Q.

1 Circle the correct one in the following MCQ’s

1. Large no. of isotopes are known for the elements whose masses are multiple of
a. two (b) four (c) six (d) eight
2. Optical rotation method is used when
a. reaction involve ions (b) change of refractive indices
b. reactions involving change of optical activity (d) none of above
3. Spectrometry applied for rate determination when
a. Reactants or product absorb U.V., I.R. light (b) Reaction involve ion
b. Reaction involve change in volume (d) none of above
4. Which is not common way of carrying chromatography
a. ascending (b) descending (c) radial/circular (d) spreading
irregular
5. If absolute temperature of a gas is doubled and the pressure is reduced to one half the
volume of gas will.

(a) remain unchanged (b) increases four times (c) reduce to (d) be double

6. At high temperature isotherm moves away from both the axis because of increase in,

(a) pressure (b) volume (c) no. of moles (d) all above

7. In the ground state of an atom, the electron is present

(a) in the nucleus (b) in the second shell (c) In the outermost shell (d) none of these
8. The energy of bounded electron in H atom is
(a) positive (b) negative (c) zero (d) none of these
9. Quantum number values for 3p orbital’s are
(a) n = 0, l = 3 (b) n = 3, l = 1
(c) n = 2, l = 1 (d) n = 1, l = 3
10. Trend of boiling points of halogens from fluorine to iodine is that it.
(a) decreases (b) increases (c) remains constant (d) negligible
11. Exceptionally low acidic strength of HF is due to
(a) strong polar bond (b) small size of fluorine
(c) strong hydrogen bonding (d) Vander Waal’s forces
12. Carbon atoms of diamond are
(a) sp hybridized (b) sp2 hybridized
(c) sp3 hybridized (d) unhybridized
13. Solvent Extraction method is particularly useful technique for separation when the product
to be separated is
a) Non-Volatile or thermally unstable b) Volatile or thermally stable
c) Non-Volatile or thermally stable d) Volatile or thermally unstable
14. Largest number of molecules are in
a) 3.6 gmH2O b) 4.8 gm C2H5OH c) 2.8 gm CO d) 5.4 gm N2O5
15. Glycerin decomposes at its
a) Melting point b) Boiling point c) Freezing point d) Critical
point
16. pH of 103 mole dm3 of an aqueous solution of H2SO4 is
a) 3 b) 2.7 c) 2 d) 1.5
17. In combustion analysis H2O vapors are absorbed by
a) Mg(CrO2)2 b) Mg(CrO3)2 c) Mg(CrO4)2 d) 50% KOH
18. Which gas will diffuse more rapidly?
(a)HCl (b) CO2 (c) NH3 (D) SO2
19. Ionic product of water (Kw) increases when temperature increases from 0 C to 100oC
o

a) 25 times b) 75 times c) 55 times d) 65 times

20. The maximum number of electrons in a sub shell is given by
a) 2l+1 b) 2l-1 c)2(2l+1) d) 2(2l-1)
21. Molarity of pure water is
a. 1 b. 18 c. 55.5 d.6
22. Pressure remaining constant at which temperature the volume of a gas will become twice of
what it is at 0oC
a. 546oC b. 200oC c. 546K d. 200K
23. In the ground state of an atom, the electron is present:
a). In the nucleus b). In the second shell c). Nearest the nucleus d). Farthest from
nucleus
24. The electrode reaction in the electrolysis of dil. H2SO4 with pt. electrode is
a. Reduction b. Oxidation c. Reduction and Oxidation d. neither Reduction nor
Oxidation
25. The potential of standard hydrogen electrode is always fixed as
a. 1 b. 0 c. 1.5 d.2
26. The example of Hexagonal system is
a. Sulphur b. NaCl c. Graphite d. Diamond
27. Standard enthalpies are measured at
a. 273 K b. 373 K c. 298 K d. All of these
28. The catalyst used for the reaction HCOOH → H2 +CO2
a. Cooper b. Alumina c. Silica d. Iron
29. Which of the following species has unpaired electrons in anti bonding molecular orbital’s
a. H2 b. He2 c. O22+ d.N22-
30. The molar volume of CO2 is maximum at :
a. STP b. 127oC and 1atm c. 0oC and 2atm d. 273oC and 2atm
31. Gooch crucible is made of
(A) Clay (B) Asbestos (C) Porcelain (D) Iron
32. Solvent extraction is a process
(A) Exothermic(B) Endothermic (c) Equilibrium (D) Non-equilibrium
33. CsF has ionic character
(A) 60 % (B) 80% (C) 92% (D) 100%
34. The Comparative rates at which solutes move in paper chromatography depend on
(A) The Size of paper (B) Rf value (C) Tank (D) Temperature
35. Which is not used as drying agent in vacuum desicator is
(A) P2 O5 (B) CaCɽ2 (C) MgCɽ2 (D) Silica Gel
36. The hybridization of carbon in C2H4 is
(A) SP3 (B) SP2 (C) SP (D) dSP3
37. A Component having small value of K (Distribution coefficient) mostly remains inefficient:
(A) Stationary Phase (B) Mobile Phase (C) Chromatographic tank (D) none of
above
38. Which of the following species has unpaired electrons in anti bonding molecular orbital’s:
(A)H2 (B)He2 (C)O2+2 (D) N2+2
39. A molecular can contain maximum electrons
(A)One (B) Two (C) Three (D) Four
40. Bond angle between two H-S-H bond is
(A)104.5o (B) 107.5o (C) 109o (D) 120o
41. In order to mention the b.p of water at 1100C, the external pressure should be
a) b/w 760-1200 torr b) b/w 200-760 torr c) 765 torr d) Any value of pressure
42. .Vapor pressure of a liquid depends upon
a) Amount of the liquid b) Suface area c) Temperature d) Size of
container
43. When external pressure is 23.7 torr the boiling point of water will be?
a) 1000C b) 2000C c) 980C d)250C
44. Exceptionally low acidic strength of HF is due to?
a) Strong polar bond b) Small size o F c) Strong Hydrogen bondingd) Wander walls
Forces
45. Down the group polarizability generally
a) increases b) decreases c) remain const d) do not follow a regular
trend
46. B.P is low for liquid with
a) High vapor pressure b) strong dipole-dipole forces c) low vapor pressure d) none of
these
47. Molar heat of vaporization of water is
a) 40.6 j/mole b) 14.06 kj/mole c) 18 kj/mole d) 40.06 kj/mole
48. London dispersion forces are the only forces present among the:
a) Molecule of water in liquid state b) Atoms of helium in gaseous state at high
temperature c) Molecules of solid iodine d) Molecules of HCl gas
49. When water freezes at 00C, its density decreases due to
50. a) Cubic structure of ice b) Empty structure present in the structure of ice c)
Change of bond lengths d) Change of bond angels
51. Evaporation ofwater is possible at
a) 1000C b) 00C c) At all temperature d) Above 1000C
52. Crystalline forms of the same, 0substance can coexist in equilibrium with each other at its
a) melting point b) transition temperature c) boiling point d) none of these
53. Which of the elements in its crystalline form will have the lowest enthalpy change of
vaporizations
a) chlorine b) argon c) phosphorous d)
silicon
54. Carbon atoms of diamond are
a) sp hybridized b) sp2 hybridized c) sp3 hybridized d) unhybridized
55. Molecular crystals are generally
a) hard b) soft c) unstable d) stable
56. Existence of an element in more than form is known as
a) allotropy b) isomorphism c) isotropy d) none of these
57. Crystals show variation in physical properties depending upon the direction. The property
is called
a) isomorphism b) polymorphism c) anisotropy d) isotropy
58. In a crystal the atoms are located at the position of
a) Zero P.E b) Infinite P.E c) Maximum P.E d) Minimum P.E
59. Cleavage planes are
a) Horizontal b) Vertical c) Inclined d) Parallel
60. Graphite shows Anisotropy because
a) Layered lattice b) hybdrization of C atom c) Presence of lose electrons in
between layers d) all
61. Close packing is maximum in the crystal
a) Simple Cubic b) face centered cubic c) body centered cubic d) All
62. The velocity of photon is
a) equal to square of its amplitude b) Independent off its wavelength
b) Equal to its wave number d) equal to velocity o light
63. The radius of 1 orbit of hydrogen atom
st

a) .329 A0 b) .429 A0 c) .529 A0 d) .229 A0

64. Bombardment of Beryllium with alpha particles generates
a) proton b) neutron c) electron d) positron
65. Goldstein discovered that besides the cathode rays, another type of rays are produced in the
discharge tube which are called
a) alpha rays b) beta rays c) positive rays d) gamma rays
66. The value of plank’s constant “h” is
a) 6.625 * 10-34 cal b) 6.625 * 10-34 J sec c) 6.625 * 10-34 kJ d) 6.625 * 10-
34 k cal
67. A spinning electron creates
a) Magnetic field b) Electric field c) Quantum field d) None of these
68. The wavelength associated with the moving stone
can be measured by many methods b) cannot be measured by any methods
c) can be measured by some methods d) None of these
69. Neutron was discovered by
a) Chadwick b) Bohr c) J.J Thomson d) Einstein
70. n+l value for 4f will
a) 2 b) 5 c) 7 d) 9
71. Which of the following quantum numbers describe energy of an electron in atom
a) principal quantum b) azimuthal quantum c) magnetic quantum d) spin
quantum
72. Which orbital has dumb-bell shape
a) s-orbital b) p-orbital c) d-orbital d) f-orbital
73. The wavelength range of visible spectrum is
a) 400-750 nm b) 300-400 nm c) 350-600 nm d) 200-400 nm
74. The energy of bounded electron in H atom is
a) positive b) negative c) zero d) none of these
75. Atom bomb is based on the principle of
a) nuclear fusion b) nuclear fission c) radioactivity d)
none
76. In an atom the electrons
a) are stationary in various energy levels
b) are distributed in three dimensional charge cloud around the nucleus
c) embedded in space around the nucleus
d) resolve around the nucleus at random
77. Gooch crucible is used to filter the solution of
a) K2Cr2O7 b) KMnO4 c) KOH d) under suction crucible
78. Rate of filtration through conical funnel can be considerably increased by using
a) Fine filter paper b) ordinary filter paper c) fluted filter d) none
79. Basic principles of crystallization is that solute should be soluble in a suitable solution at
a) Freezing temperature b) room temperature
c) High temperature d) low temperature
80. Repeated extraction using small portions of solvent are more
a) Accurate b) Efficient c) Slow d) Rapid
81. Chromatography in which the stationary phase is liquid is called
a) Partition Chromatography
b) Descending Chromatography
c) Column Chromatography
d) Adsorption Chromatography
82. In paper chromatography the rate at which solutes move depends on
a) Distribution law b) distribution coefficients
c) Law of partial pressure d) law of specific proportion
83. Solvent extraction method is particularly useful technique for separation, when the product
to be separated is
a) Non-volatile or thermally unstable b) Volatile or thermally unstable
c) Non-volatile or thermally stable d) Volatile or thermally stable
84. Which is not common way of carrying chromatography
a. Ascending b. Descending c. Radial/circular d. spreading irregularly
85. Drying agent used in desiccator is
a. Lithium Chloride b. Sodium Chloride c. Potassium Chloride d. Calcium Chloride
86. Several types of filter media are used for filtration depending on
A. nature of reaction B. nature of reactants
C. nature of precipitate D. nature of filter paper
87. Which of the following Hydrogen halides has the highest percentage of ionic character
a) HF b) HBr c) HCl d) HI
88. Which of the following bonds is least polar
a) H-Se b) P-Cl c) H-Cl d) N-Cl
89. Which element would be the least electronegative element with
a) High I.E and low E.A b) Low I.E and high E.A
c) Low I.E and low E.A d) High I.E and high E.A
90. Which of the following molecule has a pyramidal structure?
a) CH4 b) NH3 c) H2O d) C2H4
91. A bond having partial positive and partial negative charge is
a) Ionic b) Covalent c) Polar covalent d) none
92. Which of the following elements is the most electronegative
a) Li b) F c) O d) Cl
93. The 1st I.Ein a group with increasing atomic number
a) Decreases b) Increases c) Remains constant d) None
94. Ionic bonding is usually formed between the elements of -------- of periodic table
a. Group I and group VII b. Group II and group VII
c. Group I and group VI d. zero d. All of above
95. Bonding maybe 100% ionic when electro-negativity difference is----
a. 0.9 b.1.7 c. 2.4 d. 3.4
96. Among halogens, maximum electron affinity is shown by----
a. Iodine b. Bromine c. Chlorine d. Fluorine
97. The unit of the rate constant is the same as that of the rate of reaction in
(a) first order reaction (b) second order reaction
(c) zero order reaction (d) third order reaction
98. The hydrolysis of tertiary butyl has order
(a) first order (b) pseudo first order (c) fractional order (d)
zero order
99. Spectrometry applied for rate determination when
(a) Reactants or product absorb U.V., I.R. light (b) Reaction involve ion
(c) Reaction involve change in volume (d) none of above
100. When temp of reacting gases is raised to 10 K, the reaction rate becomes
(a) remain same (b) double (c) triple (d) increase four times
101. Optical rotation method is used when
(a) reaction involve ions (b) change of refractive indices
(c) reactions involving change of optical activity (d) none of above
102. h
half life period for decomposition of N2O5 at 45 oC is
(a) 24 minutes (b) 34 minutes (c) 44 minutes (d) 54 minutes
103. Large no. of isotopes are known for the elements whose masses are multiple of
(a) two (b) four (c) six (d) eight
104. The no. of covalent bond in 10gm of NH3 are
(a) 6.022 x 1023 (b) 1.062 x 1023 (c) 10.62 x 1024 (d) 1.062 x 1024
105. Largest number of H+ ions is produced by complete ionization of
(a) 0.01 mole of HCl (b) 0.0050 mole of H2SO4
(c) 0.000334 moles of H3PO4 (d) all above
106. An ordinary microscope is used to measure the object of size
(a) up to 500 nm (b) up to 850 nm (c) up to 1000 nm (d) up to 1200 nm
107. Which one of the following is a pseudo solid
(A) CaF2 (B) NaCɽ (C) Borax (D) Glass
108. Which of the hydrogen halide has the highest percentage of ionic character
(A) H1 (B) HBr (C) HBɽ (D) HF
109. Which is not a state function
(A) Energy (B) Heat (C) Temperature (D) Volume
110. Dry Ice (Solid CO2) is an example of solid
(A) Covalent (B) Molecular (C) Ionic (D) Metallic
111. London dispersion forces are the only forces present among the
(A) Molecules of water in liquid state (B) Atoms of helium in gaseous state at high
temperature
(C) Molecules of solid iodine (D) Molecules of hydrogen chloride gas
112. One calorie is equivalent to
(A) 0.18 J (B) 4.18 J (C) 18 J (D) 18. 1
113. For a given process qp and qv are related as
(A) qp= qv (B) qp< qv (C) qp> qv (D) qp= qv/2
114. Transition Temperature is
(A) 95.5oC (B) 13.2oC (C) 100oC (D) 128oC