Instructions

Tab = PT flash
1. VF values at low temperature are correct and given by file "PT flash from PR EoS – final".
2. VF values at high temperature are more accurate than previous file. For this results file used is "PT flash from PR EoS – fin
3. "PT flash from PR EoS – final2 (Updated by Prasad Sir)", this file gives more accurate Dew Temperature.

Tab = Density
1. Rho_U & Rho_S are density from Unisim and density from Scilab.
2. Rho is in Kg / m3.

Page 1
 Instructions

e used is "PT flash from PR EoS – final2 (Updated by Prasad Sir)".

e Dew Temperature.

Page 2
 BUBL T

File name = Bubble Point Temperature – final

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.01 0.49 0.2 0.15 0.15
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 11 50.13 50.05 0.08
0.005 11 60.17 60.15 0.02
0.05 13 84.86 90.05 5.19
1 14 144.63 144.65 0.02
2 17 164.53 164.55 0.02
4 24 188.28 188.38 0.1
6 36 204.89 205.08 0.19
8 82 219.73 220.02 0.29
10 52 NA 235.56 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 20 34.47 34.55 0.08
0.005 18 39.33 39.45 0.12
0.05 16 49.4 73.65 24.25
1 25 NA 67.25 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.2 0.6 0.2
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 15 211.31 212.1 0.79
0.005 7 238.91 239.68 0.77
0.05 6 296.2 296.74 0.54
1 8 433.05 432.95 0.1
2 11 483.06 482.75 0.31
3 2 522.91 517.95 4.96
4 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.1 0.4 0.3 0.1 0.1
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 16 43.36 43.25 0.11
0.005 13 49.89 49.75 0.14
0.05 12 64.05 63.95 0.1
1 19 102.6 114.05 11.45
2 24 118 124.25 6.25

Page 3
 BUBL T

4 53 NA 146.05 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.8 0.1 0.1
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 25 193.03 193.84 0.81
0.005 12 215.29 216.07 0.78
0.05 8 259.84 260.55 0.71
1 9 364.08 364.38 0.3
2 11 403.08 403.15 0.07
3 15 430.86 430.65 0.21
4 11 455.6 454.75 0.85
6 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.05 0.25 0.3 0.2 0.2
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 17 40.75 40.75 0
0.005 14 47.28 47.25 0.03
0.05 14 61.9 61.85 0.05
1 23 106.09 110.15 4.06
2 28 127.31 127.25 0.06
4 39 158.92 158.85 0.07
6 52 187.18 187.22 0.04
10 100 257.81 257.02 0.79
20 53 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.7 0.2 0.1
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 19 194.61 195.45 0.84
0.005 14 217.35 218.13 0.78
0.05 7 263.05 263.74 0.69
1 7 371.33 371.55 0.22
2 10 412.37 412.55 0.18
4 34 468.18 468.75 0.57
6 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.9 0.05 0.05
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T

Page 4
 BUBL T

0.001 12 191.64 192.45 0.81

0.005 14 213.51 214.3 0.79
0.05 6 257.13 257.84 0.71
1 8 357.91 358.21 0.3
2 11 394.8 394.85 0.05
4 52 NA 442.55 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.4 0.3 0.2 0.1
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 16 76 76.05 0.05
0.005 12 86.26 86.35 0.09
0.05 9 107.6 107.65 0.05
1 13 161.28 161.35 0.07
2 16 182.88 182.88 0
4 25 212.58 212.57 0.01
6 39 237.93 237.89 0.04
10 52 NA 196.16 #VALUE!

Page 5
 BUBL T

File name = Bubble Point Temperature (Transdecalin) – rev1

N2 CH4 N-C4H10 N-C7H16 Transdecalin

Comp =
0 0 0 0.2 0.8
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0 11 288.16 289.15 0.99
0.01 8 322.02 322.88 0.86
0.05 5 390.13 390.55 0.42
1 12 549.36 548.05 1.31
2 20 608.37 606.05 2.32
4 100 24.71 N/A #VALUE!

N2 CH4 N-C4H10 N-C7H16 Transdecalin

Comp =
0 0 0.2 0.3 0.5
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0 12 211.5 211.24 0.26
0.01 8 239.17 238.76 0.41
0.05 8 297.26 296.51 0.75
1 16 447.5 446.05 1.45
2 23 509.2 507.45 1.75
4 - N/A 598.65 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Transdecalin

Comp =
0 0 0.3 0.1 0.6
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 14 205.47 205.29 0.18
0.005 11 231.29 230.96 0.33
0.05 9 284.88 284.2 0.68
1 17 425.22 423.25 1.97
2 25 486.69 484.05 2.64
4 54 580.55 576.45 4.1

Page 6
 BUBL T

File name = Bubble Point Temperature (n-Eicosane) – rev1

N2 CH4 N-C4H10 N-C7H16 N-Eicosane

Comp =
0 0 0 0.2 0.8
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 17 290.24 288.49 1.75
0.005 9 326.93 324.88 2.05
0.05 6 406.1 403.15 2.95
1 14 657.49 651.85 5.64
2 31 N/A N/A #VALUE!
4 21 N/A N/A #VALUE!

N2 CH4 N-C4H10 N-C7H16 N-Eicosane

Comp =
0 0 0 0.4 0.6
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 25 277.87 276.64 1.23
0.005 11 310.45 309 1.45
0.05 6 377.74 375.15 2.59
1 12 564 559.05 4.95
2 35 671.44 662.45 8.99
4 30 N/A N/A #VALUE!

N2 CH4 N-C4H10 N-C7H16 N-Eicosane

Comp =
0 0 0.6 0.3 0.1
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 23 196.16 195.74 0.42
0.005 10 219.48 218.93 0.55
0.05 7 266.79 265.9 0.89
1 9 381.19 379.25 1.94
2 14 425.99 423.45 2.54
4 37 488.61 484.35 4.26

N2 CH4 N-C4H10 N-C7H16 N-Eicosen

Comp =
0 0.01 0.49 0.25 0.25
1.00
P (Mpa) Iter T_b (K) Scilab T_b (K) Unisim Delta T
0.001 0
0.005 0
0.05 0
1 0
2 0
4 0
6 0.000

Page 7
 BUBL T

10 0.000
15 0.000

Page 8
 DEW T

File name = Dew Point Temperature – final

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.01 0.49 0.2 0.15 0.15
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 256.11 250.08 6.03
0.005 37 274.67 274.36 0.31
0.05 10 320.83 320.56 0.27
1 5 414.95 414.75 0.2
2 6 443.21 443.15 0.06
4 11 471.06 471.05 0.01
6 19 483.73 483.75 0.02
8 31 487.94 488.25 0.31
10 47 485.37 486.35 0.98
20 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 258.24 259.08 0.84
0.005 13 285.71 285.32 0.39
0.05 5 336.24 335.87 0.37
1 5 442.57 442.35 0.22
2 8 476.08 475.85 0.23
4 22 509.87 509.85 0.02
6 23 525.83 525.55 0.28
8 53 NA 529.75 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.2 0.6 0.2
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 262.74 262.6 0.14
0.005 17 290.25 290.12 0.13
0.05 4 344.13 344.05 0.08
1 7 463.32 463.15 0.17
2 11 503.67 503.45 0.22
3 4 528.8 528.45 0.35
4 51 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.1 0.4 0.3 0.1 0.1
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T

Page 9
 DEW T

0.001 100 240.65 244.77 4.12

0.005 55 268.15 267.88 0.27
0.05 10 311.8 311.53 0.27
1 5 399.63 399.45 0.18
2 5 425.75 425.65 0.1
4 7 451.29 451.25 0.04
6 14 463.21 462.95 0.26
8 22 467.22 467.15 0.07
10 29 466.68 465.85 0.83
20 51 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.8 0.1 0.1
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 240.98 244.97 3.99
0.005 35 268.57 268.31 0.26
0.05 10 313.17 312.99 0.18
1 8 407.57 407.45 0.12
2 12 438 437.85 0.15
3 11 456.65 456.35 0.3
4 51 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.05 0.25 0.3 0.2 0.2
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 258.46 254.07 4.39
0.005 27 279.63 279.33 0.31
0.05 10 328.05 327.82 0.23
1 4 429.13 429.05 0.08
2 6 460.42 460.35 0.07
4 13 491.33 491.05 0.28
6 30 503.87 503.35 0.52
10 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.7 0.2 0.1
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 245.62 249.15 3.53
0.005 31 273.64 273.49 0.15
0.05 8 320.45 320.35 0.1
1 8 420.09 419.95 0.14
2 11 452.16 451.95 0.21
4 21 483.27 482.25 1.02

Page 10
 DEW T

6 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.9 0.05 0.05
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 245.45 236.57 8.88
0.005 100 258.51 258.23 0.28
0.05 11 299.77 299.59 0.18
1 9 388.01 387.95 0.06
2 11 417.46 417.35 0.11
4 24 448.82 447.95 0.87
6 52 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.4 0.3 0.2 0.1
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 254.87 249.01 5.86
0.005 36 273.34 273.11 0.23
0.05 9 319.46 319.3 0.16
1 6 414.07 413.95 0.12
2 5 442.7 442.55 0.15
4 12 470.08 470.15 0.07
6 1 474.09 481.25 7.16
10 53 NA 469.95 #VALUE!

Page 11
 DEW T

File name = Dew Point Temperature (Transdecalin) – rev1

N2 CH4 N-C4H10 N-C7H16 Transdecalin

Comp =
0 0 0 0.2 0.8
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 52 320.7 318.97 1.73
0.005 15 355.28 353.35 1.93
0.05 6 423.52 421.05 2.47
1 5 575.53 572.15 3.38
2 7 627.38 623.75 3.63
4 51 NA NA #VALUE!

N2 CH4 N-C4H10 N-C7H16 Transdecalin

Comp =
0 0 0.2 0.3 0.5
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 312.12 310.56 1.56
0.005 19 344.67 342.87 1.8
0.05 7 407.96 405.75 2.21
1 3 543.99 541.15 2.84
2 8 587.35 584.25 3.1
4 53 NA 619.85 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Transdecalin

Comp =
0 0 0.3 0.1 0.6
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 83 315.23 313.55 1.68
0.005 15 348.38 346.49 1.89
0.05 5 413.04 410.75 2.29
1 5 552.51 549.05 3.46
2 9 596.96 593.25 3.71
4 34 637.55 633.45 4.1
6 52 NA NA #VALUE!

Page 12
 DEW T

File name = Dew Point Temperature (n-Eicosane) – rev1

N2 CH4 N-C4H10 N-C7H16 N-Eicosen

Comp =
0 0 0 0.2 0.8
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 100 474.32 458.75 15.57
0.005 100 496.54 498.55 2.01
0.05 11 573.06 575.05 1.99
1 7 NA 731.75 #VALUE!
2 0
4 0

N2 CH4 N-C4H10 N-C7H16 N-Eicosen

Comp =
0 0 0 0.4 0.6
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 0
0.005 0
0.05 0
1 0
2 0
4 0

N2 CH4 N-C4H10 N-C7H16 N-Eicosen

Comp =
0 0 0.6 0.3 0.1
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 0
0.005 0
0.05 0
1 0
2 0
4 0

N2 CH4 N-C4H10 N-C7H16 N-Eicosen

Comp =
0 0 0.6 0.3 0.1
1.00
P (Mpa) Iter T_d (K) Scilab T_d (K) Unisim Delta T
0.001 0
0.005 0
0.05 0
1 0
2 0
4 0
6 0

Page 13
 DEW T

10 0
15 0

Page 14
 Enthalpy

File name = Mixture Enthalpy using Prmix – rev2

N2 CH4 N-C4H10 N-C7H16 Toluene Comp Sum

Comp =
0 0 0 0.5 0.5 1.00

H Scilab (J/mol) H Unisim (J/mol)

P (Mpa) T (K) dH (Scilab)
Vap Liq Vap Liq
200 -48374.77 -1.20E+05
250 -40975.72 -1.13E+05 7399.05
300 -32493.35 -1.05E+05 15881.42
0.22 350 -22901.64 -9.52E+04 25473.13
400 -12142.22 -8.44E+04 36232.55
405 19362.16 31504.38 -5.29E+04 31529 67736.93
410 20267.72 -5.20E+04 68642.49
450 27818.78 -4.45E+04 76193.55
500 37999.79 -3.43E+04 86374.56

N2 CH4 N-C4H10 N-C7H16 Toluene Comp Sum

Comp =
0 0 0 0.5 0.5 1.00

H Scilab (J/mol) H Unisim (J/mol)

P (Mpa) T (K) dH (Scilab)
Vap Liq Vap Liq
200 -48187.5 -1.20E+05
250 -40796.82 -1.13E+05 7390.68
300 -32329.27 -1.05E+05 15858.23
2 350 -22765 -9.50E+04 25422.5
400 -12061.46 -8.44E+04 36126.04
405 -10925 -8.32E+04 37262.5
410 -9775.91 -8.21E+04 31020.91
450 -95.78 -7.24E+04 32233.49
500 13570.75 -5.87E+04 36335.76
523 20982.19 -5.13E+04 33043.64
524 38093.6 17111.41 -3.42E+04 17130 86281.1

N2 CH4 N-C4H10 N-C7H16 Toluene Comp Sum

Comp =
0 0 0 0.5 0.5 1.00

H Scilab (J/mol) H Unisim (J/mol)

P (Mpa) T (K) dH (Scilab)
Vap Liq Vap Liq
200 -47660.2 -1.20E+05

7
400 -11785.66 -8.41E+04 35874.54

Page 15
 Enthalpy

602 44415.61 -2.79E+04 92075.81

603 44768 352.39 -2.75E+04 360 92428.2

Page 16
 Enthalpy

v2

1.6
1.4
dH (Unisim) % Diff 1.2
1
0.8

% Diff
7300 1.36
15700 1.16 0.6
25230 0.96 0.4
35971 0.73 0.2
67500 0.35
0
68410 0.34
200 250 300 350 400 450 500 550
75950 0.32
86130 0.28 T (K)

dH (Unisim) % Diff

7300 1.24
15600 1.66
25170 1
35850 0.77
36990 0.74
30830 0.62
32210 0.07
36300 0.1
33030 0.04
86010 0.32

dH (Unisim) % Diff

35630 0.69

Page 17
 Enthalpy

91820 0.28
92180 0.27

Page 18
 Enthalpy

500 550

Page 19
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.01 0.3 0.19 0.25 0.25
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.0 0.000000 100.0 0.000000 0.00%
143.0 0.000000 143.0 0.000000 0.00%
144.0 0.000000 144.0 0.000000 0.00%
146.0 0.000000 146.0 0.000000 0.00%
150.0 0.005803 150.0 0.005400 0.04%
200.0 0.220149 200.0 0.219500 0.06%
210.0 0.236105 210.0 0.235600 0.05%
1 250.0 0.276879 250.0 0.271100 0.58%
300.0 0.310639 300.0 0.307800 0.28%
400.0 0.557634 400.0 0.558300 0.07%
430.0 0.835505 430.0 0.838000 0.25%
435.0 0.919262 435.0 0.922000 0.27%
438.8 1.000000 438.8 1.000000 0.00%
500.0 1.000000 500.0 1.000000 0.00%
600.0 NA 600.0 1.000000 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.01 0.3 0.19 0.25 0.25
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.0 0.000000 100.0 0.000000 0.00%
177.8 0.000000 177.8 0.000000 0.00%
180.0 0.004432 180.0 0.000000 0.44%
190.5 0.000904 190.5 0.000000 0.09%
200.0 0.033105 200.0 0.031800 0.13%
300.0 0.239535 300.0 0.230200 0.93%
3 400.0 0.356121 400.0 0.353600 0.25%
450.0 0.535755 450.0 0.535800 0.00%
480.0 0.806496 480.0 0.808400 0.19%
485.0 0.880839 485.0 0.883100 0.23%
486.0 0.897600 486.0 0.899600 0.20%
491.4 1.000000 491.4 1.000000 0.00%
500.0 1.000000 500.0 1.000000 0.00%
600.0 1.000000 600.0 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.01 0.3 0.19 0.25 0.25
1.00
Scilab Unisim
P (Mpa) VF % Diff

Page 20
 PT Flash
P (Mpa) VF % Diff
T (K) VF T (K) VF
150.0 0.000000 150.0 0.000000 0.00%
200.0 0.000000 200.0 0.000000 0.00%
212.0 0.000000 212.0 0.000000 0.00%
220.0 0.000000 220.0 0.000000 0.00%
225.0 0.033202 225.0 0.000000 3.32%
5.5 228.7 0.000000 228.7 0.000000 0.00%
300.0 0.143838 300.0 0.143000 0.08%
450.0 0.353717 450.0 0.349700 0.40%
505.0 0.761134 505.0 0.763900 0.28%
515.3 0.991149 515.3 1.000000 0.89%
515.5 1.000000 516.0 1.000000 0.00%
550.0 1.000000 550.0 1.000000 0.00%
600.0 1.000000 600.0 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.01 0.3 0.19 0.25 0.25
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
150.0 0.000000 150.0 0.000000 0.00%
200.0 0.000000 200.0 0.000000 0.00%
220.0 0.000000 220.0 0.000000 0.00%
250.0 0.000000 250.0 0.000000 0.00%
268.5 0.000000 268.5 0.000000 0.00%
8 269.2 0.001327 269.2 0.000000 0.13%
300.0 0.054149 300.0 0.053100 0.10%
450.0 0.210912 450.0 0.210700 0.02%
505.0 0.450179 505.0 0.451200 0.10%
514.5 0.977164 514.5 1.000000 2.28%
514.9 1.000000 514.9 1.000000 0.00%
550.0 1.000000 550.0 1.000000 0.00%
600.0 1.000000 600.0 1.000000 0.00%

Page 21
PT Flash

Page 22
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.3 0.4 0.3
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.0 0.000000 100.0 0.000000 0.00%
150.0 0.000000 150.0 0.000000 0.00%
200.0 0.000000 200.0 0.000000 0.00%
300.0 0.000000 300.0 0.000000 0.00%
337.0 0.000000 337.0 0.000000 0.00%
337.1 0.000041 337.1 0.000000 0.00%
0.22 338.0 0.017392 338.0 0.012200 0.52%
340.0 0.042763 340.0 0.038200 0.46%
380.0 0.562590 380.0 0.565400 0.28%
390.1 0.975809 390.1 0.986700 1.09%
390.3 0.989165 390.3 1.000000 1.08%
390.5 1.000000 390.5 1.000000 0.00%
400.0 1.000000 400.0 1.000000 0.00%
500.0 1.0000 500.0 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.3 0.4 0.3
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
400.0 0.000000 400.0 0.000000 0.00%
483.6 0.000000 483.6 0.000000 0.00%
483.8 0.000000 483.8 0.004000 0.40%
485.0 0.027543 485.0 0.032700 0.52%
490.0 0.154683 490.0 0.160200 0.55%
2.5 500.0 0.473351 500.0 0.480000 0.66%
507.0 0.793057 507.0 0.801100 0.80%
507.2 0.804050 507.2 0.812100 0.81%
510.3 1.000000 510.3 1.000000 0.00%
550.0 1.000000 550.0 1.000000 0.00%
600.0 1.000000 600.0 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.3 0.4 0.3
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
470.0 0.000000 470.0 0.000000 0.00%
490.7 0.000000 490.5 0.000000 0.00%
491.5 0.020086 491.5 0.026105 0.60%

Page 23
 PT Flash

495.0 0.116955 495.0 0.123280 0.63%

500.0 0.273537 500.0 0.279833 0.63%
2.7 505.0 0.459782 505.0 0.467285 0.75%
510.0 0.695184 510.0 0.701920 0.67%
515.0 0.999633 514.9 1.000000 0.04%
515.1 1.000000 515.1 1.000000 0.00%
530.0 1.000000 530.0 1.000000 0.00%
550.0 1.000000 550.0 1.000000 0.00%
600.0 1.000000 600.0 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.3 0.4 0.3
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
490.0 0.000000 490.0 0.000000 0.00%
492.0 0.000000 492.0 0.000000 0.00%
500.4 1.000000 500.4 0.000000 100.00%
505.0 1.000000 505.0 0.154300 84.57%
508.0 0.259895 508.0 0.268400 0.85%
3 510.0 0.343800 510.0 0.352300 0.85%
515.0 0.588924 515.0 0.598700 0.98%
517.0 0.705884 517.0 0.716200 1.03%
519.0 0.836865 519.0 0.847800 1.09%
520.0 0.908458 520.0 0.919700 1.12%
521.0 0.984598 521.0 1.000000 1.54%
521.2 1.000000 521.2 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0.3 0.4 0.3
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
400.0 0.000000 400.0 0.000000 0.00%
480.0 0.000000 480.0 0.000000 0.00%
487.0 0.000000 487.0 0.000000 0.00%
487.5 0.966881 487.5 0.000000 96.69%
488.0 1.000000 488.0 0.000000 100.00%
3.8 490.0 0.919989 490.0 0.000000 92.00%
491.0 1.000000 491.0 0.000000 100.00%
500.0 1.000000 500.0 0.000000 100.00%
520.0 1.000000 520.0 0.000000 100.00%
526.0 1.000000 526.0 0.000000 100.00%
527.1 1.000000 527.1 0.000000 100.00%
532.0 1.000000 532.0 1.000000 0.00%

Page 24
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
40.00 0.000000 40.00 0.000000 0.00%
50.00 0.000000 50.00 0.000000 0.00%
58.60 0.000000 58.60 0.000000 0.00%
58.94 0.006062 58.94 0.000000 0.61%
0.22 100.00 0.157806 100.00 0.157400 0.04%
250.00 0.312792 250.00 0.312100 0.07%
375.00 0.854952 375.00 0.860000 0.50%
379.00 0.940343 379.00 0.947100 0.68%
381.00 0.991519 381.00 1.000000 0.85%
381.40 1.000000 381.40 1.000000 0.00%
400.00 1.000000 400.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
70.00 0.000000 70.00 0.000000 0.00%
79.00 0.000000 79.00 0.000000 0.00%
80.00 0.000000 80.00 0.000000 0.00%
83.00 0.000000 83.00 0.000000 0.00%
2.5 100.00 0.182023 100.00 0.000000 18.20%
120.50 0.160034 120.50 0.000000 16.00%
200.00 0.219771 200.00 0.219200 0.06%
480.00 0.876985 480.00 0.879200 0.22%
487.10 0.997711 487.10 1.000000 0.23%
487.30 1.000000 487.30 1.000000 0.00%
500.00 1.000000 500.00 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.00 0.152264 100.00 0.000000 15.23%
120.00 0.148445 120.00 0.000000 14.84%
137.50 0.143422 137.50 0.000000 14.34%
140.00 0.143617 140.00 0.139500 0.41%
5.00 200.00 0.176528 200.00 0.175800 0.07%

Page 25
 PT Flash

300.00 0.230702 300.00 0.230200 0.05%

400.00 0.298490 400.00 0.298100 0.04%
500.00 0.692385 500.00 0.693800 0.14%
519.30 0.995879 519.30 1.000000 0.41%
519.50 1.000000 519.50 1.000000 0.00%
550.00 1.000000 550.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.00 0.000000 100.00 0.000000 0.00%
108.00 0.000000 108.00 0.000000 0.00%
130.00 0.143796 130.00 0.000000 14.38%
136.00 0.142112 136.00 0.000000 14.21%
8.00 138.50 0.141504 138.50 0.000000 14.15%
150.00 0.139876 150.00 0.132500 0.74%
250.00 0.170859 250.00 0.170100 0.08%
350.00 0.205489 350.00 0.204800 0.07%
450.00 0.283189 450.00 0.282900 0.03%
520.00 0.659278 520.00 0.663400 0.41%
529.80 0.973506 529.80 1.000000 2.65%
530.30 1.000000 530.30 1.000000 0.00%
550.00 1.000000 550.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.15 0.15 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
114.00 0.000000 114.00 0.000000 0.00%
135.00 0.143070 135.00 0.000000 14.31%
138.80 0.139734 138.80 0.000000 13.97%
150.00 0.131472 150.00 0.130100 0.14%
10.00 250.00 0.149580 250.00 0.148700 0.09%
350.00 0.175551 350.00 0.174800 0.08%
520.00 0.420117 520.00 0.414200 0.59%
523.00 0.914252 523.00 0.457000 45.73%
523.40 0.927806 523.40 1.000000 7.22%
525.00 1.000000 525.00 1.000000 0.00%
550.00 1.000000 550.00 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

Page 26
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.05 0.25 0.3 0.2 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
70.00 0.000000 70.00 0.000000 0.00%
77.70 0.000000 77.70 0.000000 0.00%
88.87 0.026704 88.87 0.000000 2.67%
200.00 0.283973 200.00 0.283800 0.02%
0.22 300.00 0.459746 300.00 0.457600 0.21%
350.00 0.718091 350.00 0.718900 0.08%
370.00 0.976980 370.00 0.980900 0.39%
370.90 0.995346 370.90 1.000000 0.47%
371.20 1.000000 371.20 1.000000 0.00%
400.00 1.000000 400.00 1.000000 0.00%
500.00 NA 500.00 1.000000 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.05 0.25 0.3 0.2 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
120.00 0.000000 120.00 0.000000 0.00%
135.90 0.000000 135.90 0.000000 0.00%
136.00 0.000041 136.00 0.000100 0.01%
150.00 0.017720 150.00 0.017700 0.00%
2.5 250.00 0.204275 250.00 0.203900 0.04%
350.00 0.313210 350.00 0.312500 0.07%
450.00 0.741722 450.00 0.742900 0.12%
465.00 0.913029 465.00 0.914900 0.19%
470.60 0.997335 470.60 1.000000 0.27%
470.80 1.000000 470.80 1.000000 0.00%
500.00 1.000000 500.00 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.05 0.25 0.3 0.2 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
150.00 0.000000 150.00 0.000000 0.00%
172.90 0.000000 172.90 0.000000 0.00%
173.00 0.000063 173.00 0.000000 0.01%
200.00 0.035107 200.00 0.034700 0.04%
5.00 300.00 0.171522 300.00 0.171100 0.04%

Page 27
 PT Flash

400.00 0.297663 400.00 0.297200 0.05%

450.00 0.468757 450.00 0.469200 0.04%
490.00 0.834480 490.00 0.836500 0.20%
495.00 0.918612 495.00 0.921300 0.27%
498.90 0.996040 498.90 1.000000 0.40%
499.10 1.000000 499.10 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.05 0.25 0.3 0.2 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.00 0.000000 100.00 0.000000 0.00%
201.70 0.000000 201.70 0.000000 0.00%
201.80 0.000073 201.80 0.000000 0.01%
202.00 0.000284 202.00 0.000000 0.03%
7.00 210.00 0.009071 210.00 0.008800 0.03%
250.00 0.059113 250.00 0.058600 0.05%
350.00 0.158572 350.00 0.158000 0.06%
450.00 0.332896 450.00 0.333000 0.01%
490.00 0.625317 490.00 0.627200 0.19%
500.00 0.833998 500.00 0.834900 0.09%
504.40 0.998101 504.40 1.000000 0.19%
504.50 1.000000 504.50 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

Page 28
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.1 0.4 0.3 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
100.00 0.000000 100.00 0.000000 0.00%
150.00 0.000000 150.00 0.000000 0.00%
155.10 0.000000 155.10 0.000000 0.00%
155.30 0.000585 155.30 0.000000 0.06%
0.22 200.00 0.072221 200.00 0.072100 0.01%
300.00 0.184706 300.00 0.182300 0.24%
370.00 0.793202 370.00 0.795500 0.23%
375.00 0.908018 375.00 0.911800 0.38%
378.00 0.996147 378.00 1.000000 0.39%
378.20 1.000000 378.20 1.000000 0.00%
400.00 1.000000 400.00 1.000000 0.00%
500.00 NA 500.00 1.000000 #VALUE!

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.1 0.4 0.3 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
200.00 0.000000 200.00 0.000000 0.00%
300.00 0.000000 300.00 0.000000 0.00%
309.20 0.000000 309.20 0.000000 0.00%
309.40 0.000146 309.40 0.000000 0.01%
2.50 320.00 0.008174 320.00 0.008000 0.02%
400.00 0.103241 400.00 0.102900 0.03%
450.00 0.377373 450.00 0.378600 0.12%
470.00 0.642504 470.00 0.645100 0.26%
480.00 0.844134 480.00 0.847700 0.36%
485.80 0.996125 485.80 1.000000 0.39%
485.95 1.000000 485.95 1.000000 0.00%
500.00 1.000000 500.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.1 0.4 0.3 0.2
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
400.00 0.000000 400.00 0.000000 0.00%
450.00 0.000000 450.00 0.000000 0.00%
462.60 0.000000 462.60 0.000000 0.00%
462.70 0.000000 462.70 0.000300 0.03%

Page 29
 PT Flash

5.00 470.00 0.000000 470.00 0.023000 2.30%

480.00 1.000000 480.00 0.070500 92.95%
490.00 1.000000 490.00 0.151600 84.84%
500.00 0.997978 500.00 0.308300 68.97%
505.00 0.452258 505.00 0.461400 0.91%
510.62 1.000000 510.62 0.970100 2.99%
510.70 1.000000 510.70 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

Page 30
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.3 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
300.00 0.000000 300.00 0.000000 0.00%
314.60 0.000000 314.60 0.000000 0.00%
315.00 0.000588 315.00 0.005800 0.52%
316.00 0.002063 316.00 0.000000 0.21%
350.00 0.041437 350.00 0.039900 0.15%
10 450.00 0.108948 450.00 0.108100 0.08%
480.00 0.123755 480.00 0.122900 0.09%
495.00 0.110609 495.00 0.109200 0.14%
500.00 0.000000 500.00 0.082900 8.29%
501.00 1.000000 501.00 0.073500 92.65%
504.00 1.000000 504.00 0.025200 97.48%
505.40 1.000000 505.40 0.500000 50.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0.3 0.2 0.15 0.35
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
150.00 0.000000 150.00 0.000000 0.00%
230.00 0.000000 230.00 0.000000 0.00%
273.10 0.000000 237.10 0.000000 0.00%
274.20 0.002532 274.20 0.000000 0.25%
300.00 0.053395 300.00 0.051600 0.18%
317.00 0.076854 317.00 0.075369 0.15%
8 350.00 0.111160 350.00 0.110000 0.12%
450.00 0.218432 450.00 0.218000 0.04%
520.00 0.706812 520.00 0.708700 0.19%
522.00 0.814217 522.00 0.812500 0.17%
523.90 0.999246 523.90 1.000000 0.08%
524.00 1.000000 524.00 1.000000 0.00%
550.00 1.000000 550.00 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%

Page 31
PT Flash

*-

Page 32
 PT Flash

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0 0.2 0.8
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
300.00 0.000000 300.00 0.000000 0.00%
400.00 0.000000 400.00 0.000000 0.00%
408.10 0.000000 408.10 0.000000 0.00%
408.30 0.000000 408.30 0.112800 11.28%
0.22 408.35 0.000000 408.35 0.145200 14.52%
408.50 0.090624 408.50 0.243200 15.26%
408.59 0.146512 408.59 0.302700 15.62%
409.00 0.407457 409.00 0.584000 17.65%
409.50 0.749641 409.50 1.000000 25.04%
409.80 0.975305 409.80 1.000000 2.47%
409.84 1.000000 409.84 1.000000 0.00%
450.00 1.000000 450.00 1.000000 0.00%
500.00 1.000000 500.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0 0.2 0.8
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
400.00 0.000000 400.00 0.000000 0.00%
480.00 0.000000 480.00 0.000000 0.00%
483.80 0.000000 483.80 0.000000 0.00%
483.90 0.000000 483.90 0.062200 6.22%
484.20 0.048274 484.00 0.145600 9.73%
1.00 484.30 0.297990 484.30 0.400900 10.29%
484.50 0.469138 484.50 0.576600 10.75%
484.70 0.645222 484.70 0.758100 11.29%
484.90 0.827394 484.90 0.946500 11.91%
485.00 0.921169 485.00 1.000000 7.88%
485.10 1.000000 485.10 1.000000 0.00%
500.00 1.000000 500.00 1.000000 0.00%
550.00 1.000000 550.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0 0.2 0.8
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
450.00 0.000000 450.00 0.000000 0.00%
500.00 0.000000 500.00 0.000000 0.00%

Page 33
 PT Flash

559.40 0.000000 559.40 0.000000 0.00%

559.46 0.000000 559.46 0.000000 0.00%
559.50 0.059024 559.50 0.000000 5.90%
3.00 559.60 0.240259 559.60 0.162700 7.76%
559.75 0.513986 559.75 0.432100 8.19%
559.90 0.790612 559.90 0.704200 8.64%
560.00 0.977225 560.00 0.887400 8.98%
560.10 1.000000 560.10 1.000000 0.00%
561.00 1.000000 561.00 1.000000 0.00%
600.00 1.000000 600.00 1.000000 0.00%
650.00 1.000000 650.00 1.000000 0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0 0.2 0.8
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
NA 0.000000 0.00%
NA 1.000000 100.00%
0.00%
0.00%
0.00%
5.00 0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0 0 0 0.2 0.8
1.00
Scilab Unisim
P (Mpa) VF % Diff
T (K) VF T (K) VF
0.00%
0.00%
0.00%
0.00%
0.00%
7.00 0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%

Page 34
PT Flash

Page 35
 Density

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene Sum(xi)

Comp =
0.010 0.300 0.190 0.250 0.250 1.000

Vapor Liquid
P (Mpa) T (K)
Rho_U Rho_S % Diff Rho_U Rho_S
0.220 150.000 3.021 2.982 1.291 836.700 798.266
0.220 250.000 1.988 1.978 0.503 764.700 756.074
0.220 350.000 3.447 3.435 0.348 704.200 703.272

1.000 150.000 18.810 17.393 7.533 803.700 769.051

1.000 250.000 8.542 8.462 0.937 755.900 747.967
1.000 350.000 9.994 9.958 0.360 677.000 679.766

3.000 200.000 40.400 39.112 3.188 759.600 741.617

3.000 300.000 23.510 23.306 0.868 698.300 700.300
3.000 400.000 30.020 29.891 0.430 606.800 609.491

5.500 300.000 44.820 44.314 1.129 678.300 682.972

5.500 390.000 47.270 47.003 0.565 591.200 598.743
5.500 480.000 86.420 86.167 0.293 448.700 458.150
5.500 510.000 120.700 120.417 0.234 385.000 385.469

8.000 300.000 68.820 67.808 1.471 658.700 666.388

8.000 450.000 92.280 91.927 0.383 467.600 484.439
8.000 505.000 169.700 169.363 0.199 332.800 333.183

Page 36
 Density

d Sir) File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16

Comp =
0.000 0.000 0.300 0.400

Liquid Vapor
P (Mpa) T (K)
% Diff Rho_U Rho_S % Diff
4.594 0.220 340.000 5.156 5.155 0.019
1.128 0.220 360.000 5.328 5.324 0.075
0.132 0.220 380.000 5.799 5.792 0.121

4.311 1.000 420.000 23.870 23.854 0.067

1.049 1.000 430.000 24.560 24.542 0.073
0.409 1.000 440.000 25.480 25.457 0.090
1.000 450.000 26.620 26.594 0.098
2.367
0.286 2.500 485.000 73.390 73.332 0.079
0.443 2.500 495.000 76.690 76.607 0.108
2.500 505.000 80.670 80.584 0.107
0.689
1.276 2.700 495.000 83.850 83.760 0.107
2.106 2.700 505.000 88.130 88.031 0.112
0.122 2.700 510.000 90.580 90.477 0.114

1.167 3.000 510.000 103.400 103.276 0.120

3.601 3.000 515.000 106.500 106.377 0.115
0.115 3.000 520.000 109.900 109.775 0.114

Page 37
 Density

– final2 (Updated by Prasad Sir) File name = PT flash from PR EoS – final2 (U

Toluene Sum(xi) N2 CH4

Comp =
0.300 1.000 0.150 0.150

Liquid Vapor
P (Mpa) T (K)
Rho_U Rho_S % Diff Rho_U
669.800 673.939 0.618 0.220 100.000 7.508
668.400 669.625 0.183 0.220 200.000 2.980
663.200 662.386 0.123 0.220 300.000 2.842

580.000 575.872 0.712 2.500 130.000 95.080

578.200 571.421 1.172 2.500 250.000 29.280
575.600 566.021 1.664 2.500 450.000 37.840
573.000 560.453 2.190
5.000 300.000 50.770
468.900 440.350 6.089 5.000 400.000 50.180
464.900 431.589 7.165 5.000 500.000 89.990
460.700 421.886 8.425
8.000 150.000 411.500
451.400 418.336 7.325 8.000 350.000 74.680
446.600 408.251 8.587 8.000 450.000 90.340
442.300 402.886 8.911 8.000 520.000 165.200

407.400 381.205 6.430 10.000 350.000 93.450

401.000 375.028 6.477 10.000 400.000 93.680
394.400 368.672 6.523 10.000 520.000 216.300

Page 38
 Density

me = PT flash from PR EoS – final2 (Updated by Prasad Sir) File name = PT f

N-C4H10 N-C7H16 Toluene Sum(xi)

Comp =
0.200 0.150 0.350 1.000

Vapor Liquid
P (Mpa)
Rho_S % Diff Rho_U Rho_S % Diff
6.484 13.639 878.200 841.382 4.192 0.220
2.703 9.295 832.800 813.958 2.262 0.220
2.713 4.539 763.400 763.002 0.052 0.220

82.307 13.434 874.300 828.128 5.281 1.000

26.419 9.771 781.500 776.202 0.678 1.000
37.018 2.172 603.000 597.203 0.961 1.000

46.023 9.350 731.300 735.006 0.507 2.500

47.379 5.582 631.300 636.975 0.899 2.500
88.561 1.588 485.400 479.821 1.149 2.500

361.088 12.251 862.500 821.268 4.781 5.000

68.382 8.433 674.900 683.314 1.247 5.000
86.548 4.197 547.600 548.845 0.227 5.000
162.796 1.455 374.800 374.354 0.119
7.000
85.286 8.736 670.200 679.165 1.338 7.000
87.280 6.832 610.400 618.807 1.377 7.000
214.244 0.951 326.900 326.293 0.186 7.000

Page 39
 Density

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene Sum(xi)

0.050 0.250 0.300 0.200 0.200 1.000

Vapor Liquid
T (K)
Rho_U Rho_S % Diff Rho_U Rho_S % Diff
150.000 3.381 3.218 4.821 816.500 787.769 3.519
250.000 2.272 2.213 2.597 742.200 741.165 0.139
350.000 3.824 3.796 0.732 702.000 701.970 0.004

150.000 20.100 18.174 9.582 794.400 767.385 3.401

250.000 9.525 9.161 3.822 733.200 733.103 0.013
400.000 15.740 15.628 0.712 632.600 632.767 0.026

150.000 65.600 57.758 11.954 791.200 763.492 3.502

250.000 25.020 23.860 4.636 720.900 721.599 0.097
450.000 42.260 41.980 0.663 552.800 545.210 1.373

200.000 86.060 78.298 9.019 744.700 733.479 1.507

350.000 45.060 43.735 2.941 615.500 626.465 1.781
495.000 105.400 104.849 0.523 406.100 414.789 2.140

210.000 119.200 108.325 9.123 732.900 724.543 1.140

300.000 66.010 62.779 4.895 651.700 662.363 1.636
400.000 71.510 70.011 2.096 540.900 551.847 2.024
500.000 161.000 160.398 0.374 341.800 342.392 0.173

Page 40
 Density

File name = PT flash from PR EoS – final2 (Updated by Prasad Sir)

N2 CH4 N-C4H10 N-C7H16 Toluene

Comp =
0.000 0.100 0.400 0.300 0.200

Vapor Liquid
P (Mpa) T (K)
Rho_U Rho_S % Diff Rho_U
0.220 170.000 2.562 2.556 0.234 790.100
0.220 250.000 2.099 2.108 0.429 726.400
0.220 350.000 4.565 4.562 0.066 674.700

1.000 250.000 8.520 8.517 0.035 717.800

1.000 350.000 13.020 13.056 0.276 629.600
1.000 420.000 21.090 21.069 0.100 589.900

2.500 320.000 21.080 21.113 0.157 641.800

2.500 400.000 34.420 34.436 0.046 559.100
2.500 480.000 63.010 62.929 0.129 487.300

3.000 360.000 29.150 29.201 0.175 596.900

3.000 410.000 41.980 41.983 0.007 540.000
3.000 480.000 74.210 74.098 0.151 463.100

4.000 420.000 55.260 55.247 0.024 511.100

4.000 460.000 79.750 79.613 0.172 446.500
4.000 480.000 96.630 96.441 0.196 408.800
4.000 500.000 117.600 117.353 0.210 364.900

Page 41
 Density

ated by Prasad Sir) File name = PT flash from PR EoS – final2 (Updated by P

Sum(xi) N2 CH4 N-C4H10

Comp =
1.000 0.000 0.300 0.200

Liquid Vapor
P (Mpa) T (K)
Rho_S % Diff Rho_U Rho_S
768.277 2.762 0.220 150.000 2.931 2.923
725.942 0.063 0.220 250.000 1.963 1.967
675.741 0.154 0.220 350.000 3.376 3.367

717.616 0.026 1.000 200.000 10.450 10.427

637.113 1.193 1.000 300.000 8.181 8.191
585.819 0.692 1.000 400.000 13.710 13.684

651.167 1.459 2.500 200.000 30.110 30.086

562.474 0.603 2.500 300.000 19.240 19.243
464.832 4.611 2.500 400.000 25.910 25.885

606.126 1.546 5.000 250.000 48.840 48.835

542.568 0.476 5.000 390.000 42.930 42.917
443.603 4.210 5.000 490.000 83.280 83.142

514.960 0.755 7.000 290.000 59.660 59.670

445.107 0.312 7.000 380.000 56.820 56.817
406.736 0.505 7.000 450.000 79.410 79.313
365.926 0.281 7.000 500.000 122.900 122.758

Page 42
 Density

from PR EoS – final2 (Updated by Prasad Sir)

N-C7H16 Toluene Sum(xi)

0.150 0.350 1.000

Vapor Liquid
% Diff Rho_U Rho_S % Diff
0.273 863.900 828.549 4.092
0.204 791.800 785.754 0.764
0.267 740.100 740.872 0.104

0.220 817.700 799.614 2.212

0.122 742.300 745.421 0.420
0.190 673.200 674.873 0.249

0.080 787.700 773.029 1.863

0.016 728.100 732.710 0.633
0.096 642.300 646.757 0.694

0.010 739.700 739.834 0.018

0.030 623.300 632.381 1.457
0.166 484.000 485.613 0.333

0.017 697.100 705.620 1.222

0.005 614.800 627.413 2.052
0.122 520.300 529.340 1.737
0.116 423.400 424.133 0.173

Page 43