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120
X - Y diagram of Benzene and Toluene mixtures
115
110
Temperature (Kelvin)
105
100
Bubble point
Dew Point
95
90
85
80
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000
Mole Fraction of Benzene
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Question two
Y = αX/(αX+(1-X))
Answer to Question 3
Chart Title
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000
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Line I
Line II
100% vapourization implies that V=F and L=0.0. The equation of line II is a horizontal line of gradient
zero which passes thru’ x = xF and y = xF or (0.5,0.5). This line intercepts the equilibrium distribution
curve at x = 0.293 and y* = 0.50. The bubble point temperature is 99 oC.
Question 4
7.00
X Y* Y*-X 1/(Y*-X)
6.00
1 1
5.00 0.655 0.81 0.155 6.45
0.51 0.698 0.188 5.32
1/(Y*-X)
Using the middle estimate, L1/L2 = 2.556 L2 = 100/2.556 = 39.12. Amount of distillate collected is
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Question 5
Flash Evaporation
1.000
Distribution Curve for Acetone -Water mixtures
y- mole fraction of Acetone in Vapour
0.900
0.800
0.700
0.600
Phase
0.500
0.400
0.300
0.200
0.100
0.000
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000
x- Mole Fraction of Acetone in Liquid Phase
Differential mode
Rayleigh Plot
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5.000
3.000
1/(Y*-x)
2.000
1.000
0.000
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800
x - Mole fraction of Acetone in Liquid Phase
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