1. Maximum work that could be secured by A. disorder
expanding the gas over a given pressure range B. orderly behaviour is the __________ work. C. temperature changes only A. isothermal D. none of these B. adiabatic C. isentropic 8. A chemical reaction will occur D. none of these spontaneously at constant pressure and temperature, if the free energy is 2. Internal energy change of a system over A. zero one complete cycle in a cyclic process is B. positive A. zero C. negative B. +ve D. none of these C. -ve D. dependent on the path 9. Fundamental principle of refrigeration is based on the __________ law of 3. Heating of water under atmospheric thermodynamics. pressure is an __________ process. A. zeroth A. isochoric B. first B. isobaric C. second C. adiabatic D. third D. isothermal 10. For a spontaneous process, free energy 4. Van Laar equation deals with the activity A. is zero co-efficients in B. increases A. binary solutions C. decreases where as the entropy B. ternary solutions increases C. azeotropic mixture only D. and entropy both decrease D. none of these 11. A refrigeration cycle is a reversed heat 5. High __________ is an undesirable engine. Which of the following has the property for a good refrigerant. maximum value of the co-efficient of A. specific heat performance (COP) for a given refrigeration B. latent heat of vaporisation effect ? C. viscosity A. Vapor compression cycle using D. specific vapor volume expansion valve. B. Air refrigeration cycle. 6. Solubility of a substance which dissolves C. Vapor compression cycle using with an increase in volume and liberation of expansion engine. heat will be favoured by the D. Carnot refrigeration cycle. A. low pressure and high temperature. B. low pressure and low temperature. 12. In a working refrigerator, the value of COP C. high pressure and low temperature. is always D. high pressure and high temperature. A. 0 B. <0 7. Entropy is a measure of the __________ of C. <1 a system. D. >1 13. __________ increases with increase in atm, containing 50 mole % each of n- heptane pressure. and n- octane into pure compounds each at 1 A. The melting point of wax atm is B. The boiling point of a liquid A. -2 RT ln 0.5 C. both (a) and (b) B. -RT ln 0.5 D. neither (a) nor (b) C. 0.5 RT D. 2 RT 14. A refrigerator may be termed as a A. heat pump 20. Keeping the pressure constant, to double B. heat engine the volume of a given mass of an ideal gas at C. Carnot engine 27°C, the temperature should be raised to D. none of these __________ °C. A. 270 15. For a stable phase at constant pressure and B. 327 temperature, the fugacity of each component C. 300 in a binary system __________ as its mole D. 540 fraction increases. A. decreases 21. Entropy of an ideal gas depends upon its B. increases A. pressure C. remains same B. temperature D. decreases linearly C. both (a) & (b) D. neither (a) nor (b) 16. Which of the following is not an intensive property? 22. Isobaric process means a constant A. Chemical potential process. B. Surface tension A. temperature C. Heat capacity B. pressure D. None of these C. volume D. entropy 17. Out of the following refrigration cycles, which one has the minimum COP (Co-efficient 23. No work is done by the system, when a of performance)? reaction occurs at constant A. Air cycle A. volume B. Carnot cycle B. temperature C. Ordinary vapour compression cycle C. pressure D. Vapour compression with a reversible D. none of these expansion engine 24. If the vapour pressure at two 18. Measurement of thermodynamic property temperatures of a solid phase in equilibrium of temperature is facilitated by with its liquid phase are known, then the __________ law of thermodynamics. latent heat of fusion can be calculated by the A. 1st A. Maxwell's equation B. zeroth B. Clayperon-Claussius equation C. 3rd C. Van Laar equation D. none of these D. Nernst Heat Theorem
19. The theoretical minimum work required to
separate one mole of a liquid mixture at 1 25. The freezing point of a liquid decreases C. no gas can be liquified above the when the pressure is increased, if the liquid critical temperature, howsoever high __________ while freezing. the pressure may be. A. contracts D. the molar heat of energy of gas at B. expands constant volume should be nearly C. does not change in volume constant (about 3 calories). D. either (a), (b) or (c) 31. Linde gas liquefaction process employs 26. "At the absolute zero temperature, the cooling entropy of every perfectly crystalline A. by throttling substance becomes zero". This follows from B. by expansion in an engine the C. at constant pressure A. third law of thermodynamics D. none of these B. second law of thermodynamics C. Nernst heat theorem 32. Pick out the wrong statement pertaining D. Maxwell's relations to the decomposition of PCl5 represented by, PCl5 PCl3 + Cl2.Degree of dissociation of PCl5 27. During Joule-Thomson expansion of gases will A. enthalpy remains constant. A. decrease on addition of Cl2. B. entropy remains constant. B. increase on addition of an inert gas at C. temperature remains constant. constant pressure. D. none of these. C. decrease on increasing the pressure of the system. 28. The accentric factor of a materical, 'ω', is D. none of these defined as ω = -log10(Prsat)Tr-1 = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced 33. Joule-Thomson experiment is temperature. The value of accentric factor is A. isobaric always B. adiabatic A. >2 C. isenthalpic B. <1 D. both (b) & (c) C. >1 D. <3 34. Boyle's law for gases states that A. P ∝ 1/V, when temperature is 29. Degress of freedom at triple point will be constant. A. 0 B. P ∝ 1/V, when temperature & mass B. 1 of the gas remain constant. C. 2 C. P ∝ V, at constant temperature & D. 3 mass of the gas. D. P/V = constant, for any gas. 30. "Law of corresponding states" says that A. Two different gases behave similarly, 35. 1st law of thermodynamics is nothing but if their reduced properties (i.e. P, V the law of conservation of and T) are same. A. momentum B. the surface of separation (i. e. the B. mass meniscus) between liquid and vapour C. energy phase disappears at the critical D. none of these temperature. 36. In a reversible chemical reaction (where, 41. Equilibrium constant decreases as the Δx = number of moles of products-number of temperature moles of reactants ) A. increases, for an exothermic A. addition of inert gas favours the reaction. forward reaction, when Δx is positive. B. decreases, for an exothermic reaction. B. pressure has no effect on equilibrium, C. increases, for an endothermic when Δn = 0. reaction. C. addition of inert gas has no effect on D. none of these. the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) 42. The expression, , gives or zero). the free energy change D. all 'a', 'b' & 'c' A. with pressure changes at constant temperature. 37. Out of the following refrigeration cycles, B. under reversible isothermal volume which one has maximum COP ? change. A. Air cycle C. during heating of an ideal gas. B. Carnot cycle D. during cooling of an ideal gas. C. Ordinary vapor compression cycle D. Vapor compression with a reversible 43. All gases during throttling process at expansion engine atmospheric temperature and pressure show a cooling effect except 38. Pick out the correct statement: A. CO2 A. In an isothermal system, irreversible B. H2 work is more than reversible work. C. O2 B. Under reversible conditions, the D. N2 adiabatic work is less than isothermal work. 44. Compressibility factor for almost all the C. Heat, work, enthalpy and entropy are gases are approximately same at the all 'state functions'. same D. Matter and energy can not be A. pressure and temperature. exchanged with the surroundings in a B. reduced pressure and reduced closed system. temperature. C. critical pressure and critical 39. In any spontaneous process, temperature. A. only F decreases D. none of these. B. only A decreases C. both F and A decreases 45. Pick out the wrong statement. D. both F and A increase A. Activity co-efficient is dimensionless. B. In case of an ideal gas, the fagacity is 40. Which of the following is a thermodynamic equal to its pressure. property of a system ? C. In a mixture of ideal gases, the A. Concentration fugacity of a component is equal to B. Mass the partial pressure of the C. Temperature component. D. Entropy D. The fugacity co-efficient is zero for an ideal gas. 46. The co-efficient of performance (COP) of a C. Otto engine efficiency decreases with refrigerating system, which is its index the rise in compression ratio, due to of performance, is defined as the ratio decrease in work produced per of useful refrigeration to the net quantity of heat. work. The units of __________ and D. Diesel engine normally operates at COP are the same. lower compression ratio than an Otto A. kinematic viscosity engine for an equal output of work. B. work C. temperature D. none of these
47. The chemical potential of a component
(μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of sustance added for an infinitesimal addition at constant temperature and pressure. It is given by
A.
B.
C.
D. all (a), (b) and (c)
48. In jet refrigerators, the refrigerating fluid
is practically always A. water B. ammonia C. freon D. brine
49. Water on heating from 1 to 4°C
A. contracts B. expands C. has same volume D. may contract or expand
50. Pick out the correct statement.
A. Compression ratio of an Otto engine is comparatively higher than a diesel engine. B. Efficiency of an Otto engine is higher than that of a diesel engine for the same compression ratio.
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