ENGINEERING DESIGN CALCULATION - DENNIS KIRK ENGINEERING

Calculation of Gas Properties - GPSA Engineering Data Book - SI Units - 11th Edition 1998 Version 1.510

CALCULATION TITLE

Enter details and data into the cells with a yellow background only.
Calculated values on the right side are provided for reference only.
Real Cp, Cv, k and VOS are calculated using the Redlich Kwong EOS.
Uniformly Data can be stored and recovered from the Library at the right by highlighting
Normalised and copying the data within the green border and "pasting values" into the library.
mole % mole % ID
CH4 Methane 86.0115 86.0115 % ###
C2H6 Ethane 6.31691 6.3169 % ###
C3H8 Propane 2.2373 2.2373 % R= 8.314510 kJ/kg.mol.degK ###
C4H10 I-Butane 0.41556 0.4156 % MW air= 28.9625 kg/kmol ###
C4H10 n-Butane 0.56587 0.5659 % Zb air= 0.99958 ###
C5H12 i-Pentane 0.24379 0.2438 % Pb= 0 kPa(g) 0 0 psi(g) ###
C5H12 n-Pentane 0.16037 0.1604 % Ps= 101.325 kPa(abs) ###
C6H14 n-Hexane 0.16453 0.1645 % Pb= 101.325 kPa(abs) ###
C7H16 n-Heptane 0.09306 0.0931 % Tb= 15 degC 15 59 o
F ###
C8H18 n-Octane 0.04622 0.0462 % Ts= 273.15 degK ###
C9H20 n-Nonane 0.01982 0.0198 % Tb= 288.15 degK ###
C10H22 n-Decane 0 0.0000 % ###
UNITS:
C6H6 Benzene 0 0.0000 % This application is written around the calculations in the SI Units version of the Data ###
CO Carbon Monoxide 0 0.0000 % Books and all calculations are carried out in SI units. ###
CO2 Carbon Dioxide 3.24657 3.2466 % The application, however, continually provides the outcome in both SI and US units ###
H2S Hydrogen Sulfide 0 0.0000 % on the two worksheets. ###
N2+02 Air 0 0.0000 % The controls on the US units worksheet allow the operator to select which units they ###
H2 Hydrogen 0 0.0000 % want to use to enter the data for the calculations. ###
O2 Oxygen 0 0.0000 % This also resets the base pressure and temperature for the calculations to either MSC ###
(0 kPa(g) and 15 oC) or STP (0 psi(g) and 60oC) to suit. If NTP is required as the base
N2 Nitrogen 0.47847 0.4785 % ###
the user can manually change the settings.
H2O Water 0 0.0000 % ###
100.0000 100.0000 %
MW 19.4231 kg/kmol #VALUE! from AGA8 GCM2 Method
SG ideal 0.6706 Specific Gravity
SG real 0.6726 #VALUE! from AGA8 GCM2 Method ###
Zb [15oC, 0 kPa(g)] 0.9967 Compressibility at base conditions #VALUE! from AGA8 GCM2 Method m3/kg.mole
HHV ideal 41.1494 MJ/Sm3 Higher Heating Value CHECK THIS
HHV real 41.1010 MJ/Sm3 Wobbe Index 50.1169054 #VALUE! from AGA8 GCM2 Method y
LHV ideal 37.2065 MJ/Sm3 Lower Heating Value ###
LHV real 37.1594 MJ/Sm3 ###
P 10000 kPa(g) Operating Pressure 1450.4 psi(g) ###
T 30 o
C Operating Temperature 86 oF ###
P 10101.325 kPa(abs) ###
T 303.15 o
K ###
Pc 4611.91 kPa(abs) Pseudo Critical Pressure includes Wichert & Aziz Correction for Sour Gas ###
Tc 206.86 o
K Pseudo Critical Temperature includes Wichert & Aziz Correction for Sour Gas ###
Vc 0.0055 m3/kg Pseudo Critical Specific Volume ###
Zc 0.2861 Pseudo Critical Compressibility ###
Pr (Pro) 2.1903 0.0220 Pseudo Reduced Pressure ###
Tr 1.4655 Pseudo Reduced Temperature ###
Z (MW<40, P<70MPa) #VALUE! Compressibility (Pr 0 to 15, Tr 1 to 3) #VALUE! from AGA8 GCM2 Method ###
d #VALUE! kg/m3 Density #VALUE! from AGA8 GCM2 Method ###
Cpo (T -25 to 150oC) #VALUE! kJ/kmole.oC Heat Capacity (Pconstant) #VALUE! J/kg.oC ###
Cvo #VALUE! kJ/kmole.oC Heat Capacity (T constant) #VALUE! J/kg.oC ###
ko=Cpo/Cvo #VALUE! Thermal Conductivity #VALUE! W/m.oC (MW>16, 20<T<200oC, Pr<8, 1<Tr<3) ###
Cp #VALUE! kJ/kmole.oC refer Redlich-Kwong #VALUE! J/kg.oC ###
Cv #VALUE! kJ/kmole.oC Equations of State #VALUE! J/kg.oC ###
k=Cp/Cv #VALUE! Velocity of Sound #VALUE! m/sec ###
w 0.0316 Acentric Factor ###
u (T -130 to 500oC) #VALUE! cP (mPa.s) Viscosity from Fig 23-23 (P 0 to 21 Mpa) #VALUE! from John M Campbell & Co ###
ua @101.325 kPa(a) #VALUE! cP (mPa.s) or Viscosity from 23-22 (if Tr > 1.0) 1-sum^2
u/ua #VALUE! and pressure correction from 23-24 sum/Zb
u #VALUE! cP (mPa.s) Wiche
or if high levels of non hydrocarbons are present (eg 20%) CO2
E 0.04330 Eq 23-20 (corrected) H2S
E.ua 0.00048 Eq 23-21 (corrected) and Eq 23-22 A
ua @101.325 kPa(a) 0.01103 cP (mPa.s) for high levels of non hydrocarbons B
u #VALUE! cP (mPa.s) with pressure correction from 23-24 e=
H (T -30 to 480oC) #VALUE! kJ/kmol Enthalpy (Pr 0.1 to 10, Tr 1 to 4) Note:H=0 for T=0oK and P=0 kPa(abs)
#VALUE! kJ/kg Note: Values for Hexane, Heptane, Octane, Nonane, Decane are approximate only!
JT #VALUE! oC/100 kPa JT Effect of Gas Expansion
S (T -80 to 240oC) #VALUE! kJ/kmole.K Entropy (Pr 01 to 10, Tr 0.8 to 4) Note:S=0 for T=0oK and P=0 kPa(abs)
#VALUE! kJ/kg.K Note: Values for Hexane, Heptane, Octane, Nonane, Decane are not available!
denniskb@ozemail.com.au www.ozemail.com.au/~denniskb/

361786894.xls Gas Prop Calc SI 07/28/2017

 ENGINEERING DESIGN CALCULATION - DENNIS KIRK ENGINEERING
Calculation of Gas Properties - GPSA Engineering Data Book - SI Units - 11th Edition 1998 Version 1.510

CALCULATION TITLE

To carry out calculations for US pressure and temperature units:

Select the "Calculate" button to link from the US to the SI units sheet.
Enter details and data into the cells with a yellow background only.
0
Uniformly Real Cp, Cv, k and VOS are calculated using the Redlich-Kwong EOS.
Normalised Select the "Reset" button to relink from the SI to the US units sheet.
mole % mole %
CH4 Methane 86.0115 86.0115 % SI Calc Active
C2H6 Ethane 6.31691 6.3169 % 2
C3H8 Propane 2.2373 2.2373 % R= 1.9859 kJ/kg.mol.degK
C4H10 I-Butane 0.41556 0.4156 % MW air= 28.9625 lb/lb.mol
C4H10 n-Butane 0.56587 0.5659 % Zb air= 0.99958
C5H12 i-Pentane 0.24379 0.2438 % Pb= 0 psi(g) 0 0.0 kPa(g)
C5H12 n-Pentane 0.16037 0.1604 % Ps= 14.69595 psi(abs)
C6H14 n-Hexane 0.16453 0.1645 % Pb= 14.696 psi(abs)
C7H16 n-Heptane 0.09306 0.0931 % Tb= 59 degF 60 15.0 degC
C8H18 n-Octane 0.04622 0.0462 % Ts= 459.67 degR
C9H20 n-Nonane 0.01982 0.0198 % Tb= 518.67 degR
C10H22 n-Decane 0 0.0000 %
C6H6 Benzene 0 0.0000 %
CO Carbon Monoxide 0 0.0000 %
CO2 Carbon Dioxide 3.24657 3.2466 %
H2S Hydrogen Sulfide 0 0.0000 %
N2+02 Air 0 0.0000 %
H2 Hydrogen 0 0.0000 %
O2 Oxygen 0 0.0000 %
N2 Nitrogen 0.47847 0.4785 %
H2O Water 0 0.0000 %
100.0000 100.0000 %
MW 19.4231 lb/lb.mol #VALUE! from AGA8 GCM2 Method
SG ideal 0.6706 Specific Gravity
SG real 0.6726 #VALUE! from AGA8 GCM2 Method
Zb [60oF, 0 psi(g)] 0.9967 Compressibility at base conditions #VALUE! from AGA8 GCM2 Method
HHV ideal 1104.801 Btu/Sft3 Higher Heating Value
HHV real 1103.500 Btu/Sft3 Wobbe Index 50.1169054 #VALUE! from AGA8 GCM2 Method
LHV ideal 998.938 Btu/Sft3 Lower Heating Value
LHV real 997.676 Btu/Sft3
P 1450.4 psi(g) Operating Pressure 10000.0 kPa(g)
T 86 o
F Operating Temperature 30.0 C
o

P 1465.09595 psi(abs)
T 545.67 o
R
Pc 668.91 psi(abs) Pseudo Critical Pressure includes Wichert & Aziz Correction for Sour Gas
Tc 372.35 o
R Pseudo Critical Temperature includes Wichert & Aziz Correction for Sour Gas
Vc 0.0887 ft3/lb Pseudo Critical Specific Volume
Zc 0.2861 Pseudo Critical Compressibility
Pr (Pro) 2.1903 0.0220 Pseudo Reduced Pressure
Tr 1.4655 Pseudo Reduced Temperature
Z (MW<40, P<10150 psia) #VALUE! Compressibility (Pr 0 to 15, Tr 1 to 3) #VALUE! from AGA8 GCM2 Method
d #VALUE! lb/ft3 Density #VALUE! from AGA8 GCM2 Method
Cpo (T -25 to 150oC) #VALUE! Btu/lb-mole.oF Heat Capacity (Pconstant) #VALUE! Btu/lb.oF
Cvo #VALUE! Btu/lb-mole.oF Heat Capacity (T constant) #VALUE! Btu/lb.oF
ko=Cpo/Cvo #VALUE! Thermal Conductivity #VALUE! Btu/hr.ft.oF
Cp #VALUE! Btu/lb-mole.oF refer Redlich-Kwong #VALUE! Btu/lb.oF
Cv #VALUE! Btu/lb-mole.oF Equations of State #VALUE! Btu/lb.oF
k=Cp/Cv #VALUE! Velocity of Sound #VALUE! ft/sec
w 0.0316 Acentric Factor
u (T -202 to 932oF) #VALUE! cP Viscosity from Fig 23-23 (P 0 to 3046 psi) #VALUE! from John M Campbell & Co
ua @14.696 psi(a) #VALUE! cP or Viscosity from 23-22 (if Tr > 1.0)
u/ua #VALUE! and pressure correction from 23-24
u #VALUE! cP
or if high levels of non hydrocarbons are present (eg 20%)
E 0.04330 Eq 23-20 (corrected)
E.ua 0.00048 Eq 23-21 (corrected) and Eq 23-22
ua @14.696 psi(a) 0.01103 cP for high levels of non hydrocarbons
u #VALUE! cP with pressure correction from 23-24
H (T -22 to 895oF) #VALUE! Btu/lb-mole Enthalpy (Pr 0.1 to 10, Tr 1 to 4) Note:H=0 for T=0oR and P=0 psi(abs)
#VALUE! Btu/lb Note: Values for Hexane, Heptane, Octane, Nonane, Decane are approximate only!
JT #VALUE! o
F/100 psi JT Effect of Gas Expansion
S (T -112 to 464oF) #VALUE! Btu/lb-mole.oF Entropy (Pr 01 to 10, Tr 0.8 to 4) Note:S=0 for T=0oR and P=0 psi(abs)
#VALUE! Btu/lb.oF Note: Values for Hexane, Heptane, Octane, Nonane, Decane are not available!
denniskb@ozemail.com.au www.ozemail.com.au/~denniskb/

361786894.xls Gas Prop Calc US 07/28/2017

Thermal Conductivity of Natural Gas Mixtures

At 101.325 kPa(abs)
MW 19.4230521 Temp 30 C
MW
16 20 30 40 50 60
Temp C 20 0.0334 0.0295 0.0212 0.018 0.0169 0.0159
40 0.0363 0.032 0.024 0.0207 0.0188 0.0174
60 0.0393 0.035 0.0266 0.023 0.0208 0.0192
80 0.042 0.038 0.0295 0.0254 0.023 0.0212
100 0.045 0.041 0.0322 0.0282 0.0258 0.0239
120 0.048 0.0437 0.035 0.031 0.0282 0.0265
140 0.051 0.0468 0.0375 0.0333 0.0309 0.029
160 0.0539 0.0495 0.0403 0.0359 0.0335 0.0317
180 0.0568 0.053 0.043 0.0382 0.036 0.0342
200 0.0598 0.055 0.0457 0.0408 0.0384 0.0368
Te m p e ra tu re C

Molecular Weight
10 20 30 40 50 60 70 80

Pressure Correction
Pr 2.19026751 Tr 1.4654658 k/ka #VALUE!
Pr
0 0.1 0.5 0.6 0.8 1
Tr 1 1 1.05 1.15 1.25 1.5 4
1.03 1 1.05 1.15 1.23 1.42 1.78
1.05 1 1.05 1.15 1.2 1.37 1.65
1.1 1 1.04 1.12 1.2 1.28 1.43
1.15 1 1.03 1.12 1.13 1.22 1.32
1.2 1 1.02 1.12 1.125 1.18 1.25
1.3 1 1.01 1.1 1.15 1.15 1.2
1.4 1 1 1.1 1.1 1.13 1.18
R e d u c e d T e m p e ra tu re Tr

1.6 1 1 1.08 1.09 1.11 1.15

1.8 1 1 1.07 1.08 1.1 1.13
2 1 1 1.05 1.07 1.09 1.1
2.5 1 1 1.04 1.06 1.08 1.09
3 1 1 1.03 1.04 1.05 1.06

12 Conductivity Ratio k/ka

10
R e d u c e d Te m p e ra
12 Conductivity Ratio k/ka
10
8
6
4
2
0 Reduced Pressure Pr
0 1 2 3 4 5
 Thermal Conductivity #VALUE! W/m.C

70 80 90 100
Liquid Liquid Liquid Liquid
0.0164 Liquid Liquid Liquid
0.018 0.0173 Liquid Liquid
0.02 0.0189 0.018 Liquid
0.0223 0.0212 0.02 0.019
0.025 0.0235 0.0221 0.021
0.0275 0.026 0.0248 0.0233
0.03 0.0284 0.027 0.0256
0.0325 0.031 0.0294 0.028
0.0351 0.0335 0.0319 0.0301

20
40
60
80
10
0
12
0
14
0
16
Weight 0
60 70 80 90 100

Thermal Conductivity #VALUE! W/m.C

1.5 2 3 4 5 6 7 8
5.3 6 7 7.9 8.5 9 9.65 10.1
4.35 5 6.1 6.9 7.5 8 8.5 9
3.5 4.4 5.4 6.2 6.9 7.5 7.9 8.3
2.2 3.35 4.25 5 5.7 6.2 6.85 7.2
1.75 2.49 3.4 4.1 4.65 5.25 5.8 6.2
1.5 2 2.8 3.5 4 4.5 5 5.4
1.36 1.65 2.2 2.75 3.2 3.6 4 4.4
1.3 1.49 1.9 2.3 2.7 3.1 3.5 3.9
1.23 1.34 1.6 1.87 2.15 2.35 2.6 2.9
1.2 1.27 1.43 1.61 1.78 1.9 2.1 2.3
1.18 1.23 1.35 1.47 1.58 1.7 1.8 2
1.1 1.14 1.21 1.29 1.35 1.41 1.48 1.6
1.08 1.1 1.14 1.18 1.22 1.28 1.31 1.45

1
nductivity Ratio k/ka 1.0
3
 1
nductivity Ratio k/ka 1.0
3
1.0
5
1.1
1.1
5
1.2
1.3
1.4
1.6
1.8
2
uced Pressure Pr 2.5
4 5 6 7 8 9 3
 ENGINEERING DESIGN CALCULATION - DENNIS KIRK
COMPRESSIBILITY FACTORS FOR NATURAL GAS refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 23, Fig 23-4 Ver: 1.000
Valid for MW < 40 (data has been read directly from Fig 23-4 into the table below which is used as an intrpolated look up table)
Pseudo-reduced Pressure Pr
Compressibility 0 0.25 0.5 0.75 1 1.25 1.5 2 3 4 5 6 7 8 9 10 11 12 13 14 15
1 1 0.91 0.805 0.67 0.5 0.21 0.075
1.05 1 0.92 0.83 0.72 0.595 0.4 0.255 0.28 0.405 0.535 0.663 0.783 0.903 1.015 1.125 1.233 1.34 1.443 1.548 1.65 1.753
1.1 1 0.93 0.855 0.77 0.67 0.55 0.42 0.37 0.44 0.558 0.673 0.785 0.895 1.005 1.108 1.21 1.313 1.413 1.515 1.618 1.72
1.15 1 0.94 0.875 0.805 0.735 0.655 0.57 0.465 0.49 0.582 0.683 0.788 0.893 0.998 1.108 1.19 1.29 1.39 1.485 1.583 1.68
1.2 1 0.95 0.895 0.84 0.78 0.72 0.655 0.555 0.535 0.608 0.695 0.79 0.89 0.99 1.108 1.175 1.27 1.363 1.458 1.55 1.643
1.25 1 0.955 0.91 0.86 0.815 0.76 0.71 0.625 0.58 0.634 0.71 0.798 0.89 0.985 1.072 1.16 1.255 1.345 1.44 1.53 1.615
Pseudo-reduced Temperature Tr

1.3 1 0.96 0.918 0.88 0.84 0.795 0.765 0.685 0.625 0.655 0.72 0.803 0.89 0.98 1.06 1.155 1.24 1.325 1.415 1.5 1.585
1.35 1 0.965 0.925 0.89 0.855 0.825 0.79 0.73 0.67 0.688 0.742 0.815 0.895 0.98 1.06 1.15 1.23 1.31 1.395 1.48 1.557
1.4 1 0.97 0.935 0.905 0.875 0.845 0.815 0.765 0.708 0.717 0.76 0.83 0.9 0.98 1.06 1.14 1.218 1.295 1.375 1.45 1.528
1.45 1 0.973 0.945 0.915 0.89 0.865 0.84 0.8 0.745 0.747 0.788 0.845 0.91 0.985 1.06 1.135 1.2 1.285 1.363 1.437 1.51
1.5 1 0.975 0.95 0.925 0.9 0.88 0.86 0.825 0.778 0.777 0.81 0.863 0.923 0.99 1.06 1.13 1.205 1.275 1.35 1.423 1.493
1.6 1 0.983 0.96 0.94 0.925 0.905 0.89 0.86 0.825 0.818 0.845 0.892 0.945 1 1.065 1.13 1.2 1.265 1.335 1.403 1.47
1.7 1 0.99 0.97 0.955 0.94 0.927 0.915 0.893 0.865 0.857 0.878 0.918 0.965 1.018 1.06 1.133 1.198 1.255 1.32 1.38 1.44
1.8 1 0.993 0.975 0.965 0.955 0.945 0.935 0.918 0.895 0.892 0.913 0.947 0.988 1.033 1.083 1.135 1.195 1.25 1.308 1.368 1.423
1.9 1 0.995 0.98 0.97 0.963 0.955 0.945 0.934 0.918 0.918 0.935 0.968 1.005 1.047 1.09 1.14 1.193 1.247 1.3 1.353 1.405
2 1 0.998 0.985 0.975 0.97 0.965 0.957 0.947 0.938 0.938 0.955 0.985 1.02 1.058 1.1 1.145 1.195 1.245 1.293 1.34 1.39
2.2 1 0.995 0.99 0.985 0.98 0.977 0.972 0.957 0.96 0.968 0.988 1.014 1.045 1.078 1.113 1.155 1.195 1.242 1.283 1.323 1.362
2.4 1 0.9975 0.995 0.9925 0.99 0.987 0.983 0.98 0.98 0.99 1.01 1.037 1.063 1.09 1.123 1.16 1.195 1.239 1.275 1.31 1.345
2.6 1 0.999 0.9975 0.996 0.995 0.995 0.995 0.995 0.998 1.008 1.028 1.05 1.075 1.1 1.128 1.163 1.195 1.237 1.27 1.305 1.34
2.8 1 1 1 1 1 1.002 1.003 1.005 1.012 1.023 1.04 1.06 1.08 1.105 1.133 1.165 1.195 1.235 1.269 1.303 1.337
C o m p re s s ib ility F a c to r Z

3 1 1.001 1.003 1.004 1.005 1.008 1.011 1.015 1.025 1.035 1.05 1.065 1.085 1.11 1.138 1.168 1.195 1.233 1.268 1.3 1.333

1.8 Pseudo-
reduced
Compressibilty Factors for Natural Gas Temperat
1.7
ure Tr
1.6
1
1.5 1.05
1.1
1.4
1.15
1.3 1.2
1.25
1.2
1.3
1.1 1.35
1 1.4
1.45
0.9 1.5
0.8 1.6
1.7
0.7
1.8
0.6 1.9
2
0.5
2.2
0.4 2.4

0.3 Pseudo-reduced Pressure Pr 2.6

2.8
0.2 3
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Limitations of Use:
< 40 MW
< 10% Nitrogen reasonable up to 50% N2
< 2% H2S and/or CO2 ie - sweet gases
> 10 oC above saturation
< 70 Mpa
no appreciable amount of water

361786894.xls Compressibility 07/28/2017

 ENGINEERING DESIGN CALCULATION - DENNIS KIRK ENGINEERING DESIGN CALCULATION - DENNIS KIRK
PSEUDOCRITICAL TEMPERATURE ADJUSTMENT FACTOR FOR Pc and Tc refer John M Campbell & Co - Fluid Flow Systems p22 refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 23, Fig 23-8

T'c = Tc - e C
o
Values have been taken direct from Fig 23-8 P23-16
P'c = Pc . T'c / [ Tc + B' . ( 1 - B' ) . e ] Mpa
e = 0.556 . ( 120 . [ A 0.9
-A 1.6
] + 15 . [ B 0.5
- B ])
4
C
o
Comparison with the JMC formulae results at left validates the JMC method.

B = mole fraction H2S 0.2 H2S Tc 241.03 T'c 224.456275 oC

A = mole fraction H2S + CO2 CO2 0.1 16.573725 e Pc 5.7033 P'c 5.2533324 Mpa

H2S mole fraction H2S mole fraction

e 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 e 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
CO2 mole fraction 0 0 9.36012529 14.3100609 17.3577597 18.9089982 19.1209913 18.0449109 15.6689777 11.9364627 6.75467504 CO2 mole 0 0 9.5 15 17 18.9 19.1 18 15.2 12.1 7
0.1 6.72361972 13.2301491 16.573725 18.3482752 18.8061459 18.0416592 16.0729393 12.8683146 8.35798911 2.44014471 fraction 0.1 7.8 13.2 16.6 18.5 18.8 18.05 15.9 12.9 8.5
0.2 10.5936435 15.4938132 17.5642405 18.2454229 17.7268138 16.0696876 13.2722762 9.28984096 4.04345877 -2.5753614 0.2 11.2 15.5 17.4 18.3 17.7 16 13.2 9.2
0.3 12.8573076 16.4843287 17.4613881 17.1660908 15.7548422 13.2690245 9.69380256 4.97531062 -0.9720474 -8.2618162 0.3 13.3 16.4 17.4 17.15 16 13.2 9.5
0.4 13.8478231 16.3814763 16.3820561 15.1941192 12.9541791 9.69055089 5.37927222 -0.0401955 -6.6585021 -14.593129 0.4 14 16.3 16.4 15.1 13 9.8
0.5 13.7449708 15.3021442 14.4100844 12.3934561 9.37570547 5.37602056 0.36376608 -5.7266503 -12.989815 -21.546347 0.5 13.8 15.3 14.3 12.4 9.5
0.6 12.6656387 13.3301726 11.6094213 8.81498247 5.06117514 0.36051441 -5.3226887 -12.057963 -19.943033 -29.101068 0.6 12.9 13.3 11.4 8.8
0.7 10.693667 10.5295095 8.03094772 4.50045213 0.04566899 -5.3259403 -11.654002 -19.011182 -27.497754 -37.238992 0.7 11 10.4 7.8
0.8 7.89300394 6.9510359 3.71641739 -0.515054 -5.6407858 -11.657253 -18.60722 -26.565902 -35.635678 -45.943585 0.8 8 6.9
0.9 4.31453034 2.63650557 -1.2990888 -6.2015088 -11.972099 -18.610472 -26.161941 -34.703827 -44.34027 -55.199801 0.9

25 CO 25
H2S mole fraction
2
A 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
e 6 0.085673
0 0
20 7 0.10573235 20
0. 0.
8 0.12794944 1 1
0. 0.
e oC

9 0.15280649 2 2

e oC
15 15 0.
10 0.18107492 0.
3
3
11 0.21411212 0. 0.
4
12 0.25450907 4 0.
10 0. 10
13 0.30931282 5
5
0.
14 0. 6
15 6 0.
5 0. 7
16 7 5
17
18
0
19 H2S 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 H2S
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

361786894.xls Wichert & Aziz Correction 07/28/2017

 ENGINEERING DESIGN CALCULATION - DENNIS KIRK ENGINEERING DESIGN CALCULATION - DENNIS KIRK
VISCOSITY OF HYDROCARBON GASES refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 23 VISCOSITY OF HYDROCARBON GASES refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 23
Fig 23-22 and Fig 23-24 Fig 23-22 and Fig 23-24
Viscosity at One Atmosphere MW 19.42305 Temp 30 degC ua #VALUE! cP Correction for Pressure Tr 1.465466 Pr 2.190268 u/ua #VALUE!
Molecular Weight SG 0.670628 Tr
Temp 15 20 30 40 50 60 70 80 90 100 Pr 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0
0 0.01005 0.0096 0.0086 0.0077 0.0071 0.0066 0.0062 0.0058 0.0055 0.0052 0 1 1 1 1 1 1 1 1 1 1 1
10 0.0103 0.0099 0.0088 0.008 0.0074 0.0068 0.0064 0.00605 0.0057 0.0054 1 1.8 1.13 1.1 1.08 1.06 1.05 1.04 1.03 1.02 1.015 1.01
20 0.0106 0.0102 0.0091 0.0083 0.0076 0.0071 0.0067 0.0063 0.0059 0.0056 2 5.4 1.73 1.33 1.21 1.16 1.12 1.095 1.08 1.06 1.05 1.04
30 0.0109 0.0105 0.0094 0.0085 0.0079 0.0074 0.0069 0.0065 0.00615 0.0058 3 6 2.64 1.68 1.4 1.28 1.2 1.165 1.125 1.1 1.085 1.06
40 0.0111 0.0108 0.0097 0.0088 0.0082 0.0076 0.0071 0.0067 0.0063 0.006 4 6.5 3.4 2.1 1.6 1.4 1.3 1.225 1.18 1.15 1.12 1.095
50 0.0114 0.0111 0.0099 0.0091 0.0084 0.0079 0.00735 0.0069 0.0065 0.0062 6 7.8 4.4 2.8 2 1.7 1.5 1.38 1.29 1.22 1.18 1.15
60 0.0118 0.0114 0.0102 0.0094 0.0087 0.0081 0.0076 0.0071 0.0067 0.0063 8 9 5.2 3.4 2.45 1.99 1.71 1.54 1.4 1.32 1.25 1.195
70 0.0121 0.0117 0.0105 0.0097 0.009 0.0084 0.0078 0.00735 0.0069 0.0065 10 10 5.8 3.85 2.8 2.28 1.95 1.705 1.56 1.44 1.35 1.275
80 0.01235 0.012 0.0108 0.0099 0.0092 0.0086 0.0081 0.0076 0.0071 0.0067 15 12 7 4.8 3.5 2.85 2.47 2.16 1.94 1.76 1.61 1.5
90 0.0126 0.0122 0.01105 0.0102 0.0094 0.0088 0.0083 0.0078 0.00735 0.0069 20 15 8 5.4 4.04 3.32 2.88 2.55 2.3 2.08 1.9 1.73
100 0.0129 0.0125 0.0113 0.0104 0.0097 0.0091 0.0085 0.008 0.0076 0.00715
110 0.0132 0.0128 0.0116 0.0107 0.0099 0.0093 0.00875 0.0082 0.0078 0.0073
120 0.0135 0.0131 0.0119 0.0109 0.0102 0.0095 0.009 0.0085 0.008 0.00755 6
130 0.0138 0.0134 0.0121 0.0111 0.0104 0.0097 0.0092 0.0087 0.0082 0.00775
140 0.014 0.0137 0.0124 0.0114 0.0106 0.01 0.0094 0.0089 0.0084 0.00795
150 0.0143 0.0139 0.0126 0.0117 0.0109 0.0102 0.0096 0.0091 0.0086 0.00815
160 0.0146 0.0142 0.0129 0.0119 0.0111 0.0105 0.0098 0.0093 0.0088 0.00835 5
170 0.0149 0.0145 0.0132 0.0122 0.0114 0.0107 0.0101 0.0095 0.009 0.0085
180 0.0152 0.0148 0.0135 0.0125 0.0117 0.01095 0.0103 0.0097 0.0092 0.0087
190 0.0155 0.0151 0.0137 0.0127 0.0119 0.0112 0.0105 0.00995 0.0094 0.0089 0
200 0.0158 0.0154 0.0141 0.013 0.0122 0.0115 0.0108 0.0102 0.0096 0.0091 4 1
2
3
1 4
0.016
0
1
6
3 8
0
0.014 2 1
0
0
3
0.012 0 1
4 2 5
0 2
5 0
0.01
0
6
0
0.008 7 1
0
8
0.006 0
9
0
0
1
0.004 0.8 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 2.8 3
0
0 10 20 30 40 50 60 70 80 90 100 0
ua #VALUE!
Correction for N2 Correction for CO2 Correction for H2S
N2 0.47847 d(ua) #VALUE! CO2 3.24657 d(ua) #VALUE! H2S 0 d(ua) #VALUE! d(ua)N2 #VALUE!
Mole% Mole% Mole%
SG 0 5 10 15.001 SG 0 5 10 15.001 SG 0 5 10 15.001 d(ua)CO2 #VALUE!
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0.6 0 0.0004 0.0008 0.0012 0.6 0 0.00023 0.00047 0.0007 0.6 0 0.0001 0.0002 0.0003 d(ua)H2S #VALUE!
1 0 0.0005 0.001 0.0015 1 0 0.00033 0.00067 0.001 1 0 0.0002 0.0004 0.0006
1.5 0 0.00055 0.0011 0.00165 1.5 0 0.0004 0.0008 0.0012 1.5 0 0.00027 0.00053 0.0008 ua #VALUE! u/ua #VALUE! u #VALUE! #VALUE!
2 0 0.0006 0.0012 0.0018 2 0 0.00043 0.00087 0.0013 2 0 0.0003 0.0006 0.0009

0.002 0.0014 0.001

0.0018 0.0009

0.0016
0.0012
0.0008
ENGINEERING DESIGN CALCULATION - DENNIS KIRK
VISCOSITY OF HYDROCARBON GASES refer John M Campbell & Co - Fluid Flow Systems p27
0 0.001 0
0.0014 0.0007 0
1 1
1
1 1
0.0012 0.0006 1
. 0.0008 .
.
5 5
0.001 0.0005 5
2 2
2
0.0006

ug = [(7.77 + 0.006276 . MW) . T1.5 . e(x . dy)]/[(122.44 + 12.95 . MW + T) . 10 4] cP

0.0008 0.0004

0.0006 0.0004 0.0003

0.0004
0.0002
0.0002 x = 2.576 + (1914.45 / T) + 0.00953 . MW
0.0002

0 0
0.0001

0
y = 1.108 +0.0404 . x
0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 16 d = gas density gm/cc = MW . P / ( R . T . Z )
T = 1.8 . oK avg
R 8.3145
SG 0.5548 MW 16.0684
P 1500 kPag 1601.325 kPa(abs)
T 25 o
C 298.15 oK
Z 0.9741

d 10.65559 kg/m3 0.010656 gm/cc

e 2.718282

x 6.296408
y 1.362375

u 0.011431 cP #VALUE! cf GPSA viscosity u 0.011431 cP as a single step calculation

361786894.xls Viscosity 07/28/2017

 ENGINEERING DESIGN CALCULATION - DENNIS KIRK
VISCOSITY OF HYDROCARBON GASES refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 23, Fig 23-23

SG of Gas SG 0.5548
Temperature T1 25 degC T2 #VALUE!
Pressure P 1500 kPa(abs)

Viscosity of Gas U2 #VALUE! cP = MPa.s U1 #VALUE!

Correct Input Temperature for SG

SG T1 T2 1 2
9
0.5548 25 #VALUE! 0.9 8
Temperature 2
SG -20 33 86 139 192 245 298 4
0.8
5
0.55 -20 33 86 139 192 245 298 1
0.6 -29 25 74 127 177 230 281 0.7 9
2
0.7 -44 5 53 102 150 199 249
0.6
0.8 -60 -14 32 77 122 169 215
0.9 -76 -33 10 53 95 138 182 0.5
1 -92 -52 -12 28 68 108 148 -100 -50 0 50 100 150 200 250 300 350

Correct Output Viscosity for SG

SG U1 U2
0.5548 #VALUE! #VALUE!
Viscosity
SG 0.00575 0.0065 0.0074 0.0081 0.0088 0.0095 0.0104 0.0113 0.0121 0.013 0.0137 0.0145 0.0153 0.0162 0.0177 0.0192 0.0208 0.0222 0.0237 0.028 0.0322 0.036 0.0397 0.0439 0.0478 0.056 0.064 0.072 0.08
0.55 0.00575 0.0065 0.0074 0.0081 0.0088 0.0095 0.0104 0.0113 0.0121 0.013 0.0137 0.0145 0.0153 0.0162 0.0177 0.0192 0.0208 0.0222 0.0237 0.028 0.0322 0.036 0.0397 0.0439 0.0478 0.056 0.064 0.072 0.08
0.7 0.006 0.0068 0.0076 0.0084 0.0091 0.01 0.0109 0.0117 0.0125 0.0135 0.0142 0.015 0.0157 0.0167 0.0184 0.02 0.0218 0.0231 0.0248 0.0293 0.0338 0.0375 0.0413 0.0455 0.0498 0.058 0.067 0.075 0.083
0.8 0.0062 0.0071 0.0079 0.00865 0.00945 0.0104 0.0113 0.0121 0.013 0.014 0.01475 0.0155 0.0163 0.0173 0.0191 0.0208 0.0226 0.024 0.0258 0.0304 0.0349 0.039 0.0428 0.0472 0.0514 0.06 0.07 0.078 0.086
0.9 0.0064 0.0074 0.0082 0.0091 0.0099 0.0109 0.0118 0.0128 0.0136 0.0145 0.0155 0.0162 0.017 0.0181 0.02 0.0218 0.0237 0.0251 0.027 0.0318 0.0365 0.0406 0.0447 0.0491 0.0537 0.0626 0.0725 0.0815 0.09
1 0.0066 0.0076 0.0085 0.0095 0.0104 0.0115 0.0123 0.0133 0.0141 0.015 0.016 0.017 0.0177 0.0188 0.0208 0.0226 0.0245 0.0261 0.028 0.0328 0.0378 0.042 0.0462 0.051 0.056 0.065 0.075 0.085 0.094

1 0.0057
5
0.0065
0.95 0.0074
0.0081
0.0088
0.9 0.0095
0.0104
0.0113
0.85 0.0121
0.013
0.8 0.0137
0.0145
0.0153
0.75 0.0162
0.0177
0.0192
0.7 0.0208
0.0222
0.0237
0.65
0.028
0.0322
0.6 0.036
0.0397
0.0439
0.55 0.0478
0.056
0.064
0.5 0.072
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10.08

Find Viscosity SG=0.55-0.6

T2 P U1 0.1
#VALUE! 1500 #VALUE!
Temperature
P -100 -75 -50 0 50 100 150 200 250 300 350
101.3 0.0066 0.0075 0.0086 0.0105 0.0122 0.0136 0.015 0.0165 0.0177 0.0188 0.02
3500 0.0115 0.009 0.0097 0.0115 0.0133 0.0147 0.016 0.0173 0.0185 0.0195 0.0205
5000 0.044 0.0175 0.0114 0.0122 0.0138 0.0153 0.0167 0.0178 0.019 0.02 0.021
7000 0.052 0.028 0.0133 0.013 0.0145 0.0158 0.017 0.0183 0.0195 0.0205 0.0215 101.3
10000 0.056 0.035 0.0185 0.0152 0.0157 0.0168 0.0178 0.0187 0.0198 0.02075 0.02165 3500
14000 0.06 0.042 0.026 0.0195 0.0182 0.0181 0.0185 0.0194 0.0201 0.021 0.0218 5000
7000
21000 0.066 0.048 0.032 0.024 0.0218 0.021 0.0208 0.0209 0.0212 0.0218 0.0226 1000
0
1400
0.01 0
2100
0

0.001
-200 -100 0 100 200 300 400

361786894.xls Viscosity 07/28/2017

 ENGINEERING DESIGN CALCULATION - DENNIS KIRK
ENTHALPY DETERMINATION FOR NATURAL GAS refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 24, Fig 24-3, 24-4 Version 1.510
Ideal Gas State Enthalpy Ho (kJ/kg) Note:H=0 for T=0 K and P=0 kPa(abs)
o

Temperature (oC) kg/kmol kJ/kg kJ/kmol

-30 0 30 60 90 120 150 180 210 240 270 300 330 360 390 420 450 480 yi MW yi.MW Hio yi.MW.Hio
Methane 505 570 638 705 775 850 927 1005 1093 1177 1268 1360 1457 1557 1658 1762 1870 19820.860115 16.043 13.798829 #VALUE! #VALUE!
Ethane 308 358 403 460 520 580 645 720 790 865 947 1033 1120 1210 1300 1400 1500 16000.063169 30.07 1.8994954 #VALUE! #VALUE!
Propane 258 300 347 400 458 518 582 650 720 797 875 955 1040 1130 1220 1318 1410 15070.022373 44.097 0.9865825 #VALUE! #VALUE!
I-Butane 225 272 320 372 425 487 553 620 692 770 845 925 1010 1100 1190 1285 1382 14800.004156 58.123 0.241536 #VALUE! #VALUE!
n-Butane 258 300 347 400 458 518 582 650 720 797 875 955 1040 1130 1220 1318 1410 15070.005659 58.123 0.3289007 #VALUE! #VALUE!
i-Pentane 225 272 320 372 425 487 553 620 692 770 845 925 1010 1100 1190 1285 1382 14800.002438 72.15 0.1758945 #VALUE! #VALUE!
n-Pentane 245 290 335 387 442 505 572 635 705 780 860 940 1022 1110 1205 1300 1390 14850.001604 72.15 0.115707 #VALUE! #VALUE!
n-Hexane 201 246 291 343 398 461 528 591 661 736 816 896 978 1066 1161 1256 1346 14410.001645 86.177 0.1417871 #VALUE! #VALUE!
n-Heptane 301 351 402 453 508 564 623 683 742 802 862 922 982 1042 1102 1162 1222 12820.000931 100.204 0.0932499 #VALUE! #VALUE!
n-Octane 321 368 418 468 522 576 634 693 751 810 869 928 987 1046 1105 1164 1223 12820.000462 114.231 0.0527976 #VALUE! #VALUE!
n-Nonane 338 369 411 453 512 572 630 688 721 755 789 823 857 891 925 959 993 10270.000198 128.258 0.0254207 #VALUE! #VALUE!
n-Decane 355 402 452 502 556 610 668 727 785 844 903 962 1021 1080 1139 1198 1257 1316 0 142.285 0 #VALUE! #VALUE!
Benzene 128 160 193 215 265 305 345 392 440 492 545 600 660 722 785 852 920 990 0 78.114 0 #VALUE! #VALUE!
Carbon Monoxide 255 285 315 345 377 407 439 470 500 533 565 597 630 662 693 725 760 790 0 28.01 0 #VALUE! #VALUE!
Carbon Dioxide 165 190 216 242 270 297 325 353 382 412 442 474 505 538 570 605 638 6720.032466 44.01 1.4288159 #VALUE! #VALUE!
Hydrogen Sulfide 238 268 298 329 360 390 422 455 486 519 551 585 620 655 690 725 760 795 0 34.082 0 #VALUE! #VALUE!
Air 240 270 300 330 360 390 426 455 485 516 547 578 610 644 678 712 746 780 0 28.9625 0 #VALUE! #VALUE!
Hydrogen 0 2.0159 0 #VALUE! #VALUE!
Oxygen 219 245 275 302 330 360 388 417 447 475 505 534 563 592 623 655 684 715 0 31.9988 0 #VALUE! #VALUE!
Nitrogen 255 285 315 345 377 407 439 470 500 533 565 597 630 662 693 725 760 790 0.004785 28.0134 0.1340358 #VALUE! #VALUE!
Water 0 18.0153 0 #VALUE! #VALUE!
1 19.423052 #VALUE!
2000
Enthalpy (kJ/kg)

Methane
Ideal Gas State Enthalpy (Ho)
Ethane
1800 Propane
I-Butane
1600 n-Butane
i-Pentane
1400 n-Pentane
n-Hexane
1200
n-Heptane
n-Octane
1000
n-Nonane
n-Decane
800
Benzene
Carbon Monoxide
600
Carbon Dioxide
Hydrogen Sulfide
400
Air
Hydrogen
200 Temperature degC
Oxygen
Nitrogen
0
-30 90 210 330 450 Water
Enthalpy Determination JT Effect for -100 kPa and +100 kPa
P 10000 kPa(g) Hot #VALUE! kJ/kmol Ideal Gas State Enthalpy at T P 9900 10100
T 30 oC T 30 30
Pc 4611.91 kPa(abs) [Ho-H0/RTc]" #VALUE! Pc 4611.91 4611.91
Tc 206.86 oK Tc 206.86 206.86
Pr 2.190268 [Ho-H0/RTc]' #VALUE! Pr 2.168585 2.21195
Tr 1.465466 Tr 1.465466 1.465466
w 0.031593 Ho-H #VALUE! #VALUE! w 0.031593 0.031593
Ho #VALUE! #VALUE!
Hpt #VALUE! kJ/kmol Enthalpy at P and T []" #VALUE! #VALUE!
MW 19.42305 #VALUE! kJ/kg []' #VALUE! #VALUE! Cp JT
Ho-H #VALUE! #VALUE! kJ/kmol kJ/kmol/oC oC/100 kPa
Htp #VALUE! #VALUE! #VALUE! #VALUE! #VALUE!
 ENGINEERING DESIGN CALCULATION - DENNIS KIRK
ENTHALPY DETERMINATION FOR NATURAL GAS refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 24, Fig 24-6 Version 1.510
Pressure Effect on Enthalpy (Simple) [(Ho-H)/RTc]"
Reduced Pressure Pr
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 2 3 4 5 6 7 8 9 10
1.0 0.1 0.21 0.32 0.44 0.6 0.74 0.93 1.15 1.5 2.3 3.57 3.68 3.7 3.68 3.65 3.62 3.6 3.57 3.54

Reduced Temperature Tr
1.2 0.064 0.122 0.2 0.26 0.34 0.435 0.52 0.62 0.71 0.81 1.9 2.5 2.8 3 3.05 3.07 3.075 3.08 3.09
1.4 0.05 0.1 0.14 0.2 0.25 0.31 0.36 0.42 0.49 0.54 1.15 1.7 2.15 2.35 2.4 2.45 2.47 2.5 2.52
1.6 0.041 0.082 0.12 0.155 0.21 0.25 0.31 0.35 0.4 0.44 0.9 1.25 1.5 1.8 2 2.1 2.13 2.16 2.18
1.8 0.034 0.07 0.105 0.135 0.165 0.215 0.25 0.3 0.33 0.38 0.71 1 1.2 1.4 1.5 1.6 1.7 1.75 1.8
2.0 0.03 0.06 0.09 0.115 0.14 0.165 0.21 0.235 0.255 0.29 0.54 0.78 0.98 1.1 1.2 1.27 1.3 1.35 1.4
2.2 0.025 0.051 0.077 0.1 0.12 0.14 0.165 0.2 0.219 0.238 0.44 0.63 0.79 0.91 1.01 1.07 1.1 1.15 1.2
2.4 0.022 0.044 0.065 0.085 0.105 0.121 0.138 0.154 0.175 0.202 0.37 0.52 0.64 0.74 0.81 0.89 0.94 0.99 1.02
2.6 0.019 0.037 0.056 0.071 0.09 0.105 0.118 0.13 0.142 0.157 0.31 0.42 0.53 0.6 0.66 0.72 0.78 0.81 0.85
2.8 0.0145 0.032 0.047 0.061 0.077 0.09 0.102 0.115 0.125 0.135 0.26 0.36 0.44 0.51 0.56 0.605 0.64 0.68 0.71
3.0 0.0126 0.027 0.04 0.053 0.064 0.075 0.087 0.099 0.106 0.115 0.215 0.302 0.36 0.43 0.47 0.52 0.55 0.58 0.6
3.2 0.0113 0.022 0.033 0.042 0.052 0.061 0.071 0.08 0.09 0.099 0.162 0.24 0.31 0.35 0.39 0.41 0.42 0.43 0.435
3.4 0.0095 0.017 0.026 0.035 0.043 0.051 0.059 0.067 0.074 0.08 0.14 0.205 0.24 0.275 0.31 0.32 0.325 0.325 0.325
3.6 0.008 0.014 0.0215 0.0275 0.035 0.041 0.0475 0.055 0.0605 0.0675 0.116 0.16 0.2 0.225 0.24 0.245 0.24 0.235 0.23
3.8 0.006 0.012 0.017 0.023 0.03 0.035 0.04 0.046 0.05 0.055 0.099 0.13 0.155 0.17 0.18 0.18 0.17 0.165 0.16
4.0 0.005 0.01 0.015 0.02 0.024 0.029 0.034 0.038 0.043 0.046 0.08 0.108 0.123 0.135 0.14 0.135 0.125 0.12 0.11

10 5
Pressure Effect (Simple) Pressure Effect (Real)
[(Ho-H)/RTc]"

[(Ho-H)/RTc]'
4 1.
1. 0
0 1.
1 1. 1
2 3 1.
1. 2
4 1.
1. 3
6 2 1.
1. 4
0.1 8 1.
2. 5
0 1
1.
2. 6
2 1.
2. 7
4 0
0.01 1.
2. 8
6 1.
2.
-1 9
8
2.
3. 0
0
Reduced Pressure Pr
0.001 3. -2 Reduced Pressure Pr
2
0.1 1 10 0.1 1 10

Pressure Effect on Enthalpy (Real) [(Ho-H)/RTc]'

Reduced Pressure Pr
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 2 3 4 5 6 7 8 9 10
1.0 0.1 0.2 0.3 0.41 0.53 0.66 0.81 0.96 1.25 2.65 3.4 3.6 3.75 3.85 3.95 4 4.07 4.13 4.17
Reduced Temperature Tr
Reduced Temperature Tr

1.1 0.06 0.12 0.175 0.22 0.26 0.29 0.325 0.355 0.385 0.42 1.7 2.4 2.75 3 3.15 3.3 3.4 3.5 3.6
1.2 0.04 0.08 0.12 0.14 0.165 0.19 0.21 0.225 0.24 0.25 0.46 1.2 1.6 1.95 2.2 2.45 2.6 2.8 2.95
1.3 0.025 0.045 0.06 0.08 0.09 0.105 0.12 0.135 0.15 0.16 0.255 0.52 0.82 1.06 1.4 1.55 1.85 2.05 2.25
1.4 0.015 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.095 0.125 0.245 0.45 0.7 0.9 1.12 1.4 1.65 1.85
1.5 0 0.005 0.01 0.015 0.02 0.02 0.025 0.03 0.035 0.04 0.045 0.09 0.2 0.44 0.66 0.88 1.08 1.35 1.55
1.6 0 0 0 0 0 0 0 0 0 0 -0.01 -0.02 0.05 0.24 0.45 0.65 0.88 1.075 1.35
1.7 0 0 0 -0.01 -0.015 -0.02 -0.025 -0.03 -0.035 -0.04 -0.065 -0.1 -0.06 0.08 0.25 0.44 0.64 0.84 1.04
1.8 0 -0.01 -0.02 -0.025 -0.03 -0.035 -0.04 -0.05 -0.055 -0.06 -0.11 -0.016 -0.014 -0.05 0.08 0.24 0.43 0.6 0.79
1.9 0 -0.015 -0.02 -0.03 -0.04 -0.05 -0.06 -0.07 -0.08 -0.09 -0.18 -0.2 -0.2 -0.15 -0.07 0.05 0.22 0.38 0.54
2.0 -0.01 -0.02 -0.03 -0.04 -0.05 -0.06 -0.07 -0.08 -0.095 -0.105 -0.25 -0.253 -0.253 -0.25 -0.2 -0.1 0.04 0.18 0.32
2.5 -0.015 -0.03 -0.05 -0.06 -0.08 -0.095 -0.11 -0.125 -0.15 -0.16 -0.32 -0.47 -0.55 -0.57 -0.6 -0.6 -0.6 -0.6 -0.6
3.0 -0.025 -0.04 -0.06 -0.08 -0.1 -0.12 -0.14 -0.16 -0.185 -0.2 -0.4 -0.6 -0.75 -0.85 -0.95 -1.05 -1.15 -1.2 -1.25
3.5 -0.025 -0.04 -0.06 -0.08 -0.1 -0.12 -0.14 -0.16 -0.185 -0.2 -0.4 -0.65 -0.85 -1.02 -1.2 -1.35 -1.5 -1.7 -1.85
4.0 -0.025 -0.04 -0.06 -0.08 -0.1 -0.12 -0.14 -0.16 -0.185 -0.2 -0.4 -0.65 -0.85 -1.03 -1.25 -1.45 -1.65 -1.9 -2
ENTROPY DETERMINATION FOR NATURAL GAS
Ideal Gas State Entropy So (kJ/kg) Note:S=0 for T=0oK and P=0 kPa(abs)
Temperature (oC)
-80 -60 -40 -20 0
Methane 1 12.05 12.25 12.48 12.65 12.8
Ethane 2 7.68 7.8 7.95 8.1 8.2
Propane 3 6 6.15 6.3 6.4 6.53
I-Butane 4 5.1 5.2 5.3 5.41 5.56
n-Butane 5 4.8 4.9 5.05 5.17 5.3
i-Pentane 6 4.5 4.55 4.76 4.9 5
n-Pentane 7 4.4 4.45 4.66 4.8 4.9
n-Hexane 8
n-Heptane 9
n-Octane 10
n-Nonane 11
n-Decane 12
Benzene 13
Carbon Monoxide 14
Carbon Dioxide 15 4.5 4.56 4.6 4.7 4.75
Hydrogen Sulfide 16 5.6 5.7 5.8 5.9 5.97
Air 17
Hydrogen 18
Oxygen 19
Nitrogen 20 6.35 6.45 6.53 6.61 6.7
Water 21

14.5
Entropy (kJ/kg)

13.5

12.5

11.5

10.5

9.5

8.5

7.5

6.5

5.5

4.5

3.5

2.5
-80 -60 -40 -20 0 20 40 60
Entropy Determination
P 10000 kPa(g)
T 30 oC
Pc 4611.91 kPa(abs)
Tc 206.86 K
o

Pr 2.190268
Tr 1.465466
w 0.031593
ln P 4.602089 R.sum(yi.ln(yi))

MW 19.42305
 ENGINEERING DESIGN CALCULATION - DENNIS KIRK
refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 - Section 24, Fig 24-19
=0 kPa(abs)

20 40 60 80 100 120 140

12.95 13.1 13.25 13.4 13.5 13.61 13.75
8.31 8.43 8.55 8.68 8.8 8.9 9
6.65 6.76 6.85 6.95 7.05 7.15 7.24
5.7 5.8 5.9 6 6.1 6.2 6.31
5.4 5.5 5.6 5.71 5.81 5.95 6.05
5.11 5.2 5.31 5.41 5.51 5.65 5.75
5.01 5.1 5.21 5.31 5.41 5.55 5.65

4.8 4.86 4.9 5 5.02 5.1 5.12

6.04 6.1 6.18 6.2 6.29 6.3 6.35

6.8 6.89 6.91 7 7.05 7.1 7.15

Ideal Gas State Entropy (So)

Temperature degC

20 40 60 80 100 120 140 160 180 200 220

Som #VALUE! kJ/kmol.K Ideal Gas State Entropy at T

[(So-S)/R]0 #VALUE!

[(So-S)/R]' #VALUE!

So-S #VALUE! kJ/kmole.K

R.sum(yi.ln(yi)) -5.198823 kJ/kmole.K

So #VALUE! kJ/kmole.K

S #VALUE! kJ/kmole.K
#VALUE! kJ/kg.K
ULATION - DENNIS KIRK
Version 1.510

160 180 200 220 240 yi ln(yi) yi.ln(yi)

13.9 14 14.15 14.28 14.4 0.8601153 -0.150689 -0.12961
9.1 9.2 9.3 9.4 9.50.0631691 -2.76194 -0.174469
7.32 7.4 7.5 7.6 7.7 0.022373 -3.7999 -0.085015
6.41 6.51 6.61 6.7 6.81 0.0041556 -5.483298 -0.022786
6.15 6.26 6.35 6.45 6.60.0056587 -5.174561 -0.029281
5.85 5.95 6.06 6.16 6.30.0024379 -6.016618 -0.014668
5.75 5.85 5.96 6.06 6.20.0016037 -6.435442 -0.010321
0.0016453 -6.409832 -0.010546
0.0009306 -6.979681 -0.006495
0.0004622 -7.679513 -0.003549
0.0001982 -8.526234 -0.00169
0 0 0
0 0 0
0 0 0
5.19 5.2 5.25 5.3 5.31 0.0324657 -3.427571 -0.111279
6.4 6.42 6.5 6.51 6.56 0 0 0
0 0 0
0 0 0
0 0 0
7.2 7.25 7.3 7.32 7.4 0.0047847 -5.342332 -0.025561
0 0 0
1 -68.18761 -0.625271
Methane
Ethane
Propane
I-Butane
n-Butane
i-Pentane
n-Pentane
n-Hexane
n-Heptane
n-Octane
n-Nonane
n-Decane
Benzene
Carbon Monoxide
Carbon Dioxide
Hydrogen Sulfide
Air
Hydrogen
Oxygen
Nitrogen

180 200 220 240 Water

 ENTROPY DETERMINATION FOR NATURAL
Pressure Effect on Entropy (Simple) [(So-S)/R](
kg/kmol kJ/kg.K kJ/kmol.K Reduced Pressure Pr
MWI yi.MW Sio yi.Sio.MWI 0.1
16.043 13.798829 #VALUE! #VALUE! 0.80 0.15
30.07 1.8994954 #VALUE! #VALUE! 0.85 0.12
44.097 0.9865825 #VALUE! #VALUE! 0.90 0.1

Reduced Temperature Tr
58.123 0.241536 #VALUE! #VALUE! 0.95 0.08
58.123 0.3289007 #VALUE! #VALUE! 1.00 0.068
72.15 0.1758945 #VALUE! #VALUE! 1.05 0.056
72.15 0.115707 #VALUE! #VALUE! 1.10 0.048
86.177 0.1417871 #VALUE! #VALUE! 1.15 0.041
100.204 0.0932499 #VALUE! #VALUE! 1.20 0.037
114.231 0.0527976 #VALUE! #VALUE! 1.30 0.033
128.258 0.0254207 #VALUE! #VALUE! 1.40 0.0287
142.285 0 #VALUE! #VALUE! 1.60 0.021
78.114 0 #VALUE! #VALUE! 1.80 0.016
28.01 0 #VALUE! #VALUE! 2.00 0.013
44.01 1.4288159 #VALUE! #VALUE! 2.2 0.01
34.082 0 #VALUE! #VALUE! 2.40 0.00636
28.9625 0 #VALUE! #VALUE! 2.60 0.0017
2.0159 0 #VALUE! #VALUE! 2.80 -0.0028
31.9988 0 #VALUE! #VALUE! 3.00 -0.019
28.0134 0.1340358 #VALUE! #VALUE! 3.2 -0.032
18.0153 0 #VALUE! #VALUE! 3.40 -0.04
19.423052 #VALUE! 3.60 -0.048
3.80 -0.056
4.00 -0.062

4.99
[(So-S/R](0)

Pressure Effect (Sim

3.99

2.99

1.99

0.99

-0.01
0.1
Pressure Effect on Entropy (Real) [(So-S)/R]
 Reduced Pressure Pr
0.1
0.80 0.22

Reduced Temperature Tr
0.85 0.18
0.90 0.13
0.95 0.1
1.00 0.08
1.05 0.06
1.10 0.05
1.15 0.04
1.20 0.03
1.25 0.025
1.30 0.02
1.35 0.02
1.40 0.015
1.50 0.015
1.60 0.01
1.70 0.01
1.80 0.005
1.90 0.005
2.00 0.005
2.50 0
3.00 0
3.50 0
4.00 0
 ENGINEERING DESIGN CALCULAT
ATION FOR NATURAL GAS refer GPSA ENGINEERING DATA BOOK - SI 11th Edition 1998 -
py (Simple) [(So-S)/R](0)
Reduced Pressure Pr
0.125 0.15 0.175 0.2 0.225 0.25 0.275 0.3
0.18 0.23 0.28 0.33 0.38 0.45 0.52 0.6
0.15 0.18 0.23 0.255 0.3 0.33 0.38 0.42
0.13 0.16 0.18 0.205 0.24 0.26 0.3 0.33
0.1 0.13 0.16 0.165 0.18 0.22 0.24 0.26
0.081 0.1 0.12 0.137 0.155 0.17 0.19 0.22
0.068 0.081 0.1 0.1125 0.125 0.14 0.16 0.175
0.06 0.067 0.081 0.096 0.11 0.12 0.135 0.15
0.049 0.06 0.067 0.084 0.09 0.1 0.11 0.13
0.045 0.051 0.061 0.074 0.08 0.085 0.09 0.11
0.038 0.045 0.052 0.06 0.074 0.08 0.085 0.09
0.034 0.039 0.045 0.051 0.06 0.07 0.073 0.076
0.0287 0.032 0.038 0.041 0.045 0.05 0.059 0.062
0.02 0.024 0.029 0.036 0.039 0.042 0.045 0.048
0.016 0.02 0.024 0.028 0.03 0.031 0.034 0.038
0.013 0.016 0.02 0.022 0.0242 0.025 0.026 0.03
0.01 0.013 0.016 0.018 0.02 0.021 0.023 0.0253
0.006 0.0095 0.011 0.013 0.0148 0.0165 0.0186 0.02
0.00009 0.003 0.006 0.0095 0.0108 0.012 0.0137 0.015
-0.013 -0.009 -0.006 -0.001 0.001 0.003 0.005 0.009
-0.027 -0.023 -0.019 -0.015 -0.012 -0.0085 -0.0055 -0.001
-0.035 -0.028 -0.024 -0.02 -0.018 -0.014 -0.012 -0.01
-0.04 -0.035 -0.029 -0.026 -0.022 -0.02 -0.016 -0.013
-0.049 -0.042 -0.038 -0.032 -0.03 -0.026 -0.022 -0.019
-0.055 -0.048 -0.044 -0.04 -0.036 -0.033 -0.03 -0.026

Pressure Effect (Simple)

0.
8
0
0.
8
5
0.
9
0
0.
9
5
1.
0
0
1.
0
5
1.
1
0
1.
1
5
1.
2
0
1.
Reduced Pressure Pr 3
1 10 0

py (Real) [(So-S)/R] (0)

Reduced Pressure Pr
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.46 5.6 5.6 5.6 5.6 5.6 5.6 5.6
0.37 0.68 5.2 5.1 4.98 4.97 4.96 4.93
0.3 0.48 0.7 1.1 4.4 4.35 4.34 4.32
0.24 0.37 0.53 0.72 0.98 3.81 3.8 3.79
0.19 0.29 0.4 0.51 0.63 0.77 0.97 1.97
0.14 0.21 0.26 0.32 0.38 0.45 0.52 0.61
0.11 0.16 0.2 0.23 0.28 0.32 0.36 0.4
0.09 0.13 0.16 0.195 0.22 0.25 0.27 0.3
0.08 0.095 0.11 0.135 0.16 0.2 0.23 0.25
0.06 0.06 0.1 0.12 0.13 0.15 0.18 0.21
0.05 0.05 0.08 0.085 0.09 0.1 0.12 0.13
0.038 0.038 0.051 0.06 0.075 0.085 0.09 0.105
0.034 0.035 0.043 0.044 0.05 0.07 0.08 0.09
0.03 0.03 0.034 0.036 0.042 0.052 0.055 0.06
0.01 0.01 0.01 0.01 0.012 0.025 0.028 0.038
0.01 0 0 0 0 0.01 0.01 0.01
0.01 0 0 0 0 0 0 0
0.01 0 0 0 0 0 0 0
0.01 0 0 0 0 0 0 0
-0.02 0 0 0 0 0 0 0
-0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.017
-0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.02
-0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.02
RING DESIGN CALCULATION - DENNIS KIRK
K - SI 11th Edition 1998 - Section 24, Fig 24-20 & Fig 24-21

0.4 0.5 1 2 3 5 6 7
1 1.7 4.3 3.7 3.4 3.2 3.1 3.08
0.66 1.1 4 3.5 3.2 3 2.9 2.87
0.48 0.68 3.7 3.3 2.9 2.65 2.62 2.61
0.37 0.5 3.4 3 2.6 2.5 2.46 2.45
0.3 0.4 2 2.65 2.4 2.3 2.28 2.26
0.25 0.33 0.9 2.35 2.25 2.18 2.17 2.15
0.21 0.28 0.7 1.9 2.15 2.1 2.09 2.07
0.17 0.25 0.59 1.5 1.96 1.95 1.948 1.94
0.15 0.2 0.49 1.2 1.74 1.72 1.71 1.71
0.125 0.16 0.35 0.82 1.1 1.45 1.46 1.47
0.105 0.135 0.306 0.63 0.91 1.25 1.27 1.29
0.081 0.105 0.21 0.42 0.61 0.89 0.94 0.96
0.063 0.08 0.17 0.31 0.45 0.65 0.74 0.79
0.05 0.063 0.125 0.247 0.34 0.5 0.57 0.64
0.04 0.05 0.1 0.19 0.28 0.39 0.44 0.49
0.032 0.04 0.079 0.151 0.23 0.325 0.34 0.36
0.026 0.032 0.062 0.13 0.18 0.3 0.32 0.33
0.021 0.0267 0.05 0.1 0.15 0.233 0.26 0.28
0.014 0.02 0.041 0.08 0.125 0.19 0.22 0.25
0.008 0.0145 0.035 0.071 0.11 0.17 0.2 0.23
0.0008 0.008 0.031 0.062 0.092 0.14 0.17 0.19
-0.005 0.00135 0.028 0.055 0.082 0.13 0.15 0.17
-0.0101 -0.003 0.023 0.05 0.072 0.11 0.13 0.15
-0.016 -0.008 0.015 0.044 0.064 0.1 0.123 0.135

5.75 Pressure Effect (Real)

0.
[(So-S/R](0)

8 4.75
0
0.
8
5
0.
9 3.75
0
0.
9
5
1.
0 2.75
0
1.
0
5
1. 1.75
1
0
1.
1
5
1. 0.75
2
0
1.
3 Reduced Pressure Pr
10 0
-0.25 0.1 1
 1 1.5 2 3 4 5 6 7
5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6
4.9 4.85 4.8 4.8 4.8 4.8 4.8 4.8
4.31 4.3 4.24 4.22 4.19 4.18 4.18 4.17
3.78 3.75 3.75 3.8 3.83 3.85 3.9 3.91
2.6 3.2 3.35 3.48 3.55 3.6 3.65 3.7
0.7 1.95 2.5 2.85 3 3.1 3.2 3.25
0.48 0.82 1.65 2.25 2.5 2.7 2.8 2.9
0.34 0.52 0.86 1.7 2.15 2.4 2.55 2.66
0.27 0.37 0.55 1.15 1.6 1.85 2 2.15
0.22 0.29 0.39 0.73 1.2 1.5 1.7 1.8
0.15 0.22 0.29 0.49 0.79 1.1 1.353 1.55
0.13 0.18 0.24 0.37 0.59 0.85 1.05 1.25
0.106 0.15 0.19 0.27 0.45 0.65 0.84 1
0.07 0.09 0.106 0.15 0.23 0.36 0.56 0.76
0.04 0.05 0.061 0.09 0.14 0.25 0.4 0.6
0.015 0.02 0.03 0.037 0.07 0.14 0.32 0.5
0 -0.009 -0.01 -0.01 0.03 0.09 0.22 0.34
0 -0.01 -0.015 -0.01 0 0.05 0.14 0.24
0 -0.01 -0.015 -0.013 -0.01 0.02 0.08 0.16
0 -0.01 -0.015 -0.06 -0.061 -0.059 -0.059 -0.05
-0.018 -0.019 -0.024 -0.06 -0.1 -0.13 -0.15 -0.17
-0.044 -0.07 -0.094 -0.145 -0.15 -0.18 -0.21 -0.23
-0.04 -0.072 -0.095 -0.14 -0.157 -0.18 -0.22 -0.24
 Version 1.510

8 9 10
3.06 3.03 3
2.84 2.82 2.8
2.61 2.6 2.6
2.44 2.41 2.4
2.24 2.21 2.2
2.14 2.12 2.1
2.05 2.03 2
1.93 1.925 1.92
1.7 1.7 1.7
1.48 1.49 1.5
1.32 1.33 1.35
0.99 1.05 1.1
0.86 0.88 0.9
0.67 0.68 0.69
0.54 0.56 0.57
0.38 0.4 0.42
0.35 0.37 0.41
0.29 0.3 0.31
0.27 0.29 0.3
0.255 0.27 0.29
0.22 0.24 0.25
0.19 0.21 0.22
0.16 0.17 0.18
0.14 0.145 0.15

0.8
0
0.8
5
0.9
0
0.9
5
1.0
0
1.0
5
1.1
0
1.1
5
1.2
0
1.2
5
1.3
0
1.3
5
1.4
0
1.5
0
1.6
0
1.7
0
1.8
0
1.9
10 0
 8 9 10
5.6 5.6 5.6
4.8 4.8 4.8
4.16 4.16 4.16
3.92 3.93 3.93
3.7 3.7 3.7
3.3 3.35 3.4
3 3.1 3.12
2.75 2.82 2.9
2.3 2.4 2.5
1.9 2 2.1
1.65 1.75 1.8
1.4 1.5 1.6
1.2 1.35 1.45
0.92 1.1 1.25
0.74 0.88 1
0.6 0.74 0.86
0.47 0.57 0.68
0.37 0.46 0.56
0.25 0.38 0.45
-0.021 0.02 0.06
-0.18 -0.18 -0.18
-0.25 -0.28 -0.38
-0.26 -0.29 -0.4