NEET Sample Question Paper for Chemistry

SET−1

Roll No.

NEET (AIPMT) 2018

Sample Question Paper
CHEMISTRY (Theory)
General Instructions
(i) This test consists of 45 question.
(ii) Each question is allotted 4 marks for correct response.
(iii) Candidates will be awarded marks as stated above in instruction no. 2
for correct response of each question. 1 mark will be deducted for
indicating incorrect response of each question. No deduction from the
total score will be made if no response is indicated for an item in the
answer sheet.
(iv) There is only one correct response for each question. Filling up more
than one response in any question will be treated as wrong response and
marks for wrong response will be deducted according as per
instructions.

1. A gaseous mixture contains oxygen and nitrogen in the ratio of 1:4 by weight.
Therefore, ratio of their number of molecules is
(a) 1:4
(b) 1:8
(c) 7:32
(d) 3:16

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 NEET Sample Question Paper for Chemistry

2. The number of radial nodes in 3s and 2p respectively are

(a) 2 and 0
(b) 0 and 2
(c) 1 and 2
(d) 2 and 1

3. The root mean square velocity of an ideal gas at constant pressure varies with density
(d) as
(a) d2
(b) d
(c)  
(d)  

4. In the dichromate dianion

(a) 4 Cr—O bonds are equivalent
(b) 6 Cr—O bonds are equivalent
(c) all Cr—O bonds are equivalent
(d) all Cr—O bonds are non-equivalent

5. The enolic form of acetone contains

(a) 9 sigma bonds, 1 pi bond and 2 lone pairs
(b) 8 sigma bonds, 2 pi bond and 2 lone pairs
(c) 10 sigma bonds, 1 pi bond and 1 lone pair
(d) 9 sigma bonds, 2 pi bond and 1 lone pairs

6. The species present in solution when CO2 is dissolved in water are

(a) CO2, H2CO3, HCO3−, CO32−
(b) H2CO3, CO32−
(c) HCO3−, CO32−
(d) CO2, H2CO3

7. Which one of the following bases is not present in DNA ?

(a) Quinoline
(b) Adenine
(c) Cytosine
(d) Thymine

8. The pH of 0.1 M solution of the following salts increases in the order

(a) NaCl < NH4Cl < NaCN < HCl
(b) HCl < NH4Cl < NaCl < NaCN
(c) NaCN < NH4Cl < NaCl < HCl
(d) HCl < NaCl < NaCN < NH4Cl

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 NEET Sample Question Paper for Chemistry

9. Amongst the following, identify the species with an atom in +6 oxidation state
(a) MnO4−
(b) Cr(CN)43−
(c) NiF42−
(d) CrO2Cl2

10. There is no S−S bond in

(a) S2O42−
(b) S2O52−
(c) S2O32−
(d) S2O72−

11. Me2SiCl2 on hydrolysis will produce

(a) (Me2)Si(OH)2
(b) (Me)2Si=O
(c) [—O—(Me)2Si—O—]n
(d) Me2SiCl(OH)

12. Rate of physisorption increases with

(a) decrease in temperature
(b) increase in temperature
(c) decrease in pressure
(d) decrease in surface area

Hg2+/H+
13. Ph—C≡C—CH3 A, A is

O Ph
Ph O
(a) (b)
H3C
H3C
O− Ph
(c) Ph (d) OH
H3C
H3C

14. Benzoyl chloride is prepared from benzoic acid by

(a) Cl2, hv
(b) So2Cl
(c) SOCl2
(d) Cl2, H2O

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 NEET Sample Question Paper for Chemistry

15. Which one of the following alkaline earth metal sulphates has its hydration enthalpy
greater than its lattice enthalpy ?
(a) CaSO4
(b) BeSo4
(c) BaSO4
(d) ICI

16. In the following sequence of reactions

Touene KMnO4 A SOCl2 H2/Pd
B BaSO C
4

(a) C6H5COOH
(b) C6H5CH3
(c) C6H5CH3OH
(d) C6H5CHO

17. If uranium (mass number 238 and atomic number 92) emits an α-particle, the product
has mass number and atomic number.
(a) 236 and 92
(b) 234 and 90
(c) 238 and 90
(d) 236 and 90

18. When phenol is treated with excess of bromine water, it gives

(a) m-bromophenol
(b) o-and p-bromophenol
(c) 2, 4-dibromophenol
(d) 2, 4, 6-tribromophenol

19. Number of lone pair(s) in XeOF4 is/are

(a) 0
(b) 1
(c) 2
(d) 3

20. The pair of compounds having metals in their highest oxidation state is
(a) MnO2, FeCl2
(b) [MnO4]−, CrO2Cl2
(c) [(Fe(CN)6)3−, [Co(CN)3]
(d) [NiCl4]2−, [CoCl4]−

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 NEET Sample Question Paper for Chemistry

21. Among the following oxoacids, the correct decreasing order of acidic strength is
(a) HOCl > HClO2 > HClO3 > HClO4
(b) HClO4 > HOCl > HClO2 > HClO3
(c) HClO4 > HClO3 > HClO2 > HOCl
(d) HClO2 > HClO4 > HClO3 > HOCl

22. The ionisation isomer of [Cr(H2O)4Cl(NO2)]Cl is

(a) [Cr(H2O)4(O2N)]Cl2
(b) [Cr(H2O)4Cl2](NO2)
(c) [Cr(H2O)4Cl(ONO)]Cl
(d) [Cr(H2O)4Cl2(NO2)]. H2O

23. Benzene diazonium chloride on reaction with phenol in weakly basic medium gives
(a) diphenyl ether
(b) p-hydroxy azobenzene
(c) chlorobenzene
(d) benzene

24. CH3NH2 + CHCl3 + KOH → Nitrogen containing compound + KCl + H2O. Nitrogen
containing compound is
(a) CH3CN
(b) CH3NHCH3
(c) CH  N≡ C 
(d) CH  N ≡ 

 C

25. 2 moles of an ideal gas expanded isothermally and reversibly from 1L to 10L at 300K.
What is the enthalpy change ?
(a) 4.98 kJ
(b) 11.47 kJ
(c) −11.47 kJ
(d) 0 kJ

26. When benzene sulphonic acid and p-nitrophenol are treated with NaHCO3, the gases
released respectively are
(a) SO2, NO2
(b) SO2, NO
(c) SO2, CO2
(d) CO2, CO2

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 NEET Sample Question Paper for Chemistry

27. The packing efficiency of two-dimensional square unit cell shown below is

(a) 39.27%
(b) 68.02%
(c) 74.05%
(d) 78.54%

28. A substance AxBy crystallises in a face centred cubic (fcc) lattice in which atoms A
occupy each corner of the cube and atoms B occupy the centres of each face of the
cube. Identify the correct composition of the substance AxBy
(a) AB3
(b) A4B3
(c) A3B
(d) composition cannot be specified

29. Which of the following compounds will exhibit geometrical isomerism ?

(a) 1-phenyl-2-butene
(b) 3-phenyl-1-butene
(c) 2-phenyl-1-butene
(d) 1,1-diphenyl-1-propene

30. The species that do not contain peroxide ions, is

(a) PbO2
(b) H2O2
(c) SrO2
(d) BaO2

31. Which of the following hydrocarbons has the lowest dipole moment ?
(a) cis-2-butene
(b) 2-butene
(c) 1-butene
(d) HC  CH  C ≡ CH

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 NEET Sample Question Paper for Chemistry

32. The following compounds have been arranged in order of their increasing thermal
stabilities. Identify the correct order
K2CO3 (I), MgCO3 (II), CaCO3 (III), BeCO3 (IV)
(a) I < II < III < IV
(b) IV < II < III < I
(c) IV < II < I < III
(d) II < IV < III < I

33. Both [Ni(CO)4] and [Ni(CN)4]2− are diamagnetic. The hybridisations of nickel in these
complexes respectively, are
(a) sp3, sp3
(b) sp3, dsp2
(c) dsp2, sp3
(d) dsp2, dsp2

34. The reagent (s) for the following conversion,

Br ?
H H
Br
is/are
(a) alcoholic KOH
(b) alcoholic KOH followed by NaNH2
(c) aqueous KOH followed by NaNH2
(d) Zn/CH3OH

35. The ∆H°f for CO2(g), CO(g) and H2O(g) are −393.5, −110.5 and −241.8 kJ mol−1
respectively. The standard enthalpy change (in kJ mol−1) for the reaction
CO2(g) + H2(g) → CO(g) + H2O(g) is
(a) 524.1
(b) +41.2
(c) −262.5
(d) −41.2

36. The structure of XeO3 is

(a) linear
(b) planar
(c) pyramidal
(d) T-shaped

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 NEET Sample Question Paper for Chemistry

37. (CH3)3 CMgCl on treatment with D2O produces

(a) (CH3)3 CD
(b) (CH3)3 COD
(c) (CD)3 CD
(d) (CD)3 COD

38. Saturated solution of KNO3 is used to make ‘salt-bridge’ because

(a) velocity of K+ is greater than that of NO−3
(b) velocity of NO−3 is greater than that of K+
(c) velocities of both K+ and NO−3 are nearly the same
(d) KNO3 is highly soluble in water

39. The compound which reacts fastest with Lucas reagent at room temperature is
(a) butan-2-ol
(b) butan-1-ol
(c) 2-methyl propan-1-ol
(d) 2-methyl propan-2-ol

40. H3BO3 is
(a) monobasic acid and weak Lewis acid
(b) monobasic and weak Bronsted acid
(c) monobasic and strong Lewis acid
(d) tribasic and weak Bronsted acid

41. The reaction of P4 with X leads selectively to P4O6. The X, is

(a) dry O2
(b) a mixture of O2 and N2
(c) moist O2
(d) O2 in the presence of aqueous NaOH

42. An SN2 reaction at an asymmetric carbon of a compound always gives

(a) an enantiomer of the substrate
(b) a product with opposite optical rotation
(c) a mixture of diastereomers
(d) a single stereoisomer

43. The most suitable reagent for the conversion of R—CH2—OH→R—CHO is

(a) KMnO4
(b) K2Cr2O2
(c) CrO3
(d) PCC (pyridinium chlorochromate)

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 NEET Sample Question Paper for Chemistry

44. Consider a reaction, aG + bH → products. When concentration of both the reactants G

and H is doubled, the rate increases by eight times. However, when concentration of G
is doubled keeping the concentration of H fixed, the rate is doubled. The overall order
of the reaction is
(a) 0
(b) 1
(c) 2
(d) 3

45. 1-bromo-3-chlorocyclobutane when treated with two equivalents of Na, in the presence
of ether which of the following will be formed ?
Br Cl

(a) (b)
(c) (d)

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