Bubble and Dew Point Calculations

fprintf('GIVEN CONDITIONS: \n');

F=input('\n Feed input in the middle stage of the bubble point
mixture(kmol/h):');
m=input('Percentage Composition of Methanol:');
M=(m/100)*F;
fprintf('Methanol input(kmol/h): %d',M)
e=input('\n Percentage Composition of Ethanol:');
E=(e/100)*F;
fprintf('Ethanol input(kmol/h): %d',E)
p=input('\n Percentage Composition of Propanol:');
P=(p/100)*F;
fprintf('Propanol input(kmol/h): %d',P)
Rv=input('\nVapour flow rate leaving Reboiler and at each stage(kmol/h):');
fprintf('Three equilibrium stages in the column \n')
fprintf('A total Condenser \n')
fprintf('A partial reboiler')
fprintf('\n Feed tray is the 3rd tray \n')
D=input('Distillate rate(kmol/h):');
R=input('Reflux rate(kmol/h):');
fprintf('\n ASSUMPTIONS: \n')
fprintf('\n1.Constant Molar Overflow \n');
fprintf('2.Ideal Solution with Raoult law K-values from vapour pressure \n')
fprintf('3.Linear temperature profile for tear variables and liquid flow
rates ')
B=F-D;
fprintf('\n Bottom flow rate:%d',B)
fprintf('\n Methanol in the Distillate \n')
fprintf('Ethanol and Propanol in the Bottoms \n')
LRaF=input('Liquid Rate above the feed(kmol/h):');
LRbF=input('Liquid Rate below the feed(kmol/h):');
Mbp=64.7;
fprintf('\n Boiling point of Methanol(in deg C): %.2f',Mbp)
Ebp=78.2;
fprintf('\n Boiling point of Ethanol(in deg C): %.2f',Ebp)
Pbp=97.2;
fprintf('\n Boiling point of Propanol(in deg C): %.2f',Ebp)
fprintf('\n Temperature Approximations: \n')
T1=64.7;
fprintf('Distillate Temperature(in deg C),T1: %.2f',T1)
T5=(Ebp+Pbp)/2;
fprintf('\n Bottom Temperature(in deg C),T5: %.2f',T5)
d=(T5-T1)/4;
T2=T1+d;
fprintf('\n T2(in deg C): %.2f',T2)
T3=T1+2*d;
fprintf('\n T3(in deg C): %.2f',T3)
T4=T1+3*d;
fprintf('\n T4(in deg C): %.2f \n',T4)
j=[1;2;3;4;5];
Vj=[0;Rv;Rv;Rv;Rv];
Tj=[64.7;T2;T3;T4;T5];
Lj=[R;R;LRbF;LRbF;B];
fprintf('Stage Vj Tj Lj \n')
for i=1:5
fprintf('%d %.2f %.2f %.2f \n',j(i),Vj(i),Tj(i),Lj(i))
end
fprintf('\n CONSTANTS for ANTOINE EQUATION: \n')
fprintf('For Methanol \n')
mC1=16.5785;
mC2=3638.27;
mC3=239.500;

fprintf('mC1=%f \n mC2=%f \n mC3=%f',mC1,mC2,mC3)

fprintf('\n For Ethanol \n')
eC1=16.8958;
eC2=3795.17;
eC3=230.918;

fprintf('eC1=%f \n eC2=%f \n eC3=%f',eC1,eC2,eC3)

fprintf('\n For Propanol \n')
pC1=16.1154;
pC2=3483.67;
pC3=205.807;

fprintf('pC1=%f \n pC2=%f \n pC3=%f',pC1,pC2,pC3)

P=101.300;
fprintf('\nPressure taken in kPa: %.4f',P)
t=[T1;T2;T3;T4;T5];
fprintf('\nK-values and Vapour pressure for Methanol:')
for i=1:5
T=t(i);
mPs=exp(mC1-(mC2/(T+mC3)));
mK=mPs/P;
fprintf('\n mK%d=%f and mPs%d=%f \n',i,mK,i,mPs)
end
fprintf('\nK-values and Vapour pressure for Ethanol:')
for i=1:5
T=t(i);
ePs=exp(eC1-(eC2/(T+eC3)));
eK=ePs/P;
fprintf('\n eK%d=%f and ePs%d=%f \n',i,eK,i,ePs)
end
fprintf('\nK-values and Vapour pressure for Propanol:')
for i=1:5
T=t(i);
pPs=exp(pC1-(pC2/(T+pC3)));
pK=pPs/P;
fprintf('\n pK%d=%f and pPs%d=%f \n',i,pK,i,pPs)
end
%K-values and Vapour pressure values for METHANOL
mK1=1.000289;mPs1=101.329247;
mK2=1.248778;mPs2=126.501213;
mK3=1.546447;mPs3=156.655074;
mK4=1.900479;mPs4=192.518515;
mK5=2.318700;mPs5=234.884266;
mStg1=[-(D+R),Rv*mK2,0,0,0];
mStg2=[R,-(Rv*mK2+R),(Rv*mK3),0,0];
mStg3=[0,R,-((Rv*mK3)+LRbF),Rv*mK4,0];
mStg4=[0,0,LRbF,-((Rv*mK4)+3000),(Rv*mK5)];
mStg5=[0,0,0,3000,-((Rv*mK5)+B)];
fprintf('TRIDIAGONAL FORM FOR METHANOL')
mStage=[mStg1;mStg2;mStg3;mStg4;mStg5]
mD=[0;0;-(F*(m/100));0;0]
mA=[0,R,R,LRbF,3000];
mB=[-(D+R),-(Rv*mK2+R),-((Rv*mK3)+LRbF),-((Rv*mK4)+3000),-((Rv*mK5)+B)];
mC=[Rv*mK2,Rv*mK3,Rv*mK4,Rv*mK5,0];
mD=[0,0,-(F*(m/100)),0,0];
n=length(mD);
mz=zeros(1,n-1);
mz(1)=mC(1)/mB(1);

for k = 2:n-1
mz(k)=mC(k)/(mB(k)-mA(k)*mz(k-1));
end
mw(1)=mD(1)/mB(1);
for k=2:n
mw(k)=(mD(k)-mA(k)*mw(k-1))/(mB(k)-mA(k)*mz(k-1));

end
fprintf('\nmX%d=%.4f',5,mw(5))
mX(n)=mw(n);
for k=n-1:-1:1
mX(k)=mw(k)-mz(k)*mX(k+1);
fprintf('\nmX%d=%.4f',k,mX(k))
end

%K-values and Vapour pressure values for ETHANOL

eK1=0.570995;ePs1=57.841798;
eK2=0.729476;ePs2=73.895953;
eK3=0.923436;ePs3=93.544052;
eK4=1.158880;ePs4=117.394563;
eK5=1.442482;ePs5=146.123421;
eStg1=[-2600,2600*eK2,0,0,0];
eStg2=[2000,-(2600*eK2+2000),(2600*eK3),0,0];
eStg3=[0,2000,-((2600*eK3)+3000),2600*eK4,0];
eStg4=[0,0,3000,-((2600*eK4)+3000),(2600*eK5)];
eStg5=[0,0,0,3000,-((2600*eK5)+400)];
fprintf('\nTRIDIAGONAL FORM FOR ETHANOL')
eStage=[eStg1;eStg2;eStg3;eStg4;eStg5]
eD=[0;0;-(F*(e/100));0;0]
eA=[0,R,R,LRbF,3000];
eB=[-(D+R),-(Rv*eK2+R),-((Rv*eK3)+LRbF),-((Rv*eK4)+3000),-((Rv*eK5)+B)];
eC=[Rv*eK2,Rv*eK3,Rv*eK4,Rv*eK5,0];
eD=[0,0,-(F*(e/100)),0,0];
n=length(eD);
ez=zeros(1,n-1);
ez(1)=eC(1)/eB(1);

for k = 2:n-1
ez(k)=eC(k)/(eB(k)-eA(k)*ez(k-1));
end
ew(1)=eD(1)/eB(1);
for k=2:n
ew(k)=(eD(k)-eA(k)*ew(k-1))/(eB(k)-eA(k)*ez(k-1));

end
fprintf('\neX%d=%.4f',5,ew(5))
eX(n)=ew(n);
for k=n-1:-1:1
eX(k)=ew(k)-ez(k)*eX(k+1);
fprintf('\neX%d=%.4f',k,eX(k))
end

%K-values and Vapour pressure for PROPANOL

pK1=0.251331;pPs1=25.459809;
pK2=0.328592;pPs2=33.286416;
pK3=0.424935;pPs3=43.045897;
pK4=0.543907;pPs4=55.097753;
pK5=0.689487;pPs5=69.845058;
pStg1=[-2600,2600*pK2,0,0,0];
pStg2=[2000,-(2600*pK2+2000),(2600*pK3),0,0];
pStg3=[0,2000,-((2600*pK3)+3000),2600*pK4,0];
pStg4=[0,0,3000,-((2600*pK4)+3000),(2600*pK5)];
pStg5=[0,0,0,3000,-((2600*pK5)+400)];
fprintf('\nTRIDIAGONAL FORM FOR PROPANOL')
pStage=[pStg1;pStg2;pStg3;pStg4;pStg5]
pD=[0;0;-(F*(p/100));0;0]
pA=[0,R,R,LRbF,3000];
pB=[-(D+R),-(Rv*pK2+R),-((Rv*pK3)+LRbF),-((Rv*pK4)+3000),-((Rv*pK5)+B)];
pC=[Rv*pK2,Rv*pK3,Rv*pK4,Rv*pK5,0];
pD=[0,0,-(F*(p/100)),0,0];
n=length(pD);
pz=zeros(1,n-1);
pz(1)=pC(1)/pB(1);

for k = 2:n-1
pz(k)=pC(k)/(pB(k)-pA(k)*pz(k-1));
end
pw(1)=pD(1)/pB(1);
for k=2:n
pw(k)=(pD(k)-pA(k)*pw(k-1))/(pB(k)-pA(k)*pz(k-1));

end
fprintf('\npX%d=%.4f',5,pw(5))
pX(n)=pw(n);
for k=n-1:-1:1
pX(k)=pw(k)-pz(k)*pX(k+1);
fprintf('\npX%d=%.4f\n',k,pX(k))
end
fprintf('Normalization of mole fractions\n')
mx=zeros(1,5);
ex=zeros(1,5);
px=zeros(1,5);

mX5=0.1359; eX5=0.1893; pX5=0.4471;

mX4=0.2913; eX4=0.2619; pX4=0.3267;
mX3=0.4979; eX3=0.2883; pX3=0.2136;
mX2=0.7282; eX2=0.2839; pX2=0.1074;
mX1=0.9094; eX1=0.2071; pX1=0.0353;

mx=[mX1,mX2,mX3,mX4,mX5];
ex=[eX1,eX2,eX3,eX4,eX5];
px=[pX1,pX2,pX3,pX4,pX5];
for i=1:5
sum(i)=mx(i)+ex(i)+px(i);
fprintf('\nsum%d=%f\n',i,sum(i))
if sum(i)~=0
n_mx(i)=mx(i)/sum(i);
n_ex(i)=ex(i)/sum(i);
n_px(i)=px(i)/sum(i);
fprintf('Normalized values: ')
fprintf('n_mx%d=%.4f n_ex%d=%.4f
n_px%d=%.4f\n',i,n_mx(i),i,n_ex(i),i,n_px(i))
end
end