Professional Documents
Culture Documents
Thus, the limiting factor of the theory and practice of the ore flotation is
still imperfection of the used models of the flotation kinetics.
where Rmax – is the ultimate recovery of the valuable component, which is set from 0 to
100 % from the experimental data of the flotation process, % (see. Fig. 3); T – is the time
constant of flotation (the constant of inertia), secs; – is the time delay of flotation, secs;
t – is the time, secs.
where k – is the transfer coefficient of the dynamic system; T – is the time constant of the
inertia of the dynamic system, secs; – is the time delay, secs; s – is the complex
variable on Laplace.
Then (L-1– is inverse Laplace transform) it implies from (2) that the
kinetic equation for the output variable (dependent variable) Y(s) is
Also we need to take into account that the value of the input variable
(independent variable) X(s) – is the unit step influence 1(t). Then we obtain
the following expression
Let’s substitute the expression (4) in the expression (3)
Let’s substitute the expression (2) in the expression (5), then we get
Next, we carry the inverse Laplace transform L-1 and we go from the
operator form of the expression to the usual form
Let’s consider the example of the usage of I. Bobin’s equation (1) for
modeling the kinetics of flotation of copper-zinc ore.
Example
In the laboratory, we conducted studies on the kinetics of flotation of
copper-zinc ore. Grade of copper of 1.55%, grade of zinc of 0.83%. Weight
content of the class of less than 0.071 mm was of 80%. Ratio of liquid to
solid was L:S=3:1. Consumption of reagents: С4Н9ОСSSК of 5 gram/tonne,
T-80 of 15 gram/tonne. Flotation process was carried in a neutral
environment. Flotation time was of 10 minutes. The experimental curves of
the flotation kinetics for copper and zinc are presented on Fig.2. We need to
obtain the analytical dependences of the flotation kinetics for copper and
zinc.
Decision
Figure 2 shows the flotation kinetics for copper and zinc, R (t), obtained
from experiments in [2].
On the shape of the experimental curves R(t) we can conclude that the
dependence R(t) of copper has an exponential form without delay. The
dependence R(t) of zinc is S-shaped with a delay.
Let's substitute these parameter values in the Bobin’s equation (1), and
we get the mathematical model of the copper flotation kinetics RCu(t)
Actually for copper the equation (8) is converted to the equation (9)
Let's substitute these parameter values in the Bobin’s equation (1), and
we get the mathematical model of the zinc flotation kinetics RZn(t)
script
RmaxCu=62; TCu=69; tauCu=0; tCu=[tauCu:0.01:600];
xCu=(tCu-tauCu)./TCu; RCu=RmaxCu.*(1-exp(-xCu));
RmaxZn=29; TZn=65; tauZn=50; tZn=[tauZn:0.01:600];
xZn=(tZn-tauZn)./TZn; RZn=RmaxZn.*(1-exp(-xZn));
plot(tCu,RCu,tZn,RZn); title('Flotation kinetics curves R(t)');
xlabel('Time, secs'); ylabel('Recovery, %'); axis([0 600 0 65]);
The analytical dependences of the flotation kinetics for copper and zinc
obtained by simulation at MATLAB are shown in Figure 4.
Fig. 4. The analytical dependences of the flotation kinetics for copper and zinc
obtained by simulation using formula (1) of I. Bobin