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Density and

Refractive Index
Perfect solutions for quality control of liquids
Page
Overview 180 – 181
LiquiPhysics Instruments and Modules 182 – 183
LiquiPhysics Automation 184 – 185
LiquiPhysics Accessories 186 – 187
Compact Instruments 188 – 189
Good Practices 190 – 191
Overview

Density- and Refractometers


Reliable Results and Unsurpassed Reproducibility
One Click® operation Meters and
One click on the selected product or mea- Cell Modules
surement method starts the measurement
Compact Size
of density, refractive index or related val-
Great Specs
ues. The built-in temperature control brings
the sample to the required temperature,
the measurement is done automatically
and the result displayed on the touch
screen. Unlike older methods like pycnom-
eters, hydrometers and Abbe refractome-
ters, the results are operator-independent,
thus highly reliable and reproducible.

Simplified quality control


For quality control, target value and limits
can be defined for each product. The mea-
surement result is then displayed in red if
it is out of limits.

Multiparameter measurement
The modular concept allows to upgrade
any single instrument to a complete multi-
parameter system measuring density,
refractive index (or related values), pH
(or conductivity), acidity and color.
Density Meters
Refractometers
www.mt.com/liquiphysics-multiparameter Cell Modules
Overview

Automation Valuable Options Basic Solutions GDRP

Less Work Tailor-Made Quick Measurements Reliable Results


Better Repeatability Performance
Sampling Pumps and

Accessories

Compact Instruments
Automation Units

Good Practices
LiquiPhysics Instruments and Modules

Density- and Refractometers


Compact Size. Great Specs.

Density Refractive Index Cell Modules


Compact Versatile Combined

DM Density Meters RM Refractometers DX and RX Cell Modules


DM density meters determine the Brix, refractive index or con- Density and refractive index
density and/or specific gravity of centrations of dark, viscous or are frequently determined in
liquids quickly and accurately. highly volatile liquids? The RM the same lab and, increasingly
The results are automatically refractometers master the quality frequently, simultaneously. The
converted into one or several control of a wide variety of chal- upgrade of a DM density meter
pre- or user-defined units such lenging samples from routine or an RM refractometer with a
as Brix, API degrees or alcohol Brix measurements at 20 °C DX density cell module or an RX
concentrations etc. to refractive index determina- refractive index cell module is
Automatic error detection, entire tions of bitumen at 100 °C. The the most cost- and space-saving
temperature range adjustments measurement process can be solution in such cases making it
and built-in algorithms shorten completely automated with the the perfect combination for any
measurement times required added advantage of no more lab demanding fast and accurate
by up to 75% – DM and DX are manual cleaning, no more con- results.
doubtlessly the state-of-the- tact with dangerous solvents and
art pinnacle for digital density better repeatability.
measurement.

www.density.com www.refractometry.com
LiquiPhysics Instruments and Modules

The DeltaRange™ density measuring cells are tailor made solutions


for applications such as alcohol content determinations or the
quality control of organic solvents. They offer five place accuracy in
the range required for such measurements at a significantly lower
price than full range five decimal place cells.
Please order our LiquiPhysics
Excellence brochure

www.mt.com/LiquiPhysics

Technical Density Meter DM40 DM45 DeltaRange DM50


Density Cell DX40 DX45 DeltaRange DX50
specifications Measuring range [g/cm3] 0–3 0–3 0–3
Repeatability [g/cm3] 0.00005 0.000005 0.000005
(S.D. n=10) Brix [% w/w] 0.03 0.015 0.003
ethanol [% v/v] 0.1 0.01 0.01
Limit of error [g/cm3] 0.0001 0.000021) 0.000022)
0.00005 0.000033)
Brix [% w/w] 0.03 0.02 0.006
ethanol [% v/v] 0.1 0.02 0.02
Temperature range [°C] 0 – 91 0 – 91 0 – 91
Limit of error [°C] 0.05 (10 – 30 °C) 0.02 (15 – 20 °C) 0.02 (10 – 30 °C)
0.10 (0 – 91 °C) 0.05 (0 – 91 °C) 0.05 (0 – 91 °C)
1)
in the range 0.70000 … 1.00000 g/cm3 / 15.00 … 20.00 °C
2)
in the range 0.00000 … 1.00000 g/cm3
3)
in the range of 1.00000 … 2.00000 g/cm3

Refractometer RM40 RM50


Refractive Index Cell RX40 RX50
Measuring range [nD] 1.32 – 1.70 1.32 – 1.58
Repeatability [nD] 0.00005 0.00001
(S.D. n=10) Brix [% w/w] 0.05 0.01
Limit of error [nD] 0.0001 0.000023)
0.000044)
Brix [% w/w] 0.1 0.014
Temperature range [°C] 5 – 100 5 – 75
Limit of error [°C] 0.1 (5 – 100 °C) 0.03 (15 – 50 °C)
0.05 (5 – 75 °C)
3) 4)
around adjustment points entire range
LiquiPhysics Automation

Automation
Highly Reliable with Minimal Effort

Flexible automation solutions improve the quality of your


measurement and increase the troughput in your workflow

FillPal SC1 & SC30


The Robust Approach Maximum Performance

The FillPal sampling pumps simplify The SC1 and SC30 automation
the measurement of low viscous units offer fully automated sam-
samples. These pumps can be used pling, measurement, rinsing and
for all DM density meters and RM drying. In addition, the SC30 is
refractometers and are suitable for a sample changer with 30 posi-
all applications where the samples tions that is equipped with the
to be measured are of a similar ScanStraight option, even capable
nature and no intermediate complete of scanning barcode stickers on
rinsing and drying of the measuring the sample vials automatically.
cell is required. FillPal is available in
two versions: FillPal Food for water
based products and FillPal Chem for
aggressive samples including most
acids, bases and organic solvents. www.mt.com/automation-sc1
www.mt.com/automation-sc30
LiquiPhysics Automation

InMotion SC Heated Versions


High Troughput High Viscosity

The InMotion sample changer is The SC automation units are avail-


the perfect solution for the bever- able as heated versions suitable
age industry or for other kindred for performing density measure-
low viscous samples where ments of samples which are
oversampling is sufficient (same highly viscous or even solid at
as FillPal). Different beaker sizes ambient temperature such as par-
and up to 303 sample positions affins, bitumen, heavy crude oils,
offer flexibility for any application. edible fats, etc. The SC1H and the
Optional stirrer and pH measure- SC30H can handle samples with a
ment for fruit juices and automatic melting point of up to 60 °C.
degassing of carbonated bever-
ages ensure efficient workflows.

Please order our Automation brochure

Technical specifications

FillPal Food FillPal Chem InMotion SC1 SC1H SC30 SC30H


Number of samples 1 1 10 – 303 1 1 30 30
Sample vials any type any type 25 – 250 mL 6, 9 and 20 mL 6, 9 and 20 mL 6, 9 and 20 mL 6, 9 and 20 mL
Sample characteristics
max viscosity 1'000 mPas 1'000 mPas 1'000 mPas 30'000 mPas 30'000 mPas 30'000 mPas 30'000 mPas
organic solvents acetone, ethanol yes acetone, ethanol yes yes yes yes
acids no yes (most) yes 3) yes 1) yes 1) yes 1) yes 1)
bases yes yes yes 3) yes yes yes yes
Sampling suction suction suction overpressure overpressure overpressure overpressure
Rinsing manual manual semi automatic automatic automatic automatic automatic
Drying DryPal required DryPal required DryPal required automatic automatic automatic automatic
Sample recovery no no no yes yes yes yes
Temperature ambient ambient ambient ambient max. 80 °C 2) ambient max. 80 °C 2)
1)
For concentrated reducing acids only with Hastelloy needle
2)
Samples with a melting point of up to 60 °C can be handled (paraffin, edible fats, cosmetics etc.)
3)
with optional resistant tubing
LiquiPhysics Accessories

Valuable Options
Custom Tailored Performance

Multi-parameter
Measurements
Enhanced Productivity

Density, refractive index (or related values), pH (or conductivity), acidity and
color can be measured and analyzed in one go.

Advanced Barcode Plug and Play LabX Laboratory


Features Benefits Software
Convenient Sample Features Tailored Make the Most of
Data Input to Your Needs LiquiPhysics

LiquiPhysics Excellence is not LiquiPhysics systems can LabX is a new concept for
only able to read barcodes; it easily be upgraded to fulfill laboratory software (see
can also accurately interpret specific requirements. The pages 16–19). In addition
their information. With Smart LogStraight finger print reader to data aquisition, analysis
Codes containing information greatly simplifies the log-in and archiving, LabX offers
about the type of product to procedure at the instrument SOP user guidance, manages
be measured, the operator with no user names or pass- products, methods, users
simply scans in the barcodes words to enter. With ErogSens, and instruments. It connects
to start the measurements. there is no need to touch the density meters, refractometers,
No additional button to click. instrument to start the meas- melting point instruments,
urements. AtmoSens ensures titrators and balances. Con-
LiquiPhysics Excellence is highly accurate 5 place den- nection to LIMS or ERP allows
even capable of scanning sity adjustments. LevelSens full integration in the company
barcodes automatically. guarantees greater safety IT world.
The SC30 sample changers when working with automa-
can be easily equipped with tion units and makes sure
ScanStraight, a built-in bar- that the waste container never
code reader. becomes overfilled.
Auxiliary instruments
Third-party devices can be integrated easily into our LiquiPhysics systems, e.g. spectropho-
tometer for color measurement, even without PC.

www.mt.com/liquiphysics-multiparameter

Accessories Printer USB-P25 dot matrix printer 11124301


Ordering Information Barcode scanner
Hand scanner USB for 1D barcodes 21901297
ScanStraight Automatic scanner for SC30 sample changer for 1D and 2D barcodes 51337184

Complete connecting sets for additional parameters (without auxiliary instruments)


pH connecting set for SevenEasy™ / SevenCompact™ pH meter 51337023
Conductivity connecting set for SevenEasy™ / SevenCompact™ conductivity meter 51337022
Color connecting set for Lovibond PFX and PFXi 8XX and 9XX colorimeters from Tintometer 51337021
Color connecting set for Minolta CM5 and CR5 colorimeters from Konica Minolta 30025477

Sensors
AtmoSens barometric USB pressure sensor 51337020
.GXGN5GPUNGXGNUGPUQT5CHGN[RTGXGPVUYCUVGEQPVCKPGTQXGTƂNNKPI 51337026
.QI5VTCKIJVƂPIGTRTKPVUECPPGTHQTDKQOGVTKEWUGTOCPCIGOGPV 51192107
ErgoSens infrared sensor for hands-free operation 11132601

Top parts for RM refractometers and RX refractive index measuring cells


Flow cell for automatic refractive index measurements (FillPal, SC1 or SC30) 51337024
Press to measure semi-solid products, such as fruit pulp 51337155

LabX Laboratory software


LabX Express Edition for stand alone systems 11153130
LabX Server Edition for client server installations 11153131
Compact Instruments

Basic Solutions
for any Environment

DA-100M Densito and Refracto Refracto 30GS


Thermostat Included Best On-site Performance Gold and Saphire

The DA-100M density meter is The Densito 30PX and the Re- The Refracto 30GS additionally
a compact three-decimal place fracto 30PX offer all the features features a very wide measuring
density meter. It is equipped with required for successful on-site range and a quick temperature
a solid state thermostat and an density and refractive index response thanks to its special
air pump to dry the measuring measurements including: Auto- measuring cell equipped with
cell. The optional ASU-100 sam- matic temperature compensa- a gold plated stage ring and a
pling pump greatly simplifies tion, direct display of the result prism made of artificial sapphire.
density determinations of low in the desired unit, built-in clock
viscous samples. for full GLP compliance and data
output via infrared interface.
Densito and Refracto come with
practical carrying cases which
contain everything necessary to
carry out measurements.
Please order our Densito
and Refracto brochures and visit

www.mt.com/Densito
www.mt.com/Refracto

Technical Measuring range Accuracy Temperature range Part No.


specifications DA-100M 0 – 2 g/cm3 0.001 g/cm3 15 – 40 °C 51320001
Density meter (solid state thermostat)
Densito 30PX 0 – 2 g/cm3 0.001 g/cm3 ambient (5 – 35 °C) 51324450
Refracto 30PX 1.32 – 1.50 (nD) 0.0005 (nD) ambient (10 – 40 °C) 51324650
0 – 85% Brix 0.2% Brix
Refracto 30GS 1.32 – 1.65 (nD) 0.0005 (nD) ambient (10 – 40 °C) 51324660
0 – 100% Brix 0.2% Brix

Accessories ASU-100 sampling pump for DA-100 ASU-100


Infrared adapter for data transmission (Densito and Refracto) 51325006
Adapter for external syringe (Densito) 51324402
Cleaning tissues (set of 10) for Densito 30PX and Refracto 30PX/GS 51325003
Protective cover for Densito 30PX 51324430 51324430
Density water standards (for DA-100M and Densito 30PX) 51325005
Good Practices

Better Accuracy and Reliability


Reduce Risks. Increase Effectivity
It is not the accuracy of the instrument which is important
but the accuracy of the workflow.

Improve the accuracy of your density and refractive index measurement


by understanding your workflow, identifying the risks and using good
density and refractive index practices.

GDRP™ 5 Steps to Excellence


Good Density and Refractometry Practice is a 5 step program to improve
your Lab process. It covers the entire lifecycle of your investment and
helps to improve quality while reducing risks and costs.

Step 1 Evaluation Risk Check


Understanding current needs, Risk-free measurement of density
and future requirements and refractive index

Step 2 Selection
Selection of the best suitable
analytical system

Step 3 Installation
Correct installation to guarantee
the best working conditions

5VGR3WCNKƂECVKQP Take 5 minutes with our web


3WCNKƂECVKQPQHVJGRTQEGUU based risk checker to identify ar-
and professional training eas of risk which affect your pro-
cess and estimate the reliability
of your density or refractive index
measurement.
Step 5 Routine Operation
Tailored services for regular care
and maintenance. Trainings and
seminars

www.mt.com/GDRP www.mt.com/GDRP-riskcheck
Traceable Standards
Improved Data Security
The combined liquid standard reference materials from METTLER TOLEDO facilitate reliable
performance verification. They are certified for both density value and refractive index at
three different temperatures (15, 20 and 25 °C). Combined measuring systems can be veri-
fied in one step. All the information contained in the certificates is coded in a barcode with
no need to input data manually when performing a system performance test or calibration.

Standard Reference Material Density [g/cm3] at 20 °C 1) Refractive Index at 20 °C 2) Part No.


Water 0.998.. 1.333.. 51338010
Dodecane 0.749.. 1.422.. 51338012
2,4-dichlorotoluene 1.250.. 1.546.. 51338013
1-bromonapthalene 1.481.. 1.658.. 51338014
1)
Uncertainty: 0.00003 g/cm3 Typical values: May change from batch to batch
2)
Uncertainty: 0.00002 without prior notice

Installation and Qualification Pacs


Regulatory Compliance
Professionally executed installation and operational qualification (IQ/OQ) including documentation
is offered by METTLER TOLEDO for LiquiPhysics™ Excellence instruments.

Service Product Families Product Types Order No.


IPac LiquiPhysics™ Excellence Density Meters DM40 / DM45 / DM50 51710863
DX40 / DX45 / DX50
LiquiPhysics™ Excellence Refractometers RM40 / RM50 51710873
RX40 / RX50
EQPac LiquiPhysics™ Excellence Density Meters DM40 / DM45 / DM50 51710870
DX40 / DX45 / DX50
LiquiPhysics™ Excellence Refractometers RM40 / RM50 51710873
RX40 / RX50
EduPac LiquiPhysics™ Excellence Density Meters DM40 / DM45 / DM50 30047139
DX40 / DX45 / DX50
LiquiPhysics™ Excellence Refractometers RM40 / RM50 30047152
RX40 / RX50
LabX Validation LiquiPhysics™ Excellence Density Meters DM40 / DM45 / DM50
Manual I generic and Refractometers RM40 / RM50
LabX Validation LiquiPhysics™ Excellence Density Meters DM40 / DM45 / DM50
Manual II specific and Refractometers RM40 / RM50

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