a r i s e i n t h e w o r k i n g of t h i n s h e e t s .
24-
Kg.
£/a$tic
lOO-p'Sr 20 Limit
cm"
90 9
80 8 16
70
— JBrinefl (woo Kg.)
| 60 6 . HarSness "'"
Z ~..J500Kg.)
50|5
]2 40 4
20 2
10
I t i s e v i d e n t f r o m t h e s e figures, t h a t , w h a t e v e r t h e r a t e of
c o o l i n g a:n4 i n w h a t e v e r d i c e g t i o n t h e t e s t p i e c e s a r e c u t ,
DURALUMIN
36 DURALUMIN 36 ( Transverse >
Kg. per (Longitudinal) Kg. per
mm.2 mm.2 20
32 20 32
% Elongation
© 28 28
Strength/
'•CP5
to
/
Ion
15
^ ^ / 15 120
ui ^sT^^^w / 110
cm*
20 10010| 20
Elastic^ /'"^Elongation
Limit *>s I \ / x\ 90 Limits
N /
16 10 a 80 16
^Brine/I
70 '"-*.-J500. Kg.)
"-(1000Kg± "
6 12 60
1\ / .E 50
i! 8 CD 40
% Elongation- \ / ^—•**'
S3 30
I/ 20 2, %
'Shock ":
. / /Resistance. Resistance
10
**•—^.— —
0-
100 200 300 400 50.0 °C 100 200 300 400 500 °C
Annealing Temperature Annealing Temperature
F I G . 4 3 . — V a r i a t i o n i n M e c h a n i c a l P r o p e r t i e s (Tensile a n d FIG. 44.—Variation in Mechanical Properties (TenBile, Hard-
I m p a c t ) with Annealing Temperature. Metal subjected ness, and Impact) with Annealing Temperature. Metal sub-
t o 5 0 % Cold W o r k , a n n e a l e d a n d cooled i n a i r . jected to 50 % Cold Work, annealed, and cooled very slowly.
94 ALUMINIUM AND ITS ALLOYS
there are two particularly interesting annealing temperatures,
i.e. (1) 350°-375°, (2) 475°-500°.
The following table summarises the results obtained on
the longitudinal test pieces for these temperatures, after 50 %
cold work:—
DURALUMIN
Kg. per (Transverse)
mm. 2
32 20
28
•of) 15
55. -
c
jO
UJ £/astfc\
Limit \
12
o4
% Elongation:
13
/ sShock
/ / Resistance
s s
100 200 300 400 500 °C
Annealing Temperature
FIG. 45.—Variation in Mechanical Properties (Tensile and
Impact) with Annealing Temperature. Metal subjected
to 50 % Cold Work, annealed and cooled in air.
QUENCHING
(a) CBITICAL P O I N T S .
A RESEARCH on the critical points of alloys of the duralumin
type has been carried out by Chevenard, using a differential
dilatometer.*
Fig. 46 shows the results obtained on comparing duralumin
with pure aluminium.
502°
70 •2 8
°/o Elongation
60 24 15
Tensfk Strenqth
50
J40 16'" y 10
Elastic Limit
o
I 30 _. %^/ongaf/on _
2Of2-
Resistance
10
2 4 6 8 Days
Time after Quenching
I m m e d i a t e l y after quenching
48 hours „ „
4 days
5 days
8 days „ „
98 ALUMINIUM AND ITS ALLOYS
Fig. 63 shows the variation of mechanical properties with
quenching temperature after a uniform ageing of eight days.
N O T E S .
DURALUMIN
2 4 - 6 8 Days
Time after Quenching
F I G . 48.—Variation in Mechanical Properties with T i m e
after Quenching (from 350°).
80 jot 80 20
20 £
Hardness
(500 Kg)
70
CD
P//
C
60 15
d
0 %Elongatiori
.5 5 0 Q.
50
a o
Kg.m 4 16 10
10
per
ShocK
t.3 12 Resistance
Q.
2 2O Limit
v
~ 0 2 4 ~ ~ 6 8cfays 0 2 4 6 8 Days
Time Time CD
FIG. 49.—Variation in Mechanical Properties with T i m e F I G . 50.—Variation in Mechanical Properties with Time
after Quenching (from 400°). after Quenching (from 450 # ).
DURALUMIN
DURALUMIN
o
TOO 25 100 40 Kg 25
per o
%E s' mm 2
90 90 36
% Elongation Hardm$s
8 0
.£ £ 60 15
Elastic
CO
Limit ^ ^ m
<D
Kg.m Kg.m CL
per per
cm 2 c cm 2
4ko 16 \Elongation.y O"
f
>s
*' Resistance *.
30 1^ Shock Resistance 3 30 12
/
2)20
1 % Elongation
0
0 2 4 6 8 days 4 8cJays
Time Time
FlG. 5 1 . — V a r i a t i o n i n M e c h a n i c a l P r o p e r t i e s w i t h T i m e FIG. 52. - V a r i a t i o n in Mechanical Properties with Time
a f t e r Q u e n c h i n g (from 500°). after Quenching (from 550°).
QUENCHING 101
OURALUMIN
100 40 Kg per 25
90 36
% Elongation
80 32 20
70 28
24 Tensile Strength
I 60
El as tic. Urn ft c
0
MPMJt CL
.£ 50
CO
» sr "::V..... , , 11 c
o
tn
Hardness.. "••••'."' / 1
16 .,.."-'(500 Kg) \ ID "
per
v./ • • • " \
12
/ v \
8 ^Aoc/r i
\
4 <% Elongation
Temperature
F I G . 53.—Variation i n Mechanical Properties w i t h Quenching
T e m p e r a t u r e (after 8 d a y s ) .
A 20
32 .<y
Brlnell
Number
120 24 Elastic^ Hardnes^^ ^ ^ ^^ 15 in.2
11 0 Kg.
m £_
O
1 0 0 per C%_
90
80
°t8 \ ^ -"""Hardness (50o"'Kg.) * ^ ^ \ 10
^.
(0
c
0
70 7
80 6
50 5
f ^ Sh ft
40 4 5
V/^y N '*-' Resistance" \J
30 3
20 2 4
10 1
0 o00 2 0
4 6 8 10 12 14- 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 HOUTO
Time after Quenching
(c) V A B I A T I O N O F M E C H A N I C A L P R O P E R T I E S W I T H D U R A T I O N
O F T I M E A F T E R Q U E N C H I N G .
25
20
S \Hardncs8-;~°>
\... r . - / (0
C
I
XA /o Elongation,.,.
„.-.- 1'50Q Kg)
Hardness
1 0 °
= eo
50
^ , Shock^
*' Resistance
20
10
id 1A 46 56 ab tfo i66 flo i*o 1^61^ 1S6 <6o 1)6 i6o i^ 0
Dfty»
1 3 24 5 6 ; 8
Time after Quenching
Fio. 55.—Variation in Mechanical Properties with Time after
Quenching from 475° (during first 8 days).
This table shows that all the metal of this consignment has
the following properties :—
Elastic Limit . (23 ± 1 ) kg. per sq. mm. ((14-6±-63) tons
per sq. in.)
Tensile Strength. (38 ± 1 ) kg. per sq. mm. ((24-13±-63) tons
per sq. in.)
% Elongation . 14-5±0-5
After a lapse of time varying from one to three years, the
properties lie between the following limits :—
Elastic Limit . (26±3) kg. per sq. mm. ((16-51 ±1-9) tons
per sq. in).
Tensile Strength. (41 ± 3 ) k g . per sq. mm. ((26-03±1-9) tons
per sq. in).
% Elongation . 15-20.
With the exception of one test piece giving 11-05 % Elonga-
tion, a n increase in the value of all the properties can be
observed.
These particular tests, then, do not reveal any deterioration
of the metal, but, on the contrary, a slight general improvement.
I n order t o draw a reliable conclusion, we must await the final
results of t h e methodical experiments now in hand—experi-
ments in which the values of the original properties are reliable
on account of the number of the tests and the particular care
108 ALUMINIUM AND ITS ALLOYS
taken in carrying them out. These experiments will allow u s
to find out definitely whether there is any gradual improvement
in the properties.
VARIATION o r THE TIME EEQUIRED TO REACH E Q U I L I B R I U M ,
WITH THE TEMPERATURE AFTER QUENCHING.
The preceding tests constitute an investigation of t h e t i m e
required to reach Equilibrium after quenching, in which t h e
changes after quenching have been allowed to take place a t
the normal temperature. The effect of the temperature after
quenching on the attainment of Equilibrium has been investi-
gated by means of supplementary experiments.
The following temperatures were employed :—
- 20° C.
o°c.
+ 20° C.
+100° C.
150°
200°
250°
300°
350°
Immediately after quenching, test pieces were maintained
at each of these temperatures for 1, 2, 3, 4, 5, a n d 6 hours
respectively, i.e. some at —20°, others at 0°, other at + 2 0 ° , etc.
Tensile tests were carried out after each of these periods of
time, after warming up or cooling to air temperature.
The results can be summarised as follows :—
Temperature —20° After six hours there is no change in
properties.
„ 0° No change after six hours.
„ +20° After six hours the Tensile Strength
has increased by 4 kg. per sq. m m .
(2-54 tons per sq. in.) to t h e value
34 kg. per sq. mm. (21-6 tons per
sq. in.).
„ 100° After six hours the Tensile Strength
has increased by 8 kg. per sq. m m .
(5*08 tons per sq. in.) and become
38 kg. per sq. mm. (24-13 tons \>er
sq. in.).
All the properties have attained their
mean normal values.
QUENCHING 109
Temperature 150° All the properties have attained their
mean normal values after two
hours.
9, 200° The process is simply a n anneal and
and above t h e rate of cooling has a pronounced
effect.
The results obtained are strictly con-
cordant with those drawn dia-
grammatically in Fig. 57 (variation
of mechanical properties with tem-
perature of reanneal after quenching
from 475°).
F r o m these tests the following conclusions m a y be drawn :—
Changes after quenching are retarded b y low temperature.
They become more rapid as the temperature immediately
after quenching is raised between the limits of 0° and 150°,
temperatures above 150° causing, after similar cooling to air
temperature, changes in the properties. If t h e alloy be im-
mersed in boiling water, for example—a very practical pro-
cedure—Equilibrium is reached much more rapidly.
Immediately after quenching.
Tensile Strength = 3 0 kg. per sq. mm. (19-05 tons per sq. in.)
Elastic Limit = 1 0 kg. per sq. mm. (6-35 tons per sq. in.)
% Elongation =18
After immersion in boiling water for one hour after quenching.
Tensile Strength =35-5 kg. per sq. mm. (22-54= tons per sq. in.)
Elastic Limit = 1 7 - 5 kg. per sq. mm. (11-10 tons per sq. in.)
% Elongation =20
After immersion in boiling water for two hours after quenching.
Tensile Strength = 3 7 kg. per sq. mm. (23-49 tons per sq. in.)
Elastic Limit =18*5 kg. per sq. mm. (5-40 tons per sq. in.)
% Elongation =20
After six hours under these conditions.
Tensile Strength = 3 7 kg. per sq. mm. (23*49 tons per sq. in.)
Elastic Limit = 2 0 kg. per sq. mm. (12-7 tons per sq. in.)
% Elongation =20
Values which remain approximately un-
changed after further immersion in boiling
water.
Thus, by immersion in boiling water after quenching,
Equilibrium is reached more rapidly—an effect which is of
interest from the industrial point of view.
CHAPTER I I I
DURALUMIN
Kg per
mm2 25
20
\
in
\ Elondaiion
c
o
.8
£ \\ \ / Hardness,---
2 noooy ....
60 6 12
50 5 Resistance
30
2O
10 1
25
20
140
130
Z4^Elastic Limit
120
15
no
100
^'fyodb'fCgT'y^%£/ongath fon Q.
I 90
lao
70
(500 'Kg.) -•-.... \ \ \ . ^ ^
ol
=
60
I 2 \ \ " */
30 3
20 2
10 1
Fig. 56. Q u e n c h i n g f r o m 4 7 5 ° , r e a n n e a l i n g f o l l o w e d by
v e r y s l o w c o o l i n g (rate (i)).
T h e most interesting points o n these curves correspond w i t h
t h e reannealing temperature 400°.
For this temperature :—
T e n s i l e S t r e n g t h =22 k g . p e r s q . m m . ( 1 3 - 9 7 t o n s p e r s q . i n . )
Elastic Limit = 7 kg. per sq. m m . (4-44 t o n s per sq. i n . )
% Elongation =22
S h o c k R e s i s t a n c e = 5 kg. m. per sq. c m .
DURALUMIN
Kg per
25
36
% Elongation
32 Tensile A
Strengths
20
28
130
JIYV Hardness. ^ - . ^
100 JO
£. 90^9 y
.a
Hard 10
"(500 Kg) x
= 60 6
<D
£ 50 " Shock
Resistance
30 3
20 2
T h i s is a s o f t e n i n g t r e a t m e n t , g i v i n g v a l u e s a p p r o x i m a t e l y
equal to those produced b y the softening process p r e v i o u s l y
d e s c r i b e d b u t e n t a i l i n g a m o r e c o m p l i c a t e d m e t h o d of w o r k i n g .
VARIATION IN MECHANICAL P R O P E R T I E S 113
Fig. 57. Quenching from 475°, reannealing, followed by
cooling in air (rate (ii)).
No particular advantage.
Fig. 58. Quenching from 475°, reannealing and quenching
in water (rate (iii)).
The most interesting values are those corresponding with
the range of annealing temperatures 475°-500°.
This is simply a process of double quenching and gives the
alloy the following properties :—
Tensile Strength = 4 0 kg. per sq. mm. (254 tons per sq. in.)
Elastic Limit = 2 3 kg. per sq. mm. (14-6 tons per sq. in.)
% Elongation =22
Shock Resistance=5 kg. m. per sq. cm.
I t is clear from these values that a double quenching is
superior to a single one. Two quenchings improve the Elastic
Limit, the Elongation, and the Shock Resistance, and should
therefore be employed if the maximum values of these proper-
ties are required in the finished metal.
CONCLUSION.
From the practical point of view, this type of light alloy can
be subjected, after cold work, to three treatments :—
(1) Annealed at 350° and cooled very slowly (rate (i)), giving
the most suitable intermediate state from the point of
view of further mechanical work. This is the softening
process.
(2) Annealed at 475° and quenched, yielding the hardened
or final state.
(3) Annealed at 475°, quenched, reannealed at 475°-500°,
and quenched again. This process—double quenching
—yields the optimum final state.
CHAPTER I V
'0
E
E
x
Kg. ^^.^Jnjermedia te
Breaking ^te'bj--^
<S) Load cooling ^'
<n
2 6 1500 (air)
£
1400
JZ !Break in a\ j Rapid
1300 ~~Load I cooling
/(Quench)
1200
r ^Slou) cooling
sfntermediatd^Jbath)
900
300 325 350 375 400 425 450 475 500 °C
Annealing Temperature
FIG 59.—Variation in Breaking Load and Depth of Impression with Annealing
Temperature. Anneal followed by cooling at varying rates :
— • * — • — ^ — - very slow.
——— cooling in air (intermediate rate).
—— . — . cooling in water (quenching; very rapid).
R E S U L T S OF CUPPING TESTS 115
The following temperatures of annealing after cold work
and the following rates of cooling have been employed :—
Temperature of a n n e a l : 300°, 350°, 400°, 450°, 475°.
Rates of cooling : (i), (ii), and (iii) (as previously defined).
Fifteen circles were heated at each of the above tempera-
tures, and of these, five were cooled very slowly (rate (i)),
five in air (rate (ii)), and five quenched (rate (iii)).
The results of the tests are shown in Fig. 59, representing
the curves for t h e breaking loads and for the depths of impres-
sion corresponding with the different rates of cooling, plotted
against varying annealing temperature.
The general shape of these curves shows very clearly the
remarkable results of annealing at 350° and cooling very slowly
(rate (i)). This treatment gives to the alloy the maximum
ductility, and in this molecular state the maximum depth of
impression is produced.
These cupping tests confirm the preceding tests, and we
can conclude t h a t annealing a t 350°, after cold work, followed
b y very slow cooling (rate (i)), is the optimum treatment for
softening the metal, i.e. for producing maximum ductility and
maximum malleability.
Certain cupping tests have been carried out on sheets
possessing different degrees of cold work (20-100 %) under
t h e same experimental conditions, i.e. annealing at the specified
temperatures and cooling according to the three rates of
cooling mentioned.
The same conclusions were arrived at as in the case of 40 %
cold work. Furthermore, the final values, after annealing a t
350° or at 475°, followed b y variable rates of cooling, vary
directly with the amount of cold work. The maximum malle-
ability is thus obtained, for thin sheets, by cold working to the
amount of 100 % , and annealing at 350° followed by very slow
cooling.
CHAPTER V
H A R D N E S S d e t e r m i n a t i o n s w e r e m a d e a t e v e r y fifty d e g r e e s
u p t o 600° o n s i x t y cylindrical t e s t pieces, 2 0 m m . l o n g a n d
20 m m . i n diameter. T h e pressure u s e d w a s 5 0 0 kg.
T h e r e s u l t s are s h o w n i n F i g . 6 0 , w h i c h s h o u l d b e c o n s i d e r e d
side b y side w i t h t h o s e o b t a i n e d u n d e r t h e s a m e c o n d i t i o n s for
aluminium and casting alloys.
170
160
150
140
130
120
£. 110
G>
1=1
Z 90
"S 80
I 70
60
50J
40
30
20|
i
10
v
0 50 100 150 200 300 400 500 60O 700°C
Temperature
F i a 60.—High Temperature Hardness Tests (500 Kg.) on Duralumin
quenched from 475°.
PART V
MECHANICAL PROPERTIES
90 % Copper—10 % Aluminium
CHEMICAL ANALYSIS.
Copper . . . .89-15
Aluminium . . 10-10
Manganese
g . . 0-30
IIron 0-25
Nickel nil
Zinc nil
Lead nil
Tin nil
Difference 0-2
100-0
(£>) I D E T E B M I N A T I O N OF CRITICAL P O I N T S .
T h e s e critical points have been investigated b y Chevenaxd,
r t r x c l t h e results are shown in the following diagrams.
-2
F I G . 62.—Aluminium Bronze, T y p e I.
Ac 3_
Aci
F I G . 6 5 . — A l u m i n i u m Bronze, T y p e I. Tornporatnro
n o t exceeding Ac3.
(c) V A R I A T I O N I N T H E M E C H A N I C A L P R O P E R T I E S O F C U P R O -
ALTJMINITTM ( T Y P E I), T E N S I L E A N D I M P A C T , W I T H T H E
A N N E A L I N G T E M P E R A T U R E .
80 50
per
2
70 mm 45
40
60
35
50 Tensi!e_
Strength 30 f
©
40
25 Q.
Id
30 20 §
20 15
Shock, 10
10
Resistance 5
"0 100 200 300 400 500 600 700 800 90%'C
%'
Annealing Temperature
FIG. 66.—Variation in Mechanical Properties (Tensile and
Impact) with Annealing Temperature. Cast Aluminium
Bronze, Type I (Cu 90 %, Al 10 % ) .
( c 2 ) Alloy as Forged.
T h e variations in the properties are summarised in F i g . 67.
I n t h e forged state, cupro-aluminium ( T y p e I) h a s t h e
following properties :—
Tensile Strength = 5 6 kg. per sq. m m . (35-56 tons per sq. in.)
Elastic Limit = 3 2 kg. p e r sq. m m . (20-32 tons per s q . in.)
% Elongation =10
Shock R e s i s t a n c e = 2 t o 3 kg. m . per sq. c m .
124 ALUMINIUM AND ITS ALLOYS
Annealing at 850° especially improves the Shock Resistance
and Elongation, whilst lowering the Elastic Limit:—
Tensile Strength =55 kg. per sq. mm. (34-92 tons per sq. in.)
Elastic Limit =22 kg. per sq. mm. (13-97 tons per sq. in.)
% Elongation =24
Shock Resistance = 6 kg. m. per sq. cm.
80 Kg 50
per
45
70- "
Tensile Strength 40
60
35
CN
§50 30-5
C
<D
40
Elastic Limit 25 CL
LJ
30
20 §
20 15
10
5
0 100 200 300 400 500 600 700 800 900"C
Annealing Temperature
FIG. 67.—Variation in Mechanical Properties (Tensile and Impact)
with Annealing Temperature. Forged Aluininrum Bronze,
Type I (Cu 90 %, Al 10 %).
T h e v a r i a t i o n s i n t h e p r o p e r t i e s are s u m m a r i s e d i n F i g . 6 8 .
T h e m a x i m u m Shock R e s i s t a n c e a n d E l o n g a t i o n are o b t a i n e d
b y quenching from 600°, w h i c h results i n t h e following proper-
ties in the cast m e t a l : —
~& d i s t i n c t i m p r o v e m e n t o n t h e o r i g i n a l c a s t a l l o y ,
MECHANICAL P R O P E R T I E S 125
(d2) Alloy as Forged.
The variations in the properties are summarised in Fig. 69.
Quenching from 500° has little effect on this cupro-alu-
minium, which retains approximately t i e properties t h a t it
possessed in the forged state. The effect of quenching from
above 500° is distinctly noticeable.
°[Kg
per
45
70 Tensile
Strength
40
60
35
50
30
40 Elastic, AC
2 5
UJ 'Limit
30
15
Shock
20 Resistance
10
10
45
40
Tensile Strength
35
30 «_
Elastic Limit
25 I
20
30 1
15
20
10
CONCLUSION.
The following is the optimum thermal treatment for cupro-
aluminium (Type I) (90 % copper, 10 % aluminium) :—
Quenching from 900°.
Reannealing at 675°-700°.
(/) H A R D N E S S AT H I G H TEMPERATURES.
Normal Temperature.
H a r d n e s s of w o r k e d alloy u n d e r 5 0 0 k g . == 1 5 0 - 1 6 0
H a r d n e s s of cast alloy under 5 0 0 k g . =100-110
H a r d n e s s of q u e n c h e d a n d r e a n n e a l e d a l l o y under
500 kg.=110-120
100
150
140
130
120
w no Quenched \ fJ/ , .
and Reannealed \Worked
t 100
"S 90- \
^ 80 \
^o 70
60
CD
50
40
30-
20
10-
Effect of Temperature.
II. TYPE II
Cupro-Aluminiums containing 89 % Copper, 10 % Alu-
minium, 1 % Manganese
(a) CHEMICAL ANALYSIS.
Copper . . . .89
Aluminium . . .9-50
Manganese . . .0-95
Iron . . . .0-25
Nickel . . . . nil
Lead . . . . nil
Tin nil
Difference . . .0-30
100-00
1--1CT
F I G . 7 3 . — A l u m i n i u m Bronze, T y p e I I .
oo 7QQ .
F I G . 7 4 . — A l u m i n i u m Bronze, T y p e I I .
40
60
Tensile Strength 35
5(H
§ 30 ^
~c5 Elongation
40 25 |
-2
LU 30 20 £
Kg.m per
15
20
10
Shock Resistance
10
5
§50 20 30
JE
18
C40 % Elongation 25
JO 14
UJ i 20 §
^ 3 0 12 © h-
a
10 g
20 Resistance
8 £? 10
6
10
4
2
0 400 500 600 700 800 900°C
Quenching Temperature
FIG. 76.—Variation in Mechanical Properties (Tensile and Impact)
with Quenching Temperature. Forged Aluminium Bronze,
Type II (Cu 89 %, Mn 1 %, Al 10 %).
80J
V
O 100 200 300 400 500 600 700 800 900°C
Annealing Temperature
F I G . 77.—Variation in Mechanical Properties (Tensile a n d I m p a c t )
with Temperature of Reanneal after Quenching from 800°.
Forged Aluminium Bronze, Type I I (Cu 89 %, Mn 1 %, Al 10%).
80r
CONCLUSION.
(/) H A R D N E S S AT H I G H TEMPERATURES.
The hardness tests at high temperatures were carried out
under t h e same conditions as for Type I, and the results are
shown i n Tig. 78&.
T h e y were carried out only on the heat-treated alloy
( q u e n c h e d from 900° and reannealed a t 600°).
T h e y reveal a greater hardness than that of Type I for all
t e m p e r a t u r e s between 0° and 500°, but a slightly lower hard-
ness for temperatures above 500°.
10*
8 1 % C o p p e r , 11 % A l u m i n i u m , 4 % N i c k e l ,
4 % Iron
Copper 80-95
Aluminium 10-60
Manganese 0-45
Iron 4-40
Nickel 3-55
Lead nil
Tin . nil
Difference 0-05
100-00
N e i t h e r t h e e x p a n s i o n c u r v e n o r t h e c u r v e of t e m p e r a t u r e
p l o t t e d against t i m e indicates the slightest transformation
(see F i g s . 79 a n d 80).
QO
Temperature
0 TOO 200 300 4Q0 500 600 700
80 Tensile Strength
45
70
40
60
Elastic Limit 35
O50 30 °c
3 25 |
C 40
O
til 20 §
# 3 0
10 Kg. m. pen 15
cm2
20 8
10
6
ro Elongation
10 5
Shock Resistance
Tensile Strength
80 T Kg 50
per
mm 2
45
40
60
Elastic Limit 35
50
30
J 40 25
HI C
o
20
30
per
20 cm 2
%_£longation
10
10
The results of the tests are shown in Fig. 82, which shows
t h a t the change in the properties of the alloy after quenching
is only insignificant.
MECHANICAL PROPERTIES 141
(e) VARIATION I N THE MECHANICAL PEOPERTIES, T E N S I L E
AND IMPACT, WITH THE TEMPERATURE OF REANNEAL,
SUBSEQUENT TO QUENCHING THE FORGED ALLOY,
TYPE III.
The results of reannealing after quenching from 900° are
shown in Pig. 83, which shows t h a t the mechanical properties
undergo no appreciable improvement after quenching from
900° and reannealing.
CONCLUSION.
The following method of working seems to be advisable:
annealing at 900°, followed by cooling in air.
(/) HARDNESS AT H I G H TEMPERATURES.
The results are summarised in Fig. 836.
The tests were carried out on metal annealed at 900°, and
show, for all temperatures, a hardness greater than t h a t of
the alloys of Types I and II.
180
170
Temperature
F I G . 8 3 6 . — H i g h - t e m p e r a t u r e H a r d n e s s T e s t s (500 K g . ) o n
A l u m i n i u m Bronze, T y p e I I I , A n n e a l e d a t 900 .
CHAPTER I I I
MICROGRAPHY
I. CUPRO-ALUMINIUM, T Y P E I
(a) MICROGEAPHIC EXAMINATION OF SECTIONS OF METAL
FORGED AND SUBSEQUENTLY ANNEALED AT DIFFERENT
TEMPERATURES.
Plates I and I I give the microphotographs of these sections.
We will comment upon them in turn.
PLATE I.
PHOTOGRAPH 1. PHOTOGRAPH 2.
CUPRO-ALUMUSTIUM. AS FORGED. ClTPRO-ALUMINIUM. As FORGED.
/. 00. / 225.
PHOTOGRAPH 3. PHOTOGRAPH 4.
OUPRO-ALUMINIUM. FOROKD AND CUPRO-ALUMINIUM. FOU(JKI) AND
SUBSEQUENTLY ANNEALED AT 300°. SUBSEQUENTLY ANNEALED AT 300\
/ (JO.
To i'-M-v, I«I^I»
PLATE In.
PHOTOGRAPH A. PHOTOGRAPH B.
EtJTECTIG STRUCTURE. ETCHED WITH EUTEOTKJ STRUCTURE. E'rviIKI) WITH
ALCOHOLIC! FERRIC CHLORIDE. ALCOHOLIC FIORRH! CIILOIU!) K.
< 500. / K70.
(Porte vin.) (Porlovin.)
To i
PLATE II.
PHOTOGRAPH 5. PHOTOGRAPH 0.
CUPRO-ALUMINIUM. FORGED AND CUPRO-ALUMINIUM. FORGED AND
SUBSEQUENTLY ANNEALED AT 700°. SUBSEQUENTLY ANNEALED AT 700°.
X 60. X 225.
PHOTOGRAPH 7. PHOTOGRAPH 8.
ClJIMtO-ALUMINIUM. FoiU.iED AND OUPRO-ALUMINIUM. FORGED AND
.SUBSEQUENTLY ANNEALED AT 000°. .SUBSEQUENTLY ANNEALED AT 900°.
/. 00. X225.
PHOTOGRAPH 9. PHOTOGRAPH 10
To faco
PLATE IV.
TYPK I. FORGED AND SUBSEQUENTLY QUENCHED.
PlIOTOfJRAIMI K).
AND C(/I'RO-AM;MIN£I;M. FOKUKD AND
.FROM 800 . SUBSEQUENTLY O.UKN('IIKD FROM. 800".
y."2'2r>.
(Brouil.) (lireuil.)
PLATE V.
TYPE I. FORGED AND SUBSEQUENTLY QUENCHED.
PHOTOGRAPH 17.
CUPRO-ALUMINIUM, FORGED AND
SUBSEQUENTLY QUENCHED FROM: 900°.
X (SO.
(Breuil.)
PHOTOGRAPH 18.
CUPRO-ALUMINIUM, FORGED AND
SI'BSEQUENTLY QUENCHED FROM 900°.
X 225.
(Breuil.)
MICROGRAPHY 143
(i) Forged Alloy (not subsequently annealed).
See Photographs 1 a n d 2 of Plate I.
We note the two constituents previously mentioned—the
a constituent and the (a-f-y) eutectoid, which we will call
E. The a constituent appears as white dendrites, while the
eutectoid appears black.
According to Portevin,* the constitution of the eutectoid
is as follows :—
" The ]8 constituent f of the aluminium bronzes can exhibit
two formations, firstly, a cellular or honeycombed n e t w o r k ;
and, secondly, a considerably finer, lamellar, structure, analo-
gous to the pearlite in annealed steels.
These two formations can coexist in contiguous portions of
the same alloy, the reticular form being favoured in the portions
adjacent to the proeutectoid constituent a.
The lamellar form of eutectic is only capable of resolution
under high magnifications in slowly cooled alloys, while,
under the same conditions of cooling, the reticular form is
visible under low magnifications."
See Portevin's microphotographs, Plate I B .
PHOTOGRAPH 22.
rHOTOQUAPH 2 1 .
FORGED,
(.!i-!»R()-AM:MiNi.uivr. FORGED, QUENCHED
FKOM IHMT, RKANNEALED AT 000°.
/GO.
PLATE VII.
TYPE I. FORGED, QUENCHED, AND REANNEALED.
PHOTOGRAPH 31.
CDTRO-ALXJMINIUM. CAST ANI>
ANNEALED AT 900°.
X60.
PHOTOGRAPH 32.
CUPRO-ALUMINIUM. CAST AND
ANNEALED AT 900°.
X225.
To face page 144.
PLATE X.
PHOTOGRAPH 33.
CtfPRO-ALUMINIUM. CAST AND
QUENCHED FROM 500°.
XOO.
PHOTOGRAPH 36.
CUPRO-ALUMINIUM. CAST AND
QUENCHED FROM S00°.
X 60.
PHOTOGRAPH 37.
CUPRO-ALUMINIUM. CAST AND
QUENCHED FROM 900°.
X 60.
To face i'a#
PLATE XL
TYPE II. FORGED AXD ANNEALED.
To face \-SL^ iu
PLATE XII.
TYPE II. QUENCHED AND UEANNEALED.
m m m m
PHOTOGRAPH 42.
CRJPRO-ALUMINIUM. QUENCHED FROM 000°
REANNEALED AT ()00°.
X 00.
PHOTOGRAPH 43.
CUPRO-ALUMINIUM. QUENCHED PROM 000°,
AT 000°.
/. 2^5.
To faco page 144
PLATE XIII.
TYPE III. FORGED AND ANNEALED.
m m
PHOTOGRAPH 48.
ClJPRO-ALUMINIUM. FORGED AND
ANNEALED AT 800°.
X 60.
PHOTOGRAPH 49.
CUPRO-ALUMINIUM. FORGED AND
ANNEALED AT 900°.
X225.
To face page. 1 14.
PLATE XV.
PHOTOGRAPH 54.
CUPRO-ALUMINIUM, QUENCHED FROM! 900°
XGO.
PHOTOGRAPH 55.
CUPRO-ALUMINIUM. QUENCHED PROM 900°.
X 225.
II. CuPEO-ALUMiNnjM, T Y P E I I
The Photographs 38 and 39, Plate X I , refer to the alloy of
T y p e I I , as forged, a n d Photographs 40 a n d 41 refer t o t h e
same alloy as annealed after forging. They show t h e same
two constituents as do t h e preceding bronzes.
Photographs 42 and 43, Plate X I I , show t h e development
of t h e same structure after quenching from 900° a n d reannealing
at 600°.
SIS O F ALUMINIUM
vium.
metal in 100 c.c. hydrochloric acid (1 :3)
a solution is complete, transfer the liquid
evaporate to dryness on a sand bath—to
le.
oncentrated hydrochloric acid and 100 c.c.
aluminium salts are completely dissolved ;
acting the filtrate in a graduated flask of
to cool, and make up to the mark with
;he liquid into a flat-bottomed flask of
shake vigorously to make the mixture
147
148 ALUMINIUM AND ITS ALLOYS
(b) Estimation of Iron.
Act upon 2 gm. of the metal with 30 c.c. of 35 % soda (NaOH)
in a conical flask, first in the cold, then on a sand bath, until all
the aluminium is dissolved. Allow to settle, decant carefully,
transfer to a filter with distilled water and wash.
By means of a jet of water, transfer the oxide of iron to a conical
flask; dissolve by the addition of a few cubic centimetres of sul-
phuric acid ; reduce by means of zinc, and titrate against perman-
ganate of potash.
155
156 ALUMN
IU
IM AND ITS ALLOYS
*1
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A P P E N D I X I V
L A B O R A T O I R E D'ESSAIS R E P U B L I Q U E FBANCAISE.
MECANIQTJES, P H Y S I Q U E S , Ministere d u C o m m e r c e , de T i n
Registered, N o v .2 7 t h , 1 9 1 8 .
Object. Tensile tests o n test pieces of s h e e t aluminium after
thermal treatment.
N A T U R E O F S A M P L E S S U B M I T T E D .
(1) 0 * 5m m .t h i c k m a r k e d 5.
(2) 2 - 0m m .t h i c k m a r k e d 2 0 .
E a c h of t h e s e series c o n s i s t s of m e t a l h a v i n g t h r e e d e g r e e s of cold
work, n a m e l y : - 5 Q % m a r k e d R
1 0 0 % m a r k e d C.
300 % marked D .
Metal of e a c h of t h e a b o v e t h i c k n e s s e s a n d d e g r e e s of c o l d work
has been annealed under t h e following conditions : —
All t h e test pieces requiring t h e same anneal were pierced with
a h o l e a t o n e e n d a n d t h r e a d e d o n t o t h e s a m e p i e c e o f w i r e , 6 - 8m m .
apart, so as t o be immersed simultaneously in t h e annealing bath,
which w a s continuously stirred.
S h e e t s 4 0 m m . s q u a r e a n d circles 9 0 m m .i n d i a m e t e r , f o r micro-
graphic examination a n d cupping tests respectively, were subjected
to t h e s a m e anneal a t t h e s a m e t i m e a s t h e tensile test pieces.
R E S U L T S .
A. PBEUMINAKY TESTS *
* These tests have been carried out with a view to investigating the
minimum length of time necessary for complete anneal at any given tempera-
ture, "using test pieces of any given thickness.
As a result of these preliminary tests, the following experimental condi-
tions have been adopted for both types of test piece:
Temperature and anneal. Duration (minutes).
150°—300°(inclusive) 5
350°—500° „ 3
550°—600° „ 1
RemarJc8.—(1) Broken outside gauge length.
(2) Broken on gauge mark.
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162 ALUMINIUM AND ITS ALLOYS
A. PRELIMINARY TESTS—continued
Apparent Tensile
Anneal Elastic Limit Strength Elonga- Re-
Temperature Duration Maries tons Kg tons tion marks
(degrees C.) (minutes) mm2 in2 mm2 in3
B. FINAL EXPERIMENTS
Apparent Tensile
Anneal Elastic Limit Strength limn
Temperature Duration Marks Kg tons /o mtukH
(degrees C.) (minutes) 'in*"
mm8 in*
B31 12-9 819 140 8-80 12-7
B32 13-8 8-76 13-8 8-70 13*0
B33 13-1 8-32 15-4 9-78 !.{•«>
C31 14-8 9-40 14-8 9-40 11-7
5- C32 14-5 9-21 150 9-52 10-0
C33 14-2 9-02 14-6 9-27 8-3 U)
D31 17-1 10-87 17-0 11-18 0-0
D32 15-4 9-78 15-4 9-78 3'3
:
16-9 10-73 17-3 10-01) 5-0 U)
103° 5 B31 11-5 7-30 120 7-02 13'H
B32 11-1 7-05 120 7-02 14*0
B33 11-1 705 120 7-02 12-0
C31 12-1 7-68 13-5 8-f>7 14*0
2Q< C32 12-4 7-87 13-7 8-70 JOO (1)
C33 12-4 7-87 130 8 04 13*0
D31 14-9 9'4:6 100 1010 7-0 (I)
D32 13-9 8-83 15-8 10-03 0-0 (1)
D33 13-7 8-70 100 10-10 00 (I)
fB34 121 7-68 13-4 sr>i 13 3
B35 13-8 8-76 130 8-04 lf><0
B36 13-0 8-25 13-48 8-50 ifrO
C34 10-4 6-GO 14-7 0*33 KM)
C35 13-5 8-57 140 9-27 10-0
C36 12-9 819 14-9 9 "10 03 (1)
D34 12-5 7-94 10-13 10-24 3 "3 (I)
D35 13-9 8-83 14-5 9-21 3-3 (0
ll)36 12-3 7-81 14-9 9-4 0 3 *3 (1)
150 5 fB34 10-6 6-73 121 7-08 13 0
B35 10-9 6-92 12-4 7-87 I4'0
B36 10-C 6-73 12-0 7-02 13 0
C34 121 7-68 13-0 8-25 14-0
20 < C35 11-7 7-43 131 8-32 1JW)
C36 11-5 7-30 13-3 8-45 12-0
D34 12-9 819 15-4 9-78 8-2
3335 14-0 8-89 150 $M>1 0-2 (1)
D36 13-2 8-38 15-5 9-84 7 «4
fB37 120 7-62 12-2 7-75 in -3
B38 11-5 7-30 13-2 8-38 100
B39 11-8 7-49 13-2 8-38 10$ (I)
C37 130 8-25 14-4 9 14 10-0 (1)
5. C38 13-4 8-51 15-2 9 05 UiO
C39 13-4 8-51 141 8-9H 7-7
D37 13-7 8-70 10-5 10-48 i»'7 (I)
D38 14-2 902 17-0 1118
199° 5 ,D39 13-5 8-57 17-0 10-70 til) (I)
B37 9-6 610 11-5 7-30 I H ml
B38 10-3 6-54 12-0 702 UhU
B39 10-0 6-35 110 7-37 10-2
C37 12-0 7 02 13 0 8-2f> IHU
20. C38 120 7-62 13-2 8 «38 1(5-1
C39 11-0 6-98 12-8 17 0
D37 13-8 8-76 154 9-78 100
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166 ALUMINIUM AND ITS ALLOYS
B. FINAL EXPERIMENTS—continued
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PRELIMINARY TESTS*
Briuell Hardness
Anneal Apparent Tensile (using ball, 10 mm. in diameter)
Elastic Limit Strength Elonga- S-s
Series Marks tion s
Temp, Duration Kg tons Kg tons % 500Kg. 100()Kg.
(degrees C.) (minutes) mms inJ mm2 ill* Reduction Diam. Hardness Diara. Hardness
(nun.) Xo. (mm.) No.
* These tests have been carried out with a view to investigating the minimum length of time necessary for complete anneal at
any given temperature. m t . . . .
As a result of these preliminary tests, the following experimental conditions have been adopted:
100°—250° (inclusive)
275°—450°
450°—600°
SERIES Bl. (100 % COLD WORK)
Anneal Tensile Properties Shock Properties
Apparent Tensile Brinell Hardness (using 10 mm. ball)
Temp, Duration Marks Elastic Limit Strength Elonga- S-8 1000 Kg. Shock Angle
(degrees C.) (minutes) Kg tons Kg tons tion 500 Kg. Resistance of
Reduction Diam. Hard- Diara. Hard- Rupture
1 1
mm" in* mm in" (mm.) ness (mm.) ness cm (degrees) _
— —• 61 13-3 8-45 14-9 9-46 8 0-42 4-05 37 5-60 37-2 4-4 Un-
broken
62 13-4 851 14-4 9-14 8 0-39 4-15 35 5-60 37-2 36 oo
Long. 63 13-3 8-45 14-9 9-46 8-3 0-37 415 35 5-60 37-2 4-5 36
As 64 — — —. — — — — — — — 4-3 }
received 65 14-9 9-46 15-6 9-91 6-2 0-33 410 36 5-50 38-6 35 1 Un-
Trans. 66 13-6 8-64 15-2 9-65 6-8 0-35 405 37 5-50 38-6 3-8 | broken
67 12-9 8-19 15-4 9-78 6-9 0-34 4-10 36 5-50 38-6 3 J
69 13-4 8-51 14-7 9-33 7-5 0-34 4-20 34-5 5-60 37-2 3-3 34
100-5° 6 70 13-3 8-45 14-6 9-27 7-5 0-36 415 350 5-75 35 4
71 — — — — — — — — — — 3-8
72 . , 3-3
126«5° 6 73 —. . . , 4-4
74 —. — — — — — .—. — — — 4-4
75 116 737 14-5 9-21 7-2 0-33 415 35 5-60 37-2 4-3
151° 6 76 11-8 7-49 14-4 914 9-3 0-41 4-05 37 5-65 36-4 4-3
77 11-8 7-49 14-3 9-08 9-5 0-42 4-15 35 5-70 35-6 4-4
78 12-4 7-87 141 8-95 10-3 0-42 415 35 5-60 37-2 4-0
178-5° 6 79 11-8 7-49 14-0 8-89 10-2 0-40 4-20 34-5 5-70 35-6 5
80 12-6 8-00 13-8 8-76 9-3 0-37 4-10 36 5-70 35-6 4-6
81 11-5 7-30 13-9 8-83 11-5 0-38 4-20 36 5-80 344 5
200-5" 6 82 11-9 7-56 13-7 8-70 11-7 0-40 4-10 36 5-80 34-4 5
83 11-4 7-24 13-7 8-70 9-1 0-45 4-10 35 5-80 34-4 4-2
84 ' 11-3 7-18 13-4 8-51 12*0 0-51 4-10 36 5-80 34-4 5
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APPENDIX VI
NAME INDEX
Anderson, 51-55, 56, 57 Durville, 119
Archbutt, 56 Edwards, Carpenter and, 68, 117
Archbutt, Rosenhain and, 82 Escard, 82, 85
Arnon,117 Flusin, 6
Bauer, Heyn and, 58 Guillet, 8, 9, 117
Bayer, 4 Guillet, and Bernard, 84
Bayliss, and Clark, 84 Gwyer, 56, 68, 117
Bernard, and Guillet, 84 Hall, 6
Breguet, 106 Heroult, 7
Breuil, 117, 143 Heyn, and Bauer, 58
Brislee, 57 Kayser, Cowles-, 4
Campbell, and Mathews, 68, 117 Lodin, 7
Carpenter, and Edwards, 68, 117 Matthews, Campbell and, 68, 117
Carpenter, and Taverner, 51 Moldentrauer, 4
Le Chatelier, 68, 117 Pecheux, 118
Chevenard, 96, 121 Portevin, 117, 143
Clark, Bayliss and, 84 Pryn, 5
Cowles-Kayser, 4 Robin, 142
Curry, 68, 117 Rosenhain, 117
Ditte, 58 Rosenhain, and Archbutt, 82
Drouilly, 8 St. Claire Deville, 4, 117
Ducru, 59, 60 Taverner, Carpenter and, 51
SUBJECT INDEX
Abrasion, resistance of cupro-alu- Alloys: casting—
minium to, 118 hardness of, at high tempera-
Aeronautical specifications, French, tures, 73
151 lightness of, 71
Ageing, effect of, on quenched dur- mechanical properties of (hard-
alumin, 98, 104, 174 ness, shock, and tensile), 76-
Alloys— 85
aluminium-copper— micrography of, 86
containing 4% Cu, 76 porosity of, 72
containing 8% Cu, 76 specific heat of, 74
containing 12% Cu, 78 thermal conductivity of, 74
aluminium-copper-tin-nickel, 81 classification of, xi, 67
aluminium-copper-zinc, 80 copper as constituent of, 67
aluminium-magnesium, 85 eopper-aluminium,equilibrium dia-
aluminium-tin, 85 gram of, 68
aluminium-zinc, 82, 84 copper-aluminium. See " Cupro-
casting, 71 aluminium "
blowholes in, 72 elektron, 85
density of, 71 light—
extrusion of, 84 for casting purposes, 71
178 ALUMINIUM AND ITS ALLOYS
Alloys: light— Aluminium—
of great strength. See " Dur- hardness—
alumin '' of annealed, 39, 51
magnalium, 85 of cold-worked, 36-38
magnesium-aluminium, 85 impact tests on. See " Shock
soldering, 63 Resistance of "
zinc-aluminium, 84 impurities in commercial, 16
Alumina— mechanical properties of. See
electrolysis of, 4 "Hardness,'* "Shock Resist-
estimation of, in aluminium, 149 ance/' " Cupping Properties,"
importance of, as impurity, 17, 63 " Tensile Properties "
melting point of mixtures of melting point of, 15
cryolite and, 5 micrography of, 56
production of— nitride, production of, 4
from bauxite, 3 output of, 6, 12
from clay, 4 oxidation of, during manufac-
works producing, 13 ture, 5
Aluminium— physical properties of, 15
analysis of, 16, 147 polishing of, 56
annealing of, 30, 160, 169 recrystallisation of, 53
annealed— rolling of, 7
Anderson's work on, 51, 54 shock resistance—
cupping properties of, 44, 52 of annealed, 41
discussion on, 49 of cold-worked, 38
hardness of, 39, 51 soldering of, 52
shock resistance of, 41 specifications for, 151
structure of, 57 specific heat of, 15
tensile properties of, 29, 34 specific resistance of, 15
atomic weight of, 15 sulphate, 4
casting of, 8 tensile properties-r-
coefficient of expansion of, 62 of annealed, 29, 34
cold working of, 20 of cold-worked, 20
cold-worked— test pieces—
Anderson's work on, 51 dimensions of, 19
corrosion of, 58 standard, 152
cupping properties of, 41 thermal conductivity of, 15
discussion on, 48 welding of, 63
hardness of, 36-38 works producing, situation of, 12
shock resistance of, 38 world's production of, 12
structure of, 57 Aluminium bronze, 67. See " Cupro-
tensile properties of, 20 aluminium "
commercial, impurities in, 16 Ammonia, production of, 4
companies producing, 12 Analysis of—
conductivity of, 15 aluminium-copper alloys, 76, 78
corrosion of, 58 aluminium-copper-tin-nickel alloy,
cost price of, 7 81
cupping tests— aluminium-copper-zinc alloy, 80
on annealed, 44, 52 cold-worked aluminium sheet, 22,
on cold-worked, 41 25
density of, 15 cupro aluminium, 121, 132, 137
dust, 8 duralumin, 87
effect of atmospheric agencies on, light alloys of great strength, 87
58 Analysis, methods of, 147
Erichsen tests on, 52 Annealing—
estimation of, 147, 148 aluminium sheet—
extraction of, 4 duration of, 30, 160, 169
extrusion of, 8 efEect on cupping properties of,
fluoride, 6 44
foil, 8 effect on hardness of, 39, 52
grading of, 16 effect on shock resistance of, 41
INDEX 179
oaling: aluminium sheet— Castings—
effect on structure of, 57 aluminium, structure of, 57
aluminium alloy—
effect on tenBile properties of, 29, chill, method of casting, 75
34 chill, properties of, 76, 78, 80, 81
general discussion on, 49 sand, method of casting, 75
intermediate and over-annealing, sand, properties of, 76, 78, 80, 81.
54, 55 See individual alloys under
methods of, 30, 160, 169 " Alloys "
scleroscope values as measure of, aluminium alloys, light, for. See
51 "Alloys," 71
stages in, 31 cupro-aluminium—
iderson's work on, 51 difficulties in casting, 119
.pro-aluminium— micrography of, 145
Type I, effect on mechanical suitability for, 119
properties of cast, 122 effect of tin on, 85
Type I, effect on mechanical requisite properties of alloys for, 71
properties of forged, 123 test pieces, methods of preparing,
Type I, effect on microstructure 75
of, 143 Chalais Meudon Laboratory, 20, 41
Type II, effect on mechanical Chromic acid, use of, in micrography,
properties of, 132 56
Type II, effect on microstructure Coke, petroleum, 16
of, 145 Cold work—
Type III, effect on mechanical aluminium sheet—
properties of, 139 effect on corrosion of, 58
Type III, effect on microstruc- effect on cupping properties of ,41
ture of, 145 effect on hardness of, 36-38
ralumin— effect on micrography of, 57
effect on mechanical properties effect on shock resistance of, 38
effect on tensile properties of, 20
of cold-worked, 89 general discussion on, 48
methods of, 89, 91 Anderson's work on, 51
racite, 16 definition of—
>spheric agencies, effect of, on Anderson's, 51
aluminium, 58 author's, 20
genous welding of aluminium, 63 duralumin, effect on mechanical
specifications for, 153' properties of, 89
ite— method of obtaining specified
nposition of, 3 degree of, 20
•.urrence of, 3 Conservatoire des Arts et Metiers, 20,
atment of, 4 38
rid's production of, 9 Constituents, micrographic—
ing tests, specifications for, 154 in aluminium-copper alloys, 70, 86
/8, dimensions of, 8 in cupro-aluminnim, 69, 142
holes in castings, 72 martensitic in cupro-aluminium,
t—
ihor's work on, 20 143
rosion of, 59 l Cooling—
cin g load. See ' Cupping tests " hardening after, 87
11 hardness. See *' Hardness " rates of, standard, 92, 174
so, aluminium, 67. See " Cupro- duralumin, effect on properties of,
aluminium'' 92, 111, 174
quenching, (rate iii), 97, 174
tium, in aluminium-zinc alloys, Copper—
84 " as constituent of alloys, 67, 68
im fluoride, melting point of aluminium - copper alloys. See
mixtures containing, 6 "Alloys'^
im fluoride, use in manufacture copper-aluminium alloys. See
of synthetic cryolite, 4 " Cupro-aluminium "
m, gas, 16 estimation of, 148
180 ALUMINIUM AND ITS ALLOYS
Corundum, artificial, 4 Cupro-aluminium : Type I—
Critical points— micrography of quenched and
of cupro-aluminium, 121, 132, 137 reannealed, 145
of duralumin, 96 optimum thermal treatment for,
Crushing tests, specification for, 154 136
Cryolite— Type II—
melting point of mixtures of analysis of, 132
alumina and, 5 critical points of, 132
occurrence of, 4 density of, 132
synthetic, 4 hardness of, at high tempera-
Cupping tests— tures, 137
Erichsen apparatus for, 52 mechanical properties of forged,
Persoz apparatus for, 41 with annealing temperature,
results of— 132
on aluminium, annealed, 44 mechanical properties of forged,
on aluminium, cold worked, 41 with quenching temperature,
on duralumin after heat treat- 133
ment, 114 mechanical properties of forged,
specifications for, 154 with reannealing temperature
Cupro-aluminium— after quenching, 134
casting— micrography of, 145
difficulties in, 119 optimum thermal treatment for,
suitability for, 119 136
composition limits, 117 Type I l l -
dimensions of test pieces of, 120 analysis of, 137
forging, suitability for, 119 critical points of, 137
micrography of, 68, 142 density of, 137
properties, chemical and physical, hardness of, at high tempera-
118 tures, 141
resistance to wear and abrasion, mechanical properties of forged,
118 with annealing temperature,
specific resistance of, 118 139
stamping, suitability for, 119 mechanical properties of forged,
types of, 117 with quenching temperature,
Type I— 140
analysis of, 121 mechanical properties of forged
critical points of, 121 with reannealing tempera-
density of, 121 ture after quenching, 141
hardness of, at high tempera- micrography of, 145
tures, 130 optimum method of working,
mechanical properties of cast, 141
with annealing temperature, uses of, 119
122
mechanical properties of cast, Dendritic structure of cast alu-
with quenching temperature, minium, 57
124 Dendritic structure of constituent
mechanical properties of forged, in cupro-aluminium, Type I,
with annealing temperature, 143
123 Density—
mechanical properties of forged, of alloys for casting, 71
with quenching temperature, of aluminium, 6, 15
127 of aluminium-copper alloy—
mechanical properties of forged, containing 4% Cu, 76
with reannealing temperature containing 8% Cu, 76
after quenching, 127 containing 12% Cu, 78
micrography of cast, 145 of aluminium - copper - tin - nickel
micrography of forged, 143 alloy, 82
micrography of forged and re- of aluminium-copper-zinc alloy, 80
annealed, 143 of cryolite-alumina bath for elec-
micrography of quenched, 144 trolysis, 6
INDEX 181
Density— Equilibrium—
of cupro-aluminium, 118 attainment of, by duralumin after
Type I, 121 quenching, 108
Type II, 132 diagram of copper-aluminium sys-
Type III, 137 tem, 68
of magnesium-aluminium alloys, Erichsen apparatus, 52
85 Erichsen tests on aluminium (Ander-
of molten aluminium, 6 son), 52
Dilatometer, 96, 121, 132, 137 Etching of aluminium, 56
Drawing, requirements of sheet for, Etching of cupro-aluminium, 142
52 Eutectic—
Drifting tests, specifications for, o+7t of copper-aluminium alloys,
154 69, 142, 143
Duralumin— i7+CuAl2, 70, 86
ageing after quenching, 98, 104, appearance of, (a+7), 143
174 solution "M," 144
analysis of, 87, 174 Expansion, coefficient of, of alu-
critical points of, 96 minium, 62
dimensions of test pieces of, 89 Extrusion of aluminium, 8
cupping tests, after thermal treat- Extrusionof zinc-aluminium alloys, 84
ment, 114
hardness tests, at high tempera- Fluor-spar, 4
tures, 116 Flux for soldering, 63
maxima and minima in tensile Forged alloys—
properties of, 94, 176 properties of forged aluminium-
mechanical properties of— copper alloy (4% Cu), 76
after annealing, worked alloy, structure of forged cupro-alumin-
89 ium, Type I, 143
after cold work, 90 suitability of cupro-aluminium for
after quenching, worked alloy, forging, 119
98, 174 Furnaces, electric, 4, 5
after quenching, cast alloy, 102 Furnaces for remelting aluminium, 7
after double quenching, 113, 176
after reannealing, quenched al- Gauge length, standard, 152
loy, 110 Grading of aluminium, 17
effect of rate of cooling, after Grain size—
reannealing, 111 gross, apparent, in cupro-alu-
methods of annealing of, 89, 91, minium, 143
174 in aluminium sheet, 52
paper by Lt.-Col. Grard on, 174
practical treatment of, 113 Hardening of alloys due to mag-
quenching— nesium, 87
attainment of equilibrium after, Hardness—
108 Brinell-—
mechanical properties after, 98, of aluminium, thick sheet, an-
102 nealed, 38
specifications for, 153 of aluminium, thick sheet, cold
worked, 36
Elastic limit, determination of, 151. of aluminium-copper alloy, con-
See " Tensile Properties " taining 4% Cu, at high tem-
Electric furnaces— peratures, 76
description of, 4 of aluminium-copper alloy, con-
regulation of, 4 taining 8% Cu, at high
tapping of, 5 temperatures, 78
Electrodes— of aluminium-copper alloy, con-
composition of, 16 taining 12% Cu, at high
usage of, 6 temperatures, 78
Elektron, 85 of aluminium-copper-tin-nickel
Elongation, determination of, 161. alloy, at high temperatures,
See, "Tensile Properties " 82
182 ALUMINIUM AND ITS ALLOYS
Hardness: Brinell— Micrography—
of aluminium-copper-zinc alloy, of aluminium, 56
at high temperatures, 80 of casting alloys, 86
of aluminium-zinc alloys, at high of cupro-aluminium, 142
temperatures, 84
of casting alloys, at high tem- Nickel, aluminium alloys containing,81
peratures, 73 estimation of, 148
of cupro-aluminium, Type I, at Nitric acid, use in micrography, 57
high temperatures, 130 Paraffin, use in micrography, 56
of cupro-aluminium, Type II, at Polishing of aluminium, 56
high temperatures, 137 Porosity of castings, 56
of cupro-aluminium, Type III, at Potash, use of, as etching reagent,
high temperatures, 141 56
of duralumin, at high tempera- Potassium nitrate, 30, 89, 92
tures, 116 Preservation of aluminium, 58
of duralumin, after quenching, Pressing, requirements of sheet for,
102, 104 41
scleroscope— Pressing, effect of, on corrosion of
of aluminium, thin sheet, an-
nealed, 38 aluminium, 58
of aluminium, thin sheet, an- Properties—
nealed (Anderson), 53 chemical, of cupro-aluminium, 118
of aluminium, thin sheet, cold mechanical. See " Cupping,"
worked, 38 "Hardness,'' "Tensile,"
as a measure of complete anneal " Shock "
(Anderson), 51 physical—
Heat treatment. See " Thermal of aluminium, 15
Treatment" of aluminium, effect of, on
Hydrofluoric acid—use as etching soldering, 62
reagent, 57 of casting alloys, 71
of cupro-aluminium, 118
Impact tests. See " Shock Resist- Quenching—
ance " ageing after, 98, 104
Impurities— attainment of equilibrium after, 108
in aluminium, 16 of cast duralumin, 102
effect of, on soldering, 62 double, 113, 176
estimation of, in aluminium, 148 effect of—
Iron— on mechanical properties of
as impurity as in aluminium, 16, 62 duralumin, 97, 174
estimation of, 148 on mechanical properties of
oxide of, in bauxite, 3 cupro-aluminium, Typo I,
cast, 124
Laboratories, testing, ix on mechanical properties of
Laboratory, Chalais Meudon, 20, 41 cupro-aluminium, Type I,
Laboratory, Conservatoire des Arts forged, 125
et Metiers, 20, 155, 159 on mechanical properties of
Literature, contemporary, on alu- cupro-aluminium, Typo II, 133
minium, 51 on mechanical properties of
Magnalium, 85 cupro-aluminium, Type III,
Magnesium— 140
aluminium-magnesium alloys, 85 on micrography of cupro-alu-
minium, Type I, 144
cause of hardening after quench- reannealing after, 110
. ing, 87 treatment preparatory to, 97
estimation of, 148
magnesium-aluminium alloys,85,86 Reannealing—
Melting point— effect of—
of aluminium, 15, 62 on quenched duralumin, 110
of mixture of cryolite, alumina, on quenched cupro-aluminium,
and fluorides, 5 Type I, 127
INDEX 183
Reannealing : effect of— Slabs, dimensions of, 7
on quenched ciipro-aluminium, Soda, use as etching reagent, 56
Type II, 134 Sodium nitrite, 30, 89, 92
on quenched cupro-aluminium, Soldering—
Type III, 141 alloys for use in soldering alu-
on micrography of cupro-alu- minium, 63
minium, 145 of aluminium, 62
varying rates of cooling after, Specific heat—
111 of aluminium, 15
methods of, 110 of casting alloys, 74
Recrystallisation of aluminium: effect Specific resistance—
of prior cold work, 53 of aluminium, 15
Reduction of area (Anderson), 51 of cupro-aluminium, 118
Resilience, definition of {see p. Specifications, French aeronauticaly
vii), 175. See also "Shock for aluminium and alloys of
Resistance'' great strength, 151
Robin's reagent, 142 Stamping, suitability of cupro-alu-
Rolling of aluminium, 7 minium for, 151
Strip, aluminium, specifications for,.
151
Scleroscope. See " Hardness " Structure. See " Micrography "
Sections, production of, 8
Sections, specifications for, 153
Sheet— Tar, as binding material for elec-
rolling of aluminium, 7, 8 trodes, 16
specifications for, 151 Telegraph wires, corrosion of alu-
Shock resistance— minium, 59
definition of, vii, 175 Tensile properties—
determination of, 38 of aluminium—
of aluminium, annealed, 41 annealed, 34
of aluminium, cold worked, 38 cold worked, 21
of casting alloys— of aluminium-copper alloy—
4% Cu, 76 4% Cu, 76
8% Cu, 78 8% Cu, 78
12% Cu, 78 12% Cu, 78
Al-Cu-Sn-Ni, 81 of aluminium - copper - tin - nickel
Al-Cu-Zn, 80 alloy, 81
of cupro-aluminium— of aluminium-copper-zinc alloy,
Type I, cast, annealed, 122 80
Type I, cast, quenched, 124 of aluminium-zinc alloys, 82
Type I, forged, annealed, 123 of casting alloys, 72
Type I, forged, quenched, 125 of cupro-aluminium—
Type I, forged, reannealed, 127 Type I, cast, annealed, 122
Type II, forged, annealed, 132 Type I, cast, quenched, 124
Type II, forged, quenched, 133 Type I, forged, annealed, 123
Type II, forged, reannealed, 134 Type I, forged, quenched, 125
Type III, forged, annealed, 139 Type I, forged, reannealed, 127
Type III, forged, quenched, 140 Type II, forged, annealed, 132
Type III, forged, reannealed, Type II, forged, quenched, 133
141 Type II, forged, reannealed, 134
of duralumin— Type III, forged, annealed, 139
cold worked, 89 Type III, forged, quenched, 140
double quenched, 113 Type III, forged, reannealed, 141
quenched, 98, 104 of duralumin—
reannealed, 111 cold worked, 89
Silica in bauxite, 3 double quenched, 113, 175
Silicon— maxima and minima, after heat
estimation of, in aluminium, 147, treatment, 94
149 quenched, 08, 104, 175
as impurity in aluminium, 1G, 62 reannealed, 111
184 ALUMINIUM AND ITS ALLOYS
Tensile properties— Tin—
standard methods for determining, aluminium-copper-ti-1-1" ""•*
151 81
Tensile test pieces— aluminium-tin ••
dimensions of— addition of, in <
1
Q ;
aluminium, 19 estimation of, in al
xx
aluminium, standard, 152 Titanium, as impurity ^•
casting alloys, 75 17
eupro-aluminium, 120 Tripoli, use in 1 o_ _ .
duralumin, 89 Tubes, methods of c a r r y i n £
methods for casting, 75 on, 153
Thermal conductivity— Tubes, specifications f o r * -*-
of aluminium, 15
of casting alloys, 74 Units. See p. vii
Thermal treatment— Utensils, corrosion of c t * - ! l r L S
effect of—
on cupping properties of duralu- Water power, 60
min, 114 Welding of aluminium* 6 3
on tensile properties of duralu-
min, 92, 104 Zeppelin L 49, 85
optimum— Zinc—
for cupro-aluminium, Type I, 130 pp
for cupro-aluminium, Type II, aluminium-zinc a l l o y s
136 Brinell hardness of, 8 4
for cupro-aluminium, Type III, effect of t e m p e r a t u r e o
141 estimation of, in a l u m . i n . x i
practical, for duralumin, 113, 175 zinc-aluminium a l l o y s , S
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