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1.0 TITLE
2.0 OBJECTIVES
To observe and control the operation of a continuous-stirrer tank reactor.
To determine the effects of flow rate on conversion rate in a continuous-
stirrer tank reactor.
3.0 INTRODUCTION
CSTR can use to perform the reactions for all fluids which are liquids, gases, and
slurries (Schmidt, 1998). CSTR can use to handle the reaction that in different phase,
for example liquid phase, gas-liquid phase reaction and solid-liquid phase reaction
(University of Michigan, n.d). The feeds stream of the CSTR assumes provide a
uniform flow rate or composition throughout the whole process and the exit stream
has the same composition as in the tank.
The reactions occurring in the reactor is a function of residence time and rate
of reaction. Residence time, , is the average amount of time a discrete quantity of
reagent spends inside the reactor. The theory of residence time distributions
generally includes three assumptions (Residence Time Distribution, n.d):
2. Transports at the inlet and the outlet take place only by advection
1 1
() =
10.00
8.00
Conductivity (mS)
6.00
4.00
y = -0.0613x + 10.08
2.00
0.00
0 20 40 60 80 100 120
Conversion (%)
30.00
25.00
20.00
15.00
10.00
5.00
0.00
0 10 20 30 40 50
60.00
50.00
40.00
30.00
20.00
10.00
0.00
0 10 20 30 40 50
Dosing Rate (%)
Sample Calculations
( )
= [1 ] 100 %
( )
= 47.3 mS/cm
(47.31)
= [1 (128.21)] 100 %
= 63.60 %
6.0 DISCUSSION
In experiment 1, the standard solutions are used to plot the calibration curve.
The calibration curve is drawn to study the relationship between conversion and
conductivity. It was found that the conductivity decreases as the conversion of
sodium acetate, Na(Ac) increases according to the calibration curve. As the reaction
taking place, the high conducting H- ions are replaced by less conducting acetate ion
(C2H3O2-) in the mixture (Das et al. 648-656). This calibration curve is important as
it assists to obtain percentage conversion of Na(Ac) at different temperature by using
the gradient and y-intercept for further calculation.
Residence time, also called space time, holding time, , is defined as the time
required for fluids or reactants to enter the reactor completely. Therefore, it can be
obtained by volume of the reactor divided by the volumetric flow rate of the fluids
entering the reactor (Fogler, 2013). The equation is defined as following where is
the residence time, V is the volume of reactor and 0 is the volumetric flow rate of
the fluids entering the reactor.
=
0
From the equation above, residence time are affected by both volume and volumetric
flow rate. Residence time is directly proportional to volume of reactor, which mean
the bigger size of reactor, the residence time for fluids completely entering the
reactor also increases. On the other hand, the residence time is inversely proportional
to the volumetric flow rate of fluids entering the reactor which mean the higher flow
rate, the shorter time is needed.
0
V=
( )
From Figure 6.1, a plot of 0 versus X graph is showed. The volume of CSTR is the
area under the curve represented in the graph, thus when the conversion is increasing
by a certain ratio, the volume of CSTR is increasing in that particular ratio too.
Moreover, reaction between ethyl acetate and sodium hydroxide is known as
endothermic reaction where the rate of reaction is increasing as the temperature
increases. Based on the results, most of the conversion is greater when the
temperature is getting higher. The reason behind is due to the sodium hydroxide is
reacted with ethyl acetate to produce sodium acetate. The concentration of sodium
acetate is increasing with time when the temperature is getting higher. Moreover,
increasing in heat energy leads to higher conversion rate no matter is in endothermic
or exothermic reaction (The Performance In Any Chemical Process Biology Essay,
2015). Thus, the temperature does affect the conversion and conversion rate.
() = ( )
Rate of reaction is faster when the temperature increases due to the high kinetic
energy. As temperature increases, particles move faster and collide more vigorously.
As a result, greater collision frequency will lead to a higher rate reaction ("The effect
of temperature on rates of reaction", n.d.). Thus, chemical reaction is faster at higher
temperature and expected to be lower at lower temperatures.
In this experiment there are some precaution steps taken to ensure the
experiment conduct in a safety and health environment. The first precaution step is
when handling the hazardous chemical such as sodium hydroxide and ethyl acetate,
gloves was wore by the student so that, there are no skin contact to the skin and
cause itchy. Every inlet and outlet of the pipes is connected well when setting up the
CSTR. If the pipes did not link well, the chemical and hot water might split out cause
accident. The last precaution step is the disposal of the product from the CSTR. The
products should be drained out by using the cement made drain. If dispose the
products by using sink, it may corrode the sink.
CSTR is the most basic continuous reactors used in chemical processes. High
production rate (reactant constantly introduced into reactor, and product continuously
removed), had made this type of reactor more preferred to be used in production line.
Normally, these reactors are functioned under low or medium pressure and
homogeneous liquid phase reaction ("Reactors Design And Types: Its Advantages
And Disadvantages"). Besides that, CSTR are widely being used in industrial
applications, such as waste water treatment unit (activated sludge reactors)(Artin
Hatzikioseyian) . CSTR can also being used as bioreactors, which also being used for
waste water treatment in treating high hydrocarbon waste water (Gargouri et al. 427-
434).
8.0 CONCLUSION
9.0 REFERENCES