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parity (  , inversion) and time-


Experimental observation of Weyl points reversal symmetry (  )—isolated
Weyl points only exist when at
least one of  or  is broken.
Ling Lu,1* Zhiyu Wang,2 Dexin Ye,2 Lixin Ran,2 Liang Fu,1 In Ref. (13), frequency-isolated
John D. Joannopoulos,1 Marin Soljačić1 Weyl points were predicted in
1 2
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. Laboratory of Applied  -breaking DG photonic crys-
Research on Electromagnetics, Zhejiang University, Hangzhou, 310027, China. tals. In our experiment, we chose
*Corresponding author. E-mail: E-mail: linglu@mit.edu to break  instead of  to
The massless solutions to the Dirac equation are described by the so-called avoid using lossy magnetic ma-
Weyl Hamiltonian. The Weyl equation requires a particle to have linear terials and external magnetic
dispersion in all three dimensions (3D) while being doubly degenerate at a fields. This choice also allows
single momentum point. These Weyl points are topological monopoles of our approach to be directly ex-
quantized Berry flux exhibiting numerous unusual properties. We tended to photonic crystals at
performed angular-resolved microwave transmission measurements optical wavelengths.
through a double-gyroid photonic crystal with inversion-breaking, where In Fig. 1B, we plotted the
Weyl points have been theoretically predicted to occur. The excited bulk body-centered-cubic (bcc) Bril-

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states show two linear dispersion bands touching at four isolated points in louin zone (BZ) of the  -
the 3D Brillouin zone, indicating the observation of Weyl points. This work breaking DG shown in Fig. 1C.
paves a way to a variety of photonic topological phenomena in 3D When  is preserved, there
must exist even pairs of Weyl
points (13). The two pairs of
In 1929, Hermann Weyl derived (1) the massless solutions to
Weyl points illustrated in the (101) plane of the BZ, in Fig.
the Dirac equation—the relativistic wave equation for elec-
1B, are thus the minimum number of Weyl points possible.
trons. Neutrinos were thought, for decades, to be Weyl fer-
The band structure plotted in Fig. 1D shows two linear
mions until the discovery of the neutrino mass. Moreover, it
band-crossings along Γ − N and Γ − H ; the other two Weyl
has been suggested that low energy excitations in condensed
points have identical dispersions due to  . The four Weyl
matter (2–12) can be the solutions to the Weyl Hamiltonian
points are well separated in the momentum space, making
H (k ) = vx k xσ x + v y k yσ y + vz k zσ z , where vi and ki are the
their characterization easier.
group velocities and momenta and σ i are the Pauli matri- We work at the microwave frequencies around 10 GHz,
ces. Recently, photons have also been proposed to emerge as where fabrication of 3D photonic crystals is more accessible.
Weyl particles inside photonic crystals (13). In all cases, two Additive processes like 3D printing cannot yet fulfill the
linear dispersion bands in 3D momentum space intersect at material requirement of having low-loss dielectrics with
a single degenerate point—the Weyl point. Weyl points are high-dielectric constants. In order to fabricate two inter-
3D extensions of the 2D Dirac cones as in graphene, pos- penetrating gyroids with a subtractive fabrication process,
sessing unique density of states and transport properties we open up each gyroid network by layers along the [101]
(14). Remarkably, Weyl points are monopoles of Berry flux direction with equal thickness of a / 2 . Here a is the cubic
with topological charges defined by the Chern numbers (4, lattice constant. The defects are introduced in each layer of
5). These topological invariants enable materials containing the red gyroid in Fig. 1C.
Weyl points to exhibit a variety of unusual phenomena in- We approximate each gyroid network by three sets of
cluding topological surface states (15), chiral anomaly (16), hole-drillings, as illustrated in Fig. 2A. Similar methods of
quantum anomalous Hall effect (17) and others (18, 19). Fur- drilling and angled etching have been used in the fabrica-
thermore, Weyl points are the intermediate topological gap- tion of 3D photonic crystals in the microwave (21) and near
less phases between topologically distinct bandgap infrared wavelengths (22). The three cylindrical air holes of
materials (20), facilitating the search for other topological
the blue gyroid, along x , y and z , go through (0,1/ 4, 0)a ,
phases in 3D. In this work, we report on the observation of
Weyl points in an inversion-breaking 3D double-gyroid (DG) (0, 0,1/ 4)a and (1/ 4, 0, 0)a respectively. All air holes have a
photonic crystal without breaking time-reversal symmetry. diameter of 0.54 a . Gyroids approximated by this drilling
Weyl points are sources of quantized Berry flux in the approach have almost identical band structures as those
momentum space (supplementary text). Their charges can defined by the level-set iso-surfaces in Ref. (13).
be defined by the corresponding Chern numbers of ±1 (Fig. The second (red) gyroid is the inversion counterpart of
1A). So, Weyl points robustly appear in pairs and can only the blue gyroid. To break  , we shrink the red gyroid at
be removed through pair annihilation. Since the Berry cur- (1 / 4, −1 / 8,1 / 2)a to be a cylinder oriented along [101] .
vature is strictly zero under  symmetry—the product of Shown in Fig. 2B, the defect cylinder has a diameter of 0.1a

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and height of 0.2a . We separate the red gyroid by cutting contact with the opposite surfaces of the sample (Fig. 3A);
(101) planes at the centers of the defect cylinders. The blue the prisms are made of the same material as the sample (
gyroid, without introduced defects, is separated at the cor- ε = 16 ).
responding position of (−1 / 4,1 / 8, −1 / 2)a . Each layer is Both the source and receiving antennas were linearly po-
larized. To account for the complex polarization response in
a / 2 thick. The separated layers of each gyroid are identi- the 3D  -breaking photonic crystal, we summed up the
cal up to translations of a 2 (the bcc lattice vector in Fig. 1C). transmitted power of different polarizations to resolve more
One unit vertical period of DG consists of two layers from bulk states in the sample. Illustrated in Fig. 3A, the electric-
each gyroid (Fig. 2B). field directions of the s and p polarizations are vertical
The material of choice are slabs of ceramic-filled plastics and parallel to the incident plane respectively. We first set
(C-STOCK AK from Cuming Microwave) of dielectric con- the source antenna to be in one of the polarization states
stant 16 and loss tangent 0.01. Each slab has a thickness of (say s ), and measured the transmitted power twice by set-
9.5 mm ( = a / 2 ). Both the width and the length of the ting the receiving antenna to be s and p polarized respec-
slabs are 304 mm ( ~ 12 inches). The material hardness is tively. The sum of the two transmitted signals was
adjusted between 80 to 90 on a Shore D gauge to be ma- normalized to the transmission signal without the sample.
chined by carbide tools without cracking. Each layer experi- Secondly, we set the source antenna to be the other polari-
enced around 700 drillings along ± 45° away from its zation (say p ) and repeated the above procedure. Lastly, we

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surface normal (in x and z ) and about 40 ball-end millings summed the transmission power for both polarizations and
in-plane (in y ) on both top and bottom surfaces. These op- plotted it in Fig. 3C. For details, see figs. S2 and S3.
erations were performed using a computer-numerical- We map out all 3D bulk states, projected along [101], by
controlled three-axis vertical milling machine (fig. S1A). Alt- varying θ and α as shown in Fig. 3, A and B. Six transmis-
hough all slabs of the same gyroid can in-principle be ma- sion data of representative directions ( α ) are plotted in Fig.
chined together, we processed no more than two layers at 3C. The transmission data stop on the right slanted bounda-
the same time to leave a solid frame for handling. About ry, which corresponds to the maximum rotation angle in θ .
20mm were left undrilled from each of the four edges of the Close to this boundary, the transmission intensity is low due
slabs. We subsequently cut two sides of the frames of each to the smaller effective cross-section of the samples at large
gyroid for their assembly (fig. S1B). Figure 2B illustrates the angles. For comparison, the corresponding band structures
layers of the two gyroids were offset vertically by half of the (projected along the transmission direction [101]) are plot-
slab thickness (4.25 mm). A picture of the assembled sample ted as figure insets. In principle, all states in the projected
is shown in Fig. 2C (more pictures in fig. S1, C and D). The band structure can be observed in the transmission data,
final sample in measurements consists of a total of 20 lay- where the transmission amplitudes are proportional to the
ers, with 10 layers from each gyroid stacked in alternating bulk density of states. However, the coupling and transmis-
order. sion efficiencies depend on the details of the Bloch mode
We performed angle-resolved transmission measure- polarizations, modal symmetries, radiation lifetimes, finite
ments on the photonic crystal sample to probe the disper- size effects, group velocities and the Berry curvature in-
sions of the 3D bulk states (23–25). The schematic of the duced anomalous velocities. Although the signal strength
experimental setup is shown in Fig. 3A (also see fig. S1E). A varies in some areas in the experimental data, all the trans-
pair of lens antennas were placed on the two sides of the mission responses (Fig. 3C) compare very well and are con-
sample. Transmission amplitudes (S21) were recorded by sistent with the theoretical band structures in the insets.
the network analyzer. The half-power beam widths (diver- When α = 90 (in Fig. 3), the beam scans through the
gent angles) of the lens antennas were 9  . The collimated upper Weyl point along Γ − H represented by a magenta
beam impinged on the sample (101) surface, in which the sphere in Fig. 3B. The outline of the transmission intensity
incident angle is varied by rotating the sample around the in Fig. 3C clearly shows a linear point crossing around
vertical axis. As illustrated in Fig. 3B, the component of the 11.3GHz in frequency and close to 0.45(2π / a ) in wavevec-
incident wavevector parallel to the sample surface [ k0 sin(θ ) tor. As α increases from 90° to 105° and 120°, we are mov-
] is conserved up to a reciprocal lattice vector of the sample ing off the Weyl point and observe the opening of a small
lattice, due to the discrete translational symmetry. All the gap. This gap-opening is expected for a point degeneracy
bulk states of the same wavevector projection (dashed line and excludes the possibility of the state being associated
in Fig. 3B) and frequency could be excited in the bulk and with a line degeneracy [line-node (13)]. Since photons do
exit the sample in the same direction as the incident beam. not have spin or polarization degeneracies in our crystal,
The exiting signal was collected by the antenna at the oppo- every band dispersion represents a single state—excluding
site side. A pair of prisms were used to increase the magni- the possibility of being a four-fold 3D Dirac degeneracy (26).
tudes of the incident wavevectors for sampling a larger Due to the aspect ratio of our sample, we were unable to
volume in the BZ. We placed the angled prisms (12.4°) in scan the dispersions along the [101] transmission direction.

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ACKNOWLEDGMENTS
We thank Andrew Gallant and Ernest Johnson at MIT central machine shop for
machining the gyroid layers. We thank Yichen Shen, Zhang Bin, Junwei Liu, Bo
Zhen, Bingnan Wang, Ashvin Vishwanath, Hongsheng Chen, Qinghui Yan and
Chen Fang for discussions. We thank Paola Rebusco for critical reading and
editing of the manuscript. J.J. was supported in part by the U.S.A.R.O. through
the ISN, under Contract No. W911NF-13-D-0001. L.F. was supported by the DOE
Office of Basic Energy Sciences, Division of Materials Sciences and Engineering
under Award No. DE-SC0010526. L.L. was supported in part by the MRSEC
Program of the NSF under Award No. DMR-1419807. M.S. and L.L. were
supported in part by the MIT S3TEC EFRC of DOE under Grant No. DE-
SC0001299. Z. W, D. Y and L.R were supported by the Chinese National Science
Foundation (CNSF) under grant 61401395, 61401393 and 61131002,
respectively.
SUPPLEMENTARY MATERIALS

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Supplementary Text
Figs. S1 to S3
Date Accepted

15 February 2015; accepted 6 July 2015


Published online 16 July 2015
10.1126/science.aaa9273

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Fig. 1. Weyl points in the BZ of a  -breaking gyroid photonic crystal.
(A) Weyl points are monopoles of Berry flux in the momentum space. (B) The
BZ of the DG photonic crystal in (C). The (101) surfaces are highlighted in green.
Four Weyl points are illustrated on the green (101) plane along Γ − H and Γ − N ,
where H = (0,1, 0)2π / a and N = (−1 / 2, 0,1 / 2)2π / a . (C) The bcc cell of the DG
with a  -breaking defect on the red gyroid, where a1 = (−1,1,1)a / 2 ,
a=
2 (1, −1,1)a / 2 , =
a3 (1,1, −1)a / 2 and a is the cubic lattice constant. (D) The
photon dispersions are plotted along the N − Γ − H . The Weyl points are the
linear band-touchings between the 4th-and 5th bands.

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Fig. 2. Fabrication of gyroids by drilling periodic holes along the x , y and z directions.
(A) Illustration in a bcc unit cell that a single gyroid structure can be approximated by drilling
air-holes. (B) The double-gyroid structure can be made by stacking layers along the [101]
direction. The red and blue gyroids, being inversion counterparts, inter-penetrate each other.
We shrink the vertical connections of the red gyroid to thin cylinders in order to break  .
(C) Left: A total of 20 layers were stacked. Right: A zoom-in view from the top with a ruler (in
centimeters) in the background.

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Fig. 3. Transmission measurement results. (A) Schematic of the microwave transmission setup. (B) The
bulk states in the sample are excited by the incident wavevector parallel to the sample surface varied by the
angle θ . (C) Transmission data, summed over both s and p polarizations, as the sample is rotated along
the [101] axis by the angle α . The insets show the calculated band structures projected along [101] ; they
are scaled to the same range and ratio as the measured data.

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Experimental observation of Weyl points
Ling Lu, Zhiyu Wang, Dexin Ye, Lixin Ran, Liang Fu, John D. Joannopoulos and Marin Soljacic

published online July 16, 2015

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