sistema ETANOL AGUA PROCESO ISOBARICO P=760 Pmm Hg 760

ECUACION DE ANTOINE ECUACION DE MARGULES

A B C A12 A21
ETOH 8.04494 1554.3 222.65 0.6848 0.3781
H2O 7.96681 1668.21 228

X1 X2 PVP1 PVP2 log Gama1 Log Gama2 Gama1 Gama2

0.0001 0.9999 1689.06249 759.983043 0.68460172 9.914387E-09 4.83728548 1.00000002
0.1 0.9 1046.61475 462.468179 0.5050026 0.0093016 3.19891426 1.02164873
0.2 0.8 906.120957 398.265303 0.3597568 0.0347528 2.28958515 1.08331012
0.3 0.7 853.425055 374.283024 0.2453822 0.0726732 1.75947135 1.18215167
0.4 0.6 824.840018 361.297967 0.1581984 0.1193824 1.43945602 1.31638341
0.5 0.5 803.700883 351.706632 0.094525 0.1712 1.2431542 1.48320097
0.6 0.4 786.014701 343.689577 0.0506816 0.2244456 1.12378078 1.6766623
0.7 0.3 771.976927 337.331346 0.0229878 0.2754388 1.05435728 1.88555324
0.8 0.2 762.807547 333.180629 0.0077632 0.3204992 1.01803615 2.09169905
0.9 0.1 759.232751 331.562947 0.0013274 0.3559464 1.00306113 2.26958473
1.00000 0 760.627522 332.194079 0 0.3781 1 2.38836116

etanol(1) - agua(2)
Presin total 101.3 kPa

TC x1 y1 x1 y1
95.50 0.019 0.1700 0.0190 0.1700 1.2000
89.00 0.0721 0.3891 0.0721 0.3891
86.70 0.0966 0.4375 0.0966 0.4375 DATOS EXPERIMENTAL
1.0000 Li near (DATOS TEORIC
85.30 0.1238 0.4704 0.1238 0.4704
84.10 0.1661 0.5089 0.1661 0.5089
82.70 0.2337 0.5445 0.2337 0.5445 0.8000
Y1

82.30 0.2608 0.5580 0.2608 0.5580

81.50 0.3273 0.5826 0.3273 0.5826 0.6000
80.70 0.3965 0.6122 0.3965 0.6122
79.80 0.5079 0.6564 0.5079 0.6564
0.4000
79.70 0.5198 0.6599 0.5198 0.6599
79.30 0.5732 0.6841 0.5732 0.6841
0.2000
78.74 0.6763 0.7385 0.6763 0.7385
78.41 0.7472 0.7815 0.7472 0.7815
0.0000
0.0000 0.2000 0.400
 0.2000

78.15 0.8943 0.8943 0.8943 0.8943 0.0000

0.0000 0.2000 0.400
CUACION DE MARGULES

T (C) y1 y2 y1+y2
100 0.001075063 0.99987771 1.00095278
86.6540061 0.440530376 0.55951582 1.0000462
82.8482716 0.545958182 0.45415246 1.00011064
81.2937828 0.592727738 0.4075283 1.00025604
80.4169204 0.624905752 0.37547893 1.00038469
79.7520826 0.657318503 0.34319185 1.00051036
79.1845827 0.69734859 0.30329019 1.00063878
78.7265433 0.74968111 0.25107482 1.00075593
78.4236015 0.817437536 0.18339832 1.00083585
78.3046748 0.901843649 0.0990145 1.00085815
78.3511315 1.000825686 0 1.00082569

X1 vs Y1
DATOS EXPERIMENTALES DATOS TEORICOS (hal l a do)
Li near (DATOS TEORICOS (ha l l ado))

00 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000

X1
00 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000
X1
1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8
 datos teori cos
Li nea r (datos teori cos)
datos experi mental es

0.6 0.8 1 1.2

sistema ACETONA METANOL PROCESO ISOTERMICO T= 55 C 55

ECUACION DE ANTOINE ECUACION DE MARGULES

A B C A12 A21
Acetona 7.02447 1161 224 0.2762 0.2877
Metanol 7.87863 1473.11 230

X1 X2 PVP1 PVP2 log Gama1 Log Gama2 Gama1 Gama2

0.0001 0.9999 729.759366 512.652385 0.27614706 2.647E-09 1.88863078 1.00000001
0.1 0.9 729.759366 512.652385 0.225585 0.00267 1.68106691 1.00616684
0.2 0.8 729.759366 512.652385 0.179712 0.010772 1.51255787 1.02511361
0.3 0.7 729.759366 512.652385 0.138719 0.024444 1.37631867 1.0578985
0.4 0.6 729.759366 512.652385 0.102744 0.043824 1.26690485 1.10617541
0.5 0.5 729.759366 512.652385 0.071925 0.06905 1.18011682 1.17233033
0.6 0.4 729.759366 512.652385 0.0464 0.10026 1.11275614 1.25967932
0.7 0.3 729.759366 512.652385 0.026307 0.137592 1.06244633 1.37275173
0.8 0.2 729.759366 512.652385 0.011784 0.181184 1.02750513 1.51769324
0.9 0.1 729.759366 512.652385 0.002969 0.231174 1.0068598 1.70284061
1.00000 0 729.759366 512.652385 0 0.2877 1 1.93954562

1.2
X1 vs Y1

0.8
Y1

0.6

0.4

0.2

0
0 DATOS
0.2 TEORICOS (ha
0.4l l a do) 0.6 Li nea r (DATOS
0.8 TEORICOS 1(ha l l a do)) 1.2
X1
CUACION DE MARGULES

P mmHg y1 y2 y1+y2
512.738948 0.0002688 0.9997312 1.0000000
586.90988 0.20902261 0.79097739 1.0000000
641.182205 0.34430253 0.65569747 1.0000000
680.948363 0.44249234 0.55750766 1.0000000
710.064351 0.52081797 0.47918203 1.0000000
731.09962 0.58897671 0.41102329 1.0000000
745.537573 0.65352378 0.34647622 1.0000000
753.854446 0.71994151 0.28005849 1.0000000
755.475007 0.79402388 0.20597612 1.0000000
748.58536 0.88338467 0.11661533 1.0000000
729.759366 1 0 1.0000000

800

700

600

500

400

300

200

100

0
0 0.2 0.4 0.6 0.8 1 1.2
DATOS
0.8 TEORICOS 1(hal l a do)) 1.2
 1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8

1.2
 datos teori cos
Li nea r (datos teori cos )
datos experi mental es

0.6 0.8 1 1.2

sistema ACETONA METANOL PROCESO ISOTERMICO T C 55
T K 328.15
Constante universal de los gases R 1.9870 cal/molK
RT 652.03405

V1 V2 12-11 12-22
Acetona - M 67.38000 44.87400 -203.03 566.99

X1 X2 V1/V2 V2/V1 12-11/RT 12-22/RT Exp- (12-11/RT)

0.0001 0.9999 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.1 0.9 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.2 0.8 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.3 0.7 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.4 0.6 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.5 0.5 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.6 0.4 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.7 0.3 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.8 0.2 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
0.9 0.1 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806
1.00000 0 1.50153764 0.66598397 -0.3113794 0.86957115 1.3653071806

1.2
X1 vs Y1
DATOS TEORICOS (ha l la do) Li near (DATOS TEORICOS (ha l la do))
1

0.8
Y1

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1
X1
 A B
Acetona 7.02447 1161
Metanol 7.87863 1473.11

12 Exp (12-22) 21 Ln(X1+12X2) x2(12/x1+12x2 -21/21x1+x2)

0.9092727 0.4191312543 0.62934135 0.0951002535 -10000.0000100
0.9092727 2.3858874511 3.58249981 0.0851816752 -10.0088915
0.9092727 2.3858874511 3.58249981 0.0753507269 -5.0156525
0.9092727 2.3858874511 3.58249981 0.065615486 -3.3536781
0.9092727 2.3858874511 3.58249981 0.055974107 -2.5230281
0.9092727 2.3858874511 3.58249981 0.0464247972 -2.0237596
0.9092727 2.3858874511 3.58249981 0.0369658148 -1.6892612
0.9092727 2.3858874511 3.58249981 0.027595467 -1.4481573
0.9092727 2.3858874511 3.58249981 0.0183121082 -1.2647846
0.9092727 2.3858874511 3.58249981 0.009114138 -1.1193513
0.9092727 2.3858874511 3.58249981 0 -1.0000000

Y1
i near (DATOS TEORICOS (ha l la do))

6 0.8 1 1.2
X1
 C A12 A21
224 0.2762 0.2877
230

ln
equilibrio liquido -liquido