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TITLE PAGE i
TABLE OF CONTENTS ii
ABSTRACT iii
Chapter 1: INTRODUCTION
REFERENCES
APPENDICES
B. Definition of Terms
C. Problems
ALKENES
by:
physical and chemical, an alkene possess. The physical properties of alkenes were determined by
physical inspections and comparison with water and it was recognized than alkenes were
colorless, liquid, have an almost odorless odor, immiscible and less dense that water. The
chemical properties of an alkene were determined using four methods. First, bromine water,
permanganate, making contact with alkenes, also decolorized and formed a brown precipitate
(Baeyers test). Third, when heat was added to the alkene, a yellow luminous flame had evolved
showing that a complete combustion would always occur to alkenes being heated up. All this
methods showed that alkenes are vulnerable to reactions demonstrating that alkenes are
unsaturated. And lastly, alkenes acidity or alkalinity was determined when sodium hydroxide
and hydrogen chloride was added to the alkene. Neither of the two solutions showed any sign of
INTRODUCTION
Alkenes, also known as olefins, are hydrocarbons that contain at least one carbon-carbon
double bond and are said to be unsaturated. The double bond that formed causes the
of hydrogen in this hydrocarbon is lower than the concentration of hydrogen in an alkane by two
hydrogen atoms. Due to the presence of double bond, alkenes are more vulnerable to reactions.
They can easily react to certain reagents compared to alkanes because the second bond formed
between the carbon atoms are not that strong compared to the first bond. The relative weakness
of the pi bond in comparison with the sigma bond signals the energetic preference for the
unsaturation site to react additively with reagent molecules. In actuality, alkenes are relatively
stable compounds, but are more reactive than alkanes, either because of the reactivity of the
carboncarbon pi-bond or the presence of allylic CH centers. Also, most reactions with alkene
are related to the addition of the reagents to the pi bonds therefore forming new single bongs..
Chapter 2
Physical properties of alkenes were observed through physical inspection. Color, physical
state and odor were noted. Solubility and density were also determined by adding water to the
alkene.
Next tests were applied to test the chemical properties of an alkene. We have prepared
four test tubes with alkenes. The first one contains 2 ml of the alkene, the second one with 5
drops, and the third and fourth both contain 10 drops. In the first test tube, 3 drops of bromine
water (Br2) was added to the alkene. In every drop, observations were noted. After this, 10 more
The second test tube was subjected to the next step called Baeyers test for unsaturation.
In this test, 2 drops of dilute potassium permanganate solution was added to the alkene. The tube
In the next procedure, the alkene was placed in an evaporating dish. A lighted match was
The third and fourth test tubes were used to determine the alkalinity and acidity of the
alkene. 1-2 mL of NaOH and 1-2 ml of HCl was added to test tubes -one solution per tube.
This experiment determined the physical properties by simply looking at the alkene
solutions, where in this experiment hexene was used as the alkene. It was observed that alkene
possess the quality of being colorless. They are also in a liquid form having an almost odorless
odor. When we have added water to the alkene, we have observed that water went directly below
the alkene. We have shaken the solution but the two liquids didn't mix with each other.
In the next procedures, chemical properties where determined by adding solutions to the
alkene. First, we have added bromine water to it. Bromine water has the quality of having a
yellow-orange color. When we added this liquid to the alkene, it went directly below the alkene.
We stirred the mixture and noticed a decolorization of the bromine water making it colorless.
The next test, also known as Baeyers test for Unsaturation, was to add potassium permanganate
to the alkene. Potassium permanganate is solution with a purple color. When this liquid was
added, it also decolorized and slowly, a brown precipitate was formed at the bottom of the test
The third method was to ignite the alkene. The alkene placed in an evaporating dish was
ignited using a lit matchstick and we have noticed a yellow luminous flame coming from the
And the last test was to determine the alkalinity and acidity of the alkene. We have added
NaOH or sodium hydroxide to the alkene to determine the acidity of the alkene. We have added
it and we have observed that the mixture didnt create any reactions. Next we have added HCl or
hydrochloric acid to the solution to determine the alkalinity of the alkene. We have added it and
Chapter 4
The researchers were able to determine the different properties alkenes have. By physical
observations we have determined that alkenes are colorless liquid that have an almost odorless
odor, immiscible and less dense than water. These qualities of alkenes are due to their non-polar
characteristics. When we have added the two solutions, bromine water and potassium
permanganate, to the alkene, reactions were evidently observed. Bromine water changed its color
from yellow-orange to clear and the potassium permanganate solution decolorized and a brown
precipitate was formed. The reaction with potassium permanganate, also known as Baeyers test
for unsaturation, was a positive test that proved the unsaturation of alkenes. Comparing these
results to the results when this method was applied to alkanes, we have determined that reactions
were more evident to alkene compared to alkane. Because of this we could say that unsaturated
compounds are prone to reactions since alkenes have double bonds and that the second bond is
In the next methods that we have done, we have found out that alkenes undergo complete
combustion. This is evident through the yellow luminous flame that we have produced after a lit
match was used to ignite the alkenes. Since the temperature is not high enough or since the
oxygen present is in short supply, carbon, as soot, and CO were formed. Comparing this
observation to alkanes, we have found out that alkenes have sootier flame which may be because
of the reason that- as the unsaturation increases, the molecules do not appear to have enough
time to break all the necessary bonds within the flame region, to give the colorless, combustion
And lastly, we have found out that alkenes are compounds that are neutral. This is
because when we have added NaOH to the alkene, no reactions had occurred therefore alkenes
are not acidic. When HCl was added, no reactions had also occurred showing that alkenes are not
REFERENCES:
Bettelheim and Landesberg, Laboratory Experiments for General, Organic, and Biochemistry,
Seager, Spencer L. and Micael R. Slabaugh, Safety-Scale Laboratory Experiments for Chemistry
textbook/organic-chemistry-23/alkenes-and-alkynes-164/properties-of-alkenes-631-3627/
An Introduction to alkenes
http://www.chemquide.co.uk/organicprops/alkenes/background.html
APPENDICES
APPEMDIX A
1. Test tubes- is a thin glass tube closed at one end, used to hold
borosilicate glass.
time.
5.
APPENDIX B
Definition of Terms
1. Baeyers test for unsaturation- a qualitative test for the presence of unsaturation, such
From alkynes
corresponding alkene.
Vicinal dihalides can be defined as the dihalides in which two adjacent carbon
atoms are attached to two halogens. When such dihalides react with zinc metal they
Alcohol reacts with concentrated sulfuric acid which results in the formation of
alkenes due to the elimination of water molecule. As water molecule is removed in this
2+ with the loss of purple color. During this reaction, the solution becomes alkaline
(KOH) is formed and the brown precipitate of manganese dioxide can appear in the
reaction mixture.
4. What simple chemical tests may be used to differentiate the alkene from an alkane?
Bromine test- In this test the alkene or alkyne reacts with Br2 to form an alkyl
dibromide, which causes the orange-brown of the Br2 to disappear. This will be