Professional Documents
Culture Documents
R Jaffarullah, Non-member
B K Ghosh, Non-member
Blast furnace continues to be principal producer of iron even today due to its size, techno-economics, energy utilisation and quality
of hot metal, when compared to other emerging technologies of iron production. Coke forms a major portion (more than 60%)
of the cost of hot metal and sources of metallurgical coal are limited. The recent crisis of imported coal availability and their cost
increase have forced all the Indian ironmakers to think in terms of coke economy and its partial replacement by alternate fuel.
The paper describes in detail technological considerations such as role of auxiliary fuel, cooling characteristics and thermal
compensation of potential injectants and replacement ratio. The significance of indirect and direct reduction of wustite and
principles of coke economy achieved by auxiliary fuel injection with respect to C-rd diagram have been analysed. The suitability
of injection technology to Indian condition and the status of established auxiliary fuel injection technology through tuyeres, such
as, coal dust injection, natural gas injection, fuel oil injection, coal tar injection and plastic injection have also been discussed in
brief.
Keywords : Blast furnaces; Coke consumption; Alternate fuels; Replacement ratio; C-rd diagrams
16 IE(I) Journal-MM
(b) Substitution of auxiliary fuel hydrogen for coke as a
reductant, and
(c) Alteration of thermal balances in the raceway, hearth
and reduction zones.
P rob e s
Cooling Characteristics of Auxiliary Fuel and
Thermal Compensation
The use of auxiliary fuels is well-established practice in blast
G ra n ular
Zone furnace technology. It decreases the coke consumption and
provides endothermic reactions on decomposition, which
are used to control the tuyere Raceway Adiabatic Flame
C o h esive
Temperature (RAFT). The auxiliary fuels, generally considered
Zone for blast furnace injection, are all inferior to coke as heat
producer in the furnace4.
D rip p in g
The factors responsible are:
Zone
Fuel injected is usually at or slightly above, the ambient
temperature and is therefore much cooler than
R acew ay
preheated coke at raceway (around 1500oC).
D e a dm a n
Zone
Auxiliary fuel consumes an appreciable quantity of heat
for dissociation of organic C-H, C-O and C-S bonds
of the auxiliary fuel, and
Only the carbon content of the fuel is a source of heat
at the tuyeres.
Figure 1 Zones in the blast furnace
The amount of reducer and heat produced from 1 kg of
Table 1 Properties of coke and auxiliary fuels
auxiliary fuel is different from that obtained from 1 kg of
Parameter O2 in Coke Heavy Natural
blast, % fuel Oil gas ** coke. Bogdandy 5 has carried out calculations for some
Chemical Composition gaseous, liquid and solid injectants, which is reproduced in
C, % 87.0 84.0 Tables 1 and 2. The tuyere gas formed during gasification of
Ash, % 10.0 0.5 auxiliary fuels contains more concentration of reducer (CO
S, % 1.0 2.5
H, % 0.4 12.0
+ H2) than the gas formed from coke. Also the concentration
O, % 0.6 0.5 of H2 is higher. Hydrogen is a more powerful reducing agent
N, % 1.0 0.5 than CO as well as its presence in the tuyere gas gives advantage
CH4, % ≈ 100 with respect to heat transfer and aerodynamics.
Calorific value, kcal/kg 6900 9600 8580
7200cc 9800 c The change in the RAFT relative to the amount of fuel injected
Wind required to 21 3.84 3.71 2.38 is used to assess the relative cooling effects of each injectants
transform into CO and H2 22 3.67 3.54 2.27 (Table 3). Natural gas has the greatest cooling effect on the
Nm3/kg or Nm3/Nm3 ** 23 3.51 3.39 2.17
raceway, followed by fuel oil, coal tar, high volatile coal and
Table 2 Blast requirement, tuyere gas volume and composition with a blast humidity of 10 g/Nm3 and ash content of coal: 6% dry
Coal characteristic
Parameter
Anthracite 19% VM 28% VM 35% VM Lignite
Blast requirement, Nm3/kg 3.78 3.53 3.44 3.32 2.01
Tuyere gas volume, Nm3/kg 5.19 5.08 5.02 4.83 3.49
Tuyere gas composition:
CO, % 33.10 32.70 32.20 32.30 36.50
H2, % 9.00 12.20 13.40 14.80 17.80
N2, % 57.00 55.10 54.40 52.90 45.70
Note : VM = Volatile Matter
The choice of auxiliary fuel for injection does significantly FeO + nCO = Fe + CO2 + (n 1) CO + 3250 kcal
alter the cost benefit that can be obtained by the injection. (ii) Direct reduction taking place at temperature above
The primary factor that influences the cost benefit of any 1000oC
injection technology is the amount of coke that can be
replaced by the injected auxiliary fuel. FeO + CO = Fe + CO2
Replacement ratio (RR) is the ratio of kg coke saved per ton CO2 + C = 2CO (solution loss reaction)
of hot metal (thm) to the kg/Nm3 of auxiliary fuel injected Adding FeO + C = Fe + CO 36,500 kcal.
per thm2.
These two reactions are diametrically opposite in their thermal
The replacement ratio normally quoted in the literature is the effect and reducer requirement. Indirect reduction is slightly
metallurgically corrected coke rate where the coke rate is exothermic with large reducer requirement (n = 3 to 4)
corrected for furnace parameters, such as hot metal silicon because of equilibrium consideration, whereas direct
content and blast temperature to give coke rate under reduction is highly endothermic but requires only one mole
standard condition. of carbon for reducing one mole of FeO. Therefore, it is
Hoogovens, a leading coal injector has developed the two apparent that a compromise between the two reactions will
formulae to determine the replacement ratio of a coal based give the optimum carbon consumption for reduction of a
on its carbon (C), hydrogen (H) and ash contents: mole of FeO to Fe.
RR = [%C(dry basis) + (2H% (dry basis)/0.903)] / 100 C-rd Diagram
RR = ( 118.9 + 2.3C + 4.5H + 0.97 ash) / 100 If the carbon rate per ton of hot metal (thm), as dictated
6
Russians has developed replacement ratio formulas for separately by thermal and chemical requirements, is plotted
gaseous, and solid or liquid fuel using the ratio of enthalpies against the degree of direct reduction, rd = FeOD/ FeOT
of auxiliary fuel and coke. (ratio of FeO reduced directly to the total FeO per thm), a
plot known as C-rd diagram (Figure 2) is obtained. The point
Actual replacement ratios achieved in blast furnace operation of intersection of the two lines at which both the thermal
with low to moderate injection rates tend to be slightly higher and chemical requirements are satisfied, gives the optimum
due to reduced heat losses (in view of increased productivity) degree of direct reduction (rdopt) and corresponding carbon
and some increase in reduction efficiency. But, at higher rates
rate is the optimum carbon rate (Copt).
of injection, heat loss can increase which may lead to lowering
of replacements than theoretical. Table 4 shows the changes The chemical requirement line shown in the C-rd diagram
in RAFT and replacement ratio achieved with different coals. corresponds to attainment of Fe-O-C equilibrium in the top
zone (stack). In case of departure from equilibrium due to
PRINCIPLES OF COKE ECONOMY
poor reducibility or kinetics caused by poor gas-solid contact
Indirect and Direct Reduction of Iron Oxide condition, high velocity of gas etc., the line will shift upwards.
In blast furnace fuel calculations, the reduction of wustite The thermal requirement line will shift upwards if either the
18 IE(I) Journal-MM
T h e rm a l
T h e rm a l R eq u ire m e nt R e q uire m en t
O o pr
C o pr
O o pt O´
C to b e B u rnt a t C2 O
C o pt
T u y ere s C1
uy e re s
at T
e B u rn t m e n t
to b R eq u ir e
s a ry A
C R ate, k g/th m
l
N ec e s T he rm a C h e m ic a l A´ C h e m ic a l
C eet
C R ate, k g /th m
to M R e q uire m en t R e q uire m en t
C R e qu ire d fo r D ire ct R e d uc tion
[C ] fo r S olution in H ot M e ta l rd 2 rd 1
rd o pt rd o pr rd , %
rd , %
Figure 3(a) Effect of auxiliary fuel injection without thermal
compensation
Figure 2 C-rd diagram
20 IE(I) Journal-MM
M ate ria l R ec e iv in g S e c tio n D ry in g a nd G rind in g S ec tion In je c tio n S e c tion
F la m e F ro n t E qp t
B last
F urn a c e
B ag F ilte r
L a n c es (1 8/2 0 N o s)
H ig h R ise R a w C oa l
C o n ve y or S ilo
S cre w C o nv e yo r
6 0 t/h 3 50 m 3
C oal
D istrib utor
F ine C o al
S ilo
1 00 0 m 3
D rag C h air
C o nv eyo r
G ro u nd
H o pp e r
M agn etic B a ll
S ep arato r M ill To
2 1.25 t/h C h im n e y
B e lt F e e d e r 6 0 t/h ID
F an S cre e n s
R e c irc u la tio n In je c tio n 15 m 3 15 m 3
G a se s Ve sse ls
C O /B F G a s
H ot G as
A ir
G e n era tor D o sin g
N itrog e n Va lv e s
H o t G a s from S to ve s
N itrog e n fo r C o o lin g
Table 5 Quality of coals used for blast furnace injection in selected steel plants globally
Coal characteristics
Replacement
Location Coal type H2O, % Ash, VM, % S, % CV, Size, HGI ratio
% Mj/kg % <µm
Arbed, Esch-Belval Lignite 10-12 4 50 0.5 22 70<74
Lignite 11 4 44 21 70<90 0.54
LV bituminous 1 14 12 30 90<90 0.81
Usinor/ Sollca, Dunkirk LV bituminous 12-13 11-12 1.3 30 68 0.84
British Steel, HV bituminous 2 4 31 1.5 89<2 mm 0.90
Scunthorpe HV bituminous 1.4 10 22 0.4 97<2 mm 0.91
SocHF Reunis, Uckange HV bituminous 1.2 7 35 31 67<80 Variable
VEB, Maxhutte Lignite 6.8 14 51 3.5 22 90<200 0.55
Hoogovens, IJmuiden LV, MV & HV bituminous 0.7-5 4-11 18-39 0.5-1.1 80<75 45-100 0.79-0.98
2-9 6-8 32-35 0.7-1.4 0.93-1.02
Stanton HV bituminous anthracite
1 9 7 0.8 100<1.7mm 1.01
Blend: HV bituminous + 1 8 20 1 80<90 0.86
Thyssen Stahl, Hamborn etc.
semi-anthracite
ILVA, Taranto HV bituminous 1 8 26 80<90 0.83
Various blends of HV 7-10 22-40 0.3-1.0 80<74
SSAB, Lulea
bituminous + petcoke
Sidmar, Ghent MV &HV bituminous 1 7-14 23-37 0.4-0.6 28-33 90<90
Armco Ashland HV bituminous 5 4.6 38 0.7 78<74 1.1
Note : LV = Low Volatile; MV = Medium Volatile; HV = High Volatile; CV = Calorific Value; HGI = Hardgrove Grindability Index
C5H12, % : 0.1 1
of lower gas density (bosh gas) due to high hydrogen
CO2, % : 0.5 5 concentration and the decrease in nitrogen concentration of
H2S : traces the blast furnace stack gases. Natural gas requires higher oxygen
enrichment than other fuel injection.
Calorific Value, kcal/Nm3 : 8540 9150
Coal Tar Injection
Natural gas is being widely used in blast furnaces of CIS
countries, the USA and Europe because of its easy availability, Coal tar is a byproduct generated during the coke oven
low cost, high heat value, ease of handling and environment operation in a steel plant. Depending upon the market
friendly nature. Natural gas injection does not introduce any condition, tar could be an alternate fuel for injection in blast
slag forming constituents and, therefore, the net heat obtained furnace. Tata Steel has pioneered coal tar injection in India
is substantially higher per unit weight of injected gas. and it is being practiced in their four blast furnaces at present.
Maximum natural gas injection rate is limited to around 100 SAIL has also started tar injection in one of their blast furnace
kg/thm due to blast furnace operational problems. Normally, and has planned in some blast furnaces in near future.
natural gas injection is carried out in conjunction with increase A typical coal tar analysis is9 :
in hot blast temperature and oxygen enrichment of the blast
C, % : 89.5
to compensate decrease in RAFT and to increase the coke
replacement ratio8. H2, % : 5.0
S, % : 0.3
Recent discovery of large reserves of natural gas in the coastal
region of India has brightened the prospects of natural gas Ash, % : 0.5
injection in blast furnaces in India. Capital investment in natural Quinolene insoluble, % : 15
gas equipment would be less as compared to coal dust Toluene insoluble, % : 5 10
injection. Coal bed methane gas, a variant of natural gas has
Moisture, % : 34
also been discovered in huge quantity near West Bengal -
Jharkhand coal belt. This promises to be an attractive Specific gravity : 1.18 1.20
proposition for injection in blast furnaces existing nearer to Calorific Value, kcal/kg : 8600
the location of gas reserves. Published data indicate a replacement ratio of around 1.35
Table 6 shows the comparison of blast furnace performance and productivity improvement of more than 4% for an
with and without natural gas injection for Armco Steel. Use injection rate of around 40 kg/thm9. Figure 5 shows a typical
of natural gas in blast furnace introduces significant amount flow diagram of tar injection system. The main sections of
of hydrogen in the bosh gas. The presence of hydrogen in tar injection system are :
the bosh gas reduces coke consumption by decreasing the l Coal tar storage, pumping and heating system
extent of the solution loss reaction and thermal energy
requirement associated with the endothermic effect of l Coal tar ring main and supply
solution loss reaction3. The productivity will increase because l Coal tar distribution and injection system
22 IE(I) Journal-MM
CONCLUSIONS
Ta r Tan k P um p H o u se Ta r H e a te rs To overcome the availability of imported coal and to reduce
the hot metal cost, Indian ironmakers has to incorporate suitable
R e tu rn L ine auxiliary fuel injections in priority basis in all of their blast furnaces
Ta r C o o le r
by doing in-depth study of techno-economics, auxiliary fuel
D istrib utor fo r S te a m availability and feasibility of suitable injection technology.
P urging S tea m
Ta r to
Auxiliary fuel injection technology has come to stay as an
In dividu a l important part of modern ironmaking technology. Due to
T u y ere D istrib utor fo r F low M ea su re m en t Ta r to B F availability of large varieties of coal for injection, higher
Ta r a nd C on tro l injection rate and lower temperature compensation required
compared to other fuels; coal injection will be better suitable
Figure 5 Flow diagram of coal tar injection system for Indian blast furnaces.
The critical parameter for tar injection is the viscosity, which Natural gas and coal bed methane might be suitable for those
is dependent on its temperature. Proper temperature has to plants situated nearer to those production fields. Depending
be maintained for better flowability and atomization of tar upon the availability and techno-economics coal tar injection
in raceway. Maximum injection rate is limited by tar handling will be suitable for some blast furnaces. Plastic injection could
and transportation problems. be adopted because of its huge potential in coke saving and
Fuel Oil Injection environmental protection.
Lastly, more research has to be carried out for adoption and
During the 1950s, oil was the preferred injectant due to its low
maximising of the injection rates of auxiliary fuel for our
price relative to natural gas and coal. After oil price shocks of
Indian condition.
the 1970s, renewed interest in oil injection has started in Europe.
Oil injection levels upto 150 kg/thm have been practiced in ACKNOWLEDGEMENTS
the last few years with good economic results. Technically, oil Authors are thankful to the Management of R & D Centre for
injection occupies intermediate level between gas injection and Iron & Steel, SAIL, Ranchi for granting permission to publish
coal injection as regards the temperature compensation this paper. Authors are also thankful to the colleagues of their
requirement2. Oil produces large amount of reducing agents department for providing support in preparation of this article.
as well as heat at tuyere, leading to better economics. Oil injection
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