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C L A Y D I A G E N E S I S A N D OIL M I G R A T I O N I N
B R E N T G R O U P S A N D S T O N E S OF
N W H U T T O N F I E L D , U K N O R T H SEA
I. C. S C O T C H M A N , L. H . J O H N E S AND R . S. M I L L E R *
Amoco (U.K.) Exploration Co., Amoco House, West Gate, Ealing, London W5 1XL, and *Reservoirs Inc.,
115lC Brittmore Road, Houston, Texas 77043, USA
A BST R A C T: The NW Hutton Field lies within the Brent Province of the East Shetland Basin
and is located in Block 211/27, 130 km NE of the Shetland Islands. Oil of 37~API, the source of
which is the Upper Jurassic Kimmeridge Clay Formation, is reservoired in Brent Group
sandstones in a complex, highly faulted and tilted fault-block structure at an average depth of
12000 ft subsea. The Brent Group Reservoir shows a complex diagenetic sequence. Early
calcite concretions showing partial replacement by siderite occur in the marine-facies
sandstones of the Broom and Rannoch Formations. The fluvio-deltaic and marine-facies
sandstones of the Etive, Ness and Tarbert Formations show a different diagenetic sequence
(post-dating carbonate cementation) of secondary porosity formation by K-feldspar dissolution,
followed by quartz overgrowth cementation and kaolinite and iUite authigenesis. Development
of kaolinite was concentrated in the crestal areas of the structure while both illite and quartz
cements increase with depth in the downflank areas. The marine sandstones of the Broom
Formation are the exception, being kaolinite-rich with little illite even below the oil-water
contact. An early phase of oil migration into the structure appears to have been concurrent with
the later stages of quartz overgrowth and clay mineral cementation, the later main phase of
migration causing diagenesis to cease in the crestal part of the field. In the down-flank areas illite
cementation appears to have ceased soon after the main migration of hydrocarbon fluids into the
structure.
The N W Hutton Oilfield, discovered in 1973, provides some o f the deepest oil production
from Brent G r o u p sandstones in the U K sector of the N o r t h Sea (Scotchman & Johnes, 1989).
The field, located in Block 211/27 some 80 miles N E o f Shetland in the East Shetland Basin
(Fig. 1), lies at an average depth of 12000 ft subsea. The hydrocarbons, comprising a low-
G O R crude 0il o f average 37 ~ A P I gravity, are t r a p p e d in a complex Middle to U p p e r
Jurassic, SW-dipping, tilted fault-block structure formed by the re-activation and interaction
o f deep-seated N E - S W and N W - S E fault trends. The productive area o f the field is further
subdivided by N E - S W - t r e n d i n g sealing faults into four m a i n fault blocks (Fig. 2). A water-
bearing, upthrown fault block separates the field from the up-dip H u t t o n Oiltield lying at the
crest o f the major tilted fault-block system which is bounded to the east by the~ D u n l i n -
H u t t o n - N i n i a n fault system. Middle to U p p e r Jurassic Viking G r o u p shales comprising the
H e a t h e r and K i m m e r i d g e Clay F o r m a t i o n s drape the structure and are unconformably
overlain by Lower Cretaceous ValhaU F o r m a t i o n marls and shales.
O i l - w a t e r contact levels vary between the fault blocks, the eastern and central fault blocks
having a c o m m o n contact at 1 1 9 3 0 ft subsea, while in the western fault blocks the o i l - w a t e r
contact steps down from 12452 ft subsea in the inner fault block to 12934 ft subsea in the
9 1989 The Mineralogical Society
340 I. C. Scotchman et al.
0o IOE 2oE 3~
6~- "N
61o! io N
50 ~ N
0~ PE 2~ 3ON
~ BRENT PROVINCE
N 0 20 km
i I OIL FIELD
GAS FIELO
FIG. 1. Generalizedstructure map of the East Shetland Basin showingthe locationof the NW
Hutton Field.
outer block. Petrophysical and production data show a rapid decline in reservoir quality in
the western fault blocks at depths below 12000 ft subsea and, based on the 211/27-A28 well, a
productive limit has been defined at 12500 ft subsea. The eastern and central fault blocks
show a similar decline in reservoir quality with depth.
Clay diagenesis and oil migration in Brent sandstones 341
61" OB'N-
8'1" 04"N"
12000- N~
~ 71.........l~l /// / I II
: "" O~L-W/k.TER COtiTR~" L-w~HE_R C~,TACT
Fro. 2. Simplified top Brent Group sandstone depth-structure map of the NW Hutton Field and
diagrammatic NW-SE cross-section showing the structural subdivision into the four productive
fault blocks.
342 L C. Scotchman et al.
Porosity distribution
Three main types of pore space occur in the Brent Group sandstones: (i) intergranular
pores, (ii) secondary pores, and (iii) intercrystalline clay micropores. Of the three pore types,
the intergranular pores are the most significant in the storage and transmissibility of fluids,
with a thin-section point-count average of 9.5 vol%, ranging up to 18 vol%. Coarse-grained
distributary-channel sandstones with low clay content have the highest intergranular pore-
space content (average 12.9 vol%), resulting in large interconnected pores. Permeability is
therefore high and these sandstones have the best reservoir quality. The marine-bar facies
sandstones also contain abundant intergranular pores ranging from 4 to 16 vol% (average
10.4 vol%).
Secondary pores result from the partial or complete leaching of unstable grains such as
feldspar (Fig. 3d) in the sandstone framework and are present in all sandstones not cemented
by early calcite, ranging from 0 to 8 vol% (average 3.7 vol%). These pores are generally poorly
interconnected and only effectively enhance permeability and transmissibility when
connected with intergranular pores. Secondary porosity significantly promotes reservoir
quality in the Broom Formation due to the large-scale leaching of the feldspar present in these
sandstones.
The intercrystalline clay micropores are non-effective with respect to fluid transmission
due to their extremely small pore throats and high tortuosity and capillarity. Porosity in fine-
grained sandstones such as the Rannoch Formation is predominantly of this type,
particularly those with a high authigenic clay content. Here porosity is relatively high but
permeability is very low, this pore-type being associated primarily with illite, although in the
Broom Formation sandstones it is associated with kaolinite.
344 L C. Scotchman et al.
..=
L~
=
t"-
"= .~
i,+
('9
.o
,J=
~6
..=
~3
,-?.
~a
| | ++
~. ~g
~ 0 0 ~ 0 ~ 0
346 I . C . Scotchman et al.
"9.
.=.
"7.
Z
"9.
..=
~ 6 o ~ " ~ " " ~ " ~
- ~ ~ ~ ~
..=
~ ~ _. . . . ~ o 9 ~
"9.
b
"9.
N .=.
e4
m
| o~~ ~ ~ ~ ~o
=~
~
~
o
Clay diagenesi~ and oil migration in Brent sandstones 347
~ o 6 6 6 6 6 ~ AA66
~
P+
~ 0 0 0 0 0 ~ ~ 0 0 ~O00 ~
++ ++
9 ~ ++~ + ++ + ~
++++++++++++3~+i+ ++~+|
"+ ~ 'm-+ + + + ~ + +
348 I . C . Scotchman et al.
a~ o ~ ~ I~ ~
~8
I llrl~llrllllafllr
?
o
t~
i
Clay diagenesis and oil migration in Brent sandstones 349
+~
v.~
illl~liJllll~l~f ~Jlll
I~ltl~lrllllJll i i i~r
r~ ~ ~ .,..., ,...,
350 I . C . Scotchman et al.
~ O0
-.~ ~ : o
II II II II
III
e~
~.)
o=
~. fl H I[ H II
~rj
[-
H II H II u
i [-
Clay diagenesis and oil migration in Brent sandstones 351
Porosity within the N W Hutton structure shows a decline with structural depth, which is
particularly evident from the western fault blocks. Core data from the Etive Formation
sandstones show an average decline of 0.46%/100 ft from an average of 20.7% in crestal well
211/27-A 1 at 11130 ft subsea to 12.7% in downflank well 211/27-A28 at 12 870 ft subsea (Fig.
4). Etive Formation core permeability shows a rapid decline from a n average 296 md in the
crestal well to an average of < 1 m D beneath the downflank productive limit of 12500 ft
subsea (Fig. 4). Core permeability from the whole field shows a more rapid decline below
about 12000 ft subsea (Fig. 5).
352 L C. Scotchman et al.
FIG. 3. (a) and (b) Etive Formation sandstones showing the down-structure increase in quartz
overgrowth cementation. Intergranular pores have only partially been reduced in size by quartz
overgrowth development (arrows) at the crest of the structure in well 211/27-A19 (a) (~b = 16.2~,
k = 123 roD) at 11 549 ft subsea. In downflank well 211/27-A28 (b) (~b = 13.7~, k = 1.03 mD) at
12 924 ft subsea extensive quartz overgrowth cement has greatly reduced and isolated the
intergranular pores (P) and has partially infilled secondary pores (Ps). 128 x. (c) Broom
Formation sandstones in well 211/27~ at 12 238 ft subsea (~b= 2-5~, k = 0.03 mD) showing
calcite (C) and siderite (S) filling intergranular pore space and partially replacing the margins of
framework grains. Siderite appears to be replacing calcite. Note the open framework grain
fabric indicating early calcite cementation pre-dating compaction. 128 x. (d) Broom Formation
sandstone in well 211/27-A28 at 13 030 ft subsea (~ = 14.8%, k = 1.6 mD). Feldspar (F) has been
preferentially leached along crystallographic axes resulting in minor secondary porosity.
Adjacent intergranular pores are filled with diagenetic kaolinite (K), siderite (S) and quartz
overgrowth (Qo). Leaching of a former framework grain has resulted in secondary pore space
(Ps) being created. 128 x.
i
J
353
e,I i~1
/ ~' !
/ -~1 ~r.,, ~'~
~l~ ~1~
I
i ~ l~
<;
i-ll
I
I,. t~
H ~ |
I11
<
i
~.~
_o
g
a~
~ N
N.~
! o ~ o ~ .~
w
z ~ ---.. 0 9
0 b 0
i | o
oo ~ o
(SS(]^J. J.NN=II H l d 3 a
354 I . C . Scotchman et al.
§ .,.++ + +
§ +
++.,.,. i , k ~ . , , ++.,,.++,,t.+%
,,,,,,.,,.+ *'+, + ++* * + *+1 +++++
I.++ 9~ i +-+..
§
++: N." . +*+ .,I,
9 +
§
+ " ~ 4 1 +§ + + *
.II. <..+ 41,1. ..m.Nl+ +
§ 411 I ~ +'it. +..t. + §
I + 4. +
11500 I + +++,,~*O++=++
+~i ' ++ ...,+.=
+"+ ++;+ ++++ + .it,
I 9 + 9 41* + *.. +. § 2 4 79
I ~4a..,~t..,t.~ § ' ~ ' 4 ' + § 'r'''e % + #§
I ++Nil; 'Hi++ 4,+ e + t,, + + .t +
I ++ e.i..ii$.~r .r § -+ u + +
i +e. + + "~'~ _§ +. "+*j. p
, ,,,..,m.,r?z"+:+++%:p,,Z+,.++,,+:,,,,..,,,,<+m +
I I~" . . <,ti+ _ ++~..$~ ~ I ' ~ , . ~ § +.,,.++ +§247 +~, +
11930' EAST/CENTRAL
l--t -- ---'+"
+,. + ~ + ~ + ~ - = 27 <
- , . + ." z.-.. .+.- - - - +,
F+" v ' N ' + + FAULT BLOCKS
+2000 ~ +.,.+*,, ,*+,+.,t,.,.+ ~ § ++="," ++.,.1 ~ §
+ + .~ql:+ ~'4~+ r "+~-§§ § +
X -4 +++++
+ §
a++,,.."+~,,.,.t+i,7.+2
+ "-IK + I~ -','ql,r
~ +.++,,,++
+ § ~
++""
e;% :t ++,It.
,_,.
~. ~ t a.+++., , ~ , *
9" ~ +.* § + ++++++, +§ + .,-
\. . ........ ..-.-....
_~,_., e+ + + Ir +
@ § 12452' INNER WEST
.+wI- + A,-~-:,,
, +,§ FAULT BLOCK
12500- S\\ .
+++ . . . . .
+ L
++§ d ~ l l l . a " ++
RAN ~" \ ~ ' * + ++
MAXIMUM
PERMEABILITY N ' " %+++ t~++++ . . "
.w. ++ % ~+ §
\ %1.%,~\ § "
12932' OUTER WEST
FAULT BLOCK
13000-
PERMEABlUTY /
TRENO WITH
DEPTH
oIL/WATER
~ONTACT
FIG. 5. Core permeability variation with depth for the whole field showing the rapid
deterioration with depth below ~ 12 000 ft subsea.
and therefore the best reservoir quality: hence the distributary channel sands have the best
reservoir quality and the delta-front sandstones of the Rannoch Formation the poorest. The
Broom Formation sandstones are the exception: they are coarse grained but have relatively
poor reservoir quality due to differential diagenesis (see below). Detrital clay content is also
an important control on reservoir quality and is greatest in the fine-grained sandstones such
as those of the Rannoch Formation where it dramatically reduces both porosity and
permeability. In general there is an inverse relationship between grain size and total clay
mineral content. The combination of these two variables, for example in the fining-up
channel sandstone downcutting into laterally equivalent crevasse-splay sandstone sequences
(Fig. 6), or coarsening-upwards marine-bar sequences results in the large-scale variation of
reservoir quality both vertically and horizontally within the sandstone bodies and the
formation of lateral and vertical permeability barriers.
NW SE
Z5 ZO m io ~ % ~s ~0 i~ t0 ~ % POROSITy z~ 20 m I0 ~ %
----~ PERMEAelLITY
....... POROSITY
FXG. 6. Reservoir characteristics resulting from distributary channel incision into laterally
equivalentcrevasse-splaysandstones in the LowerNess Member showinglarge-scalehorizontal
and vertical reservoir heterogeneities.
Pore-filling cements
The main pore-filling phases are quartz overgrowths, calcite, siderite, illite and kaolinite.
Quartz overgrowths. Volumetrically, quartz is the most important authigenic phase with
an uneven distribution within the sandstones, averaging 12-3 vol% and ranging up to 24 vol%.
It forms euhedral syntaxial overgrowths on detrital quartz grains (Figs 3a and 7a). In the
Broom Formation sandstones, which were subject to early calcite cementation, quartz
356 I. C. Scotchman et al.
~-•
v
Clay diagenesis and oil migration in Brent sandstones 357
11000
x
11250
xx
x
11500 1
x 1~
11750 ,~
N
12000
x
x i:
~- x
=/ .
x
12250 u_ /
12500 1
i x
xl "
13000 x 1
10250.
10500
0 10.0 20.0 30.0
OUARTZ OVERGROWTH (VOW%)
Fro. 8. Quartz overgrowth cement vs. depth showing extensive cementation in down-dip
portions of the field.
cementation is of lesser importance, averaging only 4,8 vol~ (range 0-9 vol~). The Rannoch
Formation delta-front sandstones average 7.2 vol~ while the Ness Formation sandstones
have much higher values, averaging 15-6 vol~. The amount of quartz overgrowth cement
increases with depth (Fig. 8) and in the down-dip parts of the field becomes very extensive
(Figs 3b and 4), particularly in the finer-grained sandstones, resulting in poor reservoir
quality (Gluyas, 1985).
Calcite. The occurrence of poikilotopic calcite cement (Fig. 3c) is restricted to the marine
sandstone facies, in particular those of the Broom and Rannoch Formations where it occurs
as the primary cement in intervals up to 6 ft thick. The regressive marine-bar sandstones at
the base of the Upper Ness Member are also partly calcite-cemented but in the other
sandstone facies calcite is generally~absent. The calcite-cemented intervals are concretionary
358 L C. Scotchman et al.
in nature and have a limited lateral extent and erratic vertical distribution, but, where
present, completely destroy porosity and permeability. The calcite cementation is interpreted
to be a relatively early event as the sandstone fabric is undercompacted and free of quartz
overgrowths.
Siderite. Siderite is restricted to the marine facies sandstones, particularly the Broom
Formation where it averages 9.8 volvo (ranging up to 33 volvo) as discrete crystals or
aggregates partially or completely replacing calcite (Fig. 3c). The delta-front Rannoch
Formation sandstones also contain appreciable siderite (average 3-4 vol~) with a patchy
distribution of individual crystals at grain margins. In the other sandstone facies, siderite is
absent or present only in trace amounts, although siderite nodules occasionally occur in the
Ness Formation.
Dolomite. Dolomite is rare and is rstricted to the marine facies Broom and Rannoch
Formation sandstones in the downflank parts of the western fault block where it has a patchy
distribution.
Pyrite. Typically occurring only in trace amounts, pyrite is often associated with plant
debris and is most common in the Ness Formation delta-front and distributary-mouth-bar
sandstones where it partially fills pore space.
Kaolinite. Kaolinite is the second most abundant pore-filling phase to quartz overgrowths
and is of authigenic origin as evidenced by its delicate morphology of well-crystallized
booklets and platelets (Fig. 7c). XRD analysis shows an average kaolinite content of 5.3 wt~o
and a range of 1.2-17-6 wt~o. Kaolinite is most common in the Broom Formation sandstones
where it is a significant pore-filling phase, often filling the majority of the intergranular and
secondary porosity (Fig. 3d). Its prevalence is probably due both to the relatively high detrital
feldspar content of the sandstones and to their coarse nature which, coupled with overlying
impermeable shales at the base of the Rannoch Formation, caused fluid flow to be
concentrated laterally through the formation, thus promoting leaching and kaolinite
precipitation. Kaolinite has a patchy distribution in the rest of the Brent Group sandstones,
and is most prevalent in the crestal areas of the field (Fig. 4). Locally, kaolinite occludes
significant amounts of pore space, filling both primary intergranular and secondary pores.
Thin-section point-count data indicate average kaolinite contents ranging from 1.9 volvo in
the delta-front Rannoch Formation to 4.0 volvo in marine-bar sands. Within the fine-grained
sandstone facies, XRD data gives averages of 2-4 and 8-2 Wt~o for the crevasse-splay and
delta-front sandstones respectively.
Illite. Illite, and to a lesser extent mixed-layer illite/smectite, is a significant pore-filling
phase particularly in the fine-grained sandstones and in the down-dip parts of the western
fault block, where it drastically reduces reservoir quality. Average values are 2-0 wt~ for illite
(range 0.2-12,3 wt~o) and 1.1 Wt~o for illite/smectite (up to 6.7 wt~o from XRD data). Illite
concentration is lowest in the distributary-channel and marine-bar sandstones, where it
averages 0-9 and 1.3 Wt~orespectively, and highest in the distributary-mouth-bar and delta-
front sandstones of the Etive and Rannoch Formations respectively (averages of 4.0 and 3.6
wt~o). Illite/smectite exhibits a similar facies relationship.
In the coarse-grained distributary channel sandstones, illite has little effect on reservoir
quality and occurs as a patchily developed pore-lining which only rarely bridges pores. Here,
the illite filaments occur as stubs and rarely protrude into the pore space (Fig. 7c, d). In the
finer-grained sandstone facies, including the upper portions of the distributary channel
sequences and crevasse-splay lobes, illite has a much greater abundance and is developed as a
pore-filling and pore-bridging filamentous morphology comprising long filaments which
Clay diagenesis and oil migration in Brent sandstones 359
rn C~ON
' ~ o ~
~:i --~
~DO
Z-~- = Z
o
~.~~.~
360 L C. Scotchman et al.
0
5000-
00 0
0 - 167 SAMPLES ONLY SCREENED 0
I000 - Oq5 o
BY THIN SECTION
9 0@
0 00 9 000 0 0
500 - 9 57 SAMPLES SELECTED FOR
FURTHER ANALYSIS BY 9 o 0
THIN SECTION, SEM,AND XRD 0 Oo IO 0 0
0 09 O0 0
o o 0@0 0 0
0 0 9 0
I00 0 ~ 0
o oOoO 9
9 O0 00 O9
50 0 0 0 0
0 0 9
0 9 9 9
00e eo~
o 9 O0 0
E 0 00000 0
I0
000 9 0 0
..a
ii1
0
Oe "o-
0O0 0
o o800 -
@000 9 ~ o o o
I.O
0 o00~0 ~
~0 0 0 O0
OO@D
OO I~ 0
0 ~
O0
0"1
o 0
oo 0 CALCITE
00
CEMENTED
0"01
,
0
~176
0t 00
0
i
5
r
10
!
15
i
20
21
5
POROSITY (%]
FIG. 10. Relationshipof permeabilityto porosity, showing the wide range of permeabilityfor a
given porosity.
extend into and across pores and pore-throats (Fig. 9a) resulting in greatly reduced reservoir
quality. These filamentous illites contain abundant intercrystalline micropore space and have
little effect on overall porosity but greatly reduce permeability. As a result the sandstones
exhibit a wide variation in permeability for a given porosity (Fig. 10).
Illite abundance generally increases with depth, particularly below 12000 ft subsea (Fig.
11) and with finer grain size (Fig. 12), and, although the Etive and Ness Formation sand-
stones show an increase in illite content in the water zone, the increase in illite cement with
depth is not related to the present-day oil-water contact. In the western flank of the field;
illite content controls the position of the productive limit, ~hich occurs at the top of an illite-
cemented zone as illustrated by the field permeability profile (Fig. 5) and by the water-
saturation profile with depth for the Etive Formation (Fig. 4). Therefore, illite cementation
appears to have occurred prior to hydrocarbon migration, the influx of hydrocarbons causing
diagenesis to cease. Subsequently, only minor illite precipitation occurred beneath the oil-
water contact. Analogy with the present-day oil-water contact suggests that the dramatic
increase in illite cement below 12 000 ft subsea (Fig. 11) is therefore not related to the develop-
ment of a palaeo-oil-water contact, but is a palaeodepth-related phenomenon.
Clay diagenesis and oil migration in Brent sandstones 361
11000
11250
x/x
11500 1
11750- x/x
12000
^^xx\xx
~ 12250" X
APPROXIMATE ILLITE
TREND WITH DEPTH
~ 12500
\x
12750-
xx
\ X
X
xx x\
13000
x
13250"
13500
0.0 4~0 8.0 12'.0 16.0 20'.0 24.0
ILLITE (Wt %)
FIG. 11. Illite content vs. depth showing dramatic increase in illite beneath ~ 12 000 ft subsea.
Chlorite. Occurring as delicate, intergrown crystal platelets, chlorite forms a minor cement
in pore-filling and grain-coating morphologies (Fig. 9b). It is commonest in the Broom
Formation marine sandstones and Rannoch Formation delta-front facies with average
contents of 1 and 2.2 wt% respectively.
DISCUSSION
Paragenetic sequence
The paragenetic sequence of major diagenetic events is summarized in Fig. 13. Soon after
deposition, thin horizons within the marine sandstones of the Broom and Rannoch
Formations were affected by concretionary poikilotopic calcite cementation, causing
porosity to be totally occluded. A loose-framework grain fabric is preserved, indicating that
cementation occurred before significant compaction. The initial porosity of the sandstotles at
deposition is estimated to be 35-40%, derived from the minus-cement porosity.
These early calcite cements protected the sandstones from the effects of later diagenesis,
particularly the formation of quartz overgrowth cements and the dissolution of minerals such
362 I. C. Scotchman et al.
20-
15-
10-
\\\\\I
0-
I
VERY FiNE
\ \ \ \
E o
0
v///~q CALCITE
I
v////ISIDERITE
ICOMPACTION ~r>
r//////////////////////////////JQUARTZ
k\\\\\\\\\~ FELDSPAR
OVERGROWTH
_o
>r
0
3J~
1 7 7 7 ~ CH LORIT E m
V////A FERROAN DOLOMITE
EVENT I"1 I--I [ ] O I L EMPLACEMENT 0
Y / / l l PRECIPITATION
[ ~ DISSOLUTION 2~
r
lOE
, y_s 1
' TH,S'T,_EI
/ : " "
J
[ .1
, ' ' /: " t
6~ON ..-__.1 _ 51ON
HEATHER L ' "
/ . 9
/ , ".
NINIA~
SHETLAND ] / "'. .
PLATFORM/ ~ , "~ ~ ' ~ ~LWYN
/ / L \ \ '
/ I !
/
i / /
/
/ : / ~
/~ 1
\
/
/ ~ ALWYN
/ /
/
/
/
I
I~ E
FIG. 14. Kimmeridge Clay Formation isopaeh map showing the juxta-position of the NW
Hutton Field to the generating basin to the SW.
K-Ar dating of illites can be used to constrain the timing of hydrocarbon migration
(Thomas, 1986; Liewig et al., 1987; Jourdan et al., 1987). Illites from N W Hutton have an
Eocene age range of 39-49 Ma with an average of 41 Ma for the water zone and 43.1 Ma for
the oil zone (J. Cocker, personal communication, 1988). The reservoir therefore appears to
have been filled over the short period of 5 Ma, the relatively narrow range of the water-zone
samples (40.4-41-3 Ma) suggesting that large-scale fluid movement into the structure ceased
41 Ma ago.
Clay diagenesis and oil migration in Brent sandstones 365
~
ILLITE CEMENTATION OF
BRENT GROUP RESERVOIRS N.W.
2000- QUARTZ OVERGROWTH & I OIL HUTTON
~ KAOLINITE CEMENTATION J MIGRATION CREST
~ SECONDARY I
\\ \ ~oRos,r~ FM. I ; -1
4000 -
70-80 e C
"~ ,~ \ ~ I
u.
\ ~ \ I I
6000-
'I- r
I.-
W I-'W
CI ~O
W--
8000- ~~
eo
100-110" C
g il \ "-~,,,. i ",~,,..
10000-
12000-
"~l"b4
14000 130" C
83 mD
J211127-7
11000
9211127-A1
211121-7Y ~
11000
\
A211127-AI 9 OIL ZONE AVERAGEPERMEABILITY
r 2 - 0.93 ~, WATERZONE AVERAGEPERMEABILITY
11500
9 OIL ZONE
~ WATERZONE \ ' L " ~ . r==0.95
11500
F- 12.7mD
211/27-A37
~ 12001D
21112Z-A87
! 1200~ ~21t/27-A17
A211/27-A28
12500 211127-11
12500" 211127-119
211127-A25
18000
211127-A28
1800C
6 10000 1000 1()0 10 i 0~1 0,'01
CORE POROSITY(%) CORE PERMEABILITY
(a) (b)-
Fzo. 16. Comparisonof (a) porosity and (b) permeability decline with depth between the oil
zone and the water zone in the eastern and central fault blocks.
Diagenetic model
Carbonate cementation. Carbonate cementation was an early pre-compactional diagenetic
event with calcite precipitation in concretionary bands. Restriction of the calcites to the
marine sandstones suggests that Ca originated from detrital shell material which was
redistributed during early burial to form concretionary bodies, perhaps along coarser-grained
layers. Oxygen isotope studies on similar calcites from other Brent Group sandstone
Clay diagenesis and oil migration in Brent sandstones 367
30-
9 NESS FORMATION
~7 ETIVE FORMATION
9 TARBERT FORMATION
r 2 - 0.31
~ 20- V 9 9
(3
9 -,...
10-
0
o 1'o 2'0 3'0
Q U A R T Z OVERGROWTHS (Vol.%|
FIG. 17. Correlationof porosity decline with increasing quartz overgrowth cementation in the
Etive, Ness and Tarbert Formations of the western fault blocks.
10000,
1000'
A
100-
\ ,
~ 10' I \'11
9 i\
9 R
L\
8 1. 9 i,\ i
. \
\
0.1.
O.01
0 4,0 8.0 12.0 16.0 20.0
ILLITE (Wt%)
FIG. 18. Relationship between permeability and illite content of the Etive Formation of western
fault blocks.
reservoirs indicate precipitation from meteoric waters (Glasmann et al., 1989). Replacement
of calcites by siderite, particularly in the Broom Formation, indicates both a change to anoxic
conditions, favouring reduction of detrital ferric oxides, and the predominantly meteoric
nature of the pore-fluid (Curtis & Spears, 1968).
368 L C. Scotchman et al.
Feldspar dissolution and silica~clay authigenesis. Dissolution of feldspars and, to a lesser
extent, micas occurred with deeper burial in all sandstones but was concentrated in the
feldspar-rich Broom Formation, creating secondary porosity. Precipitation of authigenic
quartz overgrowths and kaolinite with later illite overlapped feldspar dissolution, which
probably supplied silica, AI, K and other cations. However, simple mass-balance calculations
show that an additional external source of silica is necessary as the volume of quartz and
kaolinite exceeds detrital grain dissolution by a factor of five to ten times.
It is generally accepted that acidic porewaters are required to create significant secondary
porosity and four main sources have been suggested (Giles & Marshall, 1986):
(i) meteoric water;
(ii) carbonic acid from CO2 generated during the maturation of kerogen;
(iii) carboxylic acids, which complex AI and greatly increase its solubility, derived from
kerogen maturation;
(iv) acidic fluids generated by clay mineral reactions in shales.
A large-scale post-burial influx of meteoric waters into the Brent Group sandstones of NW
Hutton seems unlikely as the overlying Upper Jurassic shales are not breached locally by the
base-Cretaceous unconformity which has been regionally invoked as the main period of
meteoric water influx during Brent diagenesis (Blanche & Whittaker, 1978; Bj~rlykke, 1984;
Kantorowicz, 1984; L~noy et al., 1986; Thomas, 1986; Jourdan et al., 1987; Glasmann et al.,
1989). For the nearby Heather Field, which has also remained unbreached by post-Brent
erosion, Glasmann et al. (1989) resort to a flow of meteoric water down faults from the East
Shetland Platform, which appears difficult to envisage and, even if such a mechanism were
operable, Curtis (1983) and Giles & Marshall (1986) have demonstrated that such long-
travelled meteoric waters would have been effectively neutralized early in their flow paths.
Meteoric water appears able to cause widespread development of secondary porosity during
shallow burial where low reaction rates due to low temperatures and high fluid-flow rates
favour silica transport (Giles, 1987). However, feldspar dissolution appears not to be a very
early event in the NW Hutton Field, suggesting that meteoric waters were not the main agent
for secondary porosity development.
Basin-derived acidic porewaters containing CO2 from kerogen diagenesis (Schmidt &
McDonald, 1979) or carboxylic acids (Surdam et al., 1984; Surdam & Crossey, 1985; Curtis,
1987) generated prior to kerogen maturation appear to be responsible for the large-scale
dissolution of feldspar. The zones of secondary porosity and diagenetic cement are related to
the present structure which developed prior to the base-Cretaceous unconformity, suggesting
a deep burial source for the fluids. Kimmeridge Clay Formation source rocks are capable of
generating significant amounts of carboxylic acids and CO2 at temperatures of 70~176
(6000-8000 ft burial) (Fig. 14) during late diagenesis and early maturation from mixed Type
II/Type III kerogen facies (Eglinton et al., 1987; Kawamura & Kaplan, 1987). The formation
in the vicinity of the NW Hutton Field has a total organic carbon (TOC) content of 4.5-6-5%
while underlying mudrocks of the Heather Formation (Middle to Upper Jurassic) and Dunlin
Group (Lower Jurassic) have similar kerogen compositions and could also supply acidic
porewaters, although they tend to be organically leaner with TOCs of 0.7-1-9% and 3.3-3-5%
respectively.
Clay mineral diagenetic reactions, particularly the transformation of random illite/smec-
tite to ordered illite/smectite which occurred in the source rocks at burial depths of 8000 to
10000 ft (Pearson et aL, 1983; Dypvik, 1983; Scotchman, 1987) could have generated
additional acidic porewaters (Bj~rlykke, 1983; McMahon, 1988).
Clay diagenesis and oil migration in Brent sandstones 369
Quartz overgrowth and kaolinite cements appear to rely both on feldspar dissolution by the
acidic porewaters and on an external source for the supply of cations and silica necessary for
their authigenesis (Hurst & Irwin, 1982; Gluyas, 1985). The illitization of smectite in the
source rock can create silica-charged porewaters (Boles, 1981), providing a possible external
silica source.
Illite precipitation follows quartz overgrowth and kaolinite authigenesis, with some partial
replacement of kaolinite. Two morphologies of illite exist: the filamentous form which
appears to be related to the detrital clay substrate and predominates in the poorer reservoirs,
and platy illites which do not show this relationship and appear to be neoformed (Macchi,
1987). Alternatively, Cocker (1986) suggests that the platy morphology, which predominates
in the oil zone, is the result of the hydrocarbon-water interface passing through the reservoir,
causing the iUite filaments to mat.
Illite is the predominant clay phase in the deeper, downflank parts of the field, and appears
to have formed beneath a critical depth as suggested by Hamilton et al. (1987). Kaolinite is
the main phase in the crestal regions. Hancock & Taylor (1978) report the occurrence of this
general anticorrelation between the two phases from elsewhere in the Brent Group
sandstones. The kaolinite--illite-K-feldspar phase diagram of Gluyas (1985; his fig. 6)
suggests temperature is an important factor as, with over 2000 ft of vertical relief on the NW
Hutton structure, the critical depth below which illite precipitation is favoured over kaolinite
appears to have occurred mid-structure at a present-day burial depth of ~ 12 000 ft subsea.
During the Eocene, this would equate to a palaeo-burial depth of ~8000 ft and a
temperature, assuming a surface temperature of 20~ and a geothermal gradient of 30~
of 90~176 This falls within the temperature range over which illite diagenetically formed
in Gulf Coast Tertiary sediments of the USA (Hower et al., 1976). Experimental work by
Huang et al. (1986) may also explain the kaolinite and illite distribution. They found that
kaolinite precipitates in arkosic sandstone reservoirs with a continued influx of acidic pore-
fluid, illite forming at the expense of kaoline as the fluid flow wanes. Thus early kaolinite
authigenesis occurred in the crest of the structure with the main influx of acidic porewaters
and was followed by later illitization during deeper burial as the flow of acidic waters
diminished, which mainly affected the downflank areas of the field.
The ideal diagenetic sequence of feldspar dissolution followed by quartz overgrowth,
kaolinite and illite cementation appears therefore to be due to, and be controlled by, the
generation and expulsion of acidic pore-fluids from adjacent shale source rocks, prior to
hydrocarbon generation (Fig. 15). This general sequence is repeated, causing complex
interaction of the phases and the development of late quartz overgrowth cements containing
hydrocarbon-bearing fluid inclusions (J. Cocker, personal communication, 1988) as a result
of distinct pulses of acidic pore-fluid reaching the reservoir, perhaps due to the 'seismic
pumping' effects of active faulting (Sibson et aL, 1975).
sandstones. Structural depth and initial mineralogy influence the kaolinite distribution.
Kaolinite in the Etive Formation sandstones decreases with depth, but the Broom and
Rannoch Formations remain predominantly kaolinitic with only minor iUite below the oil-
water contact (e.g. well 211/27-A28) and, indeed, contain more kaolinite. The fine-grained,
micaceous, crevasse-splay sandstones of the Ness Formation and the Rannoch Formation
contain the highest amounts of illite, suggesting an overriding lithological and depositional
mineralogical control on iUitization. Sommer (1978) and Kantorowicz (1984) report similar
patterns of illitization within the different Brent Group Formations and its relationship to
kaolinite and hydrocarbons.
Clay diagenesis in the Brent Group sandstones is therefore clearly controlled by
depositional facies and by structural depth, the relationship to the oil-water content being
relatively unimportant. Clearly the general model relating illitization to hydrocarbon
migration proposed by Hancock & Taylor (1978) is too simplistic and cannot be directly
applied to the Brent Group as a whole without taking depositional facies into account.
CONCLUSIONS
The following conclusions can be drawn from this study of diagenesis of the Brent Group
sandstones in the NW HuRon Field:
(1) Authigenic quartz overgrowth and iUite cements are responsible for the major decline in
reservoir quality with structural depth, quartz overgrowth being responsible for porosity
reduction and illite for permeability decline.
(2) Regardless of structural depth, reservoir quality remains higher in the detrital clay-free,
coarser-grained distributary sandstones than in the clay-rich, fine-grained crevasse-splay
sandstones: diagenesis reflects facies and lithological variations in the sandstones.
(3) Clay mineral authigenesis is strongly influenced by sandstone depositional facies and
lithology: the feldspathic marine sandstones are highly kaolinitic with little illite even in the
water zone, distributary channel sandstones are generally kaolinitic in crestal areas of the
field and illitic downflank, while fine-grained crevasse-splay sandstones are iUite-rich
regardless of structural depth.
(4) Illite cementation is depth-related and occurs below 12 000 ft subsea. This equates to a
palaeo-burial depth of ~ 8000 ft and a precipitation temperature of 90~176
(5) Illite cementation appears to be related neither to the present-day oil-water contact nor
to any palaeo-oil-water contact.
(6) External factors had a major influence on the course of diagenesis. Meteoric waters
predominated during early diagenesis following burial but, due to the juxta-position of
basinal source rocks, were replaced by acidic, silica-charged porewaters during deeper burial.
These porewaters were derived from the organic-rich mudrocks prior to hydrocarbon
generation and were responsible for feldspar dissolution in the reservoir sandstones and the
precipitation of quartz overgrowth, kaolinite and, later, illite cements.
(7) The relationship of illitization to hydrocarbon migration into the NW Hutton structure
appears to be complex, the oil influx causing iUitization to cease in the oil zone. Minor iUite
cementation continued in the water zone but ceased soon after oil migration due, perhaps, to
the pore-fluid composition becoming unfavourable or, more likely, to the sealing of the fluid
migration path by fault movements.
372 L C. Scotchman et al.
ACKNOWLEDGMENTS
We would like to thank Amoco and the Partners in the NW Hutton Group (Mobil, Enterprise, Texas Eastern
and Amerada Hess) for permission to publish this paper; Bruce Kennedy draughted the fgures. The text
greatly benefited from comments by Josh Cocker and two anonymous reviewers.
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