MATERIAL SAFETY DATE SHEET

AMMONIUM BISULPHITE SOLUTION

SECTION-1 PRODUCT AND COMPANY IDENTIFICATION

1.1 Product Name : AMMONIUM BISULPHITE SOLUTION.

Chemical Formula : NH4HSO3
Chemical Synonyms/
Common name : AMMONIUM HYDROGEN SULPHITE/
AMMONIUM BISULPHITE SOLUTION.
Chemical Family : INORGANIC SALT.
Manufacturer : Halol-Baroda Road,
At-Baska, Tal-Halol.
Dist-Panchmahal,
City : Baroda , State : Gujarat
Country: INDIA Pin Code -389 352.
Telephone : (02676)247227/ FAX: 247355
Emergency Number : -

SECTION-2 COMPOSITION, INFORMATION ON INGREDIENTS

2.1 CHEMICAL NAME % Toxicity Data

Ammonium Bisulphite (NH4HSO3) 70+ No information available.

Water 30

SECTION-3 HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW :
LIQUID, VAPORS OR MIST MAY BE IRRITATING TO EYES, SKIN AND RESPIRATORY TRACT. STRONG
REDUCING AGENT. MAY CAUSE PERMANENT EYE DAMAGE.CLEAR TO PALE YELLOW SOLUTION WITH A
SLIGHT SULFUR ODOR.
3.1 POTENTIAL HEALTH EFFECTS.

ROUTES OF ENTRY : Absorption, Inhalation And Ingestion.

TARGET ORGANS : Eyes, Skin, Respiratory Tract, Gastrointestinal Tract,
Lungs.
IRRITANCY : Extremely irritating to skin, eyes and mucous
membranes.
Permanent eye damage may result from eye contact.
SENSITIZING CAPABILITY : None Known.
REPRODUCTIVE EFFECTS : None Known.
CANCER INFORMATION : None Known.
SHORT TERM EXPOSURE (ACUTE)

INHALATION : Exposure to vapor, mist or liquid can produce

Irritation of the respiratory tract.
EYES : Strongly irritating to eyes. Exposure To vapor can
cause tearing, conjunctivitis and burning of the
yes. Eye contact may cause corneal Injury.
SKIN : Contact may cause burns and tissue destruction.
INGESTION : Strongly irritating to mucous membranes. Can cause
severe burns to the mucous membranes of the
digestive tract.
REPEATED EXPOSURE (CHRONIC) : None Known.
SYNERGISTIC MATERIALS : None Known.
MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE : None Known.

SECTION-4 FIRST AID MEASUIRES

4.1 EYES :
IMMEDIATELY flush eyes with a directed stream of
water for at least 15 minutes, forcibly holding eyelids
apart to ensure complete irrigation of all eye
and lid tissue.
IF IRRITATION PERSISTS GET MEDICAL ATTENTION.

4.2 SKIN : Wash thoroughly with soap and water. Wash clothing
before reuse.
IFIRRITATION OCCURS, GET MEDICAL ATTENTION.

4.3 INGESTION : Remove to fresh air. If breathing is difficult, have

GET MEDICAL ATTENTION IMMEDIATELY.
4.4 INGESTION
GET IMMEDIATE MEDICAL ATTENTION.
trained person administer oxygen. If respiration
stops, give mouth to - mouth resuscitation.
: May irritate gastrointestinal tract. Very large doses
cause violent colic, diarrhea, depression and death.
May cause severe allergic reaction in some asthmatics
and sulfite sensitive individuals. If conscious, give
plenty of water or milk. Induce vomiting by touching
finger to back of throat.

SECTION-5 FIRST FIGHTING MEASUIRES

Flash Point : Non-Flammable.

Method : Not Applicable.
Auto-Igrution : Not Applicable.

5.1 FLAMMABLE LIMITS IN AIR, BY % VOLUME:

Upper : Non-Flammable
Lower : Non-Flammable.
5.2 Extinguishing Media : Use agents appropriate for surrounding fire.
5.3 Fire Fighting Procedures : Wear positive pressure self-contained breathing
apparatus and full protective clothing.

5.4 Fire And Explosion Hazard
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
: This product is non-flammable and non-explosive
under normal conditions of use. At high temperatures
this product can decompose to give off toxic fumes.
: Not sensitive
: Not sensitive

SECTION-6 ACCIDENTAL RELEASE MEASURES

6.1 Small Leakages : Absorb small leakages on sand, earth or other inert
absorbent. Dispose of in a chemical waste landfill.
6.2 Large Leakages : Absorb area to qualified personnel. Wear proper
protective equipment. Spray product vapors with
water spray or mist. Recover as much of the solution
as possible.
SECTION-7 HANDILING AND STORAGE

7.1 HANDLING : Do not get in eyes, on skin or clothing. Do not take

internally. Wear personal protective equipment. Avoid
breathing airborne particulate, wear respiratory
protection when exposure is possible. Use with
adequate ventilation. Keep container tightly closed
and properly labeled. Wash contaminated clothing
before reuse. Wash thoroughly after handling. Wear
goggles or face shield and rubber gloves when
handling.
7.2 SPECIAL MIXING AND
HANDLING INSTRUCTIONS : Not Applicable.
7.3 STORAGE : Keep container tightly closed and properly labeled.
Store in a cool, ventilated area away from
incompatible materials.

SECTION 8 PROTECTION MEASURES

8.1 Hygiene measures : When using do not eat, drink or smoke. Follow good
housekeeping practices.
8.2 Skin and body : Wear suitable protective clothing.
8.3 Hands : Wear suitable gloves.
8.4 Eye : Safety glasses. Wear splash goggles when mists or
aerosols are anticipated.
8.5 ENGINEERING
CONTROLS : Use adequate exhaust ventilation to prevent
inhalation of product vapors. Maintain eyewash/safety
shower in areas where product is handled.

SECTION-9 PHYSICAL AND CHEMICAL PROPERTIES

9.1 Appearance AND odor : Clear to pale yellow solution with a slight sulfur odor.
9.2 Odor Threshold : Not Available
9.3 Boiling Point : 220 231F
9.4 Melting Point : Not Determined
9.5 Vapor Pressure : Not Determined
9.6 Specific Gravity : 1.250 - 1.400
9.7 % Volatile by Volume : Not Determined
9.8 Vapor Density : Not Determined
9.9 Evaporation Rate : <1
9.10 PH : 4.0 - 5.5
9.11 Solubility in Water, % by wt. : 100

SECTION-10 STABILITY AND REACTIVITY

10.1 Chemical Stability : Stable

10.2 Reacts With : Heat, Oxidizers, Acids, Alkalis.
10.3 Hazardous Polymerization : Will not occur.
10.4 Comments : Avoid contact with oxidizing agents. Avoid heat,
sparks and open flames
10.5 Hazardous
Decomposition Products : Generates toxic and irritating gases at high
temperatures.
SECTION-11 TOXICOLOGICAL INFORMATION

Toxicity for oral ingestion of ammonium bisulphite is slight because ammonium is readily excreted in
urine. Sulphite salts cause gastric irritation by liberation of sulfurous acid. The ammonium salt is basic
and may be irritating to corrosive tissues depending on the concentration.

Section 12: ECOLOGICAL INFORMATION

No ecological information is known on the product.

Section 13: DISPOSAL CONSIDERATIONS

13.1 Methods of disposal : Use procedures in accordance with Local, State and
Federal regulations where applicable.
13.2 NEUTRALIZING CHEMICALS : Water
13.3 Contaminated packaging : Keep waste packaging separate.

SECTION-14 TRANSPORT INFORMATION

14.1 Dot Classification : Corrosive Material

14.2 Proper Shipping Name : Bisulphites , inorganic, aqueous solutions.
(Ammonium Bisulphite)
14.3 DOT Hazard Class :8
14.4 UN Number : UN2693
14.5 Packing Group : III

Section 15: REGULATORY INFORMATION

Not dangerous for supply.

SECTION 16: SUPPLIER INFORMATION

One should always use chemicals with awareness of potential hazards, known and unknown, and their
effect on the human system.

We do not warrant or guarantee the accuracy or reliability, nor shall we be liable for any loss or damage
arising out of the use thereof.

The information offered is for the user's consideration and examination, and it is the user's responsibility
to satisfy him self that it is suitable and complete for his particular use.