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Refractory Design Increases Rotary Kiln Efficiency

by W. F. Rochow and W. C.Burke

Numerous designs of linings and accessories, including dams, lifters, and heat ex-
changers, contribute greatly to kiln efficiencies. Greater conductivity is achieved with
basic brick than with fireclay and high-alumina refractories, depending largely upon the
use of steel plates in radial joints between adjacent brick to increase heat transfer through
the lining. Refractory lifters expose all portions of the load to radiant or convective heat
and raise some portions to higher temperatures by cascading the load down through the
path of the hot gases.

MONG the many factors involved in rotary kiln


A efficiency, advantageous use of refractories is
of major importance. So far as kiln lining alone is
concerned durability is most significant, as shut-
downs for repairs are costly in fuel consumption
and production losses. Aside from selection of re-
fractories best suited to the widely varying condi-
tions under which rotary kilns are operated, lining
design and accessory constructions within the kiln
are highly important.
The refractory most economical for any combina-
tion of operating conditions can be selected from a
wide range of alumina-silica and basic refractories,
including insulating, castable, and plastic fire bricks.
In several cases silica brick can be used to advantage.
Alumina contents of alumina-silica refractories
range from 35 to 9 0 pct in increments of 5 to 1 0 pct.
In general, bricks of relatively low alumina content
are best for abrasion resistance, an important prop-
erty for the brick used in chain sections of cement
kilns or in feed end sections of limestone kilns.
High-duty fireclay bricks of approximately 4 0 pct
alumina and 55 pct silica are used to line the inter-
mediate zones. Super-duty fireclay brick at slightly
higher cost is warranted in operation of kilns with
high intermediate zone temperatures and severe
spalling conditions.
Alumina-silica refractories with an alumina con-
tent of 5 0 pct and higher, termed high-alumina o
0 400 800 1200 1600 2000 2400 2800
brick, are available in commercial classes of 50, 60, TEMPERATURE OF
70, 80, 85, and 9 0 pct alumina content. These refrac-
tories are generally used as high temperature zone Fig. 1-Approximate thermal conductivity curves. I-Hard-
linings or placed adjacent to the basic brick-lined fired magnesite. 2--Chemically bonded magnesite-chrome,
sections when the treatment they are required to 3-Magnesium silicate. 4-70 pct AI,O,. 5-60 pct Al,Oa.
5-Super-duty fire clay. fire clay.
withstand is excessively severe.
Use of basic refractories is confined mainly to
zones of maximum temperature and most severe chemical action. Basic refractories ordinarily em-
ployed for high temperature zone linings of many
W. F. ROCHOW, Member AIME, is Assistant to the President rotary kilns comprise the classes shown in Table I.
and W . C . BUAKE with the Technical Sales Dept., Harbison- Each class is peculiarly well suited to various par-
Walker Refractories Co., Pittsburgh, Pa. ticular combinations of working conditions.
Discussion on this paper, T P 3988BH, may be sent ( 2 copies) to The approximate chemical analyses of tKese
A l M E before M a y 31, 1955. Mansucript. M a y 5. 1954. New York classes also illustrate differences in compositions
Meeting, February 1954. with respect to the major components.

TRANSACTIONS A l M E M A R C H 1955, M I N I N G E N G I N E E R I N G 2 8 5

This page o f Minzng Transactions AIME f o l l o w s p. 1 7 6 . T h e inter-


vening non-Transactions pages appeared in Mining Engineering.
thick serve more economically than those 9 in.
thick, which of course cost proportionateljr more.
This may be explained by the fact that a coating
forms on the lining. With basic refractory linings
especially, such coatings are exceedingly desirable,
even though appreciable cost is involved in removal
when they become excessively thick or when large

Table I. Approximate Chemical Analyses of Refractories, Pct

Class SiOz A1?03 F e c 0 ~ CaO MgO Cr?Oy

-..2mically bonded magne-


site-chrome
Hard-fired magnesite-
chrome
Hard-fired magnesite-
chrome (natural calclum
silicate bond)
Hard-fired rnagnesite-
chrome (Mg0-A1203
s ~ i n ebond)
l

rings develop. The coatings provide valuable in-


sulation and protect the lining against severe de-
structive conditions. Interruptions in operation for
refractory maintenance most frequently are neces-
sitated by the consumption of the high temperature
zone linings. It is in this zone that the coatings,
when not excessive, are most desirable. Often spe-
cial procedures and practices are followed to cause
the kiln product to adhere to the lining and build
up to an optimum thickness. In the high tempera-
ture treatment of refractory dolomite and magne-
Figs. 2a and 2b-Lining of kiln interiors before and after a site for dead burning a small amount of iron oxide
typical accretion build-up which obstructs the flow of the added to the charge helps promote a satisfactory
charge. Appreciable cost is involved in removal. coating. In some cases preheating the lining close to
the operating temperature before introducing the
Among the classes of basic refractories are those charge has helped to accomplish the same results.
consisting predominantly of chrome. There has been Formation of coatings may be caused by various
only limited experience with these in rotary kiln phenomena. When not of such severity as to result
applications. in a fluid slag, chemical reaction between the charge
Since a comprehensive review of the properties and the lining can promote an accretion accumula-
of refractories commonly used in rotary kilns is tion. Coatings can also be formed without appreci-
largely outside the scope of this discussion, refer- able fluxing of the lining, as in the clinker of cer-
ence is made only to those of particular significance tain mixes and the sintering of iron ore. In lime
to this subject. On the assumption that the refrac- kilns the ash of pulverized coal used for fuel often
tories used in the kiln lining will render reasonably accounts for development of the coatings and rings
long life, the physical properties of interest in this in the burning zones.
connection are those having to do mainly with heat Conversely, under some circumstances, disad-
losses. Primarily this concerns thermal conduc- vantages far outweigh the benefits derived from
tivities of the refractories. To evaluate this property
it is necessary to consider, for example, the forma-
tion of coatings and the necessity of using steel
plates or casings for basic brick installations.
Thermal conductivity curves for several types
and classes of refractories commonly used in rotary
kiln linings are shown in Fig. 1.
In the burning of lime, in several instances,
magnesite brick and periclase brick are used beyond
the burning zone limits solely for the purpose of
securing the maximum degree of purity of lime for
exacting chemical requirements.
As illustrated by the curves, Fig. 1, basic brick
refractories have higher conductivities than do the
fireclay and high-alumina refractories. Moreover,
the successful performance of basic liners is largely
dependent upon the use of steel plates in the radial
joints between adjacent brick. This practice in-
creases the transfer of heat through the lining. De-
spite these facts, it has been determined by experi- Fig. 3-An example of desirable coating, which provides
ence at many rotary kiln plants that linings 6 in. valuable insulation and protects the lining.

286-MINING ENGINEERING, M A R C H 1955 TRANSACTIONS AlME


Fig. 4 (left)-Refractory radial blocks provided with a recess for insertion of insulating material. Fig. 5 (center)-A design offer-
ing more complete insulation. Fig. 6 (right)-An example of right-angle cross tile construction.

coatings. Serious interruptions may be necessary this type are relatively strong, they are abraded
for their removal. The coatings and rings can be- excessively by movement of the hard refractory
come of such magnitude that the kiln must be shut lining with which they are in contact. When this
down, with resulting loss of production time. happens the refractory bricks become loose and
Figs. 2a and 2b are pictures of kiln interiors ultimately fall out. However, prefired diatomaceous
showing the lining before and after a typical accre- earth insulating brick produced abroad has been
tion build-up which obstructs the flow of the regarded as suitable for this application, mainly at
charge to the extent of necessitating a shutdown. cement plants in Europe and Canada. Although it is
Fig. 3 is an example of a desirable coating. strong, it is not friable, and when subjected to pres-
Special kiln designs, boring machines, carbon sure and abrasive action, the surface in contact with
dioxide bombs, various types of guns, and carefully the hard refractory brick tends to compress slightly
controlled operations help reduce the difficulty.to a rather than to abrade away.
reasonable minimum. Table I1 presents temperature gradients and heat
Insulation: At several plants it has been the prac- losses based on thermal conductivity data and cal-
tice to insulate basic refractory linings with fireclay culated in accordance with the empirical formula
brick because of the difficulty experienced in build- commonly used. The temperature of 2200°F at the
ing and maintaining coatings. without a substantial hot face was used in the calculations, as it was con-
-
coating or adeauate insulation the shell became
overheated, owing to the relatively high conduc-
sidered most representative of a wide range of
operations.
tivity of the basic brick. A 3-in. thick course of In recent years, at a number of cement plants, in-
radial fireclay bricks laid in a close fit against the sulating fire bricks have been used for the lining
shell provides the insulation. Upon this is super- proper in kiln sections beyond the burning zones.
imposed a 6-in. magnesite brick lining with 16-gage They have been in service for several years, and
steel sheets in the radial joints. Insulating fire there is every indication that they can be expected
bricks are not used because they are not strong to last much longer. These linings are directly ex-
enough to resist the abrasion resulting from any
movement of the refractory linings.
Except perhaps in a few unusual cases, insulation
of the high temperature zones of rotary kilns holds
little promise of success. On the other hand, many
kiln linings are insulated beyond the burning zones
with measurable savings. The waste heat from ro-
tary kilns sometimes is utilized for steam generation
and other purposes and the economies resulting
from insulation of the kiln lining can be deter-
mined with some degree of accuracy. In the case of
kilns operated with concurrent feed and fuel input,
especially when endorthermic reactions are in-
volved, there can be little doubt about the value of
insulation. However, the operation of kilns with
insulated linings must be controlled closely to
benefit fuel efficiency and production rate and to
avoid merely increasing the stack temperature.
Block insulation has been used extensively for
kiln lining in applications where the interface tem- Fig. 7-Shown here are de-
perature is not high enough to cause shrinkage of tails of several refractory
shapes for cross tiling.
the insulation. Successful use of this material is
based on its slight compressibility and its capacity
to withstand the pressure imposed upon it. In most
cases rigid insulating fire bricks placed between the
kiln shell and the refractory lining have had to be
replaced prematurely. While insulating bricks of

TRANSACTIONS AlME MARCH 1955, M I N I N G E N G I N E E R I N G 2 8 7


SECTION 6-0 SECTION A - A

Fig. &This construction, which provides greater stability against forward thrust, is now being tried in two kilns, one for calcin-
ing refractory clays and the other for hard-firing dolomites.

Table I I . Calculated Temperature Gradients and H e a t Losses. Table I l l . Comparison of Physical Properties of Firebrick
H o t Face a t 2200°F -- -~
26000F
Light-weight, Class
Heat Loss, Properties High-duty High-duty Insulating
Btu ---
Temperature Per Sq
Refractory Gradient, OF F t P e r Hr Weight, lb per cu f t 130 to 140 60 to 65 45 to 50
Modulus of rupture, psi 1000 to 1500 500 to 700 140 to 230
Cold crushing strength, psi 2000 to 3500 700 to 1000 150 to 250
Pyrometric cone equivalents 32 to 32% 700 to 1000 150 to 250
6-in., high duty, with 2%-in. block
insulation
9-in., high-duty, with 2%-in. block
insulation
6-in., high-duty
of which Fig. 5 is a typical construction. However,
9-in., high-duty under certain circumstances there may be merit in
4%-in., lightweight, high-duty
9-in., high-duty using insulated rotary kiln blocks with the cutout
4Y2-in. insulating brick because of the greater stability of the lining, Fig. 6.
6-in., high-duty
Accessory Refractory Constructions as Factors of
Efficiency: As governed by the functions and vari-
posed to the mix flowing over them. The fine dust ous operating factors, kiln efficiencies are greatly
has only a negligible abrasive effect and the bricks benefited by the use of chains (with wet charges),
are strong enough to withstand pressures to which preheaters, metallic lifters, and other devices. Use
they are subjected. The important physical proper- of equipment made of metals is limited to relatively
ties of light-weight fire brick suitable for linings as low temperatures.
compared with those of dense fireclay brick are To accomplish the desired reactions in rotary
illustrated by the data in Table 111. kilns most effectively, it is necessary that the charge
Several trial installations on a relatively small be brought into intimate contact with the hot gases
scale have been made with refractory radial blocks and with the radiated heat from the refractory lin-
provided with a recess for the insertion of an insu- ings and other brickwork within the kilns. In gen-
lating material. This design is illustrated in Fig. 4. eral the accessory constructions can be regarded as
A lining of this kind is a compromise and cannot be baffles of one type or another. Various designs of
as effective as the more nearly complete insulation, lifters, dams, and pocket arrangements are used.

B-" SECTION A - A SECTION 6 - B


ELEVATION

Fig. 9-111 this design for a high-duty refractory smaller shapes are used than in the construction shown in Fig. 8. Tiles are pro-
vided with tongues and grooves bonded together by overlapping joints. Heat-resisting tubes are used for reinforcement.

288-MINING ENGINEERING, M A R C H 1955 TRANSACTIONS AlME


Quadrant Dividers: Over the past 10 years there
has been considerable experience with a right-
angle cross tile construction, now in use in about 30 Fig. 10-Preheater
rotary kilns. At a number of plants various designs construction using
were installed in different locations in kilns of 8, 9, tongue and groove
and 9 % f t diam. Figs. 6 and 7 are drawings of two shapes. The individ-
designs of these cross tiles; Fig. 7 shows the details ual shapes, shown
of several refractory shapes used. inset a t right, are
These large quadrant tiles are made in lengths up 5 15/16 x 11 15/16
x 3 in. thick.
to 4% ft in the high-duty fireclay class of refrac-
tories, which has given longest service of the several
classes tried. Up to the present this arrangement
has been used only in limestone, dolomite, and
marine shell calcining kilns. It is obvious that suc-
cessful application will be limited by kiln diafneter.
The maximum for this dimension remains to be de-
termined. Maintenance costs have been particularly
high in kilns of largest diameters. A design which
may prove to be better than others with respect to
frequency and magnitude of repairs has the advan-
tage of better stability against the forward thrust.
Fig. 8 shows this construction, a t present being tried
in two kilns, one for calcining refractory clays and
the other for hard-firing dolomite. Fig. 9 shows a
design built with smaller shapes provided with
tongues and grooves bonded together by overlap-
ping joints. Heat-resisting tubes are used to provide
reinforcement.
Some years ago a rotary dolomite calcining kiln and the charge, and greater internal refractory sur-
was equipped with a quadrant construction as face for the radiation of heat to the product.
shown in Fig. 10. Rectangular tiles having double Available data on fuel savings and increased pro-
tongues and grooves were used. During the several duction resulting from the quadrant installations
years of service no repairs were necessary. Data on vary widely. Conservatively, typical figures may
fuel consumption and the tonnage produced are not be regarded as 10 pct reduction in fuel consumption
available. and 10 pct higher tonnage.
Quadrant tile heat exchanger sections of lime- In appraising the value of this refractory acces-
stone kilns generally are 20 to 30 f t long. Both sory, it is necessary to take into consideration
longer and shorter sections have been tried, and several factors, such as correct kiln loading, reduc-
this average range, at least tentatively regarded tion of ring formation, and improvements in other
as optimum, is based on some appreciable experi- operating variables, achieved with the use of
ence. In some cases it has been considered best to quadrant dividers.
install them at a distance of about 30 ft from the Dams: Among the refractory accessory construc-
feed end, while in others they are used in the mid- tions in any type of rotary kiln, probably the most
dle of the kiln, extending toward the feed end. widely used is the dam. For efficient operation,
Pending the availability of more definite informa- regardless of the product being processed, all the
tion, generalization such as this cannot be avoided. material must be subjected to the proper time tem-
The accomplishments of the quadrant divider perature treatment. However, the rotary kiln is a
resulting in measurable economies may be briefly material conveyor as well as a heat processing unit,
summarized as improved mixing of the charge, in- and a large portion of the material, particularly the
creased contact between the more turbulent gases finest portion, comes to the top of the load only to

I I
Figs. 11 and 12-Dams are usually built with standard rotary kiln blocks in a corbelled (upper view) or stepped arrangement
(lower view) to a predetermined height. Some dams are built with special shapes, differing only in that the sides are cbmnfered
to g k e a smwth cohtour to the dam so that flow df material will not be reericted.

TRANSACTI'ONS A I M E MARCH 1955, M I N I N G ENGINEERING-289


Figs. 13, 14, and 15-A typical lifter arrangement consisting simply of longitudinal ribs is shown a t left. More intricate patterns
are shown in the sections center and right.
--

a slight extent during its travel through the kiln. tain extent by the use of refractory lifters, which
It is important that the entire charge, including this expose a portion of the load to a higher temperature
submerged portion, be p r o p ~ r l yheated. -This c3n be by lifting it up and then cascading it down through
accomplished in some ca<es by the install'afion of the path of the hot gases. In addition, the refractory
one or more dams, which increases the retention lifters break up the segregation of the particles and
time necessary to heat the entire load mme'uni- expose all portions of the load to the radiated and
formly. A series of dams will provide a uniform convected heat.
depth of load throughout the length of the kiln. Several types of refractory lifter arrangements
Dams also help retard surging of materials which are in use in various rotary kiln operations. Most
tend to flow nonuniformly throughout the length of are simply longitudinal ribs, either straight or spi-
the kiln. To control the velocitv of gas and air thev raled. Fia. 13. Some of the lifters constructed with
are freauentlv built at feed ends of the kilns. thus sDecial refractorv" s h-a* ~ e sform intricate att terns in
securing best combustion conditions and highest the lining. Figs. 14 and 15 illustrate two of these.
thermal efficiency. See Figs. 11 and 12. These lifter components are built of the class and
Lifters: Highest thermal efficiency could be ob- type of refractory best suited for the particular zone
tained only if each particle of the charge could be of the kiln and the prevailing temperature condi-
brought into direct contact with the hot gases. tions. However, the refractory lifter blocks are
However, the charge always stays at the lowest subjected to abnormally severe conditions because
part of the kiln and the hot gases pass over it. the portion of a block that protrudes above the
Moreover, the load or charge takes a set pattern in lining proper is exposed on more than one surface.
its journey through the kiln, the coarse particles Consequently the lifters are subjected to more se-
revolving around the fines. Therefore, some method vere thermal spalling conditions and abrasive action
of mixing the charge with the hot gases and stirring than are the bricks in the lining proper. Because of
it as it moves down the kiln would add greatly to this the maintenance costs in many cases outweigh
the thermal efficiency. This has been done to a cer- the value of the fuel saving.
Checkerboard or Waffle-Type Lifter: Of the sev-
eral types of lifter patterns that have been used,
one has special merit. This is shown by Fig. 16. It
consists simply of a series of staggered pockets in
the lining formed by two brick shxpes. The size of
the pockets desired naturally determines whether
standard or special sizes are needed. In the case of
standards, 9x6~4-in. and 9x9~4-in. rotary kiln
blocks are alternated in adjacent rings in such a
manner as to form pockets up to 9x4 in. and 3 in.
deep. The pockets retain the material as it flows
down the kiln, lift it up, and-then cascade it down
through the path of the hot gases. This action im-
proves the mixing of the charge and p r e v e ~ t spar-
ticle segregation.
With this construction, many sheftcomings of the
usual type of refractory lifters are avoided, and the
spalling conditions imposed upon the brick are re-
duced to a minimum. Since this pattern does per-
mit straightline flow of material through the kiln,
abrasion of brick by the charge is considerably less
than is the case with lifters, which project inward
from the face of the lining.
Fig. 16-The checkerboard or waffle-type lifter consists of Greatest experience with this pocket type con-
a series of staggered pockets in the lining formed by alter- struction has been in the hottest zones of zinc re-
nate' use.of two brick shape& one of which' is considerably covery kilns in which the charge may become
thicker than the other. somewhat viscous, similar to putty.

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