pH and calcium released

pH
NeoMTAPl 3h 1 day 3 days 7 days 14 days 28 days
1 11.4 11.8 11.3 10.8 9.1 8.6
2 11 11.4 10.9 10.4 8.7 8.2
3 11.3 11.7 11.2 10.7 9 8.5
4 11.2 11.6 11.1 10.6 8.9 8.4
5 11.2 11.6 11.1 10.6 8.9 8.4
6 11.4 11.8 11.3 10.8 9.1 8.6
7 11.6 12 11.5 11 9.3 8.8
8 11.7 12.1 11.6 11.1 9.4 8.3
9 11 11.4 10.9 10.4 8.7 8.9
10 11 11.4 10.9 10.4 8.7 8.8
MTA Plus g 3h 1 day 3 days 7 days 14 days 28 days
1 11.8 11.6 10.6 9.1 8.5 8.5
2 11.9 11.7 10.9 9.2 8.6 8.4
3 11.7 11.5 10.4 9 8.6 8.4
4 11.9 11.7 10.5 9.2 8.8 8.3
5 11.8 11.6 10.8 9.1 8.9 8.6
6 11.12 10.9 10.4 8.4 8.9 8.4
7 11.9 11.7 10.7 8.7 8.7 8.5
8 11.7 11.5 10.8 8.8 8.7 8.4
9 11.7 11.5 10.8 8.8 8.6 8.3
10 11.8 11.6 10.4 8.9 8.8 8.5

Initial
NeoMTAPlInitial setting time Final setting ti Radiopacity (mm Al) (ISO > 3)
1 130 310 3.76
2 135 315 3.63
3 125 320 3.89
MTA Plus g setting timeFinal
Initial (min)
setting time
Radiopacity
(min) (mm Al) (ISO > 3)
1 40 50 7.7
2 50 55 5.4
3 45 60 6.9

Setting time + 50% at 37 °C 99% RH before test

NeoMTAPlExterior volume (VVolume of openVolume of impervioApparent poro
Water sorptionSolubility (S %)
1 0.0983 0.0483 0.048 49 36 16
2 0.121 0.0386 0.05 47 39 19
3 0.0756 0.058 0.052 52 37 16
4 0.0985 0.0483 0.0589 54 40 18
5 0.0984 0.0386 0.0608 49 40 14
6 0.122 0.058 0.0628 53 36 14
 7 0.0755 0.0486 0.0372 46 38 16
8 0.0983 0.039 0.0391 48 32 19
9 0.121 0.0583 0.0412 54 38 18
10 0.0756 0.0483 0.05 50 35 14
MTA Plus gExterior volume (VVolume of openVolume of impervioApparent poro
Water sorptionSolubility (S %)
1 0.1502 0.0582 0.0468 45.4 42.4 18.5
2 0.1633 0.052 0.0531 47.1 40 21
3 0.1371 0.0644 0.0405 43.7 47.6 17.8
4 0.1502 0.0582 0.0468 45.4 42.4 18.5
5 0.1633 0.052 0.0531 47.1 40 21
6 0.1371 0.0644 0.0405 43.7 47.6 17.8
7 0.1502 0.0582 0.0468 45.4 42.4 18.5
8 0.1633 0.052 0.0531 47.1 40 21
9 0.1371 0.0644 0.0405 43.7 47.6 17.8
10 0.1503 0.0582 0.0468 45.4 40 18.5
 Calcium Released
NeoMTAPl 3h 1 day 3 days 7 days 14 days 28 days
1 169.9 146 72 27 18 11
2 142.9 106 90 26 27 10
3 143 110 86 28 18 9
4 115.8 150 75 39 20 12
5 170 116 94 38 28 13
6 168 146 92 20 28 9
7 143 123 96 18 20 8
8 166 126 72 39 18 10
9 143 146 72 28 17 7
10 116 106 74 27 10 11
MTA Plus g 3h 1 day 3 days 7 days 14 days 28 days
1 123 35 52 33 18 14
2 126 47 51 32 19 15
3 106 38 50 31 17 19
4 110 46 45 25 18 20
5 115 46 40 26 19 11
6 116 47 53 27 18 15
7 117 35 54 20 18 16
8 100 55 44 22 19 18
9 98 39 42 29 17 16
10 114 47 55 33 16 16

7 days at 37 °C 99% RH before test

NeoMTAPlExterior voVolume of Volume of iApparent po
Water sorptSolubility (S %)
1 0.0919 0.0476 0.0421 44.6 36.7 8.9
2 0.1146 0.0511 0.0519 50.3 40.8 10.8
3 0.0692 0.0441 0.0323 38.9 32.6 7
4 0.0921 0.0476 0.0421 44.6 36.7 8.9
5 0.092 0.0511 0.0519 50.3 40.8 10.8
6 0.1156 0.0441 0.0323 38.9 32.6 7
 7 0.0691 0.0476 0.0421 44.6 36.7 8.9
8 0.0919 0.0511 0.0519 50.3 40.8 10.8
9 0.1146 0.0441 0.0323 38.9 32.6 7
10 0.0692 0.0476 0.0421 44.6 36.7 8.9
MTA Plus gExterior voVolume of Volume of iApparent po
Water sorptSolubility (S %)
1 0.1036 0.0448 0.0587 43.3 39.7 8.1
2 0.1141 0.0495 0.065 48.1 43.3 9.4
3 0.0931 0.0401 0.0524 38.5 36.1 6.8
4 0.1036 0.0448 0.0587 43.3 39.7 8.1
5 0.1141 0.0495 0.065 48.1 43.3 9.4
6 0.0931 0.0401 0.0524 38.5 36.1 6.8
7 0.1036 0.0448 0.0587 43.3 39.7 8.1
8 0.1141 0.0495 0.065 48.1 43.3 9.4
9 0.0931 0.0401 0.0524 38.5 36.1 6.8
10 0.1036 0.0448 0.0587 43.3 39.7 8.1
pH and calcium released

pH pH_3h pH_1day pH_3days pH_7days pH_14days

NeoMTAPlus 0–3 h 3 h–1 day 1 day–3 days 3–7 days 7–14 days

1 1 11.4 11.8 11.3 10.8 9.1

2 1 11 11.4 10.9 10.4 8.7
3 1 11.3 11.7 11.2 10.7 9
4 1 11.2 11.6 11.1 10.6 8.9
5 1 11.2 11.6 11.1 10.6 8.9
6 1 11.4 11.8 11.3 10.8 9.1
7 1 11.6 12 11.5 11 9.3
8 1 11.7 12.1 11.6 11.1 9.4
9 1 11 11.4 10.9 10.4 8.7
10 1 11 11.4 10.9 10.4 8.7
1 2 11.8 11.6 10.6 9.1 8.5
2 2 11.9 11.7 10.9 9.2 8.6
3 2 11.7 11.5 10.4 9 8.6
4 2 11.9 11.7 10.5 9.2 8.8
5 2 11.8 11.6 10.8 9.1 8.9
6 2 11.12 10.9 10.4 8.4 8.9
7 2 11.9 11.7 10.7 8.7 8.7
8 2 11.7 11.5 10.8 8.8 8.7
9 2 11.7 11.5 10.8 8.8 8.6
10 2 11.8 11.6 10.4 8.9 8.8

Initial
NeoMTAPlus Initial setting time
Final
(min)
setting time
Radiopacity
(min) (mm Al) (ISO > 3)

1 1 130 310 3.76 initial_time

2 1 135 315 3.63 final_time
3 1 125 320 3.89 radiopacity
1 2 40 50 7.7
2 2 50 55 5.4
3 2 45 60 6.9
Setting time + 50% at 37 °C 99% RH before test
NeoMTAPlus Exterior volume Volume of open Volume of impervApparent porositWater sorption (
1 1 0.0983 0.0483 0.048 49 36
2 1 0.121 0.0386 0.05 47 39
3 1 0.0756 0.058 0.052 52 37
4 1 0.0985 0.0483 0.0589 54 40
5 1 0.0984 0.0386 0.0608 49 40
6 1 0.122 0.058 0.0628 53 36
7 1 0.0755 0.0486 0.0372 46 38
8 1 0.0983 0.039 0.0391 48 32
9 1 0.121 0.0583 0.0412 54 38
10 1 0.0756 0.0483 0.05 50 35
1 2 0.1502 0.0582 0.0468 45.4 42.4
2 2 0.1633 0.052 0.0531 47.1 40
3 2 0.1371 0.0644 0.0405 43.7 47.6
4 2 0.1502 0.0582 0.0468 45.4 42.4
5 2 0.1633 0.052 0.0531 47.1 40
6 2 0.1371 0.0644 0.0405 43.7 47.6
7 2 0.1502 0.0582 0.0468 45.4 42.4
8 2 0.1633 0.052 0.0531 47.1 40
9 2 0.1371 0.0644 0.0405 43.7 47.6
10 2 0.1503 0.0582 0.0468 45.4 40
 pH_28days calcium_3hcalcium_1dcalcium_3dcalcium_7dcalcium_14calcium_28days
14–28 days NeoMTAPlus 3h 1 day 3 days 7 days 14 days 28 days

8.7 pH_3h 1 1 169.9 146 72 27.1 17.8 11

8.8 pH_1day 2 1 142.9 106 90 38 27.4 10
8.6 pH_3days 3 1 143 110 86 16.2 8.2 9
8.7 pH_7days 4 1 115.8 150 75 27.1 17.8 12
8.8 pH_14days 5 1 170 116 94 38 27.4 13
8.6 pH_28days 6 1 168 146 92 16.2 8.2 9
8.7 7 1 143 123 96 27.1 17.8 8
8.8 8 1 166 126 72 38 27.4 10
8.6 9 1 143 146 72 16.2 8.2 7
8.7 10 1 116 106 74 27.1 17.8 11
8.4 1 2 123 35 52 25.2 18.5 14
8.8 2 2 126 47 51 31.4 27.5 15
8 3 2 106 38 50 19 9.5 19
8.4 4 2 110 46 45 25.2 18.5 20
8.8 5 2 115 46 40 31.4 27.5 11
8 6 2 116 47 53 19 9.5 15
8.4 7 2 117 35 54 25.2 18.5 16
8.8 8 2 100 55 44 31.4 27.5 18
8 9 2 98 39 42 19 9.5 16
8.4 10 2 114 47 55 25.2 18.5 16

7 days at 37 °C 99% RH before test

Solubility (S %) NeoMTAPlus Exterior voVolume of Volume of iApparent po
Water sorptSolubility (S %)
16 Exterior vo 1 1 0.0919 0.0476 0.0421 44.6 36.7 8.9
19 Volume of 2 1 0.1146 0.0511 0.0519 50.3 40.8 10.8
16 Volume of 3 1 0.0692 0.0441 0.0323 38.9 32.6 7
18 Apparent p 4 1 0.0921 0.0476 0.0421 44.6 36.7 8.9
14 Water sorpt 5 1 0.092 0.0511 0.0519 50.3 40.8 10.8
14 Solubility 6 1 0.1156 0.0441 0.0323 38.9 32.6 7
16 7 1 0.0691 0.0476 0.0421 44.6 36.7 8.9
19 exterior1 8 1 0.0919 0.0511 0.0519 50.3 40.8 10.8
18 open1 9 1 0.1146 0.0441 0.0323 38.9 32.6 7
 14 impervious 10 1 0.0692 0.0476 0.0421 44.6 36.7 8.9
18.5 porosity1 1 2 0.1036 0.0448 0.0587 43.3 39.7 8.1
21 water_sorp 2 2 0.1141 0.0495 0.065 48.1 43.3 9.4
17.8 Solubility1 3 2 0.0931 0.0401 0.0524 38.5 36.1 6.8
18.5 4 2 0.1036 0.0448 0.0587 43.3 39.7 8.1
21 exterior2 5 2 0.1141 0.0495 0.065 48.1 43.3 9.4
17.8 open2 6 2 0.0931 0.0401 0.0524 38.5 36.1 6.8
18.5 impervious 7 2 0.1036 0.0448 0.0587 43.3 39.7 8.1
21 porosity2 8 2 0.1141 0.0495 0.065 48.1 43.3 9.4
17.8 water_sorp 9 2 0.0931 0.0401 0.0524 38.5 36.1 6.8
18.5 Solubility2 10 2 0.1036 0.0448 0.0587 43.3 39.7 8.1
calcium_28days

calcium_3h
calcium_1day
calcium_3days
calcium_7days
calcium_14days
calcium_28days

Solubility (S %)