Course Code: CHE 2405

B.Tech – 4th Semester

Supplementary/Betterment Examinations, August 2015
Organic Chemistry
(Chem Only)

Time: 3 hours Max Marks: 70

Answer all questions
⋆⋆⋆⋆⋆

SECTION- I
5X2M=10 M
1.
a. What is Mesomeric effect?
b. Name the metal used in Reformatsky reaction.
c. Give examples for epimers
d. What is the function of Vitamin-B12
e. What are mordant dyes? Give an example.

SECTION- II
4X15M= 60 M

2. a). How Hyper-conjugation is useful in describing stability of cabo-cations?

Explain it. 8M
b). Explain electrophilic substitution reactions of benzene. 7M
OR
3. Give synthetic importance of N-bromosuccinamide and Aluminium
isopropoxide with suitable examples. 15M

4. Complete the following reactions with mechanism. 15M

OH
-
OH
a). + CHCl3 ?

CHO
CH3COOH
(CH3CO)2O ?
b). +
CH3
AlCl3
c). CH3COCl ?
+
OR
5. a). Explain Diela-Alder reaction. 7M
b). Discuss about Electrophilic addition reactions of carbonyl compounds. 8M

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 Course Code: CHE 2405
6. What are sequence rules? Explain their help in determining R & S configuration
of optical isomers. 15M
OR
7. Describe the method of preparation and uses of 15M
a). Malachite green, b). Fluorescence & c). Rosaniline

8. a). What are different types of Nylons? Give their general preparation method
and industrial applications. 9M
b). Give differences between Resins and Plastics. 6M
OR
9. a). Write about preparation and uses of Penicillin. 7M
b). Discuss about structure and industrial preparation of Benzene. 8M

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