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De. Sap © hemisphere (19) Next consider the general case of a surface element, dardy, of a surface of local principal radii of curvature Ry and Ry. In equilibrium, BF = 0 for the force components normal to the clement. This yields (b= p,dedy = 2ody sin a+ 2dzo sin 6. (20) A Ry oA Now, for small a and #, we may write ody fo 2 i sina = dx/2R; and sin@ = dy/2Ro. There- t < = fore, ap ee (@- aes 21 VbIke (Di — Pe) RiP Re) aac % For a spherical interface, 1/R, = 1/Rz = 1/R. For a cylindrical jet issuing into air, Ry =00 and Ry =r, where r is radius of jet. 81.7.1 Contact angle and Capillary rise Consider the situation shown in figure. We are considering liquid-gas-solid interfaces. A capillary tube has been introduced into a liquid and the free surface of the liquid inside the capillary tube is at a different height from the free surface levels on the outside. Also, adhesion between the tube wall and the liquid molecules pulls the liquid up in the vicinity of the solid surface both on the inside and on the outside of the tube. Therefore the liquid “wets” the solid. Leth be the height of capillary rise. The rise arises from an equilibrium between the upward force due to liquid surface tension and the weight of fluid. At (1), Py = Patm and at (2), Pam = pe pgh. Vherefore, py = pe-+ pgh, or, (Py — Pe) = pgh. Assume the liquid surface in the tube to be a section of a sphere. Then, (=m) =0(4+4) 20 cos 0 20 cos (p — Pe) = —p—sAgh = — : (23) (22) ‘Therefore, © What is the meaning of 0” © @ is known as the wetting or contact angle and it depends on the relative attraction of the molecules of the three media involved and is therefore a function of the characteristics of all three substances. O~0' fa Mercuny molecsles Watey— Clean gles bag ee affenit each ae Ee glass Apesed any (adhesien).