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Maximum pozzolan
allowed in Portland
Cement by country
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More US Experience
Wagner 1946 Oregon tuff
Ricement: 1924 Lousiana Mc Daniel 1946
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EFFECT OF CALCINATION ON
NATURAL POZZOLANS
1. Volcanic glass
2. Opal
3. Clay
3a.. Kaolinite-type clay
3b.. Montmorillonitetype clay
3c.. Illite-type clay
3d.. Mixed clay with vermiculite
4. Zeolite
5. Hydrated oxides of aluminum
6. Nonpozzolan
Mielenz, R., Witte, L. & Glantz, O. in Symposium on Use of Pozzolanic
Materials in Mortars and Concretes (eds. Stanton, T. & Blanks, R.) 4343
50 (ASTM International, 1950).
Effect of
Calcination
500C
Mielenz, R., Witte, L. & Glantz, O. in Symposium on Use of Pozzolanic Materials in Mortars and Concretes
(eds. Stanton, T. & Blanks, R.) 434350 (ASTM International, 1950).
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Temperature of calcination
400-800C Removal of OH
Peak temperature: type of binding OH;
Peak shape and range: cristalinity, particle size,
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Effect of Calcination
45
40 Kaolinite Ilite Montmorilonite
BET surface area (m/g)
35
30
25
20
15
10
5
0
0 200 400 600 800 1000
Temp C
Temperature of calcination
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Pozzoanic reaction:
CH consumption by TG
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Quarcione et all. Rev. IBRACON Estrut. Mater. v.8 no.1 Feb. 2015
http://dx.doi.org/10.1590/S1983-41952015000100002
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Mechanical Strength
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Cement production
Mixed in the concrete
Pozzolan: (in volume)
30-40% mass concrete
15-20% structural concrete
Water demand in comparison ref. cement
~120% (cement paste)
<110% cement mortar
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Andriolo, F.R. A Utilizao da Pozolana na Construo do Conjunto Hidroeltrico de Urubupung. Centrais Eltricas de So Paulo
S.A. Abril. 1975. Fonte: http://www.andriolo-eng.com/images/publicacoes/P003.pdf , consultada em junho de 2015.
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Jupia Dam
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Votorantim Calcined
Clay line (Porto Velho)
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Jirau Dam
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4000
kt/year
3000
2000
1000
0
1990 1995 2000 2005 2010 2015
http://www.wbcsdcement.org/GNR-2011/Brazil/GNR-Indicator_317-Brazil.html
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Innovation on Calcined
Clay
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Limestone consumption
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Thank you!
VMJohn@usp.br
Rafael.Pileggi@poli.usp.br
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