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portions); or (iii) by rational methods, in which the may be in the range of 55-60%. However, these
pozzolanic activity of the fly ash is taken into high strengths are achieved mostly by the utilisa-
account. The present state of the art regarding the tion of superplasticisers required for a substantial
use of fly ash in concrete was reported earlier. 1-3 lowering of the water content and thus water/
It can be seen that in spite of the numerous cement ratio. The present paper is not considering
earlier research efforts an exact quantitative this aspect of concretes with chemical admixtures
understanding of the contribution of fly ash to the but is an effort to evaluate only the effect of fly ash
strength of the concrete was still elusive. However, on normal concretes containing ordinary portland
it is recognised that the contribution of the fly ash cements cured under normal conditions. Informa-
is not a constant determined solely by its physical tion available in literature with fly ash replace-
and chemical characteristics like cementitious ments ranging from 15 to 75% has been
compounds, fineness, etc., but can also vary considered for an evaluation. Furthermore, differ-
depending on the nature of cement, water cement ent researchers have used specimens of varying
ratio, etc. It is also not known at present what sizes and shapes and all these have been con-
factors maximise the fly ash contribution. 4 verted to their equivalents for a cube of 15 cm size
The objective of the present effort is to answer through accepted guidelines. ~9 At this juncture, it
at least some of the questions raised earlier is important to emphasis once again that the
through a systematic evaluation of the available specific variations in the composition of fly ashes
results. In this context, it is important to note that used by different investigators has not been con-
fly ash being a silicious material will impart sidered for evaluation. Also, other parameters like
strength to the concrete through its pozzolanic fineness or even the special production and curing
action, but the pozzolanic reaction being slow fly procedures have not been included in the present
ash concretes may not be able to attain an equal study.
strength as that of the control within 28 days.
Furthermore the ashes of yester years, because of
the process of burning coal and the collection EFFICIENCY CONCEPTS
procedures of a generally much lower efficiency,
resulted in a larger fraction of the coarser parti- The efficiency of fly ash is generally defined in
cles apart from a larger proportion of unburnt terms of its strength characteristics with the con-
coal (reflected through its loss on ignition). In trol concrete as the reference. However, knowing
contrast, the fly ashes available today are resulting the improvements in durability due to the addi-
from burning powdered/pulverised coals and tions of fly ash, it is well recognised that other
from the improved collection systems like the characteristics like durability factors can also be
electrostatic precipitators of higher efficiency. In used for such an evaluation, though the exact
view of the above, only the results of the investiga- methodology of the durability test has to be
tions during the past about 10 years were chosen clearly defined. Furthermore, it is possible to
for an evaluation, s-~' All these fly ashes confirm define more than one durability factor (sulphate,
to the minimum characteristics specified by chloride, freeze-thaw, etc.) and it would be diffi-
ASTM C 618-89 for use as mineral admixtures in cult to compare or specify such a factor in codal
portland cement concrete.~ 7 provisions. Also, it is accepted, in general, that the
Early efforts regarding the use of fly ash in strength of concrete is a reasonable indicator of
concrete were mostly limited to replacements up the durability for at least the normal concretes
to a maximum of 35%, and the latest ACI Com- without any chemical modifications and the effi-
mittee recommendations I also limit the utilisation ciency of fly ash concrete is always defined with
to the same extent. This may be due to the respect to the strength of its control.
requirement of additional water for wetting the The simple replacement and modified replace-
finer fly ash which in turn increases the water ment methods were not found to be suitable for a
cement ratio resulting in a reduction of the general understanding of the behaviour of fly ash
strength. However, investigations in recent in concrete. The rational methods were expected
years 7,18 have shown that even with low cement to take into account the characteristic of fly ash
contents, high volume fly ash concretes can pro- which are known to influence the workability a n d
vide an economical material with strengths reach- strength characteristic of concrete. Smith 2 was
ing 60 MPa. Extensive laboratory investigations one of the first to propose a factor known as
indicate that the optimum percentage of fly ash cementing efficiency (k) such that a weight 'f' of
Efficiency offly ash in concrete 225
100
fly ash would be equivalent to a weight 'kf' of \ A & B - Fly ~ Concrete w.r.t, wl(c,f)
~ C & O - Fly q~h Concrete wr.t. wl(c.ket)
cement. The strength and workability of this con- \\ N - Control Concrete w.r.t, wit or
Fly ash Concrete w.r.t, wl(c,kef,kpl)
crete with fly ash is comparable to that of the so
(c + k)9]. Based on the experimental investigations ~r/~/~ - High Volume Fly ~ Concrete
~ 80 %,
and the results available, the value of the cement-
ing efficiency factor k was assessed to be 0.25.
This method was seen to be insensitive to the
cement used, curing conditions, etc., apart from
2O ke ~
the fact that it was not suitable for richer mixes. 21
Later investigations22 have shown that the fly
ash efficiency factor was a minimum of 0.3 and 0
0.20
l
0.30
t
0.40
1
0.50
I
0.60
I
0.70 0.80
I I
0.90 1.00
this value was also used in the German Concrete w/(c*~) or w / ( c . k e f ) or wl(tkel*kpf)
Standard DIN 1045. However, a more recent Fig. 1. Conceptual diagram showing the effect of efficiency
evaluation through studies on concretes contain- factors.
ing different cements and fly ashes 23 (fly ash con-
tents up to 28% and with water/cement ratios
varying between 0.5 and 0.65) has shown that a ash. Figure 1 shows the relation between the 28
value of 0.5 is more appropriate for this efficiency day compressive strengths of concrete and the
factor. These studies also indicated that with water cementitious materials ratio for normal and
increasing fly ash content the efficiency of the fly fly ash replaced concretes. As can be seen, lower
ash tends to diminish and that the efficiency of fly replacement levels (may be up to 20%) show
ash increases with decreasing water cement ratio. strengths higher than the control concrete while
It was also observed that the significant differ- replacements of higher magnitude result in con-
ences in the properties of fly ashes used (particu- cretes of lower strengths. ~ and 'B' are the two
larly fineness) influenced the compressive typical water cementitious material ratios of con-
strengths at 28 days only marginally. It was only at cretes at the higher and lower percentages of
greater ages the effect of the differing pozzolanic replacement, with that of the control concrete
reactivities of fly ashes were felt. The efficiency of being at 'N' for the same strength. The method
fly ash also did not show much variation in the now tries to bring the [w/(c+f)] ratios nearer to
range 20-28% replacements adopted. One that of the control concrete by applying the
important contribution of this work was that it cementitious efficiency of fly ash (k). Now the
defined the consequent reduction in water figure is replotted to check whether a unique
cementitious materials ratio of fly ash concrete as value of k can help in bringing both 'X and 'B' to
compared to the water cement ratio of the refer- 'N'. This means that the correction (Aw) required
ence concrete (A w concept) as can be achieved by the unique cementitious effi-
ciency (k) at all percentages of fly ash replace-
ment. However, this was not possible as the
={w/(c+ kf)}-{w/(c+ f)} percentage of replacements were far too different
=(w/c)[1/{1 + k(f/c)}- 1/{1 + (f/c)}] and the result was that while the high volume
replacements approach the control values due to
The above formulation clearly shows that this this correction the low volume replacements
reduction depends not only on the size of the effi- resulted in a slightly higher conservative estimate.
ciency factor (k), but depends additionally on the For this reason the value of k which is generally
water cement ratio and more importantly the fly applicable for all the replacement percentages is
ash content of the concrete mix. from henceforth defined as the general efficiency
factor (ke). This means that the points ~ and 'B'
now shift to their revised locations 'C' and 'D' due
EVALUATION OF EFFICIENCY to the application of the general efficiency factor
(ke) with the axis as [w/(c+ kJ)]. Thus the original
In principle the evaluation of efficiency was points ~2 and 'B' have been shifted to 'C' and 'D',
attempted by what was earlier discussed as the by a distance of A w~. The revised correction now
rational method. 20 The A w concept explained required (Aw2) was considered to be the effect of
earlier was used in evaluating the efficiency of fly the percentage replacement. To counteract this
226 K. Ganesh Babu, G. Siva Nageswara Rao
effect of the percentage replacement an additional percentages of replacement. It can now be clearly
factor kp has been evaluated for each percentage seen that while some of the concretes with
of replacement in a very similar way. These two replacements up to 25% show strengths higher
corrections together will bring the points W and than the control, while the higher percentage
'B' to 'N' so that the water/cement ratio of the replacements show a reduction corresponding to
control concrete and the water/cementitious the percentage replaced and the [ w/(c+ f)].
material ratio [w/(c+kJ+kvf)] will all be the At this stage, the authors studied the variation
same for any particular strength. of compressive strength with different general
efficiency factors (k~) ranging from 0.2 to 0.8.
From these studies it was observed that at a
RESULTS AND DISCUSSIONS general efficiency factor of 0.5 the compressive
strengths of fly ash concretes come closest to the
As already stated, the results of different inves- control as shown in Fig. 3 (with the A w~ correc-
tigators 5-16 were compiled from literature for con- tion applied). This resulted in the concretes con-
cretes containing ordinary portland cement with taining replacements up to 35% showing strengths
fly ash replacements ranging from 0 to 75%. Table slightly higher than the corresponding control and
1 presents the characteristics of fly ash and the
different percentages of replacements utilised in
the above studies. In general, it was seen that as 10o -~ *..*_*%.* 75 FA
the replacement percentage and the water cement ~" \,, U " . I I J 67 FA
k',, AA,,U~ 50 FA
ratios increase the strength of concrete decreases. ~ , ao oN,., '~,,:.~"~. 35 ~: FA
However, it was also evident that while concretes
e \\ ~o~. o o oQooo 0 FA
above 70 MPa can be produced with replace-
ments up to 25% fly ash, replacement of about
75% can still lead to concretes of 40 MPa through
suitable adjustments in water/cement ratio and "... " -. .. ,~ ~'-'~..~..
Table 1. Details of the fly ash concretes evaluated in the present investigation
loo 1.00
I *.*.lt*.J' 75 S FA
"4~, I,I ~ l J 67 ~ FA oolee 28 Days
k")'~ ~ 50 FA 0,80
'ao el', ~ e.O..,l,~,35 ~ FA
"~.~
\'~,L
=-~.~m.~ 25 ~
~.tx.l~ 15 ~
FA
FA
2 0,60
K~'~ ..... O~ FA
u. 0.40
"~ 0.20
4O
8 ~ -0.0o( 10 20 30 40 ~ 60 70 E~
Percentage Replacement "~...4L_.,____e
~ 20
~_-o.2o!
-0.40
w/(c+k.f)
Fig. 5. Variation of k v with fly ash replacement.
Fig. 3. Variation of strengths after correcting for k~.
100 1.50
|
i~ *..*-**J 75 ~ FA
LIPIlul 67 FA lllll 28 days
a.
~1.25
so ~,'J o.O.,0,e.935 FA
~, ~.q.apa 25 FA +
== ~ ~.~.A.A 15 ~ FA
~',~o a .... o ~ FA II 1 . 0 0 '
so
v
.i
0. 4C
o
0.75
o.5o
._.e
o
"~ 2C
=
0.25
o
Fig. 4. Variation of strengths after correcting for ke and kp. Fig. 6. Variation of overall efficiency with fly ash replace-
ment.
tion of efficiency of the fly ash to about 35% (0.35 ke=0.5) will result in conservative values
times). upto about 40% fly ash replacement as
Thus, the proposed method clearly distin- reported by earlier researchers.
guishes the effect of fly ash replacement in terms . The results clearly show that the strength of
of the general efficiency factor (ke) and the factor concrete decreases continuously from 100
corresponding to the percentage replacement to 35% at replacements varying from 20 to
effect (kp). It was also shown that while the general 75% respectively.
efficiency factor (ke) was a constant (0.5) for the . Finally, the method presented using both
28 day compressive strength for all percentages of the general and percentage efficiency factors
replacements the factor representing the percen- is able to predict quantitatively the strength
tage replacements (kp) varies between 0.75 and variation of concrete at different percen-
-0.15 resulting in the overall efficiency factor k tages of fly ash replacements and at different
varying between 1.25 and 0.35 for replacement water to ash cementitious materials ratios.
percentages of 10 to 75% of cement by an equiva-
lent weight of fly ash respectively.
ACKNOWLEDGEMENTS
10. Haque, M.N., Langan, B.W. & Ward, M.A., High fly ash strength of concrete. A CI J., Nov-Dec ( 1990) 619-26.
concretes. ACIJ., Jan-Feb (1984) 54-60. 17. ASTM C 618-89, Standard specifications for fly ash and
11. Haque, M.N., Gopalan, M.K., Joshi, R.C. & Ward, M.A., raw or calcined natural pozzolana for use as a mineral
Strength development of inadequately cured high fly ash admixture in portland cement concrete, Annual Book of
content and structural concretes. Cement Concr. Res., ASTM Standards, Vol. 04.02, 1989, pp. 296-8.
16 (1986) 363-72. 18. Langley, W.S., Carette, G.G. & Malhotra, V.M., Structu-
12. Hooton, R.D., Properties of a high-alkali lignite fly ash in ral concrete incorporating high volumes of ASTM Class
concrete, in Proc. Second Int. Conf. on Fly Ash, Silica F fly ash. ACIJ., Sep-Oct (1989) 507-14.
Fume, Slag and Natural Pozzolans in Concrete, Vol. I, 19. Neville, A.M., Properties of Concrete, 3rd Edition. ELBS
ACI SP-91, 1986, pp. 333-46. and Pitman Publishing, 1981, pp. 557-63.
13. Tse E.W., Lee, D.Y. & Klaiber EW., Fatigue behaviour of 20. Smith, I.A., The design of fly ash concretes, in Proc.,
concrete containing fly ash, in Proc. Second Int. Conf. on Inst. of Civil Engineers, London, 36(1967)769-90.
Fly Ash, Silica Fume, Slag and Natural Pozzolans in 21. Munday, G.L.J., Ong, T.L. & Dhir, R.K., Mix propor-
Concrete, Vol. I, ACI SP-91, 1986, pp. 273-90. tioning of concrete with PFA: A critical review, in Proc.
14. Gebler, H.S. & Klieger. P., Effect of fly ash on physical First Int. Conf. on Fly Ash, Silica Fume, Slag and Other
properties of concrete, in Proc. Second Int. Conf. on Fly Mineral By-Products in Concrete, Vol. I, ACI SP-79,
Ash, Silica Fume, Slag and Natural Pozzolans in Con- Detroit, 1983, pp. 267-88.
crete, Vol. I, ACI SP-91, 1986, pp. 1-50. 22. Wesche, K., Schubert, E & Weber, J.W., Zur Festigkeit
15. Nasser, K.W. & Lai, P.S.H., Creep and shrinkage of und Dauerhaftigkeit von Beton bei Zusatz yon Stein-
concrete containing 50% fly ash and superplasticizer, in kohlenflugasche, (Strength and durability of concrete
Proc. Third CANMET/ACI Int. Conf. on Superplasti- with addition of fly ash), Betonwerk und Fertigteil-Tech-
cizers and Other Chemical Admixtures in Concrete, nik, 50 (1984) 367-74.
(Supplementary papers) 1989, pp. 86-105. 23. Schiessl, P. & Hardtl, R., Efficiency of fly ash in concrete
16. Naik, T.R. & Ramme, B.W., Effects of high-lime fly ash evaluation of ibac test results. Technical Report of Insti-
content on water demand, time of set and compressive tut fiir Bauforschung, RWTH, Aachen, 1991.