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Notes: 04
(Entry-2016)
1. Constant Volume
2. Constant Pressure
3. Constant Temperature
4. Adiabatic/Constant Entropy
5. Polytropic Process
1. Constant Volume Reversible Non-Flow Process
For constant
From the non-flow energy equation, 2.2,
For mass , it is
Statement
= 2 = 2707
The process is shown on a -diagram in fig-4.4. Shaded area on this diagram is the work done, i.e.
= .
Equation 3.5 gives, = ,
i. e. work done by the mass of gas present = 0.05 0.287 514 = 7.38
3. Constant Temperature Reversible Non-Flow Process
A convenient way of evaluating energy supplied as heat is put off to when entropy will be
discussed as yet another system property.
However, once states 1 and 2 are fixed then the internal energies and may be
obtained from steam tables.
Work done is given by the shaded area on fig-4.5. It can only be evaluated by plotting the
process and measuring the area graphically or it can be evaluated (approximately exactly)
numerically by using some integration technique from numerical analysis.
Once heat flow is known then work can be obtained using non-flow energy equation 2.2,
Example 4.2
Statement
Steam at and dryness fraction expands in a cylinder behind a
piston isothermally and reversibly to a pressure of . Calculate the
change of internal energy and the change of enthalpy per of steam. The
heat supplied during the process is found to be . Calculate the
work done per of steam.
Solution
Fig-4.6 shows the -diagram for the process. The saturation temperature
corresponding to is . Therefore the steam is superheated at state 2.
Using equation 3.3, internal energy at state 1 is
Interpolating for from superheat tables at and ,
Therefore,
As for enthalpy,
Work done is the shaded area on fig-4.6. The integral can only be
evaluated graphically or numerically.
Like in processes dealt with already, an isothermal process for a perfect gas
obeys laws that relate and other properties. For instance, equation
3.5,
Statement
of nitrogen (molar mass ) is compressed
reversibly and isothermally from , to .
Calculate the work done and the heat flow during the
process. Assume nitrogen to be a perfect gas.
Solution
+ =0
= 1
which on substitution gives
Now, substituting in equation
( ) ( )
Equation 4.13 gives
Statement
of steam at and expands reversibly in a perfectly
thermally insulated cylinder behind a piston until the pressure is
and the steam is then dry saturated. Calculate the work done by the
steam.
Solution
From superheat tables at 100 and 375,
= 3017 / and = 0.02453
Since = (equation 2.7)
100 10 ( / ) (0.02453)( )
= 3017
10
Steam is finally dry saturated, i.e. = and pressure is 38 ; which gives,
from steam table (for saturated liquid/steam)
= 2602 /
Nature of process undergone by steam in the cylinder is ascertained by examining
the problem Statement which tells that the cylinder is perfectly thermally
insulated, i.e. the process is adiabatic.
Using equation 4.13 for work done,
= = (2771.7 2602)
= 169.7
Shaded area in Fig-4.10 represents the work done on a -diagram.
5. Reversible Polytropic Non-Flow Process
Some processes may not fit into any of the categories dealt with previously. Such
processes, both for vapors and for perfect gases, approximate to a reversible law
of the form , where is a constant.
or
Writing ,
or
The reversible adiabatic process for a perfect gas is a particular case of a
polytropic process with the index, , equal to . Some other useful relationships
are
Equations 2.62.9 do not apply to a vapor, since these have been derived using
. Equation 4.24, , in terms of a temperature
difference is
For heat flow or energy flow as heat, to be more appropriate, during a polytropic
process, using non-flow energy equation 2.2,
Substituting from equation 3.21, gives