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Abstract
In the present paper, it was aimed to determine the percentage of ammonia present in an
unknown ammonium salt; may it correspond to: chloride, nitrate or sulfate of ammonium. The
process was performed by retro-titration, also in the process the method was used, knows as
Kjedahl Method, and both are used macro-analytical technique as micro-analytical technique;
the latter method is specific for the determination of ammonia. After to the obtaining of
experimental data, calculations were performed with their due statistical treatment, in macro-
analytical technique and micro-analytical technique, to compare with theoretical data
obtained by stoichiometry technique, we concluded that the unknown ammonium salt
corresponded to ammonium nitrate.
Resultados
3 ( )
% 3 = 100
% 1+% 2+% 3+% 4
4
22.1227% + 20.9634% + 21.7994% + 22.2283%
3 ( )
% 3 = 100
% 1+% 2+% 3+% 4
) + + +
53.45g 100%
17g X
X1 = 31.8%
) + + +
80g 100%
17g X
X2 = 21.25%
) + + +
132g 100%
2(17)g X
X3 = 25.75%
= 0.829
=
MACROTITULACIN
20.9634% 21.7994%
=
22.2283% 20.9634%
= 0.661 < ( )
MICROTITULACIN
23.7709% 22.7410%
=
23.7709% 20.0296%
= 0.275 < ( )
H0: 1 = 2
H1: 1 2
Macrotitulacin Microtitulacin
% p/p del NH3 % p/p del NH3
Media ( ) 21.7785 21.7846
Rango (R) 1.2649 3.7413
Desviacin estndar (s) 0.5732 1.7654
Varianza () 0.3285 3.1167
Lmite de confianza (L.C) 21.7785 0.7021 21.7846 2.1626
Elaborado por Tapia y otros.
Ttab = 2.45
95%N.C.
g.l = n1+n2-2 = 6
(1 1)12 (2 1)22
=
1 + 2 2
(4 1)0,3285 (4 1)3,1167
= = 1,1807
4+42
1 2
=
1 1
+
1 2
21.7785 21.7846
=
1 1
1.18074 + 4
1
b) 0,3124 3 100,09 3
3
1 56,08
1 3
1
=
0,1750 Tomada por: David Mollocana
0,1750
% = 100
0,3448
Imagen 3. Soluciones sin titular (izquierda)
= 50,76 %
y titulada (derecha) de la sal de amonio.
40,08
c) 0,3124 3 100,09 =
3
0,1251
0,1251
% = 100
0,3448
= 36,28 %
Bibliografa