Gas Chromatograph Validation Report Summary

(Reproducibility)

Station : ORF Semarang Location : Semarang Cal. Date : 14 Nov'17

Tag No. : AT-102 Company : PT. Pertamina Gas Cal. Time : 02:37 PM
Model : Daniel 370XA Country : Indonesia Cal. Mode : Automatic
S/N : 728838-3

Calibration Gas In Use

General Information Concentration Response Factor

Manufacturer : PT. Surya Indotim Imex n-Hexane 0.0580 n-Heptane 5.64E+08
Cylinder No. : 17E307009 Propane 0.5100 Propane 1.94E+08
Bottle Pressure : 750 Psi i-Butane 0.1230 i-Butane 2.25E+08
Outlet Pressure : 30 Psi n-Butane 0.1630 n-Butane 2.27E+08
Sample Pressure : 30 Psi i-Pentane 0.0480 i-Pentane 2.66E+08
Certificate No. :27-05/G0610-S-50S/COA/SSS/VII/17 n-Pentane 0.0390 n-Pentane 2.64E+08
Certificate Date : 26 July 2017 (2 Years) Nitrogen 0.4360 Nitrogen 1.29E+08
Standard Use : Gravimetric Methane 95.9300 Methane 9.51E+07
CO2 1.4430 CO2 1.41E+08
Ethane 1.2520 Ethane 1.71E+08

Total 100.0020

Gas Component Difference

6.00E+08
5.00E+08
4.00E+08
3.00E+08
2.00E+08
1.00E+08
0.00E+00
Methane Nitrogen CO2 Ethane Propane i-Butane n-Butane i-Pentane n-Pentane n-Hexane

Gas Component

ASTM
Component Test 1 Difference Test 2 Difference Test 3 Difference Remarks
D1945
n-Hexane 0.02 0.0583 0.0003 0.0560 0.0020 0.0553 0.0027 Pass
Propane 0.07 0.5059 0.0041 0.5104 0.0004 0.5111 0.0011 Pass
i-Butane 0.07 0.1252 0.0022 0.1255 0.0025 0.1257 0.0027 Pass
n-Butane 0.07 0.1658 0.0028 0.1662 0.0032 0.1665 0.0035 Pass
i-Pentane 0.02 0.0483 0.0003 0.0479 0.0001 0.0481 0.0001 Pass
n-Pentane 0.02 0.0405 0.0015 0.0402 0.0012 0.0401 0.0011 Pass
Nitrogen 0.07 0.4415 0.0055 0.4382 0.0022 0.4390 0.0030 Pass
Methane 0.15 95.9316 0.0016 95.9403 0.0103 95.9525 0.0225 Pass
CO2 0.10 1.4398 0.0032 1.4380 0.0050 1.4373 0.0057 Pass
Ethane 0.10 1.2433 0.0087 1.2372 0.0148 1.2245 0.0275 Pass

Total 100.0002 99.9999 100.0001

Remarks :

Perform By Witnessed By Witnessed By

PT Ansi Mega Instrumenindo Konsorsium Wika Rabana Kelsri PT. Pertamina Gas / PMC
 Gas Chromatograph Validation Report Summary
(Repeatability)

Station : ORF Semarang Location : Semarang Cal. Date : 14 Nov'17

Tag No. : AT-102 Company : PT. Pertamina Gas Cal. Time : 02:37 PM
Model : Daniel 370XA Country : Indonesia Cal. Mode : Automatic
S/N : 728838-3

Calibration Gas In Use

General Information Concentration Response Factor

Manufacturer : PT. Surya Indotim Imex n-Hexane 0.0580 n-Hexane 5.64E+08
Cylinder No. : 17E307009 Propane 0.5100 Propane 1.94E+08
Bottle Pressure : 750 Psi i-Butane 0.1230 i-Butane 2.25E+08
Outlet Pressure : 30 Psi n-Butane 0.1630 n-Butane 2.27E+08
Sample Pressure : 30 Psi i-Pentane 0.0480 i-Pentane 2.66E+08
Certificate No. :27-05/G0610-S-50S/COA/SSS/VII/17 n-Pentane 0.0390 n-Pentane 2.64E+08
Certificate Date : 26 July 2017 (2 Years) Nitrogen 0.4360 Nitrogen 1.29E+08
Standard Use : Gravimetric Methane 95.9300 Methane 9.51E+07
CO2 1.4430 CO2 1.41E+08
Ethane 1.2520 Ethane 1.71E+08

Total 100.0020

Gas Component Response Factor

6.00E+08
5.00E+08
Response Factor

4.00E+08
3.00E+08
2.00E+08
1.00E+08
0.00E+00
Methane Nitrogen CO2 Ethane Propane i-Butane n-Butane i-Pentane n-Pentane n-Hexane
Gas Component

ASTM
Component Test 1 Difference Test 2 Difference Test 3 Remarks
D1945
n-Hexane 0.01 0.0583 0.0023 0.0560 0.0007 0.0553 Pass
Propane 0.04 0.5059 0.0045 0.5104 0.0007 0.5111 Pass
i-Butane 0.04 0.1252 0.0003 0.1255 0.0002 0.1257 Pass
n-Butane 0.04 0.1658 0.0004 0.1662 0.0003 0.1665 Pass
i-Pentane 0.01 0.0483 0.0004 0.0479 0.0002 0.0481 Pass
n-Pentane 0.01 0.0405 0.0003 0.0402 0.0001 0.0401 Pass
Nitrogen 0.04 0.4415 0.0033 0.4382 0.0008 0.4390 Pass
Methane 0.10 95.9316 0.0087 95.9403 0.0122 95.9525 Pass
CO2 0.07 1.4398 0.0018 1.4380 0.0007 1.4373 Pass
Ethane 0.07 1.2433 0.0061 1.2372 0.0127 1.2245 Pass
0 0.07 0.0000 0.0000 0.0000 0.0000 0.0000 Pass
Total 100.000 100.000 100.000

Remarks :

Perform By Witnessed By Witnessed By

PT Ansi Mega Instrumenindo Konsorsium Wika Rabana Kelsri PT. Pertamina Gas / PMC
                                              Final Calibration Report

Date‐Time :  11/14/2017 02:54:11 PM  Analysis time :    230.00 sec     Cycle Time       :   240.00 sec  
Stream    :  Calibration             Mode          :    Forced Calib   Cycle Start Time :   11/14/2017 02:37:55 PM
Analyzer  :  728838 3                Stream Seq.   :    1

Firmware Revision, Checksum :  1.1.2, 2015/06/11, 0x54b705b3
Calibration Certificate Details :                                                    

Component Name         Cal Conc.        Old RF        New RF  *    RF %    Old    New  *    RT %    RF %  *  RF‐  *  
                                                                   Dev.     RT     RT       Dev.    Dev.     Ord     
                                                                                                    from      er     
                                                                                                   Ideal             
                                                                                                                     
C6+ 47/35/17            0.058%               0   5.63525e+08  *    0.00   31.6   31.5  *   ‐0.38   80.26  *   11     
Propane                  0.51%    1.883235e+08  1.944826e+08  *    3.27   45.7   45.9  *    0.35    2.48       5     
i‐Butane                0.123%    2.106101e+08  2.253002e+08  *    6.97   56.2   56.1  *   ‐0.14    0.00       6     
n‐Butane                0.163%    2.113383e+08  2.265688e+08  *    7.21   63.0   63.0  *    0.00    2.36       7  *  
Neopentane                  0%               0             0       0.00   70.4   70.4       0.00  100.00  *    8     
i‐Pentane               0.048%    2.545773e+08  2.655241e+08  *    4.30   88.1   87.6  *   ‐0.54    3.44       9  *  
n‐Pentane               0.039%               0  2.639288e+08  *    0.00  101.1   98.2  *   ‐2.87    0.36      10     
Nitrogen                0.436%    1.605087e+08  1.290345e+08  *  ‐19.61  134.6  134.6  *   ‐0.03    7.85  *    2     
Methane                 95.93%    9.574991e+07  9.510528e+07  *   ‐0.67  139.6  139.4  *   ‐0.11    0.00       1     
Carbon Dioxide          1.443%               0  1.414041e+08  *    0.00  173.7  172.9  *   ‐0.45    1.47       3     
Ethane                  1.252%    1.560823e+08  1.714857e+08  *    9.87  203.0  204.4  *    0.71    7.20  *    4     

                                                                                                                     
"*" indicates RTs and RFs were updated, or RF % Devs from Ideal were out‐of‐limit, or RF orders were out‐of‐order.
"RT" = Retention Time
"RF" = Response Factor

ACTIVE ALARMS       
Alarm Name                                                              Alarm State

ANALOG INPUTS       
Analog Input                    Value                 
                                                      
Analog Input 1                  0.000                 

                                                      
 Analysis(GPA)_Nov_14_2017_14_55_39.txt
                                       Analysis Report (GPA)

Date‐Time :  11/14/2017 02:54:40 PM  Analysis time :    230.00 sec    Cycle Time        :  
240.00 sec  
Stream    :  Calibration             Mode          :    Analysis      Cycle Start Time  :  
11/14/2017 02:47:16 PM
Analyzer  :  728838 3                Stream Seq.   :    1
Company   :  EPM ASIA PACIFIC     

Firmware Revision, Checksum :  1.1.2, 2015/06/11, 0x54b705b3

Component Name              Mole Percent   Dry Gross     Dry Net      Relative  
                                                 BTU         BTU   Gas Density  
                                                                                
C6+ 47/35/17                   0.0558%          2.95        2.73        0.0018  
Propane                        0.5112%         12.89       11.86        0.0078  
i‐Butane                       0.1227%          4.00        3.69        0.0025  
n‐Butane                       0.1623%          5.31        4.90        0.0033  
Neopentane                     0.0000%          0.00        0.00        0.0000  
i‐Pentane                      0.0466%          1.87        1.73        0.0012  
n‐Pentane                      0.0393%          1.58        1.46        0.0010  
Nitrogen                       0.4309%          0.00        0.00        0.0042  
Methane                       95.9490%        971.33      874.57        0.5315  
Carbon Dioxide                 1.4522%          0.00        0.00        0.0221  
Ethane                         1.2301%         21.82       19.96        0.0128  

TOTALS                       100.0000%       1021.74      920.90        0.5880  

'*' indicates user‐defined components             

Compressibility Factor (Z) @  14.73000 PSIA and 60.0 Deg.F = 0.99787

Base Pressure                          14.73000 PSIA
‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐
Gross Dry BTU                   =     1023.9273 Corrected for Z    
Net Dry BTU                     =      922.8737 Corrected for Z
Real Relative Density Gas       =        0.5890
Total Unnormalized Mole Percent =       100.037

ACTIVE ALARMS       
Alarm Name                                                              Alarm State

ANALOG INPUTS       
Analog Input                    Value            
Analog Input 1                  0.000            

                                                 

USER CALCULATIONS   

Page 1
 Analysis(GPA)_Nov_14_2017_14_56_38.txt
                                       Analysis Report (GPA)

Date‐Time :  11/14/2017 02:55:39 PM  Analysis time :    230.00 sec    Cycle Time        :  
240.00 sec  
Stream    :  Calibration             Mode          :    Analysis      Cycle Start Time  :  
11/14/2017 02:51:16 PM
Analyzer  :  728838 3                Stream Seq.   :    1
Company   :  EPM ASIA PACIFIC     

Firmware Revision, Checksum :  1.1.2, 2015/06/11, 0x54b705b3

Component Name              Mole Percent   Dry Gross     Dry Net      Relative  
                                                 BTU         BTU   Gas Density  
                                                                                
C6+ 47/35/17                   0.0544%          2.88        2.67        0.0018  
Propane                        0.5104%         12.87       11.84        0.0078  
i‐Butane                       0.1236%          4.03        3.72        0.0025  
n‐Butane                       0.1631%          5.33        4.92        0.0033  
Neopentane                     0.0000%          0.00        0.00        0.0000  
i‐Pentane                      0.0465%          1.87        1.73        0.0012  
n‐Pentane                      0.0389%          1.56        1.45        0.0010  
Nitrogen                       0.4299%          0.00        0.00        0.0042  
Methane                       95.9232%        971.07      874.34        0.5313  
Carbon Dioxide                 1.4501%          0.00        0.00        0.0220  
Ethane                         1.2599%         22.35       20.44        0.0131  

TOTALS                       100.0000%       1021.96      921.10        0.5880  

'*' indicates user‐defined components             

Compressibility Factor (Z) @  14.73000 PSIA and 60.0 Deg.F = 0.99787

Base Pressure                          14.73000 PSIA
‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐
Gross Dry BTU                   =     1024.1439 Corrected for Z    
Net Dry BTU                     =      923.0750 Corrected for Z
Real Relative Density Gas       =        0.5891
Total Unnormalized Mole Percent =       100.111

ACTIVE ALARMS       
Alarm Name                                                              Alarm State

ANALOG INPUTS       
Analog Input                    Value            
Analog Input 1                  0.000            

                                                 

USER CALCULATIONS   

Page 1
 Analysis(GPA)_Nov_14_2017_15_00_40.txt
                                       Analysis Report (GPA)

Date‐Time :  11/14/2017 02:59:42 PM  Analysis time :    230.00 sec    Cycle Time        :  
240.00 sec  
Stream    :  Calibration             Mode          :    Analysis      Cycle Start Time  :  
11/14/2017 02:55:28 PM
Analyzer  :  728838 3                Stream Seq.   :    1
Company   :  EPM ASIA PACIFIC     

Firmware Revision, Checksum :  1.1.2, 2015/06/11, 0x54b705b3

Component Name              Mole Percent   Dry Gross     Dry Net      Relative  
                                                 BTU         BTU   Gas Density  
                                                                                
C6+ 47/35/17                   0.0542%          2.87        2.66        0.0018  
Propane                        0.5102%         12.87       11.84        0.0078  
i‐Butane                       0.1225%          3.99        3.68        0.0025  
n‐Butane                       0.1628%          5.32        4.91        0.0033  
Neopentane                     0.0000%          0.00        0.00        0.0000  
i‐Pentane                      0.0468%          1.88        1.74        0.0012  
n‐Pentane                      0.0392%          1.58        1.46        0.0010  
Nitrogen                       0.4314%          0.00        0.00        0.0042  
Methane                       95.9293%        971.13      874.40        0.5314  
Carbon Dioxide                 1.4536%          0.00        0.00        0.0221  
Ethane                         1.2501%         22.17       20.29        0.0130  

TOTALS                       100.0000%       1021.81      920.96        0.5880  

'*' indicates user‐defined components             

Compressibility Factor (Z) @  14.73000 PSIA and 60.0 Deg.F = 0.99787

Base Pressure                          14.73000 PSIA
‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐‐
Gross Dry BTU                   =     1023.9912 Corrected for Z    
Net Dry BTU                     =      922.9341 Corrected for Z
Real Relative Density Gas       =        0.5890
Total Unnormalized Mole Percent =       100.151

ACTIVE ALARMS       
Alarm Name                                                              Alarm State

ANALOG INPUTS       
Analog Input                    Value            
Analog Input 1                  0.000            

                                                 

USER CALCULATIONS   

Page 1
 CGM #1 - 728838 4 Stream=4 Det=1 2017-11-14 2:11:33 PM "Live.xcgm Trace 1 file"
100.00

139.5
90.00

80.00

70.00

60.00

50.00
Amplitude

46.3

40.00
34.6

30.00

173.2
20.00

205.2
63.6
56.7

10.00
134.6
88.8

99.3

0.00

-10.00
0.00 23.00 46.00 69.00 92.00 115.00 138.00 161.00 184.00 207.00 230.00
Time (s)