ATOMIC STRUCTURE JEE ADVANCED - VOL - I

ATOMIC STRUCTURE
Illustration: The wavelengths of the
SYNOPSIS characterstic K X-rays of iron and potassium
are 1.932 x 10-8 and 3.737 x 10-8cm, respectively.
Mosleys Experiment:By using different X-ray tubes What is the atomic number of an element for
provided with anti-cathodes of different materials, which the characterstic K wavelength is
Moseley was able to take the spectrum of X- 2.289 x 10-8cm?
rays in each case. It was observed that the Solution:From Moseleys law
wavelengths of X-ray were characterstic of each
element. The characteristic X-ray spectrum Z (or ) aZ 2
consists of discrete spectral lines which can be
ground into K-series, L-series, M-series,etc.
c 1
2
2
Moseley analysed the result as the fast aZ Z
moving cathode rays were able to remove
electrons from the inner orbits of an atom of 1
For Fe, 1
anti-cathode due to collision. (26)2
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1
K M
For K, 2
(19)2
L

108 1
For X, 3
( Z )2
Z

1 ( Z )2
Moseley showed that the square root of the fre- Now
quency of a spectral line is strictly related to the 3 (26)2
nuclear charge (Z) if the excitation potential is fixed.
21.931 108
The results obtained led to the suggestion that Z 8
(26)2
2.289 10
must be directly proportional to the atomic number of
an element (Z) Z 23.88 24
Z * Electromagnetic Spectrum
To give accurate results, Moseley modified Electromagnetic radiation is not a single
this equation as wavelength radiation, but a mixture of various
( Z b) wavelength or frequencies. All the frequencies
Where b is the screening constant, for have same speed.
If all the components of Electromagnetic
K and K lines, b = 1. Hence
Radiation (EMR) are arranged in order of
a ( Z b) decreasing or increasing wavelengths or
where a is the proportionality constant. This frequencies, the pattern obtained is known as
equation is very useful for the calculation of Z if the Electromagnetic Spectrum. The following table
frequency of K and K lines are known. shows all the components of light.

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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
S. Name Wavelength Frequency Source irradiated by monochromatic light of proper
No. (nm) (Hz) frequency, electrons are emitted from it. This
1. Radio 31014 3 107 1 1 0 5 1 1 0 9 Alternating phenomenon of ejection of the electrons from
wave current of
high metal surface was called as Photoelectric Effect.
frequency It was observed that if the frequency of incident
2. Micro 3 107 6106 1 10 9 5 1011 Klystron radiation is below a certain minimum value
wave tube
3. Infrared 6 10 6 7600 51011 3.951016 (IR) (threshold frequency), no emission takes place
Incandescent however high the intensity of light may be.
objects
4. Visible 7 6 0 0 3 8 0 0 3.951016 7.91014 Electric Another important feature observed was that the
bulbs, kinetic energy of the electrons emitted is
sun rays independent of the Intensity of the light. The
5. Ultra violet 3800-150 7.9 1014 2 1016 Sun rays, arc
lamps with kinetic energy of the electrons increases linearly
(UV) with the frequency of incident light radiation. This
mercury
vapours was highly contrary to the laws of Physics at that
6. X-rays 150-0.1 2 1016 3 1019 Cathode rays time i.e. the energy of the electrons should have
striking metal
plate been proportional to the intensity of the light, not
7. rays 0.1-0.01 3 1019 3 10 20 Secondary on the frequency.
effect
of radioactive These features could not be properly explained
decay on the basis of Maxwells concept of light i.e.
8. Cosmic rays 0.01-zero 3 1 0 2 0 -infinity light as electromagnetic wave.
Outer space
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In 1905, Einstein applied Plancks quantum

* Continuous Spectrum: When sunlight (white
theory of light to account for the extraordinary
light) is passed through a prism, it is dispersed or
features of the photoelectric effect. He introduced
resolved into a continuous spectra of colours. It
a new concept that light shows dual nature. In
extends from RED (7600 ) at one end to the
phenomenon like reflection, refraction and
VIOLET (3800) at other end. In this region,
diffraction it shows wave nature and in
all the intermediate frequencies between red and
phenomenon like photoelectric effects, it shows
violet are present. The type of spectrum is known
particle nature. According to the particle nature,
as Continuous Spectrum., Hence continuous
the energy of the light is carried in discrete units
spectra is one which contains radiation of all the
whose magnitude is proportional to the frequency
frequencies.
of the light wave. These units were called as
* Discontinuous Spectrum: Light emitted from
photons (or quanta).
atoms heated in a flame or excited electrically in
According to Einstein, when a quantum of light
gas discharge tube, does not contain a continuous
(photon) strikes a metal surface, it imparts its
spectrum of wavelengths (or frequencies). It
energy to the electrons in the metal atom. In
contains only certain well-defined wavelength (or
order for an electron to escape from the surface
frequencies). The spectrum pattern appears as a
of the metal, it must overcome the attractive force
series of bright lines (separated by gaps of
of the nucleus in the metal atom. So a part of the
darkness) and hence called as Line-Spectrum.
photons energy is absorbed by the metal surface
One notable feature observed is, that each
to release the electron, this is known as work
element emits a characteristic spectrum,
function of the surface and is denoted by . The
suggesting that there is discrete relation between
the spectrum characteristics and the internal remaining part of the energy of the photon goes
atomic structure of an atom. into the kinetic energy of the electron emitted. If
* PHOTOELECTRIC EFFECT E is the energy of the photon, KE is the kinetic
It was observed by Hertz and Lenard around energy of the electron and be the work function
1880 that when a clean metallic surface is of the metal then we have;
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ATOMIC STRUCTURE JEE ADVANCED - VOL - I

h 0 and Ei h Note: The electromagnetic radiation

(or wave) now emerges as an entity which
KE Ei KE h h0 h( 0 )
shows dual nature i.e., sometimes as Wave
Also, if m be the mass and v be the velocity and sometimes as Particle (quantum aspect).
of the electron ejected then Illustration 2 : In a photoelectric experiment,
KE 1 mv 2 h( 0 ) . the collector plate is at 2.0 V with respect to
2
emitter plate made of copper (work function
1 2 c c 4.5 eV). The emitter is illuminated by a
KE mv h v v0 h source of mono-chromatic light of
2 0 wavelength 200 nm. Find the minimum and
maximum kinetic energy of photoelectrons
1 1
hc hc 0 reaching the collector.
0 .0 Solution: Since plate potentials 2 V, minimum K.E.
will be 2 eV. For max. K.E. use the following
relation:
Absorbed energy = Threshold energy + K.E.
KE
hc
4.5 1.6 10 19 K.E.

6.626 10 34 3 108
4.5 1.6 10 19 K.E.
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9
Intensity of light 200 10
K.E. = 2.739 10 19 J 1.7 eV
Max K.E. = 2eV + 1.7 eV = 3.7 eV.
* No. of waves per revolution made by an
KE
electron in nth orbit is
v 0 Threshold frequency
2 r 2 r
nn
Frequency h \ mv
2 mvr 2 nh
n n
h h 2
* QUANTUM NUMBERS
Photo To understand the concept of Quantum
electric
current Numbers, we must know the meaning of some
terms clearly so as to avoid any confusion.
* Energy Level: The non energy-radiating circular
Intensity
paths around the nucleus are called as Energy
Levels or Shells. These are specified by numbers
having values 1, 2, 3, 4, ... or K, L, M, N, ... in
order of increasing energies. The energy of a
Photo
electric
particular energy level is fixed.
current * Sub-Energy Level: The phenomenon of
splitting of spectral lines in electric and magnetic
fields reveals that there must be extra energy levels
within a definite energy level. These were called
Frequency
as Sub-Energy Levels or Sub-Shells. There are
four types of sub-shells namely; s, p, d, f.
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 JEE ADVANCED - VOL - I
First energy level (K or 1) has one sub-shell
designated as 1s, the second energy level (L or
2) has two sub-shell as 2s & 2p, the third energy
level (M or 3) has three sub shell as 3s, 3p and
3d, and the fourth energy level (N or 4) has four
sub-shells as 4s, 4p, 4d and 4f. The energy of
sub-shell increases roughly in the order: s < p <
d < f.
* Orbital: Each sub-energy level (sub-shell) is
composed of one or more orbitals. The orbitals
belonging to a particular sub-shell have equal
energies and are called as degenerate orbitals.
s-sub-shell has one orbital, p has three orbitals,
d have five orbitals and f has seven orbitals.
To describe or to characterize the electrons
around the nucleus in an atom, a set of four
numbers is used, called as Quantum Numbers.
These are specified such that the states available
to the electrons should follow the laws of
quantum mechanics or wave mechanics.
* Principal Quantum Number: (n): This
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quantum number represents the main energy
levels (principal energy levels) designated as n =
1, 2, 3, ... or the corresponding shells are named
as K, L, M, N, ... respectively. It gives an idea
of position and energy of an electron. The energy
level n = 1 corresponds to minimum energy and
subsequently n = 2, 3, 4, ..., are arranged in order
of increasing energy.
Higher is the value of n, greater is its distance
from the nucleus, greater is its size and also
greater is its energy.
It also gives the total electrons that may be
accommodated in each shell, the capacity of each
shell is given by the formula 2n2 , where n :
principal quantum number.
* Azimuthal Quantum Number ( ): This
number determines the energy associated with
the angular momentum of the electron about the
nucleus. It is also called as the angular momentum
quantum number. It accounts for the appearance
of groups of closely packed spectral lines in
electric field.
It can assume all integral values from 0 to n1.
The possible values of are : 0, 1, 2, 3, ..., n1.
Each value of describes a particular sub-shell
in the main energy level and determines the shape
of the electron cloud.
44
ATOMIC STRUCTURE
When n = 1, = 0, i.e., its energy level contains
one sub-shell which is called as a s-sub-shell.
So for = 0, the corresponding sub-shell is a s-
sub-shell. Similarly when = 1, 2, 3, the sub-
shells are called p, d, f sub-shells respectively.
As you know for n = 1, = 0, there is only one
sub-shell. It is represented by 1s. Now for n =
2, l can take two values (the total number of
values taken by is equal to the value of n in a
particular energy level). The possible values of
are 0, 1. The two sub-shell representing the
IInd energy level are 2s, 2p. In the same manner,
for n = 3, three sub-shells are designated as 3s,
3p, 3d corresponding to = 0, 1, 2, and for n =
4, four sub-shells are designated as 4s, 4p, 4d,
4f corresponding to = 0, 1, 2, 3.
The orbital Angular momentum of electron =
h
( 1) .
2
Note that its value does not depend upon value
of n.
Magnetic Quantum Number (m): An electron with
angular momentum can be thought as an electric
current circulating in a loop. A magnetic field due
to this current is observed. This induced
magnetism is determined by the magnetic
quantum number. Under the influence of magnetic
field, the electrons in a given sub-energy level
prefer to orient themselves in certain specific
regions in space around the nucleus. The number
of possible orientations for a sub-energy level is
determined by possible values of m corresponds
to the number of orbitals in a given sub-energy
level).
m can have any integral values between to
+ including 0, i.e., m = , 0, + . We can say
that a total of (2 + 1) values of m are there for
a given value of .
In s sub-shell there is only one orbital [ = 0, m
= (2 +1) = 1].
In p sub-shell there are three orbit als
corresponding to three values of m : 1, 0 +1.
[ = 1
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ATOMIC STRUCTURE JEE ADVANCED - VOL - I
m = (2 +1) = 3]. These three orbitals are n = 6, = 0, 1, 2, 3, 4, 5, m = 0,
represented as p x , p y , p z along X, Y, Z axes = 1, m = 1, 0, +1, = 2, m = 2, 1, 0, +1,
perpendicular to each other representing three +2, = 3, m = 3, 2, 1, 0, +1,
orientations. +2, +3, = 4, m = 4, to +4
In d sub-shell, there are five orbitals including 0, = 5, m = -5 to +5
corresponding to 2, 1, 0, +1, +2, including zero.
[ = 2 m = ( 2 2 1) 5] . These five b)(i) 2p, (ii)3s
orbitals are represented as
dxy ,dyz ,dzx ,dx2 y2 ,dz2 . * SHAPES OF ATOMIC ORBITALS
In f sub-shell t here are seven orbitals i) s-orbital: An electron is considered to be
corresponding to 3, 2, 1, 0, +1, +2, +3 immersed out in the form of a cloud. The shape
[ = 3 m = (2 3 1) 7] . of the cloud is the shape of the orbital. The cloud
* Spin quantum Number (s): When an electron is not uniform but denser in the region where the
rotates around a nucleus it also spins about its probability of finding the electron is maximum.
axis. If the spin is clockwise, its spin quantum The orbital with the lowest energy is the 1s orbital.
number is +1/2 and is represented as . If the It is a sphere with its center of the nucleus of the
spin is anti-clockwise, its value is 1/2 and is atom. The s-orbital is said to spherically
represented as . If the value of s is +1/2, then symmetrical about the nucleus, so that the
by convention, we take that electron as the first electronic charge is not concentrated in any
electron in that orbital and if the value of s is 1/ particular direction. 2s orbital is also spherically
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2, it is taken as second electron. symmetrical about the nucleus, but it is larger than
Spin quantum number do not depend on other (i.e., away from) the 1s orbit.
quantum numbers.
The quantum numbers +1/2 and -1/2 for the y

electron spin represent two quantum mechanical

spin states which have no classical analogue.
Illustration 3 : Write down the values of 1s 2s
quantum numbers of all the electrons nucleus x
present in the outermost orbit of neon (At.
No. 10)
Solution: The electronic configuration of neon is1s2, Z radial node

2s2,2p6. Values of quantum numbers are:

n ii) p-orbitals: There are three p-orbitals:
m s
p x ,p y and p z . they are dumb-bell shaped, the
2s2 2 0 0 +1/2, -1/2
2p x 2 2 1 +1/2, -1/2 two lobes being separated by a nodal plane, i.e.,
1
a plane where there is no likely hood of finding
2p y2 2 1 1 +1/2, -1/2 the electron. The p-orbitals have a marked
direction character, depending as whether
2p z 2 2 1 0 +1/2, -1/2
Illustration 4 : a) An electron is in 6f-orbital. p x ,p y and p z orbital are being considered. The
What possible values of quantum numbers p-orbitals consist of two lobes with the atomic
n, , m and s can it have? nucleus lying between them. The axis of each p-
b) What designation is given to an orbital is perpendicular to the other two. The
orbital having (i) n = 2, =1, and (ii) n = 3,
p x ,p y and p z orbitals are equivalent except for
= 0?
Solution: a) For an electron in 6f-orbital, their directional property. They have same
quantum number are: energy; orbitals having the same energy are said
to be degenerated.
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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
Electronic configuration of an element is
Y
'Y Z ' is n o d a l p la n e
represented by the notation nl x .
x : number of electrons present in an orbital, l :
denotes the sub-shell
n : principal quantum number.
* Radial distribution function :
X
The function which determines the probability of
2 P x o r b ita l finding an electron at a distance r from nucleus
is called Radial distribution function.
Z

z z
z

y y y

x x x

+
px py pz

iii) d-orbitals: There are five d-orbitals. The shapes

of four d-orbitals resemble four leaf cloves. The * Quantum Mechanical Model of Atom
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fifth d-orbital looks different. The shapes of these
orbitals are given below.
y z
Considering electron as a 3-D wave
Schrodinger proposed a wave equation to de
z
scribe the electron around the nucleus at a
point

x y x 2 2 2 8 2 m
2 E U 0
x 2 y 2 z 2 h
d xy
Where (Psi) = (Wave function)
dyz dzx
y z
amplitude of electron wave
x x x,y,z = cartesian coordinates
m = mass of electron
h = plancks constant
d x 2 y 2 dz 2 E = permissible total energy

* Extra Stability of Half and fully Filled ze 2

U = potential energy r
Orbitals: A particularly stable system is obtained
when a set of equivalent orbitals (degenerate Schrodinger wave equation can be trans
orbitals) is either fully filled or half filled, i.e., each formed into a wave equation in terms of the
containing one or a pair of electrons. This effect spherical polar coordinates r, and of
is more dominant in d and f sub-shells.
This means three or six electrons in p-sub-shell, the electron with respect to the nucleus. such
that
five or ten electrons in d-sub-shell, and seven or
fourteen electrons in f-sub-shell forms a stable x r sin cos
arrangement. Note this effect when filling of y r sin sin
electrons takes place in d sub-shells (for atomic z r cos
number Z = 24, 25, and 29, 30).
x2 y 2 z 2 r 2
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ATOMIC STRUCTURE JEE ADVANCED - VOL - I
When wave equation in polar coordinates is
solved it gives the possible energy states and Node
corresponding wave function 2

r , , which is called atomic orbital 2s

r , , Rn,l r l ,m m r

Radial part angular part

radial part dependent on r and angular part

dependent on and
as a function of distance from the
nucleus(r):

1s

r Radial probability distribution : D-function

(or) distribution function
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If we imagine infinitisimally small layers

around the nucleus (a layer of thickness
2s
dV) the probability of finding the electron in
each layer is given by radial distribution
function. Consider atom of spherical volume...
Node
4
V r3
3
r
4 2
differentiating dv 3 r .dr
3
Amplitude is not a characteristic prop
erty of a wave to describe it completely. so dv 4 r 2 dr
If multiplied by 2 the probability at a point
2 is considered which is the intensity i.e.
Probability of finding the electron in a 3D- gives distribution of electron in the small layer
space * Plot of D as a function of distance:
Plots of 2 as a function of distance:- D dv. 2 4 r 2 dr 2
(I) non-directional orbitals (s)

1s
2

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JEE ADVANCED - VOL - I ATOMIC STRUCTURE

b) Which depends on two directions(d)

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Plots of radial distribution functions 4pr2y2 for

various orbitals

(II) Directional orbitals

a) Which depends only on one direction (P)

c) Which depends on three directions (f)

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ATOMIC STRUCTURE JEE ADVANCED - VOL - I
0
LEVEL - IV 8. Electromagnetic radiation having 310 A
is subjected to a metal sheet having work
SINGLE ANSWER QUESTIONS function=12.8 eV. What will be the velocity
of photo-electrons having maximum kinetic
1. Rutherfords experiment, which established energy.
the nuclear model of the atom, used a beam
of (A) 0, no emission will occur
(A) -particles, which impinged on a metal foil (B) 4.352 106 m / s
and got absorbed (C) 3.09 106 m / s (D) 8.72 106 m / s
(B) -rays, which impinged on a metal foil and
ejected electrons 9. T he r at io of slopes of K maxvs. v and V0 vs. v
(C) helium atoms, which impinged on a metal curves in the photoelectric effect gives
foil and got scattered (v=frequency, kmax=maximum kinetic energy,
(D) helium nuclei, which impinged on a metal foil V0=stopping potential):
and got scattered (A) charge of electron (B) Plancks constant
2. Given the abundances of isotopes 54Fe, 56Fe,
57
Fe are 5%, 90% and 5% respectively, the (C) work function
atomic mass of Fe is (D) the ratio of Plancks constant of electron ic
(A) 55.85 (B) 55.95 charge
(C) 55.75 (D) 56.05 10. Photoelectron emission is observed for three
3. An -particle approaches the target nucleus different metals A,B and C. The kinetic
of copper(Z=29) in such a way that the value
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of impact parameter is zero. The distance energy of the fastest photoelectrons versus
of closest approach will be: frequency is plotted for each metal.
Which of the following graph shows the
2 0 (K.E) 29e 2
(A) (B) 2 K.E phenomenon correctly?
29e 2 0
4 0 K.E
(C) (D) K.E A
29e 2
B
4. When the frequency of light incident on a
metallic plate is doubled, the KE of the emit- C
ted photoelectron will be;
K.E

(A) doubled (B) Halved

(C) Increased but more than doubled of the (A)
previous KE
(D)Remains unchanged Quantum number
5. If 1017 J of light energy is needed by the Frequency (v)
interior of human eye to see an object. The
photons of green light ( 550nm ) needed
to see the object are
(A)27 (B)28 (C)29 (D)30 A
6. A 1-kW radio transmitter operates at a B
frequency of 880 Hz. How many photons per
second does it emit? C
(A) 1.71 1021 (B) 1.71 1030
K.E

23
(C)6.02 10 (D) 1.71 1033
7. Which of the following relates to photons (B)
both as wave motion and as a stream of
particles?
Frequency (v)
(A) Inference (B) E mc 2
(C) Diffraction (D) E h
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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
13. The mass of an electron is m,charge is e and
it is accelerated from rest through a
potential difference of V volts. The velocity
A acquired by electron will be
B
2eV eV V eV
K.E C ( A) (B) (C) (D)
m m m 2m
14. In two individual hydrogen atoms electrons
(C) move around the nucleus in circular orbits
of radii R and 4R. The ratio of the time taken
Frequency
by them to complete one revolution is:
(A)1 : 4 (B)4 : 1 (C)1 : 8 (D) 8 : 7
15. The difference in angular momentum
associated with the electron in two
A
successive orbits of hydrogen atoms is
B
h h h h
C
(A) (B) (C) (D) ( n 1)
2 2 2
K.E

(D) 16. The ionization energy of a hydrogen atom

in terms of Rydberg constant (RH) is given
Frequency (v)
by the expression
(A) RHhc (B)RHc (C) 2R Hhc
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11. The given diagram indicates the energy (D)RHhcNA

levels of a certain atom. When system 17. If the wavelength of series limit of Lyman
moves from 2E level to E level, a photon of series for He+ ion is x A0 , then what will be
wavelength is emitted. The wavelength
the wavelength of series limit of Balmer
of photon produced during the transition series for Li2+ ion?
4E 9x 0 16x 0 5x 0 4x 0
form to E level is is: (A) A (B) A (C) A (D) A
3 4 9 4 9
18. The potential energy of an electron in the
hydrogen atom is -6.8 eV. Indicate in which
2E
excited state, the electron is present?
4/3 E (A) first (B) second (C) third (D) fourth
19. What is the potential energy of an electron
E present in N-shell of the Be3+?
(A) -3.4 eV (B) -6.8 eV
0 (C) -13.6eV (D) -27.2 eV
20. The distance between 4th and 3rd Bohr
3 4 orbits of He+is:
(A) (B) (C) (D) 3 (A) 2.645x10-10m (B) 1.322x10-10m
3 4 3 -10
12. Which of the following postulates does not (C) 1.851x10 m (D) 6.8x10-10m
belong to Bohrs model of the atom? 21. The ratio of velocity of the electron in the
third and fifth orbit of Li2+ would be:
h (A) 3:5 (B) 5:3 (C) 25:9 (D) 9:25
(A)Angular momentum is an integralmultiple of
2 22. If in Bohrs model, for unielectronic atom,
(B) The electron stationed in the orbit is stable time period of revolution is represented as
(C) The path of an electron is circular Tn,zwhere n represents shell no. and Z
(D) The change in the energy levels of electron is represents atomic number then the value of
continuous T1,2:T2,1 will be:
(A) 8:1 (B) 1:8 (C) 1:1 (D) 1:32
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ATOMIC STRUCTURE JEE ADVANCED - VOL - I
23. The ionization potential for the electron in 28. The energy of a I, II and III energy levels
the ground state of the hydrogen atom is 13.6 4E
eV atom-1 . What would be the ionization of a certain atom are E, and 2E
3
potential for the electron inthe first exceited respectively. A photon of wavelength is
state of Li2+? emitted during a transition from III to I.
(A) 3.4 eV (B) 10.2 eV What will be the wavelength of emission for
(C) 30.6 eV (D) 6.8 eV II to I?
24. The mass of a proton is 1836 times more
than the mass of an electron. If a sub-atomic (A) (B) (C) 2 (D) 3
2
particle of mass (m!) 207 times the mass of 29. The angular momentum of an electron in
electron is captured by the nucleus, then the hydrogen atom is proportional to
first ionization potential of H:
1 1
(A) decreases (B) increases (A) r (B) (C) r 2 (D)
(C) remains same (D) may be decrease or increase r r
25. The energy of an electron moving in nth 30. The number of revolutions made by electron
Bohrs orbit of an element is given by in Bohrs 2nd orbit of hydrogen atom is
(A) 6.55 1015 (B) 8.2 1014
13.6 2
En Z eV/atom (Z=atomic number). (C) 1.64 1015 (D) 2.62 106
n2
The graph of E Vs . Z2 (keeping n constant 31. Ratio of frequency of revolution of electron
) will be: in the 2nd excited state of He+ and 2nd state
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of hydrogen is:
Z2 1 27
32 27
(A) (B) (C) (D)
E 27 32 54 2
32. A proton is accelerated from rest through a
E
(A) (B) potential difference of V volts has a
wavelenght associated with it. An alpha
Z2
particle in order to have the same
wavelength must be accelerated from rest
through a potential difference of
(A) V volt (B) 4V volt
E E
V
(C) (D) (C) 2V volt (D) volt
8
33. If the 2nd excitation potential for a
Z2 Z2
Hydrogen like atom in a sample is 108.9V.
26. Potential energy of electron present in He+ Then the series limit of the paschen series
is: for this atom is:
e2 3e 2 RH 32RH
(A) (B) (A) RH (B) 2 (C) 2 (D) 32 R H
2 0 r 4 0 r 3 4
34. Let U1 be the frequency of the series limit
2e 2 e 2
(C) (D) of the Lyman series, u2 be the frequency of
4 0 r 4 0 r 2 the first line of the Lyman series , and u3 be
27. The velocity of an e- in excited state of H- the frequency of the series limit of the
atom is 1.093 106 m / s . What is the Balmer series, then
circumference of this orbit? (A) u1 u 2 u 3 (B) u 2 u1 u 3
(A) 3.32 10 10 m (B) 6.64 1010 m 1
(C) 13.30 1010 m (D) 13.28 108 m (C) u 3 u1 u 3 (D) u1 u 2 u 3
2
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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
35. If the following matter waves travel with 41. Which of the following graphs correctly
equal velocity, the longest wavelength is that represents the variation of particle
of a/an. momentum with associated de Broglie
(A)electron (B)proton wavelength?
(C)neutron (D)particle
36. If 1 and 2 denote the de-Broglie
p
wavelength of two particles with same p

masses but charges in the ratio of 1 : 2 after (A) (B)

they are accelerated from rest through the

same potential difference, then

(A) 1 2 (B) 1 2
(C) 1 2 (D) 1 2 .
p
p
37. An electron in a H-like atom is in an excited (C) (D)
state. It has a total energy of 3.4 eV,
calculate the de-Broglies wavelength?

(A)66.5 (B)6.66
(C)60.6 (D)6.06 42. de Broglie wavelengths of two particles A
38. The stationary Bohrs orbit can be readily 1
explained on the basis of wave nature of and B are plotted against : where V
V
electron if it is assumed that
is the potential on the particles. Which of
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(A) wave in any of the orbits is the stationary

wave the following relations is correct about the
mass of the particles?
(B) the position of maxima and minima of wave
does not change with time B
(C) the length of the circular orbit must be an
integral multiple of the wavelength A

(D) wave in any of the orbit is not stationary wave

39. Consider the following statements regarding
Sommerfelds model. Select the correct
1
statement/s.
V
(A) Around the nucleus, some of the paths are
elliptical and others are circular (A) m A m B (B) m A m B
(B) When an electron revolves around the nucleus
in a circullar path, the angle of rotation is changed. (C) m A m B (D) m A m B
(C) Both, angle of rotation and distance from 43. A proton and an alpha particle are
the nucleus, are changed when an electron accelerated through the same potential
revolves in an elliptical path. difference. The ratio of the wavelenghts
(D) All are correct associated with the proton to that associated
40. The mass of a particle is 10 10 g and its with the alpha particle is
radius is 2 104 cm . If its velocity is 1
(A) 4 (B) 2 (C) 8 (D)
106 cm sec 1 with 0.0001% uncertainty in 8
44. The ratio of orbital angular momentum and
measurement, the uncertainty in its position
spin angular momentum of an electron in p
is :
orbital is
(A) 5.2 108 m (B) 5.2 10 7 m
3 3 2 2 2
(C) 5.2 106 m (D) 5.2 109 (A) (B) (C) (D)
2 2 3 3

52 Narayana Junior Colleges

ATOMIC STRUCTURE JEE ADVANCED - VOL - I

45. Probability of finding the electron 2 of s 52. For a f electron the orbital angular
orbital does not depend upon momentum is
(A) distance from the nucleus (r) h h h h
(B) energy of s orbital (a) 12 (B) 6 (C) 3 (D) 15

(C) principal quantum number
(D) azimuthal quantum number 53. If 0.53 A0 is Bohrs radius for the first orbit.
46. The orbital angular momentum of an elec- It suggest in the light of the wave mechanical
tron in 2s-orbital is model that
h h 2h (A) the product of 2 and 4r 2dr increase till
(A) (B) zero (C) (D)
4 2 2 it reaches at the distance of 0.53 A0
47. The subshell that arises after f is called the
(B) only 2 goes on increasing, 4r 2 dr remains
g subshell. How many electrons may occupy
the g subshell? constant till it reaches at the distance of 0.53 A0
(A) 9 (B) 7 (C) 5 (D) 18
48. The quantum numbers of most energetic (C) 2 goes on increasing , 4r 2 dr goes on
electron in Ar atom when it is in first excited
decreasing till it reaches at the distance of 0.53 A0
state is
(A)2, 1, 0, 1/2 (B)4, 1, 1, (D) only 4r 2 dr goes on increasing , 2 remains
(C)4, 0, 0, 1/2 (D)4, 1,
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0, 1/2 constant till it reaches at the distance of 0.53 A0

49. For a d electron, the orbital angular 54. Magnetic moments of V(Z = 23), Cr(Z = 24),
h Mn(Z = 25) are x, y, z. Hence:
momentum is (A) x = y = z (B) x < y < z
2
(C) x < z < y (D) z < y < x
(A) 6 (B) 2 (C) (D) 2 55. The value of the magnetic moment of a
50. The quantum numbers +1/2 and 1/ 2 for the particular ion is 2.83 Bohr magneton. The
electron spin represent ion is
(A) rotation of the electron in clockwise and (A) Fe2+ (B) Ni2+ (C) Mn2+ (D) Co3+
anticlockwise direction respectively 56. If the nitrogen atom has electronic
(B) rotation of the electron in anticlockwise and configuration 1s7, it would have energy lower
clockwise direction respectively than that of the normal ground state
(C) magnetic moment of the electron pointing up configuration 1s 2 2s 2 2p 3 because the
and down respectively electrons would be closer to the nucleus. Yet
(D) two quantum mechanical spin states which 1s7 is not observed because it violates
have no classical analogue (A) Heisenberg uncertainty principle
51. The schrodinger wave equation for hydrogen (B) Hunds rule
atom is (C) Pauli exclusion principle
3 (D) Bohr postulate of stationary orbits
1 1 2 r a 0
2s 2 e
4 2 a 0 a0 57. If the subsidiary quantum number of a
subenergy level is 4, the maximum and
where a 0 is Bohrs radius. If the radial node in minimum values of the spin multiplicites are
2s be at r 0, then r0 would be equal to: :
a0 a0 (A) 9,1 (B) 10,1 (C) 10,2 (D) 4,-4
(A) (B) 2a 0 (C) 2a 0 (D)
2 2
Narayana Junior Colleges 53
 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
58. The orbital diagram in which both the Paulis 64. Choose the correct statement(s) regarding
exclusion principle and Hunds rule are the photo-electric effect.
violated,is: (A) No electrons are ejected, regardless of the
intensity of the radiation, unless the frequency
(A) (B)
exceeds a thershold value characteristic of the
metal
(C) (D) (B) The kinetic energy of the ejected electrons
varies linearly with the frequency of the incident
MULTIPLE ANSWER QUESTIONS radiation and its intensity
(C) Even at low intensities, electrons are ejected
59. When alpha particles are sent through a thin immediately if the frequency is above the
metal foil, most of them go straight through threshold value
the foil because: (D) An intense and a weak beam of
(A) alpha particles are much heavier than monochromatic radiations differ in having number
electrons of photons and not in the energy of photons
(B) alpha particles are positively charged 65. The energy of an electron in the first Bohr
(C) most part of the atom is empty space orbit of H atom is 13.6eV . The possible
(D) alpha particle move with high velocity
energy value(s) of the excited state(s) for
60. Many elements have non-integral atomic
masses because electrons in Bohr orbits of hydrogen is/are
(A) they have isotopes (A) 3.4 eV (B) 4.2 eV
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(B) their isotopes have non-integral masses (C) 6.8eV (D) 6.8eV
(C) their isotopes have different masses 66. In which of the following conditions the de
(D) the cosstituents, neutrons, protons and
Broglie wavelength of particle A will be less
electrons combine to give fractional masses
61. Which statement about cathode rays is than that of partilce B m A m B ?
correct? (A) Linear momentum of these particles are same
(A) They travel in straight lines towards cathode
(B) Move with same speed
(B) They produce fluorescent discharge through
the walls of the tube (C) Move with same kinetic energy
(C) They produce heating effect (D) have fallen through same height
(D) They can affect photographic plate 67. Which of the following quantum numbers is/
62. Which statements concerning Bohrs model are not allowed?
are true? (A) n 3, l 2, m 0 (B) n 2, l 2, m 1
(A) Predicts that probability of electron near
(C) n 3, l 0, m 1 (D) n 5, l 2, m 1
nucleus is more
(B) Angular momentum of electron in H-atom = 68. Which represent a possible arrangement ?
n m s
nh
(A) 3 2 2 1/2
2
(C) Introduces the idea of stationary states (B) 4 0 0 1/2
(D) Explain line spectrum of hydrogen (C) 3 2 3 1/2
63. In Rutherfords gold foil experiment, the (D) 5 3 0 1/2
scattering of -particles takes place. In this 69. T he pr obability of finding the electr on in p x-
process: orbital is
(A) coulombic force is involved (A) maximum on two opposite sides of the
(B) nuclear force is involved nucleus along x-axis
(C) path of -particle is parabolic (B) zero at the nucleus
(D) path of -particle is hyperbolic (C) same on all the sides around the nucleus
(D) zero on the z-axis
54 Narayana Junior Colleges
ATOMIC STRUCTURE JEE ADVANCED - VOL - I
70. g orbital is possible if
(A) n = 5, l 4 ASSERTION & REASON QUESTIONS
(B) It will have 18 electrons
(C) Sublevel will have 9 orbitals 76. Statement- 1 : The kinetic energy of photo-
(D) It will have 22 electrons electrons increases with increase in
71. Choose the correct statement(s):
(A) For a particular orbital in hydrogen atom, frequency of incident light where 0 .
the wave function may have negative value Statement - 2: Whenever intensity of light is
(B) Radial probability distribution function may increased the number of photo-electron ejected
have zero value but can never have negative value always increases.
(C) 3d x 2 y 2 orbital has two angular nodes and (A) If both the statement are TRUE and
one radial node. STATEMENT -2 is the correct explanation of
STATEMENT -1
(D) yz and xz planes are nodal planes for d xy (B) If both the statements are TRUE but
orbital STATEMENT-2 is NOT the correct explanation
72. Choose the correct statement(s): of STATEMENT-1
(A) Heisenbergs principle is applicable to
(C) If STATEMENT-1 is TRUE and
stationary e STATEMENT -2 is FALSE
(B) Paulis exclusion principle is not applicable (D) If STATEMENT-1 is FALSE and
to photons STATEMENT-2 is TRUE
(C) For an e , the product of velocity and 77. Statement -1: Half -filled and fully-filled
principal quantum number will be independent degenerate orbitals are more stable
of principal quantum bumber
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Statement - 2: Extra stability is due to the

(D) Quantum number l and m determine the value
of angular wave function symmetrical distribution of electrons and
73. Select the correct statements about the wave exchange energy
function . (A) If both the statement are TRUE and
(A) must be real STATEMENT -2 is the correct explanation of
(B) must be single valued, continuous STATEMENT -1
(C) has no physical significance (B) If both the statements are TRUE but
STATEMENT-2 is NOT the correct explanation
(D) 2 gives the probability of finding the
of STATEMENT-1
electrons
(C) If STATEMENT-1 is TRUE and
74. Which of the following is/are correct energy
order for H-atom? STATEMENT -2 is FALSE
(A) 1s < 2s < 2p < 3s < 3p (D) If STATEMENT-1 is FALSE and
(B) 1s < 2s = 2p < 3s = 3p STATEMENT-2 is TRUE
(C) 1s < 2p < 3d < 4s 78. Statement -1: The ground state
(D) 1s < 2s < 4s < 3d configuration of Cr is 3d 5 4s1
75. Ground state electronic configuration of Statement - 2:A set of half-filled orbitals
nitrogen atom can be represented by
containing one electrons each with their spin
parallel provides extra stability.
(A) (A) If both the statement are TRUE and
STATEMENT -2 is the correct explanation of
STATEMENT -1
(B) (B) If both the statements are TRUE but
STATEMENT-2 is NOT the correct explanation
of STATEMENT-1
(C)
(C) If STATEMENT-1 is TRUE and
STATEMENT -2 is FALSE
(D) (D) If STATEMENT-1 is FALSE and
STATEMENT-2 is TRUE
Narayana Junior Colleges 55
 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
79. STATEMENT-1 80. The ratio of the wave numbers for the
For hydrogen orbital energy increases as 1s < highest energy transition of e in Lyman and
2s < 2p < 3s < 3p < 3d < 4s < 4p Balmer series of H-atom is:
STATEMENT-2 (A)4 : 1 (B)6 : 1 (C)9 : 1 (D)3 : 1
The orbital with lower (n + ) value has lesser 81. If proton in H-nucleus be replaced by
energy and hence filled up first. positron having the same mass as that of
(A) If both the statement are TRUE and electron but same charge as that of proton,
STATEMENT -2 is the correct explanation of then considering the nuclear motion, the
STATEMENT -1 wavenumber of the lowest energy transition
(B) If both the statements are TRUE but of He+ ion in Lyman series will be equal to
STATEMENT-2 is NOT the correct explanation (A)2 RH (B)3 RH (C)4 RH (D)RH
of STATEMENT-1
(C) If STATEMENT-1 is TRUE and PASSAGE 2
STATEMENT -2 is FALSE A german physicist gave a principle about
(D) If STATEMENT-1 is FALSE and the uncertainties in simultaneous
STATEMENT-2 is TRUE measurement of position
and momentum of small particles. According
COMPREHENSIONS QUESTIONS to that physicist. It is impossible to measure
simultaneously the position and momentum
PASSAGE 1 of small particle with absolute accuracy or
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For a single electron atom or ion the wave certainty. If an attempt is made to measure
number of radiation emitted during the any one of these two quantities with higher
transition of electron from a higher energy accuracy , the other becomes less accurate.
state (n = n2) to a lower energy state (n = n1) The product of the uncertainty in position
is given by the expression:
x and uncertainty momentum p is
1 1 1
R H .z 2 2 2 (1) always constant and is equal to or greater
n1 n2
than h / 4 , where h is Plancks constant
22 m k 2e 4 i.e.
where R H = Rydberg constant for
h 3c h
H-atom x p
4
where the terms have their usual meanings.
82. If uncertainty in position is twice the
Considering the nuclear motion, the most
uncertainty in momentum, then uncertainty
accurate expression would have been to
in velocity is
replace mass of electron (m) by the reduced
mass ( ) in the above expression, defined h 1 h
(A) (B)
as 2m
m.m
1 1 h
m m (C) h (D)
2m 2 2m
where m ' = mass of nucleus
For Lyman series : n1 = 1 (fixed for all the lines) 83. The uncertainty in position of an electron
while n2 = 2, 3, 4, for successive lines i.e. 1st, m 9.1 10 28

gm moving with a velocity
2nd, 3rd lines, respectively. For Balmer series
: n1 = 2 (fixed for all the lines) while n2 = 3, 4, 5 3 10 4 cm / s accurate upto 0.001% will be
for successive lines. (A) 3.84 cm (B)1.92 cm
(C)7.68 cm (D)5.76 cm

56 Narayana Junior Colleges

ATOMIC STRUCTURE JEE ADVANCED - VOL - I
84. If uncertainty in the position of an electron 88. The orbital angular momentum of electron
is zero , the uncertainty in its momentum 1 makes an angle of 450 from Z-axis.
would be The LZ of electron will be
(A) zero (B) h / 4
(C) h / 4 (D)Infinite h h h h
(A) 2 2 (B) 0 2 (C) (D) 3
2 2
PASSAGE 3: 89. An orbital has n=5 and its value is the
In the Rutherfords experiment, -particles maximum possible. The orbital angular
were bombarded towards the copper atoms momentum of the electron in this orbital will
so as to arrive a distance of 10-13 metre from be
the nucleus of copper and then getting either h h
deflected or traversing back. The - (A) 2 (B) 6
2 2
particles did not move further closer
86. The velocity of the -particles must be h h
(C) 12 (D) 20
(A) 8.32 108 cm / sec 2 2
(B) 6.32 108 cm / sec PASSAGE 5
The sum of spins of all the electrons is the
(C) 6.32 108 m / sec total spin(S) and (2S + 1) is called spin
(D) 6.32 108 km / sec multiplicity of the electronic configuration.
87. From Rutherfords -particle scattering, it can Hunds rule defines the ground state
be concluded that configuration of electrons in degenerate
orbitals i.e., orbitals within the same sub-shell
1 which have the same values of n and l , states
(A) N sin (B) N
2 sin 4 that in degenerate orbitals pairing of
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1 electrons does not occur unless and until all

(C) N 4 (D) N sin such orbitals are filled singly with their
sin ( / 2) 2 parallel spin. A spinning electron behaves
88.It can also be concluded that the electrostatic as though it were a tiny bar magnet with
potential energy is equal to poles lying on the axis of spin. The magnetic
1 q1q2 1 5Ze 2 moment of any atom, ion or molecule due to
(A) 4 r (B) spin called spin-only magnetic moment (ms)
0 4 0 mv 2 is given by the formula.
Ze 2 s n n 2 B.M
(C) (D) mv 2
r where n = number of unpaired electron(s)
PASSAGE -4 90. The spin-only magnetic moment of Cr3+ ?
h (A) 3 B.M. (B) 8 B.M.
L 1
2 (C) 15 B.M. (D)Zero
On the other hand, m determines Z- 91. The spin-multiplicity of Fe3+ (Ec=[Ar]3d5) in
component of orbital angular momentum as its ground state
h (A)6 (B)2 (C)3 (D)4
Lz m
2
Hunds rule states that in degenerate INTEGER TYPE
orbitals electron s do not pair up unless and
until each such orbital has got an electron 92. Spin multiplicity of Nitrogen atom is
with parallel spins.
Besides orbital motion, an electron also 93. The work function of some metals is
possess spin -motion. Spin may be clockwise listed below. The number of metals which will
and anti-clockwise. Both thes spin motions show photoelectric effect when light of 300
are called two spin states of electron nm wavelenght falls on the metal is (2011)
characterised by spin.
1 1
Q.N (s): s and s respectively..
2 2

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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
94. Difference between nth and (n + 1)th Bohrs 107. One mole of photons, each of frequency 250
radius of H atom is equal to its (n 1)th sec-1 would have approximately a total
Bohrs radius. The value of n is energy in ergs
95. A single electron system has ionisation en-
ergy 11180 KJ mole-1. The number of pro- MATRIX MATCHING TYPE
tons in the nucleus of the system is ...
96. The number of spectral lines produced when 108. Column I Column II
an electron jumps from 5th orbit to 2nd orbit (A) 310 (p) 5 f
in the hydrogen atom is.
97. In an collection of H-atoms , all the elec- (B) 120 (q) 3 px or 3 p y
trons jump form n=5 to ground level finally (C) 530 (r) 3 pz
(directly or indirectly), without emitting any
line in Balmer series. The number of pos- (D) 311 (s) impossible
sible different radiations is:
98. In a single isolated atom an electron make 109. Column I Column II
transition from 5th excited state to 2nd state (A) Thomson model (p) Electrons are
then maximum number of different types of of atom present in extra
nuclear region
photons observed is
(B) Rutherford model (q) Atom is electrically
99. The number of waves made by a Bohr
of atom neutral
electron in Hydrogen atom in one complete
(C) Bohr model of atom (r) Positive charge is
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revolution in the 3rd orbit is. accumulated

100. The minimum number of waves made by an in the nucleus
electron moving in an orbit having maximum (D) Sommerfeld model (s) Uniform sphere of
magnetic quantum number +3 is. of atom positive charge with
101. The wave function of an orbital is embeded electrons
represented as 420 . The azimuthal quantum 110. Column I Column II
number of that orbital is (A) Radial function ( r ) (p) Principle Q.No.
102. The radial distribution curve of the orbital
(B) Angular function ( ) (q) Azimuthal Q.No.
with double dumbbell shape in the 4 th
principle shell consists of n nodes, n is (C) Angular function ( ) (r) Magnetic Q.No
103. A compound of vanadium possesses a (D) Quantized angular
magnetic moment of 1.73 BM. the oxidation momentum (s) Spin Q.No
state of vanadium in this compounds is: (t) Shape of orbital
104. Magnetic moment of M x is 24BM . The 111. Column- I Column- II
number of unpaired electrons in M x is. (A) Radius of n orbit (p) Inversely
th

proportional to z
105. How many d electrons in Cu ( At.No 29)
(B) Energy of n orbit (q) Integralmultiple of
th

1 h
can have the spin quantum ? ` 2
2
(C) Velocity of electron (r) Proportional to x10-
10
106. The maximum number of electrons can have m in the nth orbit
pricipal quantum number n = 3 and spin (D) Angular momentum (s) Inversely of electron
proportional to n
1 (t) Inversely
quantum number Mz is (2011)
2 proportional to n 2

58 Narayana Junior Colleges

ATOMIC STRUCTURE JEE ADVANCED - VOL - I
112. Column- I Column- II 2. Which of the following does not characterise
(Phenomenon related (Character of the to X-rays?
electron) electron) (A) The radiation can ionize gases
(A) Working of electron (p) Wave nature
(B) It causes ZnS to fluoresce
microscope
(B) Photoelectric effect (q) Particle nature (C) Deflected by electric and magnetic fields
(C) Diffraction (r) Particle nature (D) Have wavelengths shorter than ultraviolet rays
dominates the wave nature 3. A 3p orbital has
(D) Scintillation (s) Wave same (A) two non-spherical nodes
dominates the particle nature. (B) two spherical nodes
113. Column I Column II
(C) one spherical and one non-spherical node
(A) 2p orbital (p) Number of
(D) one spherical and two non-spherical nodes
spherical nodes =0
(B) 3d orbital (q) Number of nodal 4. The orbital angular momentum of an electron
plane =0 in 2s orbital is
(C) 2s orbital (r) Orbital angular 1 h
momentum number =0 (A) . (B) zero
2 2
(D) 4f orbital (s) Azimuthal quantum
number=0 h h
(C) (D) 2.
114. Column I Column II 2 2
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h 5. The first use of quantum theory to explain

(A) Orbital angular (P) s s 1
2 the structure of atom was made by
momentum of an electron (A) Heisenberg (B) Bohr
(C) Planck (D) Einstein
(B) Angular momentum (Q) n n 2
6. For a d-electron, the orbital angular
of an electron in an orbit momentum is
nh (A) 6 h / 2 (B) 2 h / 2
(C) Spin angular (R)
2
momentum of an electron (C) h / 2 (D) 2 h / 2

h 7. The electrons, identified by quantum

(D) Magnetic moment (S) 1 numbers n and l , (i)n = 4, l = 1, (ii) n = 4, l
2
of atom =0,(iii)n=3, l = 2, and (iv) n = 3, l = 1
can be placed in order of increasing energy,
PREVIOUS YEARS IIT JEE QUESTIONS from the lowest to highest, as
(1999)
SINGLE CORRECT ANSWER TYPE (A) (iv) < (ii) < (iii) < (i)
(B) (ii) < (iv) < (i) < (iii)
1. Which of the following relates to photons (C) (i) < (iii) < (ii) < (iv)
both as wave motion and as a stream of (D) (iii) < (i) < (iv) < (ii)
particles? 8. The number of nodal planes in a px orbital is
(A) Inference (B) E mc 2 (2000)
(C) Diffraction (D) E h (A) one (B) two
(C) three (D) zero

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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE
9. The radius of which of the following orbits is
same as that of the first Bohrs orbit of 83) B 84) D 85) D 86) B
87) C 88) C 89) D 90) C
hydrogen atom?
91) A 92) 4 93) 4 94) 4
(A) He+ (n = 2) (B) Li2+ (n = 2)
95) 4 96) 6 97) 7 98) 4
(C) Li2+( n = 3) (D) Be3+ (n = 2) 99) 3 100) 4 101) 2 102) 1
103) 4 104) 4 105) 5 106) 9
MULTIPLE ANSWER TYPE 107) 1
108) A-r; B-s; C-p; D-q
10. Which of the following statement(s) is/are 109) A-q,s; B-p,q,r; C-p,q,r; D-p,q,r
correct? (1998) 110) A-p,q; B-q,t; C-r,t; D-q,s
(A) The electronic configuration of Cr is 111) A-p,r; B-r,t; C-s; D-q
[Ar]3d54s1. (Atomic number of Cr = 24) 112) A-p,s; B-q,r; C-p; D-q
(B) The magnetic quantum number may have a 113) A-p; B-p; C-q,r,s; D-p
negative value. 114) A-s; B-r; C-p; D-q
(C) In silver atom, 23 electrons have a spin of
PREVIOUS IIT JEE QUESTIONS
one type and 24 of the opposite type.
(Atomic number of Ag = 47)
KEY
1.(D) 2.(C) 3.(C) 4.(B)
(D) The oxidation state of nitrogen in HN 3 is 3
5.(B) 6.(A) 7. (A) 8.(A)
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9.(D) 10.(A), (B), (C)

LEVEL - IV - KEY

1) D 2) B 3) B 4) C LEVEL - IV - HINTS
5) B 6) D 7) D 8) C
9) A 10) C 11) D 12) D 1. It is Rutherford - scatering experiment
13) A 14) C 15) B 16) A
PM P M P M
17) B 18) A 19) D 20) C 2. Avg: At wt 1 1 2 2 3 3
21) B 22) D 23) C 24) B 100
25) B 26) C 27) C 28) D 1 QQ
3. r0 . 1 2
29) A 30) B 31) A 32) D 4 0 KE
33) A 34) A 35) A 36) C
4. h =h 0 +KE , threshold frequency of metal is
37) B 38) C 39) D 40) A
41) D 42) B 43) C 44) C constant
45) D 46) B 47) D 48) C hc
5. E n.
49) A 50) D 51) B 52) C
53) A 54) C 55) B 56) C hc
57) B 58) D 59) A,C 6. E n. (1kW =1000J)

60) A,C 61) B,C,D 62) B,C,D 7. Planks quantum theory
63) A,D 64) A,C,D 65) A
hc 1
66) B,D 67) B,C 68) A,B,D 8. mv 2
69) A,B,D 70) A,B,C 71) A,B,D 2
72)B,C,D 73) A,B,C,D 74) B,C 9. KE h h 0
75) A,D 76) B 77) A 78) A eV0 h h 0
79) D 80) A 81) B 82) D
h
ratio of slopes = h / e e

60 Narayana Junior Colleges

ATOMIC STRUCTURE JEE ADVANCED - VOL - I
10. Different metals have different work function ie 25. y mx plot
different threshold frequencies
1 ze2
hc 26. PE .
11. 2E E E 40 r

27. Vn 2.18 108 / n cm / sec
4 E
E ? New wave length = 3 Where n=2
3 3
12. Bohrs concept Circum ference = 2rn
1 hc
13. v 28. Apply E
n
vn cons tan t nh
29. mvr
T1 n13 2
14. Tn 3 Where n1 1, n 2 2
T2 n 32 rn n 2
nh angular momentum of e r
15. mvr
2 Vn,z
16. IE E1 30. f n,z
2rn,z
R H ch z2 15
R H ch 6.56 10 3
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n
1 1 1 z2
17. 2 2 R H .z 2 31. f n,z
n1 n 2 n3
18. PE=2(T.E) h
32.
19. PE 2 T.E 2mq.v

13 Z 2 m p. 1 .V
2 2
n p 4m p . 2 .x
n2 v
20. rn ,z 0.529 x
Z 8
n3 1 1
21. Tn,z
z2 33. E 13.6 z 2 2 2
n1 n 2
n3 z=3
22. Tn,z
z2
1
2 R H .z 2 2 RH
Z 3
23. I.E
n2 34.
24. I.E R H .ch

2 2 4e 4 .K 2 1
3
RH
Ch 3 3

m1.m 2
Where reduced mass 1 2
m m 1

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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE

h 54. n n 2
35.
mv
55. n n 2 Where n=2
h
36. 56. Pauli exclusion principle concept
2.m.q.v
57. Spin multiplicity =2s+1
2rn 58. filling rules concept
37. n=2 2rn n n n
n 59. Ruther fords ray experiment concept
38. 2 rn n n P1M1 P2 M 2 ...
60. At.wt
39. sommerfeds concept p1 p 2 ....
h 61. Cathode rays properties
40. x where v 1012
4m.v 62. Bohrs concept
h 63. Ruther fords -ray experiment concept
41. .p constant graph
p 64. Photo electric effect concept
h 13.6
65. En ev / atom
42. 2m.q.v n2
66. Quantumm numbers concept
h 68. Quantum Numbers concept
43.
2m.q.v 69. Px-orbital has dumb bell shape and is situated
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h along x-axis
44. Orbital angular momentum= L 1 . 70. Orbital concept71. Orbital concept
2
h 1
72.
Spin angular momentum= s s 1 . n
2
45. For s orbital, depends only on n quantums
2
r, , R n,l r . l,m . m
no
73. Properties of
h 74. In H-atom, all are degenerate orbitals in a given
46. L 1 .
2 main shell
47. g subshell has 9 orbitals 75. Hunds maximum multiplicity rule
48. quantum numbers concept
76. h h 0 KE
h
49. L 1 . 77. Electronic configuratio concept
2
78. Electronic configuration concept
50. Spin quantum number concept
79. For H-atom, all are degenerate orbitlas in a given
51. At node 2 0 hence 0
main shell
r 2a 0
h
1 1
L 1 . 80. R H .z 2 2 2
52.
2 n1 n 2
1 1
81. R H .z 2 2 2 =3R
n1 n 2 H

82. x 2 p
53.
h
x.v
4m

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h 102. no. of radial nodes n 1

83. x
4m.v 103. s n n 2 Where n=1
h
84. x. p 104. s n n 2 Where n=4
4
85. CONCEPTUAL 105. configuration is Ar 3d10
86.At the distance of closest approach 106. n = 3, l = 0,1,2
2 Ze2e 1 1 1
v2 for l = 0 m = 0 mz ,
4 0 r0 m hence, substituting the value of 2 2
m = 4, Z = 29, e = 1.66 x 10-19, ro = 10-13m. 1 1
87.CONCEPTUAL l=1 m = -1 mz ,
2 2
88. L z L cos
1 1
h l=1 m = 0 mz ,
L 1 . 2 2
89.
2 1 1
l=1 m = 1 mz ,
90. s n n 2 2 2
91. Spin multiplicity =2S+1
92. Spin multiplicity = 2S + 1 1 1
for l = 2 m = -2 mz ,
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93. Incident radiation energy is 4.13 ev 2 2

Condition : E E 0
0 1 1
94. R n 0.529 n 2 A for l = 2 m = -1 mz ,
2 2
52 4 2 32 1 1
1312 for l = 2 m = 0 mz ,
I .E. Z2 2 2
95. 2
n
n n 1 1 1
96. no. of spectral lines = for l = 2 m = +1 mz ,
2 2 2
n n 2 n 1 1 1
for l = 2 m = +2 mz ,
2 2
5 OR
n=3
4
number of electors 2n 2 2 32 18
3
97. 1 18
2 electons with ms 9
2 2
1 107. Total energy = N0hv
108. Based on quantam mechanics
98. In a single isolated atom, no .of spectral lines 109. Different atomic models concept
formed=n2-n1. 110. Based upon orientation of electrons
99. no. of waves in n th orbit n
n2 z2
100.CONCEPTUAL 111. rn,z E n,z
z n2
101 n,l,m is the wave function of given orbital
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 JEE ADVANCED - VOL - I ATOMIC STRUCTURE

z Hence, the plane yz is called nodal plane as it

Vn,z mvr n has zero electron density in it.
n
112. Dual nature of light concept z
y
113. no. of radial nodes n 1
no.of nodal palnes = x

h
L 1 .
2
h nh 0.529n 2 o
9. Radius of an orbit = A
114. L 1 . mvr Z
2 2
In case of hydrogen Ist orbit n = 1, Z = 1,
h
Spin angular momentum = s s 1 .
o

2 rH 0.529 A
for Be 2+ , n = 2, Z = 4 =
Magnetic moment s n n 2
0.529 n 2 0.529 2 2 o

PREVIOUS YEARS 0.529A

Z 4
IIT JEE QUESTIONS 10. (A) Electronic configuration of Cr (Ar) 3d54s1.
HINTS (B) Magnetic quantum can have a negative value
c as m = l to l .
1. E h h relates for wave motion. (C) In Ag[Kr]4d105s1
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23 electrons have spin of one type and 24 of the
E mc 2 as particles. opposite type.
2. X-rays being neutral are not deflectd by magnetic 24 electrons have spin of other type due to 5s1.
and electric fields.
3. Number of radial nodes = n l 1 Fo r 3p- ***
orbital n = 3, l 1 for p-orbital
Number of spherical or radial nodes = 3 - 1- 1
=1
Number of angular nodes = l
For 3p, l = 1 for p-orbital, angular node = 1
It has one spherical and one non-spherical node.
h
4. l l 1 for s-orbital l 0 . Hence,
2
orbital angular momentum 0.0
5. Bohr made use of quantum theory and gave the
structure of atom.
h
6. l l 1 ; For d-orbital l 2 ;
2
h h
23 6
2 2
7. Aufbaus principle
8. Nodal plane is that plane at which probability of
finding electron density is zero. In case of px the
dumb-bell shape orbital has two lobes on x-axis.
64 Narayana Junior Colleges