Professional Documents
Culture Documents
Energy
journal homepage: www.elsevier.com/locate/energy
a r t i c l e i n f o a b s t r a c t
Article history: Replacing traditional open re stoves, characterized by low efciency, with improved ones is an
Received 12 July 2010 important challenge for developing countries. Adding TE (thermoelectric) generators can provide elec-
Received in revised form tricity that permits not only the use of an electric fan increasing the ratio air to fuel to achieve a complete
10 December 2010
combustion in the stoves but also the satisfaction of basic needs: light, phones and other electronic
Accepted 10 January 2011
Available online 18 January 2011
devices. A review of existing TE generators for stoves is presented. To test the TE modules, an experi-
mental device has been carried out in our laboratory where a gas heater simulates the stove. The
generator set-up is described including the switching electric regulator that stabilizes the uctuating
Keywords:
Thermoelectric
voltage from the modules and stores the energy in a battery. The performance of the generator mostly
Power generator depends on the heat transfer through the modules and especially on the thermal contact resistances.
Biomass stove First experiments show the inuence of the pressure on these resistances. Then a study of temperatures
Thermal energy and electrical power measurements is compared to a theoretical analysis using TE and heat transfer
Heat recovery equations. The very reasonable value of the obtained contact resistances shows that the mechanical
design of the generator is almost optimized. The TE generator has produced up to 9.5 W.
2011 Elsevier Ltd. All rights reserved.
Open res or rudimentary stoves are widely used in developing - It does not need extra energy from the stove.
countries by about 2.5 billion people [1]. These traditional stoves or - The TE generator is incorporated into the cook stove and
res are characterized by low efciency that results in inefcient use requires no electrical link with the outside world, unlike solar
of scarce fuel-wood supplies [2]. These rudimentary re stoves also panels.
lead to high emissions of health damaging air pollutants and smoke - It is silent in operation as it involves no moving parts.
is highly linked to ARI (acute respiratory infection) [3,4]. Building - The maintenance is very light: nothing moves, everything is
clean and efcient cook stoves reduces carbon dioxide and methane inside the house, only the battery needs to be changed when it
emissions while providing social and health co benets through is done for.
reduced fuel consumption and reduced indoor air pollution. - The TE generator works when the stove is on, day and night in
Improved cook stoves also have the potential to reduce signicantly good or in rainy weather (monsoon period) unlike solar panels.
black carbon emissions (short-lived non-CO2 climate warmer) [5]. The battery does not need to be oversized as each use of the
Again 1.6 billion people lack access to electricity [6]; providing stove recharges the battery unlike a solar system where it is
10 W to cover basic needs such as light and radio to these low-income necessary to store energy for cloudy days.
populations living mostly in rural areas, will require more than
16 GW power plants (resistive losses in the conductor grid) and all As this generator is destined to low-income houses in devel-
the dispatching. Individual TE (thermoelectric) generators coupled oping countries, the cost is also an important issue. Previous studies
with cook stoves are an interesting option to provide electricity. [7e9] have shown that the price per watt is about the same as for
solar systems.
The Non Governmental Organization Plante Bois develops
* Corresponding author. Tel.: 33 (0) 5 59 40 76 97; fax: 33 (0) 5 59 14 90 14.
energy-efcient multifunction mud stoves based on traditional
E-mail address: daniel.champier@univ-pau.fr (D. Champier). stove designs (Fig. 1). The wood is put into the stove vertically
0360-5442/$ e see front matter 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.energy.2011.01.012
D. Champier et al. / Energy 36 (2011) 1518e1526 1519
through the top of the pyrolysis chamber before the lid is closed. 2. Review of existing TE generators for stoves
The bottom part of the wood rests on a bed of embers maintained
through the entry of primary air at this level. Combustible gases are 2.1. TE generators
emitted as a result of decomposition by heat (pyrolysis) in the
absence of ames and sucked toward a nozzle. These gases are then TE generators directly convert a very small part of the heat go-
in contact with the oxygen from the secondary air. The ame then ing through them into electricity as described in Fig. 3. They are
breaks out downstream of the injection of secondary air. The wood composed of three parts: two heat exchangers and a TE module.
burns down so that the bed of embers is renewed. These improved The efciency of the TE module depends on the properties of the
stoves use a smoke extract fan that allows a control of the ratio air materials used for the thermocouples. For the moment semi-
to fuel and therefore optimizes the combustion. The fan also conductors offer the best efciency.
permits the use of a horizontal pipe avoiding the necessity of long The only couple of materials available on the market at
metal pipes and of building chimneys in countries where local a reasonable price is bismuth telluride (Bi2Te3). These materials can
workers do not have the technology to make it go through the roof. work at a temperature as high as 260 C continuously and inter-
These stoves are called CLIP for Combustion Latrale Inverse mittently up to 380 C. Other materials are being studied for hig-
Performante the French terms for powerful reverse side combus- her temperatures, such as clathrates, skutterudites, alloys Heusler,
tion. These types of equipment are under validation in Morocco phases of Chevrel and oxides [10] but are not commercially available.
(Fig. 2) where electricity is available. The next important challenge is
the providing of countries without electricity with this stove. 2.2. TE generators for stoves
The goal of our work is to study the feasibility of using TE modules
in this stove in order to generate electricity. The expected power is In the literature review, only the experimental studies have
about 10 W not only for the fan but also for basic needs: lighting, radio been selected. The heat generator is the hot smoke of the stove and
and charging cell phones as well as other small electronic devices. all the TE modules are made of bismuth telluride (Bi2Te3).
To test the TE modules, an experimental device has been carried Nuwayhid et al. [11] have studied the possibility of using
out in our laboratory where a gas heater simulates the stove. a proportion of the heat from 20 to 50 kW wood stoves, to provide
The rst part of this paper presents a review of existing TE a continuous 10e100 W electric power supply. In a rst prototype
generators for stoves. Then the entire generator set-up is described they used cheap Peltier modules for their TE Generator. The
including the thermal and mechanical parts as well as the maximum power for a module was very low (1 W) mostly because of
switching electric regulator which converts the uctuating voltage the limited temperature difference due to the maximum tempera-
from the TE modules into a constant voltage and stores electrical ture supported by the module and also because of the geometry
energy in a battery. After showing the inuence of the pressure on which is optimized for cooling and not for generating power. In
the contact resistance, experimental electrical power measure- a following prototype [12] their TE generator used 1, 2 or 3
ments are compared with the results of a theoretical analysis using commercially available low-cost power generator modules. The cold
TE and heat transfer equations. side of the TE modules was naturally cooled with the surrounding
1520 D. Champier et al. / Energy 36 (2011) 1518e1526
air. They got a maximum power of 4.2 W for one TE module and they heat sink [13]. The maximum power was about 3.4 W. Lertsa-
showed that the output power per module decreased when the titthanakorn [14] investigated the same type of prototype and he got
number of TE modules in the TE generator increased. This is a result a power output of 2.4 W. He added an economic analysis indicating
of the reduction of the temperature difference between the hot and that the payback period tends to be very short.
cold surfaces. They also made a TE generator using heat pipes for the Mastbergen and Wilson [7] presented at the ETHOS 2005
congress (Engineers in Technical and Humanitarian Opportunities
of Service) a prototype of TE generator with a forced air-cooling for
the cold side with a 1 W fan. The net power of 4 W generated by the
TE generator was sufcient to power an array of high intensity LEDs
(light-emitting diodes). Field tests [15] have been made in different
countries but results are not available in the literature.
BioLite [16], an industrial lightweight backpacking stove, has
been presented at the 2009 ETHOS conference. The TE generator is
only used to create clean, efcient cooking with a forced-air draft
fan for this wood burning stove.
Plante Bois and our laboratories explore water cooling cold
heat sink TE generators [8e17]. Plante Bois multifunction cook
stoves produce hot water. The best location to put the TE generator
is under the water tank as the heat ux from the hot gas to the tank
(about 30 L) can be used to produce electricity without losing heat.
So there is almost no additional energy cost. The heat exchanges
with water are generally better than exchanges with air and the use
of water guarantees that the cold heat sink temperature will always
stay under 100 C.
Recently Rinalde et al. [9] presented a forced water cooling
system. Their laboratory prototype uses an electric heater for the
heat source. They obtained a maximum power of 10 W but needed
a pump which certainly decreases the available output power.
The different prototypes are summarized in Table 1.
These results show that it is possible to obtain an electrical
power of about 10 W. However, further experiments are necessary
to study the feasibility of using thermoelectrical modules with our
stove and to improve the generated electrical power.
3. Generator set-up
Table 1
TE generators using bismuth telluride commercial modules.
At the beginning of the burning, the temperatures are very low 3.3. One-dimensional steady-state analysis
and the TE generator does not produce any electricity. The autonomy
of the cooking stove requires a battery to store the electrical energy TE modules are made of n couples of p-type and n-type semi-
produced by the TE modules and to restore it at the beginning of the conductor pellets connected with metal solder. For electrical
burning. insulation, two ceramic wafers sandwich the pellets (Fig. 5).
A lead-acid battery has been chosen because it currently offered We used the one dimensional model commonly described in
the best response in terms of price, energetic efciency, lifetime literature (1-D heat ow) of a typical TE module made of n ther-
and availability in developing countries. mocouples [21,22].
VRLA (valve regulated lead-acid) batteries have been selected as These equations are obtained from the study of a single n- or
they can be used directly in home environment; they are self- p-type element assuming that all connections between the pellets
contained and safe, they can be stored and used in any orientation are perfect: no electrical and thermal resistance.
and are maintenance free. In normal use, they are environmentally We also assume that there is no conduction, convection or
friendly. radiation via the ambient, which means that the only path to tra-
Since the fan, LEDs, radios and cell phones only need low voltage nsfer heat from one side of the pellet to the other is through the TE
and also because of availability, we have chosen 6V batteries. material. These assumptions give the following TE equations for the
The expected service life of the standard VRLA battery is typi- heat released on the cold side, qc, the heat absorbed on the hot side,
cally 5 years when used in oating voltage. For a 6 V battery the qh, and for the generated electrical power Pelec.
oating voltage is about 6.75 V. " #
The lead-acid charging process is somewhat lenient as long as it Rpn $I 2
qh n$ apn $I$Th Kpn $Tc Th ; (1)
is not overcharged, overheated, or let to form excessive gas. There 2
are different methods of charging lead-acid battery [19,20]. We
have chosen a simple but efcient method: constant voltage, " #
current limited charging. In the initial charging stage, the current Rpn $I 2
qc n$ apn $I$Tc Kpn $Tc Th ; (2)
owing into the battery is limited to a value of the maximum 2
charging current about 20% of capacity in Ah. In the second stage
the constant voltage maintains the battery in a fully charged oat h i
condition. Pelec n$ apn $I$Th Tc Rpn $I 2 ; (3)
An electrical power of about 6 W available for the battery
implies a charging current of 0.9 A. As the maximum charging where I is the current, Tc and Th are respectively the temperatures of
current is about 1/5 of the capacity, a 4.5 Ah battery is selected for the cold side and the hot side of the TE module.
our experiment. The parallel thermal conductance, Kpn, serial electrical resis-
Since the heat produced by the combustion vary a lot during the tance, Rpn, and Seebeck coefcient, apn of one thermocouple are:
use of the stove (wood supply, quality of wood, cooking) and the
temperature of the water is modied when people take or add ln Sn lp Sp
Kpn ; (4)
water, the temperatures on each side of the TE generator vary a lot. Ln Lp
As a consequence, the output voltage of the generator uctuates
a lot. A power electronic circuit is required to regulate the output rn Ln rp Lp
voltage and to boost it to the battery level. As the voltage of the one Rpn ; (5)
Sn Sp
module TE generator is low a boost regulator is necessary.
An electronic converter (Fig. 6) has been developed using a step-
apn ap an ; (6)
up switching regulator MAX642 which works in the 5 mW to 10 W
range with a very good efciency. Some electronic circuits are Ln, Lp and Sn, Sp are respectively the leg length and cross-sectional
added to limit the charging current of the battery. area of the pellets.
This electronic converter was tested with a laboratory power ap, an, ln, lp, rn, and rp are temperature dependent and are
supply. Simple tests made on a resistive load showed that the evaluated at the average temperature Ta Th Tc =2, the values
efciency stands in a range from 80% to 85% [17,18]. are taken from the Thermoelectric Handbook - Material Properties
n- and p-type Bi2Te3 [21,23].
For the selected commercial modules n 126, Lp Ln 1.4 mm,
Sn Sp 6.6 mm2.
For an electric load RE, current I can be calculated with
Eo n$apn $Th Tc
I ; (7)
nRpn RE nRpn RE
Ralb R
Tc Th3 Th3 T (11)
Rala
lal l
eb ec es al x
lceram lsolder
Tc Th3 Th3 Th4 (12)
ea
with
lal
x
hcontact
the analysis was done with ea 13.9 mm, eb 3.2 mm, ec 1 mm,
es 0.7 mm, lsolder z lal 237 W m1 K1, lceram 25 W m1 K1.
The parameter x (hcontact) will be tted by comparison between the
measured power and the calculated power.
4. Results
Fig. 7. Thermal resistance model of the thermoelectric module.
temperatures Th and Tc are calculated by using the energy conser- The temperatures, tensions, currents and pressure (Pr) applied
vation assuming that the aluminum blocks are well insulated from on the module are recorded by an Agilent 34970A Data Logger. The
the ambient: qc qsc and qh qhc. measurement system enables us to obtain a precision of 0.01% for
For example the tensions, 0.1% for the currents and 0.5 C for the temperatures.
But, because of the difculty in measuring a temperature accu-
Th4 Th3 T Tc rately, the temperature errors are evaluated to 1 C. The precision of
qc h3 ; (8) the pressure measurements is 0.25%.
Rala Ralb R
Th1, Th2, Th3, TH4, Pr and also Vout, Vbat, Ibat and IL (see Fig. 6) are
with recorded.
ea eb The output power from the TE module Pelec VTE $I and the
Rala ; Ralb (9)
lal $S lal $S available power for the end users are calculated:
Fig. 9. Measured electrical power (Pelec) as a function of the pressure for a temperature difference of 120 C.
This rst experiment shows that a choice of 500 kPa (5 bar) is This impedance RE is not exactly matched but it is possible to
a reasonable value to minimize the contact resistance. A more calculate the maximum power that would be obtained if the elec-
important value might be destructive for the delicate thick ceramic tronic convertor matched the load.
plate because of the thermal expansion during the transient states. As VTE Eo RE =RE nRpn , then Pelec can be expressed as:
2
4.2. Electrical power measurements Eo $RE 1
Pelec $ (15)
RE nRpn RE
This experiment aimed at determining the electrical power
and for a matched load
(regulated and not regulated) of the TE generator, comparing it
with the theoretical power given by the 1D model and assessing the
max Eo2
value of the thermal contact resistance. The nal goal of the Pelec (16)
4nRpn
measurements was to nd out if we got the maximum available
power from our prototype and to analyze what could be improved. The maximum power (dashed line) on Fig. 11, can be calculated
For this experiment, the complete TE generator including the by:
electronic part with a load resistor of 12 U was tested. Fig. 10 shows
2
the hot and cold side temperatures and the corresponding electrical
max RE nRpn
power for a half hour experiment. Pelec Pelec (17)
4$nRpn $RE
The TE module produced a maximum electrical power of 9.5 W
and because of losses in the electronic convertor a maximum power Then this maximum power is compared with the power
of 7.6 W was available. obtained with the 1D model for a matched load using x as tting
The resistor RE seen by the TE module can be calculated by using parameter. A value of hcontact of 20,000 W m2 K1 guarantees
the voltage and current measurements: RE VTE =I. a good matching of the two curves for different trials (variations on
Fig. 10. Cold and hot side temperatures and electrical powers during the experiment. Fig. 11. Measured electrical power and calculated maximum output electrical power.
D. Champier et al. / Energy 36 (2011) 1518e1526 1525
5. Conclusion
[13] Nuwayhid RY, Hamade R. Design and testing of a locally made loop-type [19] Yuasa Battery Sales. NP valve regulated lead acid battery manual, www.yuasa-
thermosyphonic heat sink for stove-top thermoelectric generators. Renewable battery.co.uk; 1999 [last accessed June 2010].
Energy 2005;30:1101e16. [20] Daoud A, Midoun A. Fuzzy control of a lead acid battery. Journal of Electrical
[14] Lertsatitthanakorn C. Electrical performance analysis and economic evalua- Systems 2005;1e1:52e9.
tion of combined biomass cook stove thermoelectric (BITE) generator. Bio- [21] Rowe DM. Thermoelectrics handbook macro to nano. London: CRC Press; 1996.
resource Technology 2007;98:1670e4. [22] Mitrani D, Salaza J, Tur A, Garca JM, Chavez JA. One-dimensional modeling of
[15] Joshi S, Mastbergen D, Willson B. Field testing of stove-powered thermo- TE devices considering temperature-dependent parameters using SPICE.
electric generators. Kirkland, Washington. Available at. In: Presented at the Microelectronics Journal 2009;40(9):1398e405.
ETHOS international stove research conference, www.vrac.iastate.edu/ethos/; [23] Rowe DM, Min G. Design theory of thermoelectric modules for electrical
2007 [last accessed December 2010]. power generation. IEE Proceedings: Science, Measurement and Technology
[16] URL: www.biolitestove.com/BioLite.html; [last accessed June 2010]. 1996;143(6):351e6.
[17] Champier D, Rivaletto M, Strub F. TEGBioS: a prototype of thermoelectric [24] Min G, Rowe DM. Peltier devices as generators. CRC handbook of thermo-
power generator for biomass stoves. In: Proc. of ECOS 2009 22nd international electrics. New York: CRC Press; 1995. pp. 479e488.
conference on efciency, cost, optimization, simulation, and environmental [25] Rohsenow WM, Hartnett JP, Cho YI. Handbook of heat transfer. 3rd ed.
impact of energy systems; 2009. Paran, Brazil. McGraw-Hill; 1998.
[18] Champier D, Rivaletto M, Strub F. Improving biomass stove with a thermo- [26] Eakburanawat J, Boonyaroonate I. Development of a thermoelectric battery-
electric generator. In: Proc of SDEWES 5th Dubrovnik conference on sustainable charger with microcontroller-based maximum power point tracking technique.
development of energy water and environment; 2009. Dubrovnik. Applied Energy 2006;83:687e704.