Hallar la ecuacin cintica para los siguientes modelos de rx:

a) Rx: 2A + B Productos, de primer orden para el reactante A y se segundo

orden para el reactante B

2A + B Productos
aA + bB Productos

a = 2 y b = 1 (Coeficientes estequeometricos)

1 d[A] 1 d[B]
v= . = . = k[A][B]2
a dt b dt

1 d[B]
v == . = k[A][B]2
b dt

d[B]
v= = bK[A][B]2
dt

Se sabe que:

[B] [B]0 b
=
[A] [A]0 a

a a
[A] = [B]+[A]0 [B]0
b b

a a
v = d[B] = bk ( [B] + [A]0 [B]0 ) . [B]2
b b

d[B]
a a = bkt
[B]2 . ([A]0 [B]0 + [B])
b b

[B] t
d[B]
= bkdt
[B] 2 . ([A] a [B] + a [B])
[B]0 0 b 0 b 0

Ahora igualamos:
a
p = [A]0 [B]0
b
a
s=
b
[B] = x
 dx 1 s p + sx
= + ln ( )
x 2 (p+ sx) px p x

Se resuelve por el mtodo de fracciones parciales:

1 c d e c(p + s[B]) + d(p + s[B]). [B] + e[B]2
= + + =
[B]2 (p + s[B]) [B]2 [B] p + s[B] [B]2 (p + s[B])

Por lo tanto, se tiene que cumplir que:

c(p + s[B]) + D(p + s[B]). [B] + e[B]2 = 1, es decir:

cp = 1 1 s s2
cs + dp = 0 c= , d = 2, e= 2
p p p
ds + e = 0

Sustituyendo c, d y e tenemos que:

1 1 s s2
= +
[B]2 (p + s[B]) p[B]2 p2 [B] p2 (p + s[B])

[B] [B] [B] [B] t

d 1 d[B] s d[B] s sd[B]
2
= 2 + 2 = bkdt
[B] (p + s[B]) p [B] p [B] p p + s[B]
[B]0 [B]0 [B]0 [B]0 0

1 1 1 s [B] s p + s[B]
( + ) 2 . ln ( ) + 2 . ln ( ) = bkt
p [B] [B]0 p [B]0 p p + s[B]0

Donde:
a a
p + s[B] = [A]0 [B]0 + [B] = [A]
b b
a a
p + s[B]0 = [A]0 [B]0 + [B] = [A]0
b b

Por lo tanto:
1 1 1 s [B] s [A]
( + ) 2 . ln ( ) + 2 . ln ( ) = bkt
p [B] [B]0 p [B]0 p [A]0
 1 1 1 a [A][A]0
. [( )+ . ln ( )] = kt
b[A]0 a[B]0 [B]0 [B] b[A]0 a[B]0 [B][B]0

1 1 1 a [A]. [B]0
. [( )+ . ln ( )] = kt
b[A]0 a[B]0 [B]0 [B] b[A]0 a[B]0 [B]. [A]0

1 1 1 a [A]. [B]0
kt = ( )+ . ln ( )
b[A]0 a[B]0 [B]0 [B] b[A]0 a[B]0 [B]. [A]0

Si: a = 2, b = 1
1 1 1 2 [A]. [B]0
kt = ( )+ . ln ( )
[A]0 2[B]0 [B]0 [B] [A]0 2[B]0 [B]. [A]0