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MATERIAL SAFETY DATA SHEET

Product: 39297 AddNox PPA Masterbatch

. 1. Identification of the substance/ preparation and of the company/ undertaking

Trade name 39297 AddNox PPA Masterbatch


Chemical Name Polymeric preparation based on
additives.
Type of Product For more detailed information, see Point 9.

Company ALOK MASTERBATCHES PVT. LTD., INDIA


Emergency phone No 91- 11-41612244

2. Composition / information on ingredients


Main components Polyethylene& proprietary additives.

CAS numbers 9002-88-4


Substances presenting a health hazard None to our knowledge
Chemical family Blend of Polyolefins & additives with processing
stabilizers
3. HAZARDS IDENTIFICATION:

Main hazards None to our knowledge


Symptoms related to use
-inhalation If heated to more than 2500 C. the product may form vapors of
fumes which may cause irritation of respiratory tract and cause
coughing and sensation of shortness of breath.
Skin contact In contact with hot material, may cause severe thermal bums
Physico- chemical hazards Combustible if exposed to flames flowing product can create
electrical charge, resulting sparks may ignite dust or cause an
explosion in some concentration ranges.
4. FIRST AID MEASURES:

Route of exposure
inhalation Exposure to fumes and vapors produced by heated or burned
product in case of severe exposure to fumes or vapors move
the affected person into fresh air Get medical advice if the
symptoms continue.

-Skin Contact Exposure to splashing of hot product treat the affected part with
cold water (by spraying or immersion) no attempt should be
made to detach molten product adhering to the skin or to
remove clothing attached with molten material, the injured body
part would risk being pulled out, usually the layer detaches itself
after a few days.

Eye contact In case of severe bum, seek medical advice immediately


exposure to splashing of hot product treat the eyes with cold
water Seek immediately special attention at hospital or medical
center Fine dust may cause irritation to ocular mucous.

ALOK MASTERBATCHES PVT. LTD.


C-65/1, Okhla Industrial Area, Phase-2,
New Delhi-110 020, INDIA Phones : +91-11-41612244 - 47, Fax No: +91-11- 41610333-34
e-mail : sales@alokindustries.com, www. alokmasterbatches.com
ROC CIN No. U74899DL1995PTC065403
-Eye contact In case of irritation caused by fine dust: wash with copious
volumes of water, until the irritation disappears. Ingestion during
handling is not likely.
Ingestion In case of ingestion of small quantities, no import effect
observed, in case if ingestion of larger amounts: abdominal
pain, diarrhea.
5. Fire -fighting measures
Technical measures Stop the fire spreading. Call the fire brigade immediately.
Evacuate non-essential personnel. Protective clothing, goggles
and self-contained breathing equipment should be made
available for foremen.
Extinguishing media
-Suitable For minor fires: carbon dioxide or powder, water for more
extensive fires: foam . water spray (mist) to cool the surfaces
exposed to the fire.
-Not to be used Do not use water jets (stick jets) in the early stages of
extinguishing fire since they could help to spread the flames.
Combustion products Complete combustion, with an excess of oxygen forms: carbon
dioxide and water vapor partial combustion, forms also : carbon
monoxide, soot and cracked products: aldehydes. Ketones,
hydrocarbons and volatile fatty acids.
Protective equipment for firefighters Wear suitable breathing equipment, in case of risk of exposure
to vapour or fumes.
6. Accidental release measure
See also chapters 8 and 13 after spillage / Granules spilled on the floor can cause a risk of slipping on
leakage- on smooth surface. Recover the spilled product by sweeping or
suction, put it in containers to facilitate its disposal.
soil Dispose safely in accordance with local or national regulations.
Prevent the spilled material from spreading.
- on water If the material has been discharged into a stream or a sewer ,
inform the authorities of the possible presence of floating
materials. Clean up the water surface by creaming off debris
from the top. Refer to a specialist for waste disposal in a safe
manner in accordance with local or national regulations.
7. Handling and Shortage
Technical protective measures Handling All pneumatic transport equipment must be electrically earthed.
Storage Store at ambient temperature and at atmospheric pressure in
original packaging (plastic or cardboard boxes) or in silo made
appropriate material aluminium, stainless steel,) Do not store
near highly flammable materials, store away from heating
source, avoid static electricity build up with connection to earth.
Store in dry, well ventilated area. Avoid dust accumulation by
use of filters in the pneumatic transport equipment.
(VbF- Klasses Germany ) see also chapter 8 Non applicable

8. Exposure controls / personal protection:

Exposure controls (%)


TA- LUFT CL .I (mg/m3) Non applicable
TLV- 8h TWA (ACGIH) 5 inhaled dust
10 (whole dust)
Personal protection
In case of risk of overexposure to dust, vapour or fumes (during
-Respiratory protection product processing) it is recommended that a local exhaust
system is placed above the conversion equipment (a fume
hood) and the working area must be properly ventilated.

ALOK MASTERBATCHES PVT. LTD.


C-65/1, Okhla Industrial Area, Phase-2,
New Delhi-110 020, INDIA Phones : +91-11-41612244 - 47, Fax No: +91-11- 41610333-34
e-mail : sales@alokindustries.com, www. alokmasterbatches.com
ROC CIN No. U74899DL1995PTC065403
-Skin protection If contact with hot materials is possible, wear heat-insulating
and chemical proof gloves as well as a face shield.
-Eye protection When the splashing of molten droplets may occur, wearing
goggles / spectacles
Other personal protection Safety non-slip shoes in areas where spills or leaks can occur
9. Physical and Chemical properties
Appearance Pellets from diameter of 2 to 3 mm solid
Physical state at 20 oC Solid pellets
Melting range(oC) From 100 to 200C
Flash Point (ASTM D 1929) (o C) 340
Auto ignition temperature >350
Explosion Limits )kg/ ( M 3 ) -lower 0.015 (for polymer dust <100 urn)
Mm ignition energy at 20o C (mJ) NA
Vapour pressure at 20o C (hPa) None
Solubility in water (% weight) insoluble
Viscosity (mm s) Non applicable
10 Stability and reactivity
Stability Stable under operating conditions
Conditions to avoid Avoid contact with strong oxidizing materials and fluorine. Avoid
proximity or contact with flames or sparks. do not heat to
temperatures exceeding 300oC
Hazardous reactions Dust may form an explosive mixture with air, ignited by sparks
or sources of ignition.
Advice to prevent explosion Avoid dust accumulation by use of filters in the pneumatic
transport equipment. Thoroughly ventilate the working place.
Use explosion proof electrical equipment. All conductive
materials must be electrically earthed. In case of pneumatic
alimentation, feed the extruders by aspiration. Use nitrogen as
carrier gas.
11. Toxicological information
Symptoms related to use inhalation Low risk for temperatures below 40oC
If heated to more than 250oC, the product may form vapors or
fumes which may cause irritation of respiratory tract and cause
coughing and sensation of shortness of breath. Dust may cause
irritation on respiratory system.
Skin Contact No risk for temperatures below 40oC. in contact with hot
material, may cause severe thermal bums.
Eye Contact Fine dust may cause irritation to ocular mucous. Splashing of
molten droplets cause ocular tissues injury
Ingestion Minimal toxicity
Rat oral LD50 (mg/Kg) No information available
Carcinogenicity IARC (International Agency on Research on Cancer): category
3 the agent is not classifiable as to its carcinogenicity to
humans.
12. Ecological information
Information on ecological effects Avoid losses to the environment whenever possible.
Mobility There is a slow loss by evaporation .
-air Because of its physico chemical properties, the product
generally has a low soil mobility.
-water Because of its low solubility, the product should not be
dangerous for aquatic life.
Persistence and degradability Persistent in the environment.
Biodegradation This substance is non biodegradable.
Bioaccumulative potential Potential bioaccumulation of the product in environment is very
low

ALOK MASTERBATCHES PVT. LTD.


C-65/1, Okhla Industrial Area, Phase-2,
New Delhi-110 020, INDIA Phones : +91-11-41612244 - 47, Fax No: +91-11- 41610333-34
e-mail : sales@alokindustries.com, www. alokmasterbatches.com
ROC CIN No. U74899DL1995PTC065403
Ecotoxicity Non ecotoxic
BOD 5 Below the detection limit
13. Disposal Considerations
Disposal According to local regulations
Authorized disposal. As refuse
For reprocessing
Do not dispose off by means of sinks, drains or into the
immediate environment may be used as fuel in suitably
designed installations. Incinerate with household refuse in a
municipal solid waste incinerator plan.
Industrial waste number symbol -
14. Transportation Information
Road (ADR) / Rail (RID). ADNR Not restricted for transport
Marine (IMO- IMDG Airline Not restricted for transport
(ICAO/ IATA) Not restricted for transport

15. Regulatory information


Labelling and Classification EC
-Symbol(s) EC Not classified according to ECC directive 67/548/EEC and
88/379/EEC
EU Norms Complying the RoHS Norms
CONEG Complying the CONEG (EU) norms
Germany
Registration Listed on the EEC inventory EINECS (European Inventory of
Existing Commercial Chemical Substancec)

16. Other information

Further information No information available


Revised : 01.04.2016
This data sheet conforms to standards defined by directives 91/155 & 93/112/EEC

IMPORTANT:

The information in this Data Sheet applies only to the products designated herein and produced or supplied by us it is cased on our experience and on the
data available to us at the time of its issue and is accurate to the best of our knowledge. The customer is strongly advised to observe and ensure that its
employees and customers observe all direction contained herein. However , no warranty is made or implied that the information is accurate or complete and
no liability will be accepted whatsoever arising out of the use of the information or the products designated herein . Where third party products are used in
conjunction with or instead of products produced or supplied, customers should themselves obtain all necessary technical, health and safety information
about such product from the third party.

ALOK MASTERBATCHES PVT. LTD.


C-65/1, Okhla Industrial Area, Phase-2,
New Delhi-110 020, INDIA Phones : +91-11-41612244 - 47, Fax No: +91-11- 41610333-34
e-mail : sales@alokindustries.com, www. alokmasterbatches.com
ROC CIN No. U74899DL1995PTC065403

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