Professional Documents
Culture Documents
3.1.2Adsorbate ...................................................................................................... 43
INDEKS ...................................................................................................................... 52
40
DAFTAR TABEL
Tabel 3- 1 Properties of Drimarene Red X-6BN (C.I. Reactive Red 243) ................. 43
Tabel 3- 2 Reactive Red 3BS (C.I. Reactive Red 239) - Two reactive groups........... 44
Tabel 3- 3 Constants k for calculations of dye concentration of dyes used ................ 48
Tabel 3- 4 Recipe for temperature equilibrium sorption studies................................. 49
41
DAFTAR GAMBAR
Gambar 3- 1 the molecular structure of Reactive Red X-6BN (C.I. Reactive Red 243)
..................................................................................................................................... 45
Gambar 3- 2 the absorbance spectrum of Red X-6BN in visible wavelength,
λmax=511nm............................................................................................................... 45
Gambar 3- 3 the molecular structure of Reactive Red 3BS ........................................ 46
Gambar 3- 4 the absorbance spectrum of Red 3BS in visible wavelength,
λmax=537nm............................................................................................................... 46
Gambar 3- 5 Calibration curve for Red X-6BN at hmax = 511 nm............................ 47
Gambar 3- 6 Calibration curve for Red 3BS at hmax = 537 nm ................................ 48
42
CHAPTER 3 MATERIAL AND METHODOLOGIES
3.1 Material
3.1.1 Adsorbent
3.1.2Adsorbate
Two commercial reactive dyestuff were used in the project,
namely, Drimarene Red X-6BN (Table 2-1), and Reactive
Red 3BS (Table 3-2). The reason for selecting these dyes is
that their chemical structures are disclosed so that the
properties of these two dyes can be identified and easier to
interpret the isotherms’ results.
43
system ne
+
Monochlortriazi
ne
Molar mass 1136.31
Max absorbance 511 nm
Company Clariant
Tabel 3- 2 Reactive Red 3BS (C.I. Reactive Red 239) - Two reactive groups
+
Vinylsulf
one
Molar mass 1136.35
Max absorbance 537 nm
Company Many producers
44
Gambar 3- 1 the molecular structure of Reactive Red X-6BN (C.I. Reactive
Red 243)
0.25
0.2
X-6BN (ABS)
0.15
0.1 X-6BN
0.05
0
0 100 200 300 400 500 600
Waveleng (nm)
45
Gambar 3- 3 the molecular structure of Reactive Red 3BS
0.25
0.2
0.15
3BS (ABS)
A
0.1
0.05
0
350 450 550 650 750
-0.05
Wavelength (nm)
46
700 nm. After that, the maximum absorbance of each dye
was plotted against the concentrations (Jansson, 1994).
0.25
0.2
0.15
3BS (ABS)
A
0.1
0.05
0
350 450 550 650 750
-0.05
Wavelength (nm)
47
0.25
0.2
0.15
3BS (ABS)
A
0.1
0.05
0
350 450 550 650 750
-0.05
Wavelength (nm)
48
(Peterson DL & Wong, 1990).
49
5 0.2 18 0.036 0.18
6 0.2 20 0.04 0.2
7 0.2 25 0.05 0.25
8 0.2 30 0.06 0.3
9 0.2 40 0.08 0.4
10 0.2 50 0.1 0.5
50
3.4 Calculation of dye concentration of isotherm
The chitosan sorption capacity qe was precisely calculated from:
qe = Dye concentration in sorbent at equilibrium
CO = Initial dye concentration in liquid phase
Ce = Liquid phase dye concentration at equilibrium
V = Total volume of dye solution used
M = Mass of sorbent used
3.5 Apparatus
A Grant OLS 200 shaker was used for the dye adsorption.
A Beckman J2-21 centrifuge was used for separation of
chitosan and dye solution. A spectrophotometer (Perkine
Elmer Lambda 18) was used to determine the UV-IS
absorption absorbance of the dye (Redlich & Bonneau,
1995).
51
INDEKS
Absorbance, 48 Liquid, 50
Adsorbate, 43 Material, 43
Adsorbent, 43 Spectrophotometer, 46
Apparatus, 50 temperature, 48
calibration, 46 UV-IS, 49, 50
Calibration, 42, 47 Vinylsulfone, 44
isotherms, 43
52
DAFTAR PUSTAKA
Gandhi, A. R. (2015, April 6). Adsorption of dyestu†s from aqueous solutions with
activated carbon. I.
Jansson, C. (1994, Mei 23). Uranium and vanadium sorption by chitosan and
derivatives. p. 12.
Okamoto, Y., & Kataoka. (1993, Maret 23). Adsorption of acid dye on crosslinked
chitosan. pp. 10-11.
Peterson DL, R., & Wong. (1990, Juli 29). Process Biochem. pp. 80-100.
Redlich, P., & Bonneau. (1995, Januari 4). Comparative cost of color removal from
textile. pp. 34-35.
53