EQUAO DE ANTOINE

B p = presso de vapor, mmHg

log p= A T = temperatura, C

C+T A, B, C = constantes

Substncia Frmula A B
1 Acetona C3H6O 7.02447 1161.00
2 cido actico C2H4O2 7.18807 1416.70
3 gua H2O 7.96681 1668.21
4 Anilina C6H7N 7.24179 1675.30
5 Benzeno C8H6 6.90565 1211.03
6 i-Butano C4H10 6.74808 882.80
7 n-Butano C4H10 6.83029 945.90
8 Estireno C8H8 6.92409 1420.00
9 Etanol C2H6O 8.04494 1554.30
10 ter dietlico C4H10O 6.78574 994.20
11 Etilbenzeno C8H10 6.95719 1424.26
12 Etilenoglicol 7.88080 1957.00
13 n-Heptano C7H16 6.90240 1268.12
14 n-Hexano C6H14 6.87776 1171.53
15 n-Octano C8H18 6.92370 1355.13
16 i-Pentano C5H12 6.78967 1020.01
17 n-Pentano C5H12 6.85221 1064.63
18 Tolueno C7H8 6.95464 1344.80
19 o-Xileno C8H10 6.99891 1474.68
20 m-Xileno C8H10 7.00908 1462.27
21 p-Xileno C8H10 6.99052 1453.43
OINE
vapor, mmHg

C
224.00
211.00
228.00
200.00
220.79
240.00
240.00
206.00
222.65
220.00
213.21
193.80
216.90
222.37
209.52
233.10
232.00
219.48
213.69
215.11
215.31
 Presso = 760 (mmHg)

SUBST. A = Benzeno 5 SUBST. B =

CTE. A = 6.9057 CTE. A =
CTE. B = 1211.0330 CTE. B =
CTE. C = 220.7900 CTE. C =
Teb = 80.1 Teb =

Temp. (C) pA pB x y
80.1000 760.00 292.23 1.0000 1.0000
81.6263 796.39 307.94 0.9255 0.9698
83.1525 834.13 324.34 0.8546 0.9379
84.6788 873.26 341.42 0.7870 0.9043
86.2051 913.81 359.23 0.7227 0.8689
87.7313 955.80 377.77 0.6613 0.8316
89.2576 999.29 397.07 0.6027 0.7924
90.7839 1044.30 417.15 0.5467 0.7512
92.3101 1090.87 438.04 0.4932 0.7079
93.8364 1139.03 459.75 0.4420 0.6625
95.3627 1188.82 482.31 0.3930 0.6148
96.8889 1240.28 505.75 0.3461 0.5649
98.4152 1293.45 530.08 0.3012 0.5126
99.9415 1348.35 555.33 0.2581 0.4579
101.4677 1405.03 581.53 0.2167 0.4006
102.9940 1463.53 608.71 0.1770 0.3408
104.5203 1523.87 636.87 0.1388 0.2783
106.0465 1586.11 666.06 0.1021 0.2131
109.0991 1716.40 727.60 0.0328 0.0740
110.6253 1784.54 760.00 0.0000 0.0000

Curva de equilbrio:Benzeno / Tolueno

 Tolueno 18
6.9546
1344.8000
219.4820
110.6

a
-
2.5862
2.5718
2.5577
2.5438
2.5301
2.5167
2.5034
2.4904
2.4775
2.4648
2.4524
2.4401
2.4280
2.4161
2.4043
2.3927
2.3813
2.3590
#DIV/0!
 Curva de equilbrio: Benzeno / Tolueno
1.0000

0.9000

0.8000

0.7000

0.6000
Y

0.5000

0.4000

0.3000

0.2000

0.1000

0.0000
0.00000.10000.20000.30000.40000.50000.60000.70000.80000.90001.0000
X
 Diagrama das temperaturas de ebulio
116.0000
112.0000
108.0000
104.0000
100.0000
96.0000
92.0000
88.0000
T

84.0000
80.0000
76.0000
72.0000
68.0000
64.0000
60.0000
56.0000
52.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
X