Professional Documents
Culture Documents
Lean burn engines – by adjusting the carburetor the ratio of air:fuel can be altered. The higher the ratio the less carbon
monoxide emitted as more ____________________________________ occurs. Unfortunately, this produces higher
temperatures so more NOx is produced. At lower ratios ________________________ but
___________________________ will be emitted.
Catalytic converter – the hot exhaust gases are passed over a catalyst of platinum, rhodium or palladium. These fully
oxidize _________ and unburned ____________, and also catalyze the rxn between CO and NO.
Acid Deposition
Acid deposition refers to the process by which acidic particles, gases and precipitation leave the atmosphere. Both wet
deposition (________________________________) and dry deposition (_________________________________) occur.
Rain is naturally _________________ because of dissolved __________, but acid rain has a pH of < ______.
True “acid deposition” is caused by oxides of nitrogen and oxides of sulfur.
The oxides can react with water in the air to form sulfurous acid and sulfuric acid:
The nitrogen dioxide then reacts with water to form nitric acid and nitrous acid:
Lakes and rivers – increased levels of aluminum ions in water can kill fish. Aquatic life is also highly sensitive to pH.
Below pH 6 the number of sensitive fish, such as salmon and minnow, decline as do insect larvae and algae. Snails
cannot survive a pH less than 5.2 and below pH 5.0 many microscopic animal species disappear. Below pH 4.0 lakes are
effectively dead. The nitrates present in acid rain can also lead to eutrophication.
Buildings – stone, such as marble, that contains calcium carbonate is eroded by acid rain. With the sulfuric acid the
calcium carbonate reacts to form calcium sulfate, which can be washed away by rainwater thus exposing more stone to
corrosion. Salts can also from within the stone that can cause the stone to crack and disintegrate.
Human health – the acids formed when NOx and SOx dissolve in water irritate the mucus membranes and increase the
risk of respiratory illness, such as asthma, bronchitis and emphysema. In acidic water there is more probability of
poisonous ions, such as Cu2+ and Pb2+, leaching from pipes and high levels of aluminum in water may be linked to
Alzheimer’s disease (the jury is still out on this one).
…or by the reaction of water vapor with oxygen free radicals that are formed when ozone decomposes.
The hydroxyl radicals then react directly with NOx and SOxin the presence of water to give the dissolved acids.
SMOG
Two types:
1. Oxidizing smog: “___________________________________________________” – result of NOX rxns in the
presence of UV light (occurs in dry sunshine). This is responsible for the brown cloud of LA.
2. Reducing smog: “pea soup smog” – result of carbon particulates and sulfur dioxide (occurs in cold, damp
weather). Creates yellow-green smog --- due to env. controls, largely a thing of the past (thank goodness!!!)
Thermal Inversions: occur when the normal temperature gradient is ______________________ (temp. with altitude).
Photochemical Smog (today’s air pollution problem) - caused by traffic exhaust fumes
Free radical rxns between __________________________,__________________ and __________________.
5
IB Option E Environmental Chemistry
6
IB Option E Environmental Chemistry
chlorodifluormethane
Flammable
HFCs Good refrigerant
Greenhouse gases
1,1,1,2-tetrafluoroethane
Flammable
hydrocarbons Good refrigerant
Greenhouse gases
2-methylpropane
Part 3: Water
8
IB Option E Environmental Chemistry
________________________________________: too much of a good thing - killing a lake with excess nutrients
o Excess nitrates (from artificial fertilizers) and phosphates (from artificial fertilizers and detergents) accumulate in
lakes.
o These nutrients cause CRAZY growth of algae.
o Excessive algal growth kills all life in the lake.
o Too much decaying algae, insufficient DO, products of anaerobic decay poison life in the lake (plus it blocks the
light from penetrating beneath the surface of the water), leading to more decay, etc.
N NO3-
H H2O
S SO42-
P PO43-
Thermal Pollution
Water that is removed from rivers by power stations can be returned with a temperature increase of up to 20C.
Concentration of D.O. _____________________________ with rising temperature.
Oxygen in water may be insufficient for fish to survive.
Metabolic rate of organisms increases with temp., placing additional demand for _____________________ in the water.
Spawning, fertilization and hatching of eggs, is very sensitive to temperature.
Thermal pollution can be reduced by trickling water through a porous material and blowing air in the opposite direction..
The heat is transferred to the____________ where it is less damaging.
9
IB Option E Environmental Chemistry
o Heavy metals
o Ions in polluted water may include cadmium, mercury, lead, chromium, nickel, copper and zinc.
Table 7: Sources and hazards of some heavy metals
Metal Sources Health hazard Environmental hazard
Paints, batteries, Causes severe damage to the Biomagnification up food chain;
agriculture nerves and the brain. causes reproductive system failure
in fish; inhibits growth and kills fish
Lead pipes, lead paint Can cause brain damage, Biomagnification up food chain;
and glazes, leaded fuel especially in young children toxic to plants and domestic
(tetraethyl lead, animals
banned in US)
Metal plating, Makes enzymes ineffective by Toxic to fish; produces birth
rechargeable batteries, replacing zinc; causes brittle defects in mice
pigments, byproduct of bones; can lead to lung and
zinc refining kidney cancer
o Pesticides
o Include insecticides, fungicides and herbicides, which kill insects, fungi and weeds respectively.
o Since they are poisonous, they can be problematic when washed off land into water.
o Example: _______(derived from old imprecise name dichlorodiphenyltrichloroethane)
pesticide introduced into environment at low levels harmless to birds and
animals (including humans), but because it is stable and fat soluble it
accumulated and became concentrated over time via ____________________
___________________________. Has been banned in many countries because
it had disastrous effects on bird life.
o Dioxins
o Group of compounds whose structure consists of two benzene rings connected via one or two oxygen
atoms. Each benzene ring can have up to four chlorine atoms.
o 2,3,7,8-tetrachlorodibenzodioxin (a.k.a. “dioxin”) is _______ times more poisonous than the cyanide ion.
o Sources: one of the herbicides present in Agent Orange used during the Vietnam war, and also forms
when waste materials containing organochloro-compounds are not incinerated at high enough
temperatures. Accumulate in ___________ and liver cells and therefore persist in environment.
o Symptoms of exposure include cirrhosis of the liver, damage to the heart and memory and depression.
Also causes malfunctions in fetuses.
10
IB Option E Environmental Chemistry
Waste Water Treatment - Purpose: remove _________________________ materials, reduce ____________ and kill
______________________________ before the water is returned to the environment.
Primary treatment:
1. ______________________________: waste water passed through screens and grids to filter out debris.
2. ______________________________: water is then passed into a sedimentation tank where it is allowed to
settle.Resulting sludge is removed from the bottom of the tank.
Tertiary treatment:involves specialized chemical, biological or physical processes which further treat the water and
removeremaining organic material, heavy metals, phosphates and nitrates by chemical or biological processes.
Precipitation: Heavy metals such as Cd, Pb and Hg can be removed as sulfide salts, which have low solubility.
Ion exchange: all nitrates are soluble and are thus more difficult to remove. Resins or zeolites can be used to exchange the nitrate ions in
polluted water with hydroxide ions. Positive ions can also be exchanged with H+ ions. The resulting OH- and H+ will then combine for
form water.
Biological methods: algal ponds can also be used to remove nitrate ions by using the nitrate ions as nutrients which are then converted
back into atmospheric nitrogen.
Activated carbon bed method: activated carbon consists of tiny carbon granules with large surface area which have been treated and
activated by high temperatures. Activated carbon readily adsorbs organic chemicals from the water.
Waste
Table 7: Methods of Waste Disposal
Method Advantages Disadvantages
Landfill Efficient method to deal with large volumes Local residents may object to new sites
Filled land can be used for building or other Once filled, needs time to settle, and may
community purposes require maintenance as methane released
Open Dumping Inexpensive Causes air and ground water pollution
Convenient (for the dumper) Health hazard: encourages rodents and insects
Unsightly
Ocean Dumping Source of nutrients Danger to marine animals
Convenient and inexpensive Pollutes the sea
Incineration Reduces volume Expensive to build and operate
Requires minimal space Can cause pollutants, e.g. dioxins, if inefficiently
Produces stable, odor-free residue burned
Can be used as a source of energy Requires energy
Recycling Provides a sustainable environment Expensive
Difficulty in separating different materials; not
possible in all cases
12
IB Option E Environmental Chemistry
Table 8: Recycling
Material Description Comments
Metals Mainly aluminum and steel. The metal are sorted, then Particularly important for metals such as
melted and either reused directly or added to the aluminum, which require large amounts
purification stage of metals formed from their ores of energy to produce directly from ore
Paper Taken to the plant, sorted in grades. Washed to remove Energy required to transport. Composting
inks, etc., made into a slurry to form new types of paper, may be as efficient.
such as newspaper and toilet rolls.
Glass Sorted by color, washed, crushed, then melted and Glass is not degraded during the recycling
molded into new products process, so can be recycled many times
Plastics Industrial plastic is already sorted, but household waste Fewer pollutants formed, and energy
plastic must first be sorted. Degraded to monomers by used to recycle rather than to make from
pyrolysis, hydrogenation, gasification, and thermal crude oil. Better to reuse than to recycle.
cracking, then repolymerized
13
IB Option E Environmental Chemistry
Many metal sulfides have very low solubility products, but can still be precipitated out by bubbling other compounds
through the water, making use of the common ion effect.
14
IB Option E Environmental Chemistry
15