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Article history: The strength, Young’s modulus and hardness properties of iron matrix composites reinforced by differ-
Received 3 February 2010 ent types of ceramic particles (SiC, Cr3 C2 , TiC and Ti(C, N)) prepared by the dynamic temperature control
Received in revised form 15 July 2010 direct current heating technology were investigated experimentally. The stress–strain curves of the dif-
Accepted 12 August 2010
ferent composites and stress in reinforcing particles were simulated by Eshelby approach modeling in
order to interpret the experiments and to reveal the strengthening mechanisms. It was found that SiC
reinforcing particles show the strongest effect on improving the strength of the composite among the
Keywords:
four types of reinforcements experimentally. The theoretical analysis exposes the reason as its higher
Iron matrix composite
Reinforcing particles
fracture toughness and hardness as well as a limited decomposition to increase matrix strength. The
Stress–strain curve strength of the four composites all presents a maximum value at 10% volume fraction and the reason
Modeling can be interpreted by that glomeration of particulate reinforcements happens remarkably only when the
Strengthening mechanism fraction is over 10%. The stress–strain curves by the modeling agree well with those of the experiments
on TiC/Fe and Ti(C, N)/Fe composites but not on SiC/Fe and Cr3 C2 /Fe composites. This suggests that the
strengthening mechanisms of the composites rely not only on load sharing of the reinforcements but also
on increasing matrix strength.
© 2010 Elsevier B.V. All rights reserved.
0921-5093/$ – see front matter © 2010 Elsevier B.V. All rights reserved.
doi:10.1016/j.msea.2010.08.029
7546 J. Li et al. / Materials Science and Engineering A 527 (2010) 7545–7551
were proposed to predict the variation of the elastic modulus for means of optical microscopy and SEM with an energy spectrome-
graphite/Al and SiC/Al composite [16]. The Mori–Tanaka model, the ter.
two-phase self-consistent model and so on were developed to sim-
plify predictions of the monotonic uniaxial response of an isotropic 2.2. Model
particle-reinforced metal by calculating the stress–strain curves
of Al2 O3 /Al and Al/Al composites [17]. The particle-compounded Following Eshelby’s idea, based on the concept of mismatch
mechanical model based on Eshelby approach has been devel- strain between the reinforcing particles and the matrix during com-
oped to calculate load partition between reinforcements and matrix posite straining, the compliance tensor of the composite with two
during straining based on the load transfer mechanism [18–20]. random types of reinforcements, Cc−1 , can be derived [20]:
The model was used to simulate the stress–strain curves of SiC
particulate reinforced aluminum alloy matrix composites success- Cc−1 = Cm
−1
(I + fI QI (I + L) + f2 Q2 (I + L)), (1)
fully [18–20]. Such modeling on iron matrix composites is needed where QI = ((CI − Cm )SI + Cm )−1 (Cm − CI ), SI is the Eshelby ten-
to supply a theoretical analysis on experimental results by cal- sor of particle type 1, Q2 = ((C2 − Cm )S2 + Cm )−1 (Cm − C2 ),
culating stress in different reinforcing particles and stress–strain S2 is the Eshelby tensor of particle type 2,
curves. L = (I + fI (SI − I)QI + f2 (S2 − I)Q2 )−1 ( − fI (SI − I)QI − f2 (S2 − I)Q2 ), I
The purpose of the present work is to reveal the strength- is the unit matrix, fI and f2 are the volume fractions of two types
ening mechanisms of the iron matrix composites reinforced of particles respectively, CI , C2 and Cm are the stiffness tensors of
by different types of ceramic particles prepared by the direct particle type 1, type 2 and the matrix respectively. The composites
current heating technology. The SiC, TiC, Cr3 C2 and Ti(C, N) studied here have only one type of reinforcing particles, so f2 = 0
in the same size were chosen to study effect of differ- and C2 = 0 in this paper.
ent reinforcing particles and volume fraction (5%, 10% and Young’s modulus and Poisson ratio of both the reinforcing
15%) on properties of the composite. Modeling based on particles and the matrix are constant within elastic stage of the
ours previous work is carried out to explain experimental composite during tension so composite modulus can be calculated
results. by Eq. (1). However, when the plastic deformation takes place in
composite, that is the matrix begins to yield, the stress and strain
of the matrix is no longer linear relationship but may follow the
2. Materials and methods constitutive relation of measured matrix alloy stress–strain curve,
and the Young’s modulus and Poisson ratio of the matrix should be
2.1. Materials and experimental procedure substituted by secant ones. The secant modulus Es and the secant
Poisson ratio s of a material are defined as [18–20]:
The four types of SiC, Cr3 C2 , TiC and Ti(C, N) reinforcing
particles used in the experiment are all commercial pow- 1
Es = , (2)
der products with ≥99.85% purity rate. The average particle 1/E 0 + (ε̃p /(y + h(ε̃p )n ))
size of all the ceramic powders is 3 m in commercial nomi- 1
1 Es
nal standard. The iron powder used is commercial deoxidized s = − − 0 , (3)
2 2 E0
powder of 98.68 wt.% purity, and the maximum C content is
0.015 wt.%. The average particle size of iron powder is 50.6 m where ε̃p is the equivalent plastic strain, and it can be calculated
and 1 wt.% zinc stearate was added as caking agent and lubri- according to the equation ε̃p = ε − /E 0 in which ε and are the
cant. flow strain and flow stress. (y + h(ε̃p )n ) is the flow stress, .
Each powder mixture was blended for 16 h and then com- The numerical secant modulus of matrix from experimental
pressed into a block of 60 mm × 30 mm × 10 mm in volume by tensile test curve of the matrix has been used to calculate the
240 MPa pressure. All the green compact blocks were sintered secant modulus of the composite at different strains by Eq. (1).
by a dynamic temperature control direct current heating tech- To begin with a small strain of the matrix, we set a strain incre-
nology, which has been developed in our laboratory with new ment of 0.001 and repeat the process so that one more point on
equipment adapted from a traditional hot pressing furnace [8–10]. the curve of the composite can be simulated. After a number of
Intense current passes the powder compacts directly by using repetitions, the stress–strain curve of the composite will be finally
ceramic dies in addition of a dynamic temperature control to simulated.
speed up the sintering for the purpose of avoiding the reaction The stress in the particles under the applied stress 0 is found
between reinforcements and the iron matrix. The pressure dur- out as [19]:
ing the sintering in this study was limited to 40 MPa according
I = m + I0 + ¯ I = 2Cm (I + (SI − I) QI ) (I + L) e0 , (4)
to the performance of the ceramic die and the sinter volts were
5 V. The sintering includes two stages, i.e. heating stage and hold- where e0 is the elastic strain of the matrix under the applied stress
ing stage. The heating up time of the first stage was 100 s and the 0 , eT is the transformation strain or eigenstrain, ec is the con-
holding time of the second stage was 200 s. The current was con- strained strain with ec = SI eT . Therefore, we can also calculate the
ducted for 1 s and broken for 1 s alternately during the holding load sharing of reinforcing particles during straining the composite.
stage. The model was applied to simulate the stress–strain curve of SiC
Tensile tests were performed at room temperature with a veloc- particulate reinforced aluminum alloy matrix composites [18–20]
ity of 0.3 mm/min and the specimens are of 28 mm gauge length formerly and shown a very good agreement with the measured
and 5 mm diameter. At least three tests were carried out on each curves. The model is used here for the iron matrix composites and
experimental datum. The extension to the tensile strength was will be compared with the experiment to check flexibility of the
measured from load–displacement curves. The tensile test was model. The modeling will be used to examine the effect of different
carried out on CCS electronical stretcher and both the extensome- reinforcing particles on improving the strength of the composite as
ter and the strain gauge were used in order to obtain whole a function of volume fraction to discuss the strengthening mecha-
stress–strain curves. Specimens were unloaded just after yield- nism.
ing and then reloaded until failure to measure elastic modulus The stress–strain curve of monolithic iron matrix is needed in
accurately. The microstructure of the composites was observed by order to simulate the stress–strain curves of the composites. There-
J. Li et al. / Materials Science and Engineering A 527 (2010) 7545–7551 7547
ment between the modeling and the experiment tells us that load
fore, a monolithic iron matrix alloy was prepared by the same
sharing of the reinforcements is the chief strengthening mecha-
processing as for the composites. The stress–strain curve of the
nism of those composites. However, the experimental stress–strain
alloy was obtained from tensile test and is shown in Fig. 1(b). The
curves of the composites reinforced by SiC and Cr3 C2 particles are
0.2% proof stress and Young’s modulus of the iron matrix alloy
both much higher than the curves predicted by modeling shown
are 422 MPa and 168 GPa respectively by tensile test and used in
in Fig. 1(b). This suggests that better strengthening effect of the SiC
the modeling. The elastic properties of the reinforcements are tab-
and Cr3 C2 ceramic particles comes not from their good elastic prop-
ulated in Table 1, which are used for the present modeling. The
erties that the modeling takes account for but may come from their
Poisson ratio of the iron matrix is taken as 0.28 [21] and the aspect
good mechanical properties and better chemical properties to the
ratio of all the reinforcing particles is selected as 1.2 approximately
iron matrix. The much higher stress–strain curves of the compos-
according to the microstructure observation.
ites than the predictions indicate that the reinforcements are not
only to share load from the matrix but also to increase the strength
3. Results
of the matrix.
Fig. 2 shows the comparison of the yield strength between
Comparison of the stress–strain curves between modeling and
modeling and experiment for the composites. The experimental
experiments for the composites reinforced by different types of
data in Fig. 2(a) indicates the SiC reinforcing particles having the
ceramic particles is shown in Fig. 1 and the volume fraction of
strongest effect on improving the yield strength among the other
reinforcements is 10% for all the composites. It is shown that the
reinforcements. This can offer a very significant reference for the
curves of TiC/Fe and Ti(C, N)/Fe composite predicted by the model-
development of particulate reinforced iron matrix composite and is
ing agree well with the corresponding experimental curves shown
first reported in literature. The Cr3 C2 reinforcements also present
in Fig. 1(a). This is a quite cheerful result to prove the great flexi-
a good strengthening effect over the TiC and Ti(C, N) reinforcing
bility of the Eshelby mean field model, which we have only proved
particles. However, the modeling results show a very small differ-
its affectivity for aluminum matrix composites before. The agree-
ence between the four types of reinforcement shown in Fig. 2(b)
and even expose the best effect of Ti(C, N) owing to its highest
Table 1 elastic modulus over the others. This suggests that the mechan-
Elastic properties of the reinforcements used in present modeling.
ical, chemical or physical properties of reinforcing particles may
Reinforcement Young’s modulus (GPa) Poisson ratio Reference play very important roles on strengthening the composite. It can be
SiC 450 0.17 [18] found out in Table 2 that SiC reinforcing particles have higher frac-
Cr3 C2 380 0.24 [21] ture toughness than the other three reinforcing particles, as well
TiC 438 0.19 [21] as higher hardness. These two factors probably make SiC the best
Ti(C, N) 525 0.21 [22]
reinforcement type in iron matrix.
7548 J. Li et al. / Materials Science and Engineering A 527 (2010) 7545–7551
Table 2
Mechanical and physical properties of the different types of reinforcing particles used in present study.
Reinforcing particles Fracture toughness Hardness (HV) Electrical resistivity Melting point (◦ C) Coefficient of Reference
(MPa m1/2 ) (×10−6 m) thermal expansion
(×10−6 K−1 )
It is surprisingly noticed that the yield strength of four compos- and experiment. The successful prediction of the modeling on the
ites all demonstrates a same phenomenon of maximum value at modulus implies the load sharing nature of the reinforcements in
volume fraction of 10% by experiment shown in Fig. 2(a) whereas the composites during straining. However, it can be seen if with
the yield strength of the four composites all increases continu- a careful examination of Fig. 3 that the modulus value of the com-
ously with the increase of reinforcement volume fraction linearly posites by experiment comes a series of SiC/Fe, Cr3 C2 /Fe, TiC/Fe and
by modeling shown in Fig. 2(b). The discrepancy here suggests not Ti(C, N)/Fe from high to low whereas the modeling gives the series
only a further strengthening mechanism apart from load sharing in a consequence of Ti(C, N)/Fe, SiC/Fe, TiC/Fe and Cr3 C2 /Fe. The
in the composites but also the complexity in effects of process- affectivity of different reinforcements on stiffness of the compos-
ing procedures upon the property. A most possible explanation ite predicted by modeling goes wrong in the series, which suggests
may rely on that there are some micro-voids in the composites that the stiffness of the composites is not depended on elasticity of
if the volume fraction is higher than 15%, which would result in a reinforcement but on the bond condition with the matrix because
fracture mechanism of the composite instead of yielding failure to the yield strength of the composites comes the same series as the
lead to a strength abrupt drop. This needs a further observation of stiffness both in experiment.
microstructure to provide evidence in next section later. The influence of reinforcement type and volume fraction on ten-
The comparison of Young’s modulus between modeling and sile strength of iron matrix composites by experiment is shown
experiments for the composites is given in Fig. 3. Young’s modulus in Fig. 4(a). It is apparent that the trend of tensile strength as a
of the composites by the modeling agrees well with the experi- function of reinforcement volume fraction as well as types of rein-
ments for all the four composites as a function of volume fraction. forcing particles is similar to that observed for the yield strength.
The modulus of the composites increases with increasing volume The Vickers hardness values of the composites by experiment are
fraction of reinforcing particles monotonously both in modeling given in Fig. 4(b). The hardness shows general same phenomena
Fig. 3. Comparison of Young’s modulus between modeling and experiments: (a) by Fig. 4. Influence of reinforcement type and volume fraction on the tensile strength
experiment and (b) by modeling. and hardness of the composites by experiment: (a) tensile strength and (b) hardness.
J. Li et al. / Materials Science and Engineering A 527 (2010) 7545–7551 7549
Fig. 6. Microstructure of iron matrix composites reinforced by SiC and Ti(C, N) particles with different volume fractions, respectively: (a) 5 vol.% SiC, (b) 10 vol.% SiC, (c)
15 vol.% SiC, (d) 5 vol.% Ti(C, N), (e) 10 vol.% Ti(C, N), and (f) 15 vol.% Ti(C, N).
Fig. 7. Microstructure of the iron matrix composites reinforced by different types of reinforcing particles: (a) 10%TiC/Fe, (b) 10%Ti(C, N)/Fe, (c) 10%Cr3 C2 /Fe, and (d) 10%SiC/Fe.
reaction with the iron matrix to leave a pure Ferrite microstructure SiC/Fe composite to have a higher strength over the Cr3 C2 /Fe com-
shown in Fig. 7(a) and (b), whereas the Cr3 C2 and the SiC particles posite to become the best composites among the investigated four
take a slight reaction with iron to form some Pearlite in the matrix composites.
shown in Fig. 7(c) and (d). The Pearlite + Ferrite matrix has much
higher strength than the pure Ferrite matrix [25] so that the SiC/Fe 5. Conclusions
and Cr3 C2 /Fe composites should have much higher strength than
the TiC/Fe and Ti(C, N)/Fe composites. Moreover, the SiC/Fe com- (1) SiC reinforcing particles show the strongest effect on improving
posite in Fig. 7(d) has more Pearlite in the matrix than the Cr3 C2 /Fe strength of the iron matrix composite compared with the other
composite shown in Fig. 7(c). The SiC has higher fracture tough- three types of Cr3 C2 , TiC and Ti(C, N) reinforcements experi-
ness than the Cr3 C2 (please see Table 2). These two factors help the mentally. The reason may rely on that SiC has higher fracture
J. Li et al. / Materials Science and Engineering A 527 (2010) 7545–7551 7551
toughness and hardness as well as a limited decomposition to Innovative Research Team in University (IRT0713) is also acknowl-
increase matrix strength. edged.
(2) The strength of all the four composites reinforced by different
ceramic particles presents a maximum value at 10% volume References
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50471024, and support from Program for Changjiang Scholars and