Professional Documents
Culture Documents
Introduction to Aspen Plus
Pl
Short Courses on Computer Applications for ChE Students
Speaker: JianKai Cheng (程建凱)
p g (程建凱)
d95524021@ntu.edu.tw
PSE Laboratory
Department of Chemical Engineering
Department of Chemical Engineering
Nation Taiwan University
What
What is Aspen Plus
is Aspen Plus
• Aspen Plus is a market‐leading process modeling tool
for conceptual design, optimization, and
performance monitoring for the chemical, polymer,
specialty chemical, metals and minerals, and coal
power industries.
2
Ref: http://www.aspentech.com/products/aspen-plus.cfm
What
What Aspen Plus provides
Aspen Plus provides
• Physical Property Models
– World’s largest database of pure component and phase equilibrium
data for conventional chemicals electrolytes solids and polymers
data for conventional chemicals, electrolytes, solids, and polymers
– Regularly updated with data from U. S. National Institute of Standards
and Technology (NIST)
• Comprehensive Library of Unit Operation Models
– Addresses a wide range of solid, liquid, and gas processing equipment
– Extends steady‐state simulation to dynamic simulation for safety and
d d l d l f f d
controllability studies, sizing relief valves, and optimizing transition,
startup, and shutdown policies
– Enables you build your own libraries using Aspen Custom Modeler or
programming languages (User‐defined models)
3
Ref: Aspen Plus® Product Brochure
More Detailed
More Detailed
• Properties analysis
– Properties of pure component and mixtures (Enthalpy,
density, viscosity, heat capacity,…etc)
– Phase equilibrium (VLE, VLLE, azeotrope calculation…etc)
– Parameters estimation for properties models (UNIFAC
method for binary parameters, Joback method for boiling
points etc)
points…etc)
– Data regression from experimental deta
• Process simulation
P i l ti
– pump, compressor, valve, tank, heat exchanger, CSTR, PFR,
di till ti
distillation column, extraction column, absorber, filter,
l t ti l b b filt
crystallizer…etc 4
What course Aspen Plus
can be employed for
• MASS AND ENERGY BALANCES
• PHYSICAL CHEMISTRY
• CHEMICAL ENGINEERING THERMODYNAMICS
• CHEMICAL REACTION ENGINEERING
CHEMICAL REACTION ENGINEERING
• UNIT OPERATIONS
• PROCESS DESIGN
• PROCESS CONTROL
5
Lesson Objectives
Lesson Objectives
• Familiar with the interface of Aspen Plus
• Learn how to use properties analysis
• Learn how to setup a basic process simulation
6
Problem Formulation 1: Calculation
the mixing properties of two stream
1 2 3 4
Mole Flow kmol/hr
WATER 10 0 ? ?
BUOH 0 9 ? ?
BUAC 0 6 ? ?
Mass Balance
Total Flow kmol/hr 10 15 ? ?
Temperature C 500 80 ? ? E
Energy B
Balance
l
Pressure bar 1 1 1 10 Enthalpy
Enthalpy kcal/mol ? ? ? ? Entropy…
E t
Entropy cal/mol-K
l/ l K ? ? ? ?
Density kmol/cum ? ? ? ?
7
Problem Formulation 2:
Flash Separation
120
T-x
T
T-y
115
T=105 C
T ( C)
110
o
Saturated Feed P=1atm
105
P=1atm
F=100 kmol/hr 100
zwater=0.5 0.0 0.2 0.4 0.6 0.8 1.0
zHAc=0.5 xWater and yWater
10
1.0
0.8
Reflux
ratio ? 0.6
yWater
0.4
0.2
Duty ?
0.0
0 0
0.0 0.2 0.4 0.6 0.8 1.0
xWater
Outline
• Startup in Aspen Plus (Basic Input) (45 min)
– User Interface
– Basic Input: Setup, Components, Properties.
• Properties Analysis (1 hour)
– Pure Component
– Mixtures (phase equilibrium)
• Running Simulation (1 hour)
– Blocks (Unit Operations)
– Streams (flow streams)
– Results
10
Introduction to Aspen Plus – Part 1
Startup in Aspen Plus
11
Start with Aspen Plus
Start with Aspen Plus
A
Aspen Pl
Plus User
U IInterface
t f
12
Aspen Plus Startup
Aspen Plus Startup
13
Interface of Aspen Plus
Interface of Aspen Plus
ProcessFlowsheet
Process Flowsheet Windows
Windows
Model
ModelLibraryyy ((View|
Library (View||| Model
ModelLibrary
Library
yy) )
Stream
14
Status message
More Information
More Information
15
Help for Commands for Controlling Simulations
Data Browser
Data Browser
• The Data Browser is a sheet and form viewer with a
hierarchical tree view of the available simulation
input, results, and objects that have been defined
16
Status Indicators
Status Indicators
17
Basic Input
Basic Input
• The minimum required inputs to run a simulation
are:
– Setup
– Components Property Analysis
– Properties
– Streams
Process Simulation
– Blocks
18
Setup – Specification
Setup –
Setup
Run Type
Input mode
19
Setup – Run Type
Setup –
Setup Run Type
Run Type Description Use to
A standalone assay data
A t d l d t Analyze assay data when you do not want to
A l d t h d t tt
Assay Data Analysis
analysis/pseudocomponents generation run perform a flowsheet simulation in the same run.
Fit physical property model parameters required
A standalone data regression run. Can contain by Aspen Plus to measured pure component,
D t R
Data Regression
i property constant estimation and property analysis
t t t ti ti d t l i VLE, LLE and other mixture data. Aspen
VLE LLE d th i t d t A Pl
Plus
calculations. cannot perform data regression in a Flowsheet
run.
Prepare a property package for use with Aspen
C
Custom Modeler, with third party commercial
M d l i h hi d i l
Properties Plus A Properties Plus setup run engineering programs, or with your company's
in house programs.
You must be licensed to use Properties Plus.
P f
Perform property analysis by generating tables
l i b i bl
A standalone property analysis run. Can contain
of physical property values when you do not
Property Analysis property constant estimation and assay data
want to perform a flowsheet simulation in the
analysis calculations.
same run
E i
Estimate property parameters when you do not
h d
Property Estimation A standalone property constant estimation run want to perform a flowsheet simulation in the
same run.
A Flowsheet run (including sensitivity studies and
( g y
optimization). also include the following
Flowsheet Perform process simulations
calculations: Property estimation, Assay data
analysis and Property analysis 20
Components – Specification
Components –
Components
IInput components
t t
with Component name or Formula
21
Input components
Input components
22
Specification
To do this Click this button
Find components in the databanks Find
Define a custom component that is not in User Defined
a databank
Generate electrolyte components and Elec Wizard
reactions from components you entered
Reorder the components you have Reorder
specified
Review databank data for components Review
you have specified (Retrieved physical
property parameters from databanks )
property parameters from databanks.)
23
Find Components
Find Components
Click “Find”
24
Find Components (cont
Find Components (cont’d)
d)
Input Component name or Formula or
p p CAS number
25
NIST Chemistry WebBook
NIST Chemistry WebBook
NIST Chemistry
26
Properties
Process type(narrow the number of
Process type(narrow the number of
methods available)
27
Property
Property Method Selection –
Property Method Selection
Method Selection – Assistant
28
Assistant Wizard
Assistant Wizard
Specify Component type
Chemical Systems
Is the system at high pressure?
(NO)
Two liquid phases
29
30
Reference: http://www.et.byu.edu/groups/uolab/files/aspentech/
Thermodynamic Model – NRTL
Thermodynamic Model –
Thermodynamic Model
Vapor EOS
NRTL
Liquid gamma
Liquid enthalpy
Liquid volume
Liquid volume
31
Modify Property Model
Modify Property Model
Check “Modify
y Property
p y Model”
Specify
p y New Method Name
32
NRTL – Binary Parameters
NRTL –
NRTL Binary Parameters
Click
Cli k “NRTL” andd th
then bbuilt-in
ilt i binary
bi parameters
t
appear automatically if available.
33
Access Properties Models and
Parameters
34
Review Databank Data
Review Databank Data
Including:
Ideal g
gas heat of formation at 298.15 K
Ideal gas Gibbs free energy of formation at
298.15 K
Heat of vaporization at TB
Normal boiling point
Standard liquid volume at 60°F
60 F
….
Description of each parameter
35
Pure Component Databank Parameters
Pure Component Databank Parameters
36
Help for Pure Component Databank Parameters
Pure Component
Temperature‐‐Dependent Properties
Temperature
CPIGDP‐1 ideal gas heat capacity
CPSDIP‐1 Solid heat capacity
DNLDIP‐1 Liquid density
DHVLDP‐1 Heat of vaporization
PLXANT 1
PLXANT‐1 Extended Antoine Equation
Extended Antoine Equation
MULDIP Liquid viscosity
KLDIP Liquid thermal
q conductivityy
SIGDIP Liquid surface tension
UFGRP UNIFAC functional group
37
Example: PLXANT
Example: PLXANT‐‐1
(Extended Antoine Equation)
Corresponding Model
38
Example: CPIGDP
Example: CPIGDP‐‐1
(Ideal Gas Heat Capacity Equation)
Corresponding Model
39
Summary
40
File
File Formats in Aspen Plus
Formats in Aspen Plus
45
Properties Analysis – Pure Component
Properties Analysis –
Properties Analysis Pure Component
Use this form To generate
Tables and plots of pure component properties as a function of temperature
Pure
and pressure
Binary Txy, Pxy, or Gibbs energy of mixing curves for a binary system
Residue Residue curve maps
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
Ternaryy
systems
This feature locates all the azeotropes that exist among a specified set of
Azeotrope
components.
Ternary diagrams in Aspen Distillation Synthesis feature: Azeotropes,
Ternary Maps Distillation boundary, Residue curves or distillation curves, Isovolatility curves,
Tie lines, Vapor curve, Boiling point
Tables and plots of properties of either multi‐phase mixtures (for example,
VLE, VLLE, LLE) resulting from flash calculations, or single‐phase mixtures
Generic
without flash calculations. Properties analysis of multi‐components (more
than three) is also included.
46
Properties Analysis – Pure Component
Properties Analysis –
Properties Analysis Pure Component
47
Available Properties
Available Properties
Property (thermodynamic) Property (transport)
Availability Free energy Thermal conductivity
Constant pressure
Constant pressure
Enthalpy Surface tension
heat capacity
Heat capacity ratio Fugacity coefficient Viscosity
Constant volume heat Fugacity coefficient
Constant volume heat Fugacity coefficient
capacity pressure correction
Free energy departure Vapor pressure
Free energy departure
Density
pressure correction
Enthalpy departure Entropy
Enthalpy departure
Volume
pressure correction
py
Enthalpy of
Sonic velocity
Sonic velocity
vaporization
Entropy departure 48
Example1: CP (Heat Capacity)
Example1: CP (Heat Capacity)
4. Specify
p y range
g of temperature
p
2. Select phase
5 S
5. Specify
if pressure
Add “N-butyl-acetate”
Data results 50
Example2: H (Enthalpy)
Example2: H (Enthalpy)
2. Select phase
5. Specify pressure
3. Select component
6 S
6. Select
l t property
t method
th d
Data results
52
Properties Analysis – Binary Components
Properties Analysis –
Properties Analysis Binary Components
Use this form To generate
Tables and plots of pure component properties as a function of temperature
Pure
and pressure
Binary Txy, Pxy, or Gibbs energy of mixing curves for a binary system
Residue Residue curve maps
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
Ternaryy
systems
This feature locates all the azeotropes that exist among a specified set of
Azeotrope
components.
Ternary diagrams in Aspen Distillation Synthesis feature: Azeotropes,
Ternary Maps Distillation boundary, Residue curves or distillation curves, Isovolatility curves,
Tie lines, Vapor curve, Boiling point
Tables and plots of properties of either multi‐phase mixtures (for example,
VLE, VLLE, LLE) resulting from flash calculations, or single‐phase mixtures
Generic
without flash calculations. Properties analysis of multi‐components (more
than three) is also included.
53
Properties Analysis – Binary Components
Properties Analysis –
Properties Analysis Binary Components
Binary Component Properties Analysis
Binary Component Properties Analysis
Use this Analysis type To generate
Temperature‐compositions diagram at
Txy
constant pressure
Pressure‐compositions diagram at
Pxy
constant temperature
Gibbs energy of mixing diagram as a
function of liquid compositions. The
A
Aspen Physical Property System uses this
Ph i l P S hi
Gibbs energy of mixing
diagram to determine whether the
binary system will form two liquid phases
at a given temperature and pressure
at a given temperature and pressure.
Example: T‐
Example: T‐XY
Example: T
2. Select phase (VLE, VLLE)
1. Select analysis
y type
yp ((Txy)
y)
Data results
Example: Generate XY plot
Example: Generate XY plot
Water-BuOH
120
110
100
T ( C)
o
90
80
70
0.0 0.2 0.4 0.6
? 0.8 1.0
Mole Fraction (Water)
Bi
Binary A l i cannott generate
Analysis t LLE data
d t below
b l azeotrope.
t
Property Analysis – Generic
Property Analysis –
Property Analysis
Use this form To generate
Tables and plots of pure component properties as a function of temperature
Pure
and pressure
Binary Txy, Pxy, or Gibbs energy of mixing curves for a binary system
Residue Residue curve maps
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
Ternaryy
systems
This feature locates all the azeotropes that exist among a specified set of
Azeotrope
components.
Ternary diagrams in Aspen Distillation Synthesis feature: Azeotropes,
Ternary Maps Distillation boundary, Residue curves or distillation curves, Isovolatility curves,
Tie lines, Vapor curve, Boiling point
Tables and plots of properties of either multi‐phase mixtures (for example,
VLE, VLLE, LLE) resulting from flash calculations, or single‐phase mixtures
Generic
without flash calculations. Properties analysis of multi‐components (more
than three) is also included.
61
Properties Analysis – Ternary
Properties Analysis –
Properties Analysis
Ternary Map
Ternary Map
6. Specify temperature
3. Select property method (if LLE is slected)
D t results
Data lt
Property Analysis – Generic
Property Analysis –
Property Analysis
Use this form To generate
Tables and plots of pure component properties as a function of temperature
Pure
and pressure
Binary Txy, Pxy, or Gibbs energy of mixing curves for a binary system
Residue Residue curve maps
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
Ternaryy
systems
This feature locates all the azeotropes that exist among a specified set of
Azeotrope
components.
Ternary diagrams in Aspen Distillation Synthesis feature: Azeotropes,
Ternary Maps Distillation boundary, Residue curves or distillation curves, Isovolatility curves,
Tie lines, Vapor curve, Boiling point
Tables and plots of properties of either multi‐phase mixtures (for example,
VLE, VLLE, LLE) resulting from flash calculations, or single‐phase mixtures
Generic
without flash calculations. Properties analysis of multi‐components (more
than three) is also included.
65
Generic analysis is used if properties analysis of mixture is performed.
When to Use Generic Analysis
When to Use Generic Analysis
Enthalpy of Mixtures ?
Water-BuOH
120
110
100
T ( C)
o
90
80
70
LLE ? ?
Specific composition
0.0 0.2 0.4 0.6 0.8 1.0 66
Mole Fraction (Water)
Property Analysis – Generic
Property Analysis –
Property Analysis
67
Add New Analysis
Add New Analysis
Select Generic
68
Specification
Specification of System
of System
4 S
4. Specify
if the
th corresponding
di composition
iti
69
Determine
Determine Adjusted Variables
Adjusted Variables
Temperature
Pressure
Vapor fraction
Mole flow
Mass flow
StdVol flow
Mole fraction
Mass fraction
StdVol fraction
Specify range of adjusted variables
70
Specify Property‐
Specify Property‐Sets for
Calculation Results
71
Add New Property‐
Add New Property‐Set (User‐
Add New Property Set (User‐Defined)
Set (User
Description
72
Add New Property‐
Add New Property‐Set (cont
Add New Property Set (cont’d)
d)
If the system requires VLLE calculation…
calculation
Select “Vapor” “1st liquid” “2nd liquid”
73
Specify Property‐
Specify Property‐Sets
Specify Property
74
Run Properties Analysis
Run Properties Analysis
75
Example1: Calculation of Enthalpy
Change for binary mixtures
Change for binary mixtures
Molar ratio of Butanol/Water=1:1 Temperature = 50 C
o
-60000 -56000
-58000
-62000
Liquid -60000
Vapor Liquid
-64000 -62000
Enthalpy (cal//mol)
Vapor
mol)
-64000
Enthalpy (cal/m
-66000
66000
-66000
-68000 -68000
-70000
-70000 -72000
E
-72000 -74000
-76000
-74000 -78000
40 50 60 70 80 90 100 0.0 0.2 0.4 0.6 0.8 1.0
o
Temperature ( C) Mole fraction of Water in BuOH and Water
76
Search Physical Properties for
Enthalpy of Mixtures (HMX)
Select HMX.
Others are optimal.
Add Property-Set
77
Calculate of Enthalpy Change As
Calculate of Enthalpy Change As
Temperature Varies
Temperature Varies
1 2
78
Read Calculation
Read Calculation Results
Read Calculation Results
Results
79
Exercise
o
Temperature = 50 C
-56000
-58000
-60000
-62000 Liquid
Vapor
Enthalpy (ccal/mol)
-64000
-66000
-68000
-70000
-72000
-74000
-76000
-78000
0.0 0.2 0.4 0.6 0.8 1.0
Mole fraction of Water in BuOH and Water
80
Example 2:
Example 2: Calculation of
Calculation of LLE
LLE
for Binary system
for Binary system
Water-BuOH
120
110
100
T ( C)
o
90
80
70
0.0 0.2 0.4 0.6 0.8 1.0
Mole Fraction (Water)
81
Add
Add New Property
Add New Property‐
New Property‐Set (cont
Set (cont’d)
d)
Select Vapor-liquid-liquid
4
Calculation Results
Calculation Results
Water-BuOH
120
110
100
T ( C)
o
90
80
70
0.0 0.2 0.4 0.6 0.8 1.0
Mole Fraction (Water)
Property Analysis
Property Analysis –
Property Analysis – Conceptual
Conceptual Design
(Optional)
Design
Use this form To generate
Tables and plots of pure component properties as a function of temperature
Pure
and pressure
Binary Txy Pxy or Gibbs energy of mixing curves for a binary system
Txy, Pxy, or Gibbs energy of mixing curves for a binary system
Residue Residue curve maps
Ternary maps showing phase envelope, tie lines, and azeotropes
y p gp p , , p of ternary y
Ternary
systems
This feature locates all the azeotropes that exist among a specified set of
Azeotrope
p
components.
Ternary diagrams in Aspen Distillation Synthesis feature: Azeotropes,
Ternary Maps Distillation boundary, Residue curves or distillation curves, Isovolatility curves,
Tie lines Vapor curve Boiling point
Tie lines, Vapor curve, Boiling point
Tables and plots of properties of either multi‐phase mixtures (for example,
VLE, VLLE, LLE) resulting from flash calculations, or single‐phase mixtures
Generic
without flash calculations Properties analysis of multi‐components (more
without flash calculations. Properties analysis of multi‐components (more
than three) is also included.
85
Conceptual Design
Conceptual Design
Conceptual Design
Conceptual Design
• Conceptual design enables the user to:
1. Locate all the azeotropes (homogeneous and
heterogeneous) present in any multicomponent mixture
2. Automatically compute distillation boundaries and
residue curve maps for ternary mixtures
id f t i t
3. Compute multiple liquid phase envelopes (liquid‐liquid
and vapor liquid liquid) for ternary mixtures
and vapor‐liquid‐liquid) for ternary mixtures
4. Determine the feasibility of splits for distillation columns
Azeotrope Analysis
Azeotrope Analysis
Azeotrope Analysis
Azeotrope Analysis
Close analysis input dialog box (pure or binary analysis)
Azeotrope Analysis Report
Azeotrope Analysis Report
Ternary Maps
Ternary Maps
Ternary Maps
Ternary Maps
3 Select property method
3.
1. Select three components 4. Select phase (VLE, LLE)
1 2 3 4
Mole Flow kmol/hr
WATER 10 0 ? ?
BUOH 0 9 ? ?
BUAC 0 6 ? ?
Total Flow kmol/hr 10 15 ? ?
Temperature C 500 80 ? ?
Pressure bar 1 1 1 10
Enthalpy kcal/mol ? ? ? ?
E t
Entropy cal/mol-K
l/ l K ? ? ? ?
Density kmol/cum ? ? ? ?
96
Example 2: Flash Separation
Example 2: Flash Separation
120
T-x
T
T-y
115
T=105 C
T ( C)
110
o
Saturated Feed P=1atm
105
P=1atm
F=100 kmol/hr 100
zwater=0.5 0.0 0.2 0.4 0.6 0.8 1.0
zHAc=0.5 xWater and yWater
10
1.0
0.8
Reflux
ratio ? 0.6
yWater
0.4
0.2
Duty ?
0.0
0 0
0.0 0.2 0.4 0.6 0.8 1.0
xWater
Setup – Specification
Setup –
Setup
Select Flowsheet
99
Reveal Model Library
Reveal Model Library
100
Model Library: Mixer/Splitter
Model Library: Mixer/Splitter
102
Model Description Purpose Use for
Pump P
Pump or hydraulic
h d li Changes stream pressure when the
Ch t h th Pumps and hydraulic
P d h d li
turbine power requirement is needed or turbines
known
Compr C
Compressor or Ch
Changes stream pressure when
t h P l t i compressors,
Polytropic
turbine power requirement is needed or polytropic positive
known displacement compressors,
isentropic compressors
isentropic compressors,
isentropic turbines
Mcompr Multistage Changes stream pressure across Multistage polytropic
compressor or
compressor or multiple stages with intercoolers compressors, polytropic
multiple stages with intercoolers. compressors polytropic
turbine Allows for liquid knockout streams positive displacement
from intercoolers compressors, isentropic
compressors isentropic
compressors, isentropic
turbines
Valve Valve pressure Models pressure drop through a Control valves and pressure
drop valve changers
Pipe Single segment Models pressure drop through a Pipe with constant diameter
pipe single segment of pipe (may include fittings)
Pipeline Multiple segment
Multiple segment Models pressure drop through a
Models pressure drop through a Pipeline with multiple
Pipeline with multiple
pipeline pipe or annular space lengths of different
diameter or elevation103
Adding a Mixer
Adding a Mixer
104
Adding Material Streams
Adding Material Streams
105
Adding Material Streams (cont’d)
Adding Material Streams (cont d)
106
Adding Material Streams (cont’d)
Adding Material Streams (cont d)
When moving the mouse on the arrows, some description appears.
107
Adding Material Streams (cont’d)
Adding Material Streams (cont d)
108
Reconnecting Material Streams
(Feed Stream)
109
Reconnecting Material Streams
(Product Stream)
B1
110
Specifying Feed Condition
Specifying Feed Condition
111
Specifying Feed Condition
Specifying Feed Condition
113
Specifying Input of Mixer
Specifying Input of Mixer
114
Specifying Input of Mixer (cont
Specifying Input of Mixer (cont’d)
d)
Run Start or continue calculations
Step Step through the flowsheet one block at a time
Stop Pause simulation calculations
Reinitialize Purge simulation results
116
Status
Status of Simulation Results
of Simulation Results
Message Means
The run has completed normally, and results are
Results available
present.
present
Results for the run are present. Warning
messages were generated during the
esu ts t a gs
Results with warnings
calculations. View the Control Panel or History
l l i Vi h C l P l Hi
for messages.
Results for the run are present. Error messages
Results with errors were generated during the calculations. View the
Control Panel or History for messages.
Results for the run are present, but you have
p , y
changed the input since the results were
Input Changed
generated. The results may be inconsistent with
the current input.
117
Control Pannel
Control Pannel
Click here
119
1 2 3
Substream: MIXED
Mole Flow kmol/hr
WATER 10 0 10
BUOH 0 9 9
BUAC 0 6 6
Total Flow kmol/hr 10 15 25
Total Flow kg/hr 180.1528 1364.066 1544.218
Total Flow cum/hr 0.18582 1.74021 1.870509
Temperature C 50 80 70.08758
Pressure bar 2 1 1
V
Vapor Frac
F 0 0 0
Liquid Frac 1 1 1
Solid Frac 0 0 0
Pull down the list and select Enthalpy kcal/mol
Enthalpy kcal/mol ‐67.81
67.81 ‐94.3726
94.3726 ‐83.7476
83.7476
“Full” to show more properties Enthalpy kcal/kg ‐3764.03 ‐1037.77 ‐1355.82
Enthalpy Gcal/hr ‐0.6781 ‐1.41559 ‐2.09369
results.
Entropy cal/mol‐K ‐37.5007 ‐134.947 ‐95.6176
Entropy cal/gm‐K ‐2.0816 ‐1.48395 ‐1.54799
Density kmol/cum 53.81564 8.619647 13.36534
Density kg/cum 969.5038 783.851 825.5604
Average MW
Average MW 18 01528
18.01528 90 93771
90.93771 61 76874
61.76874
Enthalpy and Entropy Liq Vol 60F cum/hr 0.1805 1.617386 1.797886
120
Change
Change Units of Calculation Results
Units of Calculation Results
121
Setup – Defining
Setup –
Setup Defining Your Own Units Set
Your Own Units Set
122
Setup – Report Options
Setup –
Setup Report Options
123
Stream Results with Format of
Mole Fraction
124
Add Pump Block
Add Pump Block
125
Add A Material Stream
Add A Material Stream
126
Connect Streams
Connect Streams
127
Pump – Specification
Pump –
Pump Specification
3. Efficiencies (Default: 1)
128
Run Simulation
Run Simulation
129
Block Results (Pump)
Block Results (Pump)
130
131
Streams Results
Streams Results
132
Calculation Results
(Mass and Energy Balances)
1 2 3 4
Mole Flow kmol/hr
WATER 10 0 10 10
BUOH 0 9 9 9
BUAC 0 6 6 6
Total Flow kmol/hr 10 15 25 25
Temperature C 500 80 70.09
0 09 71.20
1 20
Pressure bar 1 1 1 10
Enthalpy kcal/mol -67.81 -94.37 -83.75 -83.69
E t
Entropy cal/mol-K
l/ l K -37.50
37 50 -134.95
134 95 -95.62
95 62 -95.46
95 46
Density kmol/cum 969.50 783.85 825.56 824.29
133
Exercise
1 2 3 4 5 6
Mole Flow kmol/hr
Water 10 0 0 ? ? ?
Ethanol 0 5 0 ? ? ?
Methanol 0 0 15 ? ? ?
Total Flow kmol/hr 10 15 15 ? ? ?
Temperature C 50 70 40 ? ? ?
Pressure
essu e ba
bar 1 1 1 1 4 2
Enthalpy kcal/mol ? ? ? ? ? ?
Entropy cal/mol-K ? ? ? ? ? ?
Densityy kmol/cum ? ? ? ? ? ?
120
T-x
T
T-y
115
T=105 C
T ( C)
110
o
Saturated Feed P=1atm
105
P=1atm
F=100 kmol/hr 100
zwater=0.5 0.0 0.2 0.4 0.6 0.8 1.0
zHAc=0.5 xWater and yWater
Vapor ESHOC
Liquid gamma
q g
Liquid enthalpy
Liquid volume
Check Binary Parameters
Check Binary Parameters
Association parameters of HOC
Association parameters of HOC
Binary Parameters of NRTL
Binary Parameters of NRTL
Binary Analysis
Binary Analysis
T‐xy plot
Data results
Generate xy plot
Generate xy
Generate
Generate xy plot (cont
Generate xy
Generate plot (cont’d)
d)
Flash Separation
Flash Separation
120
T-x
T
T-y
115
T=105 C
T ( C)
110
o
Saturated Feed P=1atm
105
P=1atm
F=100 kmol/hr 100
zwater=0.5 0.0 0.2 0.4 0.6 0.8 1.0
zHAc=0.5 xWater and yWater
Saturated Feed
(Vapor fraction=0)
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Block Input: Flash2
Block Input: Flash2
Flash2: Specification
Flash2: Specification
T=105 C
P 1 t
P=1atm
Required Input Incomplete
Required Input Incomplete
42.658 kmol/hr
zwater=0.501
zHAc=0.409
T=105 C
Saturated Feed P=1atm
P=1atm
F=100 kmol/hr
zwater=0.5 57.342 kmol/hr
zHAc=0.5 zwater=0.432
zHAc=0.568
Review Distillation Separation
Review Distillation Separation
McCabe- Thiele Graphical Method
1
y
Stripping
pp g section:
LS B 0.4
yn xn 1 xB
VS VS
02
0.2
0
0 02
0.2 04
0.4 06
0.6 08
0.8 1
x
Trade‐off Between
Trade‐
Capital Cost and Operating Cost
Shortcut Design:
RR≈1.2×RRmin
NT ≈ 2×NTmin
Distillation Separation
Distillation Separation
• There are two degrees of
freedom to manipulate
d ll
distillate composition and
d
bottoms composition to
RR ? manipulate the distillate and
manipulate the distillate and
bottoms compositions.
• If the feed condition and the
If the feed condition and the
number of stages are given,
QR ? how much of RR and QR are
required to achieve the
specification.
Add Block: Radfrac
Add Block: Radfrac
Add Block:
Add Material Stream
Add Material Stream
Flowsheet Connectivity for
Connectivity for RadFrac
Connectivity for RadFrac
RadFrac numbers stages from the top down, starting with the condenser
(or starting with the top stage if there is no condenser).
Connect Material Stream
Connect Material Stream
Specify Feed Condition
Specify Feed Condition
Saturated Feed
(Vapor fraction=0)
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Block Input: Radfrac
Block Input: Radfrac
Block Input:
Radfrac:: Configuration
Radfrac: Configuration
Radfrac : Configuration
Radfrac::: Streams (Feed Location)
Radfrac: Streams (Feed Location)
Radfrac Streams (Feed Location)
Types of Feed Stage
Types of Feed Stage
Use this convention To introduce a feed
Above‐stageg Between stages, above the designated stage
g , g g
On‐stage On the designated stage
On the designated stage, all‐liquid feed
On‐stage‐liquid
On stage liquid
which is never flashed
On the designated stage, all‐vapor feed
On‐stage‐vapor
g p
which is never flashed
which is never flashed
To the decanter attached to the designated
Decanter
stage
Radfrac:: Column Pressure
Radfrac: Column Pressure
Radfrac : Column Pressure
Run Simulation
Run Simulation
I l d condenser
Include d duty,
d t distillate
di till t rate,
t reflux
fl rate,
t reflux
fl ratio
ti
Summary of Reboiler
Summary of Reboiler
Summary of
I l d reboiler
Include b il duty,
d t bottoms
b tt rate,
t boilup
b il rate,
t boilup
b il ratio
ti
Column Profile: TPFQ
Column Profile: TPFQ
Column Profile: Vapor Composition
Column Profile: Vapor Composition
Column Profile: Liquid Composition
Column Profile: Liquid Composition
Plot Wizard for Column Profile
Plot Wizard for Column Profile
Plot Wizard for Column Profile (cont’d)
Plot Wizard for Column Profile (cont d)
After entering
g the block,, “Plot” appears.
pp
Plot Wizard
Plot Wizard
Plot Types
Plot Types
Steps
Steps for Composition Plot
for Composition Plot
Composition Profiles
Composition Profiles
Temperature Profiles
Temperature Profiles
INTRODUCTION TO ASPEN PLUS
INTRODUCTION TO ASPEN PLUS
Some Tips and Others
202
Tips: Next
Tips: Next
Invokes the Aspen Plus expert system. Guides you through the
p required
steps q to complete
p your
y simulation.
Status message Meaning
Flowsheet Not Flowsheet connectivity is incomplete. To find out why, click
Complete the Next button in the toolbar.
Required Input Not Input specifications for the run are incomplete. Click Next
C
Complete
l on the toolbar to find out how to complete the input
h lb fi d h l h i
specifications, and to go to sheets that are incomplete.
203
Example:
Example: “NEXT”
NEXT
204
Tips: “What’s
Tips: What s this
this”
205
Tips: “What’s
Tips: What s this
this”
206
Tips: Window
Tips: Window
If you are using You should
Workbook mode Click the Process Flowsheet tab
Flowsheet as Wallpaper
p p Click the flowsheet in the background
g
Normal View Select the Process Flowsheet window
207
Help Topics
Help Topics
Go to “Help”
p
Select “Help Topics”
208
Help Topics
Help Topics
Unit
U it O
Operation
ti M Model
d l Reference
R f Manual
M l
Physical Property Methods and Models
Physical Property Data Reference Manual
209
Help Topics
Help Topics
Calculation of Properties Using an Equation-of-State Property Method
210
File
File Formats in Aspen Plus
Formats in Aspen Plus
213
如何進入講義下載及填寫問卷