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This work presents an energy management strategy (EMS) for a sustainable hybrid system. It is based on wind–solar
energy and bioethanol. The bioethanol reformer produces hydrogen with sufficient quality to feed a PEM fuel cell
system, which can supply the load together with the wind–solar sources. The new concept consists on having multiple
power sources to supply the load where the necessary heating for the bioethanol reforming reaction can be provided
by the wind–solar sources to enhance the efficiency of the hydrogen production. An optimal sizing methodology
based on genetic algorithms to design this stand-alone system is proposed. The developed model allows testing
the potentiality of the proposed EMS under different scenarios of load demands using historical climate data over a
period of one year. Then, the system is tested using several load scenarios to validate the proposed methodology.
© 2013 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
Keywords: Energy management strategy; Renewable energy sources; Bioethanol; PEM fuel cells; Sustainability; Stand-
alone power systems; System sizing
1. Introduction in any case to guarantee that the load requirements are com-
pletely satisfied. The use of energy storage systems (e.g.,
The new technologies of energy production from renewable different types of batteries, supercapacitors, etc.) is growing
sources, like solar or wind energy and biofuels, are receiving but including energy storage for extended periods of time may
much attention worldwide since the burning of fossil fuels not be feasible. Therefore, the use of a back-up system as
must be replaced soon. Fossil fuels have low efficiency and well as an energy storage system is necessary to achieve a
high level of emissions that contribute to global warming with reliable operation despite of the atmospheric conditions. Fuel
devastating consequences for the environment. Furthermore, cells together with a bioethanol reformer can offer a environ-
it is expected a fuel shortage for the next decades. ment friendly and reliable supply of electricity to support load
Renewable energy sources have a great number of advan- demand the for long periods.
tages including sustainability, reduction of carbon dioxide In this work, a new concept of renewable energy system
or other chemical pollutants and economic benefits. How- (RES) is introduced. The innovative idea is to use the hydrogen
ever, because of the intermittent nature of many renewable from bioethanol reforming to enhance the source energy from
resources, hybrid combinations of two or more power gener- solar and wind power when these two sources are not capable
ation technologies, along with energy storage, are necessary to satisfied the load demand. This is performed through the
to improve the system sustainability. For example, wind and use of a PEM fuel cell, which is feed with hydrogen from the
solar resources in a given area can be complementary in a reforming process. In turn, another innovative idea is to use
certain period of time (Nehrir et al., 2011). Although hybrid part of the remaining energy of wind and solar power in the
solar–wind energy systems reduce the energy storage require- bioethanol reforming process, which increases the efficiency
ments, the addition of some energy storage system is required of that process as it is shown. Therefore, hydrogen production
∗
Corresponding author. Tel.: +54 341 4237248 304; fax: +54 341 482 1772.
E-mail addresses: feroldi@cifasis-conicet.gov.ar, dferoldi@gmail.com (D. Feroldi).
Received 9 October 2012; Received in revised form 14 March 2013; Accepted 18 March 2013
1
Also with Universidad Nacional de Rosario – FCEIA-DCC, Pellegrini 250, S2000BTP Rosario, Argentina.
2
Also with Universidad Tecnológica Nacional – FRRo, Zeballos 1341, S2000BQA Rosario, Argentina.
0263-8762/$ – see front matter © 2013 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.cherd.2013.03.007
chemical engineering research and design 9 1 ( 2 0 1 3 ) 1440–1455 1441
Nomenclature
Tft power failure time [s]
BRS bioethanol reformer system Top operation time [s]
CSTR continuously stirred tank reactors Tt total time [s]
EMS energy management strategy u control signal of the PV power converter
ESR ethanol steam reformer v wind velocity [m s−1 ]
GA genetic algorithm Vbus bus voltage [V]
PEM polymer electrolyte membrane Voc battery open circuit voltage [V]
PV photovoltaic Vb battery bank voltage [V]
RES renewable energy system WH2,rct rate of hydrogen reacted [kg s−1 ]
WGS water gas shift reactors ˇ blade angle [rad]
A swept blade area of the wind turbine [m2 ] T sampling time [s]
Ac cell deviation from the ideal p-n junction char- ı function that maps states and input events to
acteristic states in the statechart
C capacitance [C] tip speed ratio
CPV initial cost of PV panels [USD] ωm speed angle of the turbine shaft [rad s−1 ]
C∗b battery capacity [Ah] penalization term
CC initial cost [USD] a air density (1.2 kg m3 )
Cf design constant of the blades p penalization term
CM maintenance cost [USD] set of possible input events in the statechart
CP efficiency of the turbine x vector of decision variables
CR replacement cost [USD]
E energy [Wh] Subscripts and superscripts
Ego band-gap energy of the semiconductor used in av available
the photovoltaic cell b battery
Ior reverse saturation current at the reference tem- FC fuel cell
perature [A] h heater
Iph photovoltaic cell current under a given insola- init initial
tion [A] L load
IPV photovoltaic current [A] lim limit
Isc short-circuit photovoltaic cell current [A] lw lower
Io current on the output terminal of the PV power max maximum
converter [A] min minimum
Irs photovoltaic cell reverse saturation current [A] nom nominal
J cost functional PV photovoltaic
K Boltzman constant (1.3806488 × 10−23 J K−1 ) r rated
Kl short-circuit current temperature coefficient rct reacted
L inductance [H] ref reference
LPSP loss of power supply probability req required
LPSPa allowed loss of power supply probability thr threshold
Nb,p number of batteries in parallel un unitary
Nb,s number of batteries in series u used
Nb number of batteries up upper
NFC number of fuel cells w wind
NPV number of PV panels
Nw number of wind turbines
np number of PV cells in parallel from bioethanol with a more efficient use of the raw material
ns number of PV cells in series is accomplished, taking advantage of the available renewable
P power [W] energy sources.
P/E power/energy ratio The topology of the proposed system is shown in Fig. 1.
PFC fuel cell power [W] This figure shows how the load power can be supplied by the
Pb battery power [W] wind turbine and the PV array. Hybridization between wind
Ph heater power [W] and solar energies has been reported in several works (Kellogg
PL load power [W] et al., 1998; Chedid et al., 1998; Borowy and Salameh, 1996;
Pw wind turbine power [W] Koutroulis et al., 2006; Yang et al., 2008; Ekren and Ekren,
q charge of an electron (−1.602176565 × 10−19 C) 2008). This type of hybrid power generation systems is suit-
r radius of the blades [m] able for stand-alone applications (e.g., residential household)
Rint battery internal resistance [] because of the complementary nature of wind and solar ener-
S set of nodes in the statechart gies but also for grid-linked applications. A recent review on
s0 initial state in the statechart hybrid renewable energy systems for power generation in
SOCb battery state of charge [%] stand-alone applications is given in Bajpai and Dash (2012).
T temperature [◦ C] Besides, another review about optimum sizing of stand-alone
hybrid solar–wind power generation systems is given in Zhou
1442 chemical engineering research and design 9 1 ( 2 0 1 3 ) 1440–1455
et al. (2010). Hybridization between fuel cells and solar energy 2003). However, despite its abundance in nature, hydrogen is
has been reported in Hwang et al. (2009) where it is consid- not available in a pure form. Therefore, some processes are
ered a photovoltaic (PV) cell as the main power source using necessary to obtain hydrogen with sufficient quality. As it was
the remaining power to operate an electrolyzer that produces mentioned, one alternative for hydrogen production is from
hydrogen from water. The hydrogen is stored in a pressurized electrolysis. Another interesting alternative is from ethanol.
tank and consumed by a fuel cell when extra power is required The advantages of ethanol, compared with other raw mate-
by the load. Furthermore, in Thounthong et al. (2011) a hybrid rials, are its high hydrogen content, availability, low toxicity
energy system that uses renewable energy from solar cells, and safety of storage and handling. In addition, ethanol can
fuel cells and supercapacitors is proposed with an EMS based be produced by fermentation of biomass sources such as agri-
on the flatness properties of the system. Other authors, such cultural residues, forestry, livestock and urban organic. The
as (Z’Graggen et al., 2008), have considered the use of concen- ethanol produced in this way is called bioethanol (Basualdo
trated solar radiation (energy source with high temperature) et al., 2011).
to produce hydrogen by steam gasification of carbonaceous The most usual methods of obtaining hydrogen from
materials. Additionally, a hybrid wind/PV/fuel cell alterna- bioethanol are catalytic partial oxidation and steam reform-
tive energy system for stand-alone applications has also been ing. The latter method is used in this work because it achieves
reported in Wang and Nehrir (2008), Nelson et al. (2006) where high concentration of hydrogen required to feed a PEM fuel
wind and solar energies are the primary power sources and a cell system. There is considerable research about the reaction
fuel cell-electrolyzer combination is used as a backup and a pathways of bioethanol steam reforming. An extensive review
long-term storage system. about different technologies of integrated fuel processors for
In Fig. 1 can be seen that the fuel cell system can also fuel cell applications is given in Qi et al. (2007). However,
provide power to de DC bus when necessary. Polymer elec- this type of process requires external heating to complete the
trolyte membrane (PEM) fuel cells are an excellent alternative reforming reaction. A solution to this necessity was reported
for the production of electricity because the high efficiency in Basualdo et al. (2011), which involves burning a portion of
compared to other technologies (e.g., internal combustion bioethanol in a separate reactor and to provide the reaction
engines) and, basically, the only local emissions are water heat from the obtained gases. However, this solution has a
and heat. In addition, PEM fuel cells have the advantage over negative impact on system efficiency due to the extra con-
other types of fuel cells to work at relatively low temperatures, sumption of bioethanol.
which makes them good candidates to work in numerous In order to avoid this situation, renewable energy sources
applications, including stationary power generation, automo- can be used to reduce the oxidation of fresh ethanol to obtain
tive applications and portable electronics. Several works use the required heat (Degliuomini et al., 2012). This paper pro-
a PEM fuel cell as a back-up unit together with renewable poses to use the wind–solar energy, which provides electricity
sources. in Erdinc and Uzunoglu (2011, 2012), Bilodeau and to a heating system in the bioethanol reformer. However, these
Agbossou (2006), Ipsakis et al. (2009) it is used wind and solar power sources have a high natural variability. For example,
energy to supply the load while the excess energy produced by wind power can change very abruptly due to sudden gusts of
the sources is stored in hydrogen by using an electrolyser. This wind, making it necessary to include an energy storage sys-
hydrogen is converted into electricity with a fuel cell when the tem, such as a battery bank, acting as a buffer to cover the
weather conditions are unfavorable. A similar approach is pre- energy balance.
sented in Zhou et al. (2008) but without wind energy. On the In this context, an energy management strategy (EMS) is
other hand, the same approach is presented in Del Real et al. necessary for the correct operation of the energy subsystems,
(2009) but using wind energy as main energy source. Another in order to meet the load demands. The EMS is an algo-
approach of a photovoltaic/wind/fuel cell system for stand- rithm capable of commanding in real time the energy sources
alone applications is presented in Eroglu et al. (2011). In this involved in order to meet the load requirements, while reduc-
approach there is no electrolyzer for hydrogen production. ing consumption (Feroldi et al., 2009). Different approaches for
PEM fuel cells need to be fed with high-purity hydrogen addressing EMS in hybrid systems with multiple renewable
to prevent degradation of the catalyst (Larminie and Dicks, energy sources are found in literature, depending on whether
chemical engineering research and design 9 1 ( 2 0 1 3 ) 1440–1455 1443
the application is stand-alone or grid-connected. In the first 2.1. Bioethanol reformer system (BRS)
category, which is the case covered here, different approaches
can be found such as supervisory control switching between The bioethanol reformer (BRS) system consists of an ethanol
operation modes (Valenciaga and Puleston, 2005; Degliuomini steam reformer (ESR), which performs most of the conversion
et al., 2012) or supervisory predictive control based on model of bioethanol to hydrogen, followed by three water–gas shift
predictive control (Qi et al., 2011). A stand-alone PV-H2 system reactors (WGS). The catalyst of the fuel cell can be damaged if
with a double hysteresis control scheme is in Zhou et al. (2008). the hydrogen that enters the anode contains carbon monox-
Three EMS based on switching between different modes are ide. Therefore, further processing is necessary to remove this
presented and compared in Ipsakis et al. (2009), applied to damaging substance. Three WGS perform the hydrogen clean-
a stand-alone power system based on a PV array and wind ing. First, there are a high-temperature reactor (HTS) followed
generators that stores the excessive energy in the form of by a low-temperature reactor (LTS), which favors the reac-
hydrogen. tion equilibrium at higher rates of CO conversion. In the third
The organization of this paper is as follows. In Section 2 a reactor, a preferential oxidation of carbon monoxide (CO-Prox)
detailed description of the power generation system is per- is produced, which performs the oxidation of CO in CO2 .
formed. Section 3 deals with the component sizing of the Besides, it produces undesired oxidation of H2 , so the catalyst
hybrid renewable energy system. Section 4 deals with the is selected to improve the CO conversion.
energy management strategy used to manage the flow of In the first step to produce the decomposition of ethanol,
energy within the designed system. In Section 5, the obtained the bioethanol is mixed with vaporized water, and then sup-
results are presented and discussed. Finally, in Section 6 the plied to the ESR:
conclusions and future work lines for further research are
stated. (ESR) CH3 CH2 OH + 3 × H2 O ↔ 6 × H2 + 2 × CO2 .
anode, extending through the diffusion layer and reaches the This generation system consisting of a PEM fuel cell with rated
catalytic layer, which is oxidized releasing electrons and pro- power of 10 kW, where the most relevant control loop from
tons according to the point of view of efficiency is the control of the cathode air
supply.
2H2 → 4H+ + 4e− .
The hydrogen consumption map of a PEM fuel cell system
The electrons cross the metal and granulate coal of the anode clearly reveals a zone, below a limit power, where the efficiency
catalytic layer, reaching the cathode through the external cir- is very poor meanwhile the zone above this limit power has
cuit, while the protons are transported through the membrane a significant higher efficiency (Feroldi et al., 2009). Therefore,
to the cathode catalyst layer. At the same time, oxygen is the PEM fuel cell system is operated in this advantageous zone
injected in the feed channels of the cathode, which propagates where the efficiency is high. The maximum power is limited
through the diffusion layer to the catalytic layer where it reacts by the rated power, whereas the minimum must be limited to
with protons and electrons generating water according to a value below which it is not suitable to operate because the
parasitic load is too large, reducing the system net power:
O2 + 4H+ + 4e− → 2H2 O.
Therefore, the overall reaction in the fuel cell is the following: Pmin max
FC ≤ PFC (t) ≤ PFC . (4)
The cathode reaction is exothermic, where the heat released is of reactants and the power cannot be decreased faster than a
dependent on the voltage that is directly related to efficiency. certain power fall rate (PminFC ) to prevent overpressure into the
The rate of hydrogen consumed in the electrochemical stack (Feroldi et al., 2009):
reaction in the fuel cell anode is a function of the fuel cell
current: Pmin max
FC ≤ PFC (t) ≤ PFC , (5)
MH2 n
WH2 ,rct = IFC , (3) where PFC (t) = PFC (t) − PFC (t − T) and T is the sample time.
2F
where WH2 ,rct is the rate of hydrogen reacted, MH2 = 2.016 × 2.3. Wind power system
10−3 kg mol−1 is the molar mass of oxygen, n is the number
of cells in the stack, F = 96485 C mol−1 is the Faraday number, The wind power generation system comprises a wind tur-
and IFC is the stack current. This is the amount of hydrogen bine, a multipolar synchronous generator with permanent
that is required to the bioethanol processor system presented magnets, a rectifier and a DC–DC converter to connect the
in Section 2.1. generator to the DC bus. The wind turbine has three blades
In order to produce energy, it is necessary to integrate which convert the energy of the wind into rotational forces
the fuel cell with other components to form a generation that drives the generator. The pitch angle of the blades is vari-
system, controlling a number of variables such as tempera- able allowing to be adjusted operating the wind turbine at its
tures, pressures and reactant flows. These components can optimal performance (Borowy and Salameh, 1996). Therefore,
be divided into the following subsystems, which are strongly the power extracted from the wind turbine can be maximized
interrelated: reactant supply (hydrogen and air), heat and tem- according to the actual wind speed in a certain range.
perature control, water management, power conditioning, and The mechanical power captured by a wind turbine is pro-
power management. portional to the swept blade area (A [m2 ]), the air density (a ),
A generic diagram showing the interrelation between the the wind velocity (v [m s−1 ]) and the coefficient of power (CP ),
main components of the generation system based on fuel cell, which expresses the efficiency of the turbine as a function of
as well as the control study, based on predictive control for the the ratio defined as = rωm /v, where r [m] is the radius of the
correct operation of this is reported in Basualdo et al. (2011). blades and ωm [rad s−1 ] is the speed angle of the turbine shaft
chemical engineering research and design 9 1 ( 2 0 1 3 ) 1440–1455 1445
The solar power system is composed of a PV cell array and a where np is the number of parallel modules, and ns is the num-
buck DC/DC power converter. In a PV array, the electromag- ber of cells connected in series in each parallel module (values
netic radiation of solar energy can be directly converted into in Table 1). Therefore, the available power generation from a
electricity through photovoltaic effect. Therefore, the electric PV array is
energy generated by a PV cell depends on several parameters
and atmospheric conditions such as insolation and temper- Pav av
PV (t) = VPV (t)IPV (t). (13)
ature. This atmospheric conditions affects significantly the
performance of the PV cells. Some of the parameters affecting As is shown in Fig. 1, the PV array is connected to the
the performance are related with the effective area, deter- DC bus through a DC/DC buck converter, allowing to reg-
mined by its configuration, and the particular technology. ulate the power generation. The dynamic response of the
The electric behavior of a PV cell can be modeled by a non- solar subsystem is determined by the operation of the DC/DC
linear current source connected in series with the intrinsic cell buck converter. The dynamic response of the system can be
series resistance. The current provided by this equivalent non- expressed through the following equations:
linear source (IPV [A]) depends mainly on the actual insolation
and the temperature (Valenciaga et al., 2001): 1
V̇PV (t) = (IPV (t) − Io (t))u(t), (14)
C
q(VPV (t) + IPV (t)Rs )
IPV (t) = Iph (t) − Irs (t) exp −1 , (9) 1
Ac KT(t) İPV (t) = (−Vb (t) + VPV (t))u(t), (15)
L
where Iph is the generated current under a given insolation, Irs where C and L are the capacity and inductance in the DC/DC
is the cell reverse saturation current, VPV is the voltage level on converter, Vb is the voltage on the battery bank terminals, Io is
the PV panel array terminals, q is the charge of an electron, Rs the current on the output terminal of the DC/DC voltage, and
is the intrinsic cell resistance, Ac is the cell deviation from the u is the control signal commanding the DC/DC. The control
ideal p-n junction characteristic, K is the Boltzman constant, signal u is a switched signals with discrete values 0 (switch
and T is the cell temperature. The reverse saturation current opened) and 1 (switch closed), fixed frequency, and variable
1446 chemical engineering research and design 9 1 ( 2 0 1 3 ) 1440–1455
where Tt is the total time of weather data used in the analysis where CC, w , CC, PV , and CC, b are the initial cost of one wind tur-
and Tft is the power failure time, which is defined as the time bine, one PV panel and one battery, respectively; CM, w , CM, PV ,
that the load is not satisfied: and CM, b are the yearly maintenance cost of one wind tur-
bine, one PV panel, and one battery, respectively; CR, w , CR, PV ,
Tt
and CR, b are the replacement cost of one wind turbine, one PV
Tft = ϕ(t)T, (22) panel, and one battery, respectively; and Top is the operation
t=0 time.
The total available power in the DC bus is
where T is the sample time in the discrete data, and
req Pav av av
T (t) = Nw AD Pw, un (t) + NPV DD PPV, un (t)
1 if Pav
T (t) < PT (t),
ϕ(t) = (23) + NFC DD Pav dsch
FC, un (t) + Nb DD Pb, un (t), (30)
0 otherwise.
and
and p → ∞ is a sufficiently large constant to avoid solutions
that do not meet the LPSP requirement. req 1 req req
PT, 2 (t) = P (t) + Ph (t). (35)
The total cost CT (x) can be expressed as DA L
atmospheric conditions. The operation must ensure that the the intended application is in geographical areas with wealthy
energy balance in (1) is met, subjected to the constraints in (2). wind regimes. Therefore, the first objective is that the pro-
The available power from the wind subsystem is Pav w (t) = posed energy management strategy operates the wind turbine
av
iw (t)Vbus (t) according to (8), while the available power from at its maximum power point so long as possible. Thus, the
the solar subsystem is Pav av
PV (t) = iPV (t)Vbus (t) according to (13). role of the solar subsystem is to reinforce the wind subsys-
av
The available currents iPV (t) and iav w (t) are defined according tem. Similarly, the battery bank also reinforces the wind–solar
the input currents to the DC-DC converters (see Fig. 1) and the subsystems.
respective conversion ratios. The wind turbine, solar cells and The EMS can be formalized using a state machine
the reformer-fuel cell are usually controlled by inner regula- approach. State machine is a powerful tool to implement deci-
tion loops. The dynamics of these loops are much faster than sion making algorithms. It can be used both as a development
those of outer control loops. Therefore, the current of each tool for approaching and solving problems and as a formal
power source is considered to follow its reference perfectly way of describing the solution for later developers and sys-
(Thounthong et al., 2011). tem maintainers. In the state machine concept, the system
In the proposed EMS, the main generation role is in charge makes a transition from one state (mode) to another, provided
of the wind subsystem while the solar subsystem plays a com- that the condition defining the change is true. Thus, a state
plementary role. The motivation for this criterion is because of machine consists of state variables, which encode its states,
and events, which transforms its states. A state machine can
be represented by a statechart. The statechart representing the
proposed EMS is given in Fig. 7. The statechart can be defined
by a tuple S, , ı ⊆ S × × S, s0 where
SOCmin
b Minimum state of charge 20%
SOCmax
b Maximum state of charge 90%
SOCthrb Threshold of the state of charge 20%
thr
i Threshold of the load current 15 A
s1 5 s4
6 s5
1 s2
s2 5 s4
6 s5
2 s1
3 s3
s3 5 s4
6 s5
4 s2
s4 7 s1
s5 8 s1 Fig. 8 – Average hourly temperature and insolation profile.
chemical engineering research and design 9 1 ( 2 0 1 3 ) 1440–1455 1451
6. Conclusions
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