..

. ., l
l,
. Y.' /i

C$ {p.) ... "2 olo

DO NOT OPEN THIS TEST BOOKLET UNTIL YOU ARE ASKED TQ IJO SO
T.B.C. : N-DTQK-EJG 11:':81' BOOKLET SERIES

Serial

TEST BOOKLET
CHEMISTRY

Tittu! Alh>u'<td : 'l'llm llourl.< Maxim um Marl:IJ : 300

INS'riU Jf:'I'JONS
1. Al"'fER Tm: OV THE EXAMINAT !Ol', YOU SBOUlJ> CHl'.CK
THAT THIS n::->'1' HOOKLg'l' DOI>S NO'J' UNPIUN'n :D 0 1! TORN OR MISSING
PAGES 01( ITEMS. IF SO, IT IW l\ COMI'Urn: BOOKLET.
2. nn: n:S'r IJ()I)KLJIT SEnU:s A, B. C On D AS rm: MAY BB IN 'l'llE
AI'PROI'RlA'l'P:. 1'1.\n; IN 'l'H lr. SHEIO:I'
3.. htt\"t th Hafl l,)n
Booklt.t in Box Jlr<>vid.,J
DO N07' IYr!t<> unytlsiiJI( "" th !!u<lkicl.
-t. 'l'csl Hooklet contnin 120 i<emo F.>l<h iwm i prlnw<l bollo in IUndl nnd Englboh.
H.om J(uu wiU the which Ytltl W9ll\ on
tn t.hfl1. if :.non ! t.hun one oorrecr. IXMpml.sc. rn"rk
which ynu tht lhHit. lrt any (),VLY ();.''llr for c.at.h itcJn,
3. Yc,u h.:a mnrk uH y<Jar ptXwidxJ. Soo dite-c:tl(.1ns in

6.. All tllitfkil..
7. yo\J liJ mnrk m tht ArHsWcJ rcapunS1tJ t(J varivuro ttenu; in Tc8t 1\ouldet, you
bHV('j to nu in '7<.lm(' portkuln1'$ )n s\mm"Cf Shoei !lEI to }'t)U with )'U\if
Admlnsion C(!rtifieat.e.
8. J\.f\..:, ...vu ... t; 1n otH yrJu, ... on \he Atu:::w(!r Sltt.>t!l r.he bas
l:)hi>uld t;.; Invigl!:tt1')r only lh" Answer 'b'u nn. permitted to
with )'vu thE, Hooldt:t,
9. nmgh H\ ..Jd<!t At t.hc end.
10.. l,cnatt.y for wrong :
'I'HF:RF! WILl. I'!'.NAI.'fY !'Oil WRONG ANSWJ.:RS MARKF.ll IW A CANrJIDAn: [!>: 'l'tll:

i l) 1'h<.>j't,<> CU'f,' (uur

fm tht! l:itlfl\.1le"J tA) r;Uf!Jition for whic.b n wrung

been t{iw:m
the trr th., (U:ll;ofgm.d W that
will he ptnnJt)'.
U rt t'anduJnte trH)re une w.ttli.IW<.'r. it. wm ts'! trttntisd a wrung if vnu af
dw tiaf'lmn& (n be and WiU be abnvt tG that qucatiUl\.
iilft If >I blf\,\1$, t.., Ah8WCT it t.hC t.htTC w$U bot'! no pc!mt.lt) for
t.h!'t questiml.

DO NOT OPEN TillS TEST BOOKI..ET UNTIL YOU. ARE A."iKltl> TQ DO SO

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Directi.Oii's : f.'or the three i/J!no. u;hi<h (o/Jnu: : D irec tion s : P.:;r lite three <Uhi<h (o/IO<c :
rttree cornpmmds A, B a:1d c; have the form\lm B6lh methane And cih ano cnn ix, used as fuels.
C6 H 10 All r.on>p()unr.ts rapidly Th( valoes (>f tor GH., i gi, C}i;; i g ;,
ar2 in GC1.1 t-JI! thrM soluble in C0 2 (g) atu:l Hp !li art> .. 7484,
<;nlr.t <:otic.. ... 8468. ... :l93f., and . 9.!1fi k,l nwr . 1
Cc,m'f,l)Urtr.l A gives
when ln<ateol wil.h AuN0;1 in aq.
N'lI:J compvunda ll >lfld C do n<>t. -1 . Vlh:\t the ent.huJpy r..f c.mnbust.\on uf
(;(Jifl p<otmds ;\ <md B l,oth yil:ld whrm
l'\l f!thAJll?' '!
they " " ' with 1!2 it> lh e
pn!sem:e of Pt. cat.el)''t. Undor t.h;..,;e ronditions !a I - 1!0066 kJ mul' 1
C only mtlar llf H 2 a nd ibi - 65533 k.J mot 1
1\IV(>F. a pro<lur.t with the rurmula C,;H 12 . Whom 1
<d kJ mol"
A oxidized with KMnO, find tlu'
solution ()nh' urgnnk I d1 - 2226(; k.l mc;l"' 1
pJ'T.t(hH:t thnt be isnlatt!d ts
i
Similar <>XidaLion uf B 5. much hea t per gtnm of
unly lJtld C giw:s only !
FI020.CH 2;4C0 2 H.
t nl 260 lvJ
(l)J 390 kJ
l.
[(:) 52() k.J
( <)) 650 k,J
!b; CH,P '
'* CCH,,CH,C!L1 - ll '

lei CH.,CH.,GH ..CIt.C ,. C'fl

'>) " "
6. How mnny is
I ell more (.\tllcamt. t.hs.n fJth an (l :'

2., lh<> Sl.l'lJCl.urc or <'Ompaund II.!; 0 ( ttl 093

!<11 CHF H2 CH:G .. OCH 3 lbl 107

!ci u ;;
fb) CH 3Cl!i;

(d t 201
lei
=< CCH.:c
id l .... CH

a. Wh!> L d n; Et:l'\\Ctlln> ,,f com pound IC! ., 7. 'Ft)r !1 given solut:h1n or Schrodinge!' wrnc
the value qf is c:xpre...oe;, S:J k.!f.
! nl
Ojl f! r >. fr x >. ii.yt. Whtl doos ""' ''(!
CH,

l p) (:o i f<irbil.ai function bnly

1h 1 dnrbit.al f'nn<:tion only
1c ClL,c l'I.F "
l<l p<>rbital funct i<JII unly
1<11 HC ''" ldi p nncl d-o rbitnl run.,t.'t!n

N D'T O K EJG I 2 - A f

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8. Tr.k ing int<l t!tcounl tht1 i$oolt>ct.roni' pl'itlcipl<l 1 /)irer.ti(>n : For two w lti<:h {i>llmv :
and thtt>ry, prc<lict in which on e of t.hcl
Th( t>f o column of
pu.lrs, h<1th . .slp(.)c:ies have
{}{)5 M NaOH sol ution uf I cnl itttd
pyramidal '?
78 5 em 50{){) rJh nJ .
, <"'
.. ,. f'('):t..
.) ;J ntHI
3
ibi .. and NO'3 \.\'htit i.'j \.he f1iiiStiv(ty Of !
so;- alld CIO 3"

c1o-3 tb; 40 n em
id! SO:o and
it.i 30 0. em
9. Whid one of the followi ng is the C<Jr rect (d'> Ncme of ,;bmc
Sl<ll<!mCn l t\b{.Ul l.ha K<KllllOIJ')I <.>f wr,- '!

(a i h. hll " d a hcdt'lt.l with nne 13. What i;; molar '<ln rluctivHy ol' lhc
pair fiiCO l.'f <1d .nhed.ron. Molut inn '?
fhi It reg-utnr c,ctnhedrtd stru dun..'. (t<i 200 S t'm" mul "1
i(:> h. pcl\ll\I!Oilul hipy-ramidtl tucture ib i 1 ()() S cm2 m(tl" 1
with puir rJct:upying a.n axial f c, 60\) S n n2 mul" 1
J?OE\itwn.
.:d ) o r
d! or

f.)irectimu : 1/w lu>o it/!m .< w/ii(:h {i)/lou ; 1-1. A plot or t;ondanl Gibbs r"'" tm.,rgy t.f
Two
iX) and fY'I tlC t h;, fonnation f,f mctttl oxidr. U!luinttt h..mpt)rntu.n.
r()f"mule-. Cdi i,> t.h( fvll-:wiug '" k nt)Wn
! 141 Tnnab.' SngHYW

l. Roth o:h sch >lrged colctur <>f' in CC1.1 ihi Ellinghnn1

'> tXj glv(MI a wit.h nmrntJnlur..a l it : MO diagrnm

and on ox.id(ttiir.m gi ve-t; prop::utoic td i L<'wis diaf.,'l'am
ac;id an d C0 2
:l. fY; ch:J:,; nvl t;lv(: with 1 5,
On H H2
AgNO:I m1d. <.m mddftt.i on
by the following of :
"in;s oxalle aci d GO:!
10. Wht is \tl(\ rormuln nf ll() '!
;a; CH3 C '" CCH:J f
1""r?;u.c"fl with !Wfuli:nn uf Z j
;b; n i 3GH 2C " CH

icr Ct-1 2 CH - CR =C!i 2

id; CH2 " C CH - CA 3
What " "" X, Y. 1.. in the S(.'Quence or rea ctio n.<
I I. Whsl is \Yi 7 '!
i<l l CH 3CI! = C = C H 3 (3J tC0 2 +H 2 ;. NH., OH
1b ; C H:,C "' CCH;, ' ;,; H 2 ;. cCO+H 2 i.
'"' CH CCH3Cii:1
; ,., ICO+H 2 i, <CO?.'H 2 '> ,
fd) C llt C H ... C H CH 2
;cJ; ;'CO+H./ d l 2 1'!20l. C"O

N-DT0 K JG

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S. 'llll$<'t<tlf-m; VSl:l'H all m t:
m w. "'"'"$e fir. t
a5t.l <l' P.<f>. Wl'lil awf4Frl Tiffll t ? 1 em 1'!:!m 3IR 78!"> f!l<fr$ aJli!005 M NaOH
1a > 31\< 1?ifO 11'11 m1 ll'WJ !riiRru 5000 ohm
t. l
rbl :lt No;
!ei CIOi
ld! S03 :!l\1 CIOj lai 50 n nn
9. P-!::,f..bf'bn If <' m \!ill lflr $ row ;bi 40 nan
ma lli!R ? lc) 30 n em
(8 ) '7it 3il\%i'ii11Ttl '{'<mJ Jd ) "i1 alit ;#.
3; Wl<5 <R P.<f> l!ltn<Ci T11 3<f:ZlW
t. I
t3. <!5t lTIR< '""""''" 1m\
!ai 200 S cm 2 mor 1

o,, 400 s crn 2 mor

;c; 600 S cm 2 mol" 1

f.lhT ' if} wolf fr1l! :

'IIlii'! C.Hu if !tlfi'r.ll1 \Xi IYI 14. tn'l 3li<rol$$ II> &lfcr-1 ci;'! llRID 'Jfll J'i5ll <5t.
' nltl a> m ?

CCI.1 11 Rr2 tfl'l !ltlffih<I'Jtct m:

iIll i;.!f;} - ::mm
I. i
ih ; :!A'Rx
2 iX 1 :11tt'lf'lll1'<4 AgN0 3 :il l?<l'l Jfaaiq i.m1 t id MO
:iliT :><1wnili'<VI ifl'f.J rr< JITn Jftf
\di
co2 trn t. 1
;L ;y; Jlli\tl1't iNQ ,\ gN<):l t.f ;;,-.sa)lf am f. Hi.
""- H 1 351 :l<'llll':t

.)1\'{ .:s!ICR\\,fHOI m::!\ <f{ 3!l<'t
ii; 3'1jlb'fl:;fih fii;m :;n <fif;ffi
co1 to 1
illtl <m l'ltO X trlQ' y
I 0. (X J ifil l).!i: ll'lJI !! ? -:;;Jifii;;CM;;;;,
s;s
lni CH3 C ., CCII 3
lhl
{ct

CH

CH 1 = Cl-1 - C:fl = Cfl 2

z Jlltllftn
1
H2
(d 1 GH2 C a C:H - il> 31-jlb'f ii X. Y, Z l5rm' lf<ll t ?
11 . m 1flll t. ? ial I CO .. H 2 ;, i C02 +H.1l, Nrl 40 fl
la J CH3CH C Cf! 1
ib! tCO+H2 i,
(bl .. GC H,1
\CO+ ll 2'>, <G02 ... H 2 !. K 2 C0 3
!cl C! "
!di CH 2 ... GH ... CH =CH 2 \d> <CO .. !l2 i, ... H2()'t, CaO

111-0TQ -K-E..;G ( 5 - A I

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16. Whtm lleryl!ium with ! IS. >he follnwing n><>n<>StH!churidcs :
Ut:E,lti(: ln WUier, tht- n')rmerl is CHO CHO
irli Ber,vllium l)o(CHl:Om2 H - 1--- :
OH HO I
I
H.
HO H HO _ ,........__ f!
!b1 Ha.sic l:rorylliurn ncl!t.at<!, B.,Q(CH3C00l6 ,
H + - OH H +OH
!ci Basic beryllium ncetnlc.
lk-< 0<CH3C<X>>6
H ---t- OH H - t - OH
CH 20 H Cl-! 2 011

(d i B=< lwrylhum RC<)Ult.e, II

B.sOUi2 6CH3C0012
CH,,OH
1 - CHO
17. CoMider the hydrogan nt.oms rnllrkNi
1\, 1\ and Hd in th o foll11wing mt>lt\cule Gnd

il ----1'- - OH

- r--
statements l. 2, :3 nnd 4 ttboul Lheir HO H H O - -- H
!
t(tpidty : H 01! JJ OH
H
.'
II - f - - 0!1 HO H
I
CH,PH

l!! IV
Which of l.htl following 9i.ntemenls !II'U Cl>rYU(l
in respect at' the abtwc '.'

I nod I!
2. l is Dglumot! ancl Ill is D-fru(ti'J<W.
l. H,. Hb arc (lfld ) !,.. H,1 a re
l ,. n-glucOc IV
dimrtttrH)tnpic.
l.l nnd Ill will form the Slln><'
;!. H.,. HI> llrC di.a.llt(lrCOt Op iC i\lld n. H. Seleet r.mrc.ct using th<' t:ode giv'!n
t."n:\nt.:Cot.opic. hdc.w:
;a} J and 2 tmly
:i . ! 0 , H, nre homotopic *'" oro H11 , Ho!.
tb., 1. 3 nnd 4
4. ll , . .H d a rt' hon1otoJ)ic and fl ,,. Hd are tr.! J, 2 and 4

!d! 2 and 4 i)niy

Which of st.utcmen l& given above lw'u rc

m The critical a nd n.'<iut'Cd
tempcraturt? or a gas are 150 K and 3
(3 ! 1 Ol>ly rt>Spetliw:ly. \\.'hat is lM tcmpcn<lure of the
ga,; 1
2 unl.v ! ;) j 50 I<
147 !o[
it;:i 2 and I
15:1
ft:;
( dj 450 1\ ''
N-OTDK JG

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w. \\!lm.t. wouid Uu... rA tio of rnetuH;quar e i
..,;)\ucity uf hydr"ll(<r\ gns lit 5() I< 11nd thnt of
OllY!:"" At. 800 K ? ,
I ;\ C:(1T1Jptnu;d f;f b<wtH' ry{' rm

which nn further he:.J.t.ing givt'S glassy
s wcil*',

St\lid ''t,... The t.ranspurt:nl solid y

; <)n wit.h

cc,mpn\.md. Ttur
(b ) 2 tbrrnuh1 of X. Y :.u \d ruHn( <.,f t.h l;'
res.peclive ly :ue
k; <I
iu> B20:; and ring
{di 16
ibf . IOH2 0. B20 3 and bora" b"'d
lc.:o-l
21. Which one of following is C<>ITCcl. an
ide11l gRi' is nnd (C) H3 B03 , B2 0 3 and burnx bclld IA.>s\
"'!
:a; q = o. w nc.,lT. ali "nC,.rl'l' ! ; tli NaB02 . 4H20. a nd name :A:>st

;t. ; <I 0. W 0 . .:\0 = nC_clT 125. ln AI.,CI-. whith

" . dimerit strutlum.
;,) q = o. w " .. .. il ' 1 Atl ;\.I Cl bonds buud
!engths
..\! - C! ihrminni'J Mt: l<lng4!r thnu
.-\1 Cl !bidg<.<d) ]l(>tH)$
22. !.d l k,J mt)t ' 1 thr ,;\j ... Cl (t.(.'rmlnah btmds .\tr\'r

in <!1.\thulpy f'cit l O g :of wnlur f'rozen lll I t.hun Al .... Cl tbridgcd; bonc!s
H....-; nonnni frt''l"Zing PQU'\t '! 1 ; d : Nont:! of t.ho
!
!at ... 322 k,J
2-f>. Whith onE. t)f t.hv !()!lowing
;h) ... :l22 .i

i<:; :J-.::2 J (a; N;.v\11-1.1 nnd NaHH.1 ('l r<," rN'lclily

(rH ;')?.2 kJ

d>l NaAiH.1 ;md NaBH 4 "'" nol.

23. \\!'htH' an i<h:-al gall. J>t niL
and irrtwe-ri:!ibly froJT\ vo\umc V \ V2 thnr:
(ti NnAlll 4 is hydooly8e<l rrum! reud\ly
whkh ono the he corr1:!-d '!
Na BH.
!:' ' .:\ S h;)".&l(\rn) 0 t'nd
\di hydn>iysi?d more readily lhllll
vt?-
NaA JH 4 .
=+vt! :utd
.:h"l .:\.'5
.
tsys\.e-m I
0
..,_
.. '" \<'l.r6thionic acid.
s- s oond .,
lh( llllmbcr or
{C! :\S t SySt(lf'ni 0 and ; ti i 'fy.:l,
:.\ S : 0
; 1,; Thrt'e
1d .\S 1 =vc n.nd :,; :
.'\S it:::urr<.undinJJ'K'
.di

-F..IG 8 Ai

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28. Consider the bonds mnrkcd n b. c. d in Lhe :J1. t <>r u ga;;wus reaction t\ + 3B =-> 2C.
st.ructure : Mf 0 - fiOO k,J, <lb"' " -- 200(.1 .) I{ .. 1
.. a b
c nL MJO K. \Vha1 is .
/.'"/ '-.... ., .., fi)r t.ht
' ......... ' l :l
.... A + - H "-' C at. ,jO() 1\ .,
\ Vhti' Lhe unJt\r uf hml\<JJyLic 2 2
l,),()ttd 'l irH ... .'\{j k.J

il)l " iO () k.J

(c) - !50 kJ
<r 1 '' > U > d > c (rJ.I - 260 k-J

az. C<lJlsider fill!owi .

{ ()JJ .,
29. Cll>ider f<;llrowin)!; r..<<lllJ><>IHlli> : I.

I. PhN<\
II. f'hCN
Ill. l'hNC
0
j:
IV l'hC NI!ClL1
Whtch (0( aoo;e ll.Y<! thl' thermodynamic
ls {:Ofrt:t:l ordc.'r \)(' l.h( pK11 \'Clh.H.\Ii or ntillt.ionio>?

l)n;.dur;;:..; (d. n:dUI:'1.1wn v.tth rn.hi um
:t lum inittr.ll '? 1u '; 2 unly
!111 II l! I . IV I l, h! a l:.nly

!bJ fV :. II! > ll > I

!,; and 2 I
\d l :! and a
td I ;. Ill ' ll > IV
<d1 IV: !I : Ill : I t\cc:ording f.{) thl! which unc 1.1f
tlf C : 2, p a
30. A nH:[mic mbc:tr.sr c t)f cu1 :./\J rencts u.nd F 1 :
wlth thun mw an vptkaUy ru:. I!H heHi.cd. in uu ittnpty
pur.: dllr!!l nd <l thloridrl \IlL Thr: i;; in equilibri\llll w'iLh NR, i.g, and

IUt
proouc< fc.rnt('ll. sho"ld IN a

'3tn(>unt.s.
m lxt.ure- of cnaotiotl'lers m equal I <b)
HCl !g'i
NH,CJ is) hentc<l in k
o:nn taln ing (UHJlC u.rnnunta t;f NH is
3
lb; m ixtUi\: (lf (l'W,.t 1'1 tH)l'n(r:'-> m l<noquaJ i 111 e(!uilibtium with Nl'L1 !V.;I Hmi HCi !g;
:unmJn!.l;.
A saturntecl >()lution of N:,S0.1 with
; 1: I of di t'S (.t rl't (\ in lt' ln :l('f\)Hihrium with

in n c hu;t"d
! tl l rnix turt:
tlffi(iUR!..!;:.
,,( d Hl uru!'qu;:ll I
I
I <P Noru: uf ihc ubtwc:
'
NDTOK UG 10 A )

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 -----------------------------.....
............. ..

$4 . il complex htB trifConal $8. nulLa! <.:mnmonly empl<>y''<l ronetion in extrnct\Or> of

bipyramida! gaomotry. T!w J>oiolt l,:'r<lup !A)
whit:h lh'-' moJl:'<.'ule Miongs lt'
i ,'\u .. NaCN 2 H10 + X .., 4 N;.aOH
fu1 Cav V to prtodpl"-t(!l
Au
i b) c3 Wl>tl sre X und Y in t he r<}nction
': D:;;,
ta; N2 ;md Cu
i'dJ c..
\ )> ) (J
2
and :t.n

35. When
KCN is added U) AIGl3 ! CI <''0
. snn. N.
.. }
2
snlu!icm. which one of i.he fo!lowinR results ? ldl C02 and Ag

39. CoMidN l. 2. and 4 m t ho

!Al!C:N ;.''" l(rmwd
. "' fhllt)w[ng :
lei IAI!CNi 4 J" formed
0
li tl
id l Ali.CN ;;, iJ precipitated l iCk)(;; -(."h .. - l. C- c;"H., Cl! l. - t"U r"'"
l V'It) H
I

C:R - sn .! (' Cl!,

li i ll
38. ln th<t of purE' Ni . thft fi)llo\ving 1 I) Cl

rt?tll:tinl\ uttlhwd : Whi<:h of Lh<> h<ndr 1>TO P"'Ptide bonda '!

Nin , X - - "' NiiC(I>, - .............................. _ ........, N!
,. SO "C \'
inJ I :md 4 only
In th(> above ronction whal nr< X 11nd
temperatun' V rCi;}N-'Ctiveiy "! tb l I and 2 rmly

lai CO ;and 100 I<: I 2 and 3 cmly

; bi <C COl 1111d 150 'C i dl l, 2 and a

<ci dl 1 COl :md 2:m c
4().. ,\ n corgan\t compullnci absorptie>ns At
ill> CO and 230 c :12M irn,br.i and 1650 (Htrl cm 1 belride8 other

;11 its ffi s pc<.;trum. \\'bidl of the
3'1. In prl>tilaH for the ma oul'lct.uring <>f lhllfJwing fnr <:vmpl)und
HilVIII', molloo lontl is with wit,h thMe m lues >

lrii N1 ll PhCONH.2

"' 1hl PhCONHCH:1
tc: Zint' I (' ) PhCOCH.,NH .. . .
idi
i cl \

N OTQ -K-E.JG l 2 - \ )

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 l:{lVm hy tht} Henr.v'f; law. rr
the frot:tlng poin t of
law fhr a in
tll
by 0 25 J.{ ()r 1l11tlthe-r K 555 10 Torr ;1nd thit pnrlhtl
1

t><mvuls!ile Y in iOO go( I>Gli:Wrtt: alt.u prHSur;; of tbe g11 i6 200 T1.1rr, ihen what i
dt>pres;;.,s the free:t\ng point .,r oonzenc hy lh u ;mmunl tti tlw gru; in 10 kJ: of
025 ''C Wh<>t ie rnoll'c.,);u mass c,f Y '' w:lt(:r '?

( :l ) 50 <' :t I ') .. (1 10'"'' Uh't1

ib; I iJ() (bJ 2{> >. to 5 mol

iC! i5(!
! c;l r . l
10-" mol

\d l 12. m<;l
id l()lJ() '

l:"m n <i<.'t.w n ,., t- aB ...) 2C .;.. 2D, r.hf.l

::>f 1\ chnnges from 001 5{) trl
42. An i dl";.!.l soh.1UOCI l!"\ folmt;d hy lnlxing t.WlJ
0 0 13 5 M m I minul.e. Whal is the ratA> of
A and 13 nnd X , the
1 "f C in Ms- 1 ?
fra<"'t.ions >f A and H ;n
tht: t;oluthm $fSrl Yn t.ht nlf:lt1 i4\ j '
)1)"5
f 1f :\ nnd B respt'<:t.ivd.v Hl
vapnur A plo t of 1.:'\"A: y tlX'is ; 1,>I :tt Hi- 5

:\ gu.in.-;.l : i!'X xt rs ight

11 fc1 :\0 X to 5
lina. '>''h at is tho slopt> nf !ine '!
( (j l 50 ,. to-

l) (i

'" 16. Pni' t.:a nt:er rHcliutn hn"

. li.i) ..
by ..... L<L .,., Co
,,
f bi prepntr.d by :n. pi tmd t r., y; reactions.
Wtn.H ilrt< targM nuclei ror theGil rMCli<>n
?
(iH , . ..
! "i lli; N\ anti ' ,, ( .(t
(

d ll
!,fi c nnd
!XI
Ni
!1 () 20

t)O C'
:n ..n
) !Hid
P\ nnd Pn nr('
.,
\"UP<HH'
(t
I
ttf pur<. ':tanpfmClll (.S A and B
! ld l
;

N -OTC:H< EJG 14 - lJ,

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 4 6. On comm.,rcinl :U \n I' 49. Which carbocatiom in euch of the fuilowing
Jndi::\ tt:: br tnakn'IJ! Ufif.o .,r puir;. iii. !l, C. 0! .nc11e st11blE" than

f

:\. iiI CH;1 U iii1 tCII ,,.. i.,.. N .. ';'ht.,..

a
<iii iC ilal 0

(dl rad10ttl:t.ivc rru'lll!riiil of low c !il Iii\

moh:or.\!krr W(!ight

/ ' ....,_, (;HCH,.

l7.

1 g c,1f tthiium
Tht?
a O t ()W pet tid v
(t f t.ht:' ;:,r)n rtide$ i.s t.)h: (tl).$W tH' t.tw cc,dc
Hl':' rns l and :-nass fJf ti'U? 1.c particln h; bt!li>W :
6 6 !0... kg. Whot lotnl kinetic
v 1./1>1 A B c D
.!1\i!''lt\' (,f Ute: a ... t..m itted from J g Qr ia t i ii';. iin. fi i. lij
1'1!diun ?
lb l i i:. i i;. ( ii ;
<>I I iH!l I 9 .j li L :lJ. t ii ), i i;
(d ; tit (ii ). I i)

.....

ll CH:,
48. The: I UPAC thr
(PuNH:1;, i WtCl.1 ; I \Vh:H.

I.S
?
tompuund t\ ;,, tJ:w

!Itt
n
plfJtfnum i ) Vi "'tntchl<>l'(o I
r
<b l plnlinurn 1l) ! tt:ttaddorn
p!ati nal<: dh

1(:) ( lr,
(>li:t.Unurn ( J t i

\dJ Tt,tr:mmmine pint:tnum l lJ l

:TV:

N .Qf01< .1G 16 A

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 51 . Comider the following &tatements :
T'he mole fractiotl nf:.. $\\)Ut.t: in n tK:hltion i8
). ..ruitnt. nf t:CJompcruturco.
',,;

2. NJU:<l w mMtf LO(Y.J li:lr dilute olution

im = rnollllity of Lhc >lnd M 1
ttw mass t)f th<!
\Vhkh of nhove (sr/ant
corr.::c..i. ?
( Il l i only
fhl 7. <>niy 56. urw or thv follnwi ng hus
,.('. !loth I and
,, w
::rrc;tl() ?

1d j i nor ?. C< )

!h)
1)2. 100 mL <;fa so!u!:fon ('\nltaining 10 g of NnCI
\mohlr mass 585, is fuund to ht! wilh
200 ml, of a ll<olut,ion 12-o g (If
>l:hrco5e <m.ols.r mUS>; 180> What. tho
ur dissociation of NaCI ?
( 1\ ) 050 57. \!nnsidc-r folh)Wil'lg c:omponndn
lb) l)(;:)
OH Cl
<e.; !J70

l di ()-\):) /...- - /
1
sa. ml. or
C!
M llciU !.pK .. =- 50J is
c.ilYnt.,d vgainst a 02 M st.r<mg ba 8;:,. is fl
the pli llt the equiva len<c poinl . 1
lln !
I b '1 i l)
tl,.... ,,l!


9 1)
id! I 10
Cl Cl
54. erwq,')' iJf Jlvtl d.. in Il l IV
qua re plal\aJ s tnmg Jigl)nd field is
ts !)('rpcndicuiJJc to the plan'-' of Which <of the bavto com!)ounds exhibit
: optitul ncUvit.y al mom tcmporaturt '!

I:11 I and l1
! .. '!/.:...
t' ll
,. ,jX}' .
}
("' 1Ct

(h! C>J l rmd IV

! <j IV (dlly

(d j Hi) Ill and rv

"< DTO Kf.JG

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58. Co n11idor the followiJlg strucw res : 61 . GivN! st.andnrd redu c:t.lon pownt.inl

H + GOOH
Br
COOH
B ...,t__ ON
,nlues of
f"e:.l.. .. v .. ,.
.. ;k .., Fe :
Fi!2 : F.' = Oi7 V
e - OO-t v
H l -
eHs
1\r Ur -+-
H
CH 3
\.Yhat. is th( ''aiuft of fur ..... :i.o .... ?
(u') o no v
II .. (} t9f.l v
;;; ; - ll--145 v
1'11- Br
i i cl! 0>.\!t v
H - + - -COOl! HOOC =t---H
HaG -1- Br 1-1 ....... ,.... - . CH
3
62. If E'"' .
Cu.!.+
= 0:11 V and E"
t\" 1

,. OSO V.
H n.. what i.hc emf of t.hr. c<:'ll
Ill rv C11 ) Cu 2 \OCil M' ! l i\g ' WOl Mi i
t\l. 298 I{ ?
Whidl 01\e of th<> ab<wc ''
di,.slere<>mer of erylhro-2.8-dibro mobutanoic
cni 0 40 v
acid ?
<h "o 0 46 v
Oli I i {-:} O.'iO v
tbi ll '1.1": -0,;2 v
(t} lll
fd ) IV 63. (f with 1) v1.1Jr,t:hy c;f i/lOO"h
f.lf lit.:ht in first Bnhr urbit. what is
59. The of H 0 10 M Wl!.ak >A<:id HA in 11 a s vl!iocity (relativ( the t'1f lighu in
<.urtductlvity call 21) , 11)3 ohm . cell th4} n:.} Hnhr orblt,?
"nNtl!.nl of c_<ll is 0 78 .. J and \, <Jf th(l 0002
add 390 S cm 2 m<,J- 1.
() 1
statenu\nts .
(.' i 05
I. pH of the atid solution = 3
2. pK, of acid " 5. qji 07
3.
" or diAAociation of th< =o-o l. "o l . \Vhich .,r the follo... $\lll<!mc l\l(Rl illiare
Which of Lilc Blalt)tn("niS given correctly applkablc w all t-ransition
OOIT&e-\ ? clcm,ms w.;t}, :n omic 121 - 29l '!
ta' l ont! 2 only t .
oxid:lt.ion f 1':
ibi 1 antl :l tmly
2. The 4s-mbilal is tomplculy fiU<>d m the
td i IH:td 3 only ground statf:'.
id) 1. 2 3
;J 'l'lw :lciMhit.,l incomplal(ly in r.Jw
00. 'l'h< reaction t,akin1: pl11ce in tht <:oil
g-l'ound state.
4 . t!m in th,J i +2) (J:tidatinn
1'\ i I HCI ( 10 M! I AgCl lA,;
1 .-tn1
tiw Mlswer U!ill'\): th11 L"l\Hle
;.,) Al..'Cl ii/?.i -+ As; + H' + Cl" :

i b) Ag .. I!' -+ Cl .. - AgCI + <. l/2i H.l "'' l. 2 l111d 3

( i> i :1 and l only
!d 2Ag' + 2Ag + ZW (c-! 4 uniy
id l 2Ag .. 2H' - > 2Ag + H 2 !ti: 3 rsn)y

N-D1 0K EJG ! 20 .. A

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65. AddibO!> r>f BY t< All i11 formation :69. t)f JbUowjng N (!\ VtrHH') f)rojN':ti(HH+
of an a.JdueL i\H - llY, thm u g-h bond. , ..
vf AH lmnd in thr,
addu d. Ph
! d
'i: 1.< 1.1\;.H m.
'yllr
w-'(___
AH
frP.J'
J
i.b: increas.t<s ns corn pared l:o tJ>al. in
AH
rrue: r'"/nr
!C} dl>es allor '
Ph II
idl fannol. : ) prodictcd
fl
66. In lhc MO ronligurn lion of Xcr how many
llf p r l't'Ot>l in bonding MO. Ph
11011-bonding MO nnd MO
? PhYT'\:' Br
?., (). 2
'

. ..J.
,/'-.

b ?. . I. l : -/--.. fk
c! 2, () H l'h
.:d; 1. )
I

!ll rv
cuH;wm
,,,.. btlnN
;n Cb<ti r with bnth mot.l>yl in a xial
j)(lHit lnn i:t 1 I and II
Chair wi1.h h1lLh in I ancl Ill

Chair. wHh ll n f. in n ,md rn

P<sit.ion ,,, t.)u:t in
Cl X \:ql pt:IS\l) ( 1n fd! li I and I \1
i <1; Ho111.

6!l. the Ybll<>wing :

70. ! h.&.$ n sped ft-c rol.atwn <f
,.., OH
- i 3 52". A sample of 2-but:HJo) obset\'f.d

spe.;ilie r6tlttit:n of + 6 76" 11\' lwl l.hu

Tlw
VD of lhe Left nod righL chiru l
prJn.-enta.ge ee
sample?
of 1he

centres in un.o iui 25

ier RR ,,n
:bi
,__
l'"'
!hi

l ;_,: ; SR 67

<d; ss !'di 7

NDTO KEJG I 22 Ai

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 ---------------------------,

00. DY AH it '*r 'I'!' mim! 69. >!! 'fl l'l i'rlt

d!>h<%i AH - BY t f. AH ?
3lliR1 rEt n-r.! . Ph Ph
IJ l!'ffi
r\H <ilt 'WR o it
iii 'ffi'Rl H Hr
!bl "fT!> AH <5\ lWI a\) if.!'!! it '(c
(c) qfMl'ii! f.Ml # li Br Hr
<dl llliJffi' "lt! .m '3!1 lll!i<ll Ph H
n
66. :XeF2 a; MO P.r>!lm it. 3mia<T MO. 3RJitr-T .MO
:ffi:t llfa-31lliu:! MO '/i g;rm; ftmr-

Brri)H
Ph Ph
t? Ph Br
la) 2. 0. 2
(b)
lei 2, 2, 0
2, I, I
H
H
Br H9'Hr Ph
I d) l. 2. I
Ul IV
6?. i"ll"'1!f if>l m Eltn
41a fu? 'Ill! im m 1!'f{ 3iR
la) <:);f, U'J:(' lmffi

\aJ I 311< 11

ibJ ar.:lf fu&! tbl 1 3l'R m

'41:11
! c) 3ll<i<t) f5ffiii T!W il!W'n Jftt (cl Ill
fJfu 'c)i tiT
td)
tdJ m rv

68. fil"''fillR<ln fd'61'<i:Glf'J!I:'

70. \Rl28J.to 1!il -1:!!>2' t r

-a; \1ll5 if>l

:mJffi
cr-o w ll 0111 ua <:fe!lll a;
+ 6 76'
mmsrun iRl1
t t
?
a; ee I eli!

il\'11ll! t (a) 25
Uti RH
tbl 50
tbl ns
(e) 67
I<) Sit
(d) ss tdi 75

N-OTOKEJG ( 23 - A I

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71. Kinct.it'5 of tht A {gJ ...... 2B C lgt
ts f'c)Jlow<.d by t.otc1l m.
h. is \"t\n
Jnj t'H of 1' ().;3 at..rn
T(>tal pr<)8Stll'" 111l.P.r 2 hours = 0 7 utm
R.ate nf the '::::' 1 j( loa

tht::! rate of .. wlwn

<
C',;
Ml
dt

(en :HJ < I (J" 4 M

r
.._ T: .......
. \.ilT Hi X j(l
.. Ms".! , "
I'
(c : 50 X JO 1 .. ,

l ri:: 7 <i :< 10' 4 Ms..

A of' !"41a 2SO: v.tiU bt oJddh-:t):l

Nu 2SO,, by KMtOi sHlur.ioo in all :cidk
li:Mn04 is r<.>duced til Huw
72.
rnnl<s of ""'ill t)(: by
onP. of KM nO .1 ')
UP.ous of NaC I

\.

2.
i.di mole
75. V.ihich uf th\: about
gas will m'""'t"d :.h.:> >

1. It ii; a iu:jd.

1. Jt !.'aU jn '.\'ilt(;J tV fhnn I aq.;

Ylhich of 4 h. s B n)n3t(d bas(!.

!'
<:orrf.'{,'t
e,;()rr<(:t 80SWr

ii:t.i ! and 2
.1. 2 and
tb.i 2 and iJ
;h; 2, :l and 4
(I; : a !tnd ;j r,' : i, i.l .j

). :J
< und i

NDTO KEJG

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 .................... - - -- - - - - - - -- - - - - - - - - ,

711. A metal M rtlld.ity MS O which is 178. A <iiono!, C 10 H!s0. on dohydratioll foilow.ed

wuik<r lt forms nn itiR<>Iuhli> hydroxide by or.onqlysis gave mpthanal, propanon11. t111d
whidt in excess NoOH 2-k<'t<lplmi.aMdia!. is the likely
solution. What i t.h e M 'l structur(! uf the d.ient>Jl ?

ibi Ba

! d! Ct\nnor. ttP rli1.rr-minod :.u; daw re

!bJ

77. fhllowiog compounds :

icJ

!1.
79.

,./,,
L
2.
GH 3J
A:gp
I

l" )

('Jl
------. Products,
., H
. ... :$ > . en .

rv. whH the major produ.;t :r

W!ult i$ lhc correct E(l. notlltion for the

configuration of lhe 800\'C compound; 'I
lb; ()
tn; 7.. F., F.. z /'

ib i E. z. z. E

!O Si'
'" z. E. ll,

fd! l .. z.

NOTOKl'JG f Z6 ... A

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 ... ,,,,....... ,,,,_.,,,,,.,,,,_.,,.. ___ ,,,,,,,,,,,,,,,,, __ - -..-""""""'"'""""""""''"""""""''"""

76. f!O! 171<1 M t.r Mso. iF1I Jil 78. tl'm SJWUM. C10H 180 3U;;tr-!
la<\a <l1l l.'<fi
1 MIOIIi2 <ltl;;tr-i'IMfum Q'l(lT!{ r.wt"n-t
lRTffi "sti NaOl-1 ij; 3llftrtro ;) faffil I fflf,! M :liR t a'!! <rnlfum
lNI ? tfl!ltmrn tffir-11 lim t ?

(F.) Mg
(Jt..,
in)
)' l -...Cl!.p ll
(b)
CH3 CH:;
If! k<

!d) P-m!fu! 'l'tfl f.t;ln ;m "ffi1;1ll 3llmt (b)

3111' -

(d

(d )

ll.
l
79.
L C!f.,l
,,, ,, , __ ''. Jn!V<m
- 0
_ _ _____,. Ji'1r?.'.

Ill
CNJ...cH
I 3
:1. J;Uil

H
'!j"&:l iJ7.T! t! ?

lbi r.!"':l
11 a
/

(01 Z. t-:. z
(h) z. z. '

(<') Z, z
ld i z. z. J!;. F.; (0) ! =

NOl'C K E"J G 1 n " 1

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 Consider following con1pound : Con.sidcr the following in TP.Sfl<!l"'. <)f 21
order :

l. tw is propol'tional lu the initial

2. 'l'ime t aken for Lhe t:ompletion <lf

reaction is twice its t in.
Whal is U1e obtained on the
a bo<te collpound '!
3. Cuncentrati<.n of the decrea"'cs
linearly with

\Vhich of thl' statement-s give n nbovc n rc

correct ?

(a ) 1 nnd 2 only

(bi i bl I .and :1 only

(Cl 2 and :3 only

2 and a

83. n rcaetiou

A B .,. C
k2
,.
ka
(dl
B .. J) Products !l'i
If approximation for
intenncdia< B is applied. what will bo the
raw of the reaction .d.Ll'.l ''
' dl
81. The nmount of currcnt is passed
through eadl solutum of ferrous sulphace. and
silv(IT n itraw. It th11 anunmt of ilver
de!)<l8it...>d is :.! 7 g, wha t Is thto amoul\l of iron
dej)(l8it<ld ''
diP! -_
.... _ _ _____
k,!Aif0 !
k 1,....,.;(
dt k 2 !CI + k 3 !Dl
<Ag : 108, f' c = l\6, S "' 32

ta) 140 g d! !'l

dt
ib l 270 g

! c: 0 70 g dl P)

1d ; <h
1.3!; g

N-DTO K E.JG ( 28 A

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.................. -- --- - -- - - - - - - - - - - - - - - - - ,
&l. Wh:ll ill thll appro>Cimi<W pH value ,,r 0 H) M 87 . lh\:1 sl.l1tem.ent.s in rt.lSJ;tttd
ilQUt'JJ\l. .()(:ll\tlJ) Of ;:, mon00tu;h; we;tk Jicid (If' :
i pKa :e !)l? I. Th" uf iil'
incrn<lS<M from l.,o!OH.:..! U>


2. hmthnnid" iOI\0 Yi/' fcnd
rbt a Cc.
\\.'hit:h <)f givtm llbtlV"

85.
ploL () f' 1/l.'. f'
along
\'tn::qs tim" \>1)
i t:j

Hli
BrA.h l Clnd 2
l nor 0
j(UVI.' a wit.J) n
88. Whith i.IM :1f foi:(owinl( >ctnht!dm!
t'l,pe equal til (}01. if the initjrJI cnmplt:');C..o; n( roboll \ lll j icn would rto/ Hhcw
e<>nCl'ntra r.i.m of iAI w l IJ J\1, then consider 1 #\f\1 io:om .o>ti.s.m ?
Stt1 te'mt.'nt.-t . "( ' . . ..
! : Uff!l}J.J J
t thf: nu:titln \w. :t.t'>'.
ox
} ..
J \ IU...t '1"!
s ..; . >
(' '.. u m1 )'l{'!
, 1.
2
i. t r:l th< rt\:s<.'t.ion i."'= 10:) s. <d'1 'r'lJ/l.'i"
. 'If'<
,, I 'l(''l
'f') , ').I)'

t:VA' 1 \' 1:.f tht: n::u:hon wi IJ

in 3(r() <.
. #9. tht following
1,. PI.('i'l''
.... s
\<\."hidl d 1t
-:>.
- ,;.... ('"
,; .t') i 1
J
.."1. J''\..,.IJ'm A'5) ,:
HJi tlnd 2 only 6
4
!b l nnd 3 on}:;
Which .,r th< rum ploxc.;; oh<y
2 uotd :l I rule '!
l di I. llOd :;
i tt :
(bi
l anci 2
2. :1 and ... onty

KO. i.;: I . 2. :,J -1

tf 'hf. cl!:-cAncirtt.1rm c.oa!'itf.lnt. nf :J MOH jtJ
l " l O :, whnt the pH valu,;, of ; d.: Ni:n.:. c,f tht:'

Js Ol nw lnr solutlt.H': of has(' '!

flO. Whkh <>f>< of t.llf.' following will with
i:l i :1 rlp11:.pylrnngn>)siuor.bromidol liJIIOw(>d b.v acid
tmat.fl'INtl t<.) gh:c.: but.all1tl ?

th} t<"iH' Jlt!\.. a c-id
n FumHI<i<.'hyd..-
id i A("<:t.yt chJondD

N tHQ .. I\ EJG I 30

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84. :Jll<'f tpK,, ,. ill in 01() M :;ffittt 87. ij; <!llr-\'l -q CR
fircrl:l'l ;m p H 11R t: ?
t. ifi Cll1 e!r{'<f>Tt! II'T1IC'tl
Lut0Hi:1 c'Rii I
2. 31lil'"', tu'', Yb2 ' Ce
Rmj!l&<t\)Q I
id 4
$ it t'l avtl <1ft ?
tdl 5 {IIi l
(bi 2
85. nA -. Jl\iT.:'. ll'WR <! l!lli Slf'lftntn aJ Prm y3lllf !c) 3i'r< 2 tRl 1
idi "' ffi I 3i'J< "' 2
1R <r.t. <-Jl'.l IR '+J'll7.; lsl il5
I} (ll '\:Ti'l cr;!,r rnr I af7.' liT<fl!IP m:;:t!T 88.
it ilit<lrR t fl! 1 Jlm:i ffil <fit.:! 'fll
I M lO M i?r m <t>n ..1 IH Rrnrt 'ffiJ><'f :tit. ;
..o.c::....
<r>U ..ill] . !ul
fbl ..
1. 3lftrfifiU1 'i!>Ti'rri l!'rr.mra; I " M" 1 I
!c l
Z. .1.,. I01) t\
JrrtlftJmT a;r I ,, I (. l l
' I mns- f('..11l I ' (''I
1 '
" ">
a ':1! 1 3!M.l11.:n aoo s ti tj,il !() - 1
89.
31lzJm ii :!?1'1 tr ml'i t
1. 1-'e(C(J;, ,,
t:d I 2. NiWO),
;_()/ ifiJR I a.
,l KIIFe\GNi,", ) .
1( i:m!i'i 2 :1 t. Na3 1Cu!SCNi,1i
<c:H t. 3lh :l -n m'r-1 #J mm1 m1
<ll'<il ?
inI i;;<rn l :lff< 2
86. rifa t'<l> ll!H MO!l llll fif<lbf'l fum-dl l 10" 7 it. !b) 2, 3 Jt.{ i
ell lh'R ir> O l :;rf1\"a IJ>'! pH l( ) !. 2. 33ft< 4
'1!'1 iflll i i di 3tllfm q <) l!l)f 'lti
ial 3
00. R'"lfffi<lld li r.n
ibi 6 <l 3fla' Jilm< <1
i ll)
( c;r 8
lb l
(d) 1(\ !c) ff.:I$S

r 31 .. '' '
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..........................,,,, _____
91. Conliuier the ncJd:> : 93.

r..... ,.\
----.8
( : ,..i
B I
i ...........,.il
l
<..,() ....: ...--t;
1. ....ii
I il Ill

IV v
1.
.. i
Cli,
.a i l and II <-nly
Which nf the alwve cllrl:roxylic c:tuwot oo
!'f.ynth(S"i:r.i.-d fn::ml mnlonic <'.St.tr '! \b; !l. lll and IV
HJ. [V IH l<i V

'!.. :) t).nd l
Consider the following rmnpmHHls. :

,./"-..,...,

92. l, 0
'!$ CIL
.. ,j
C!!., C ... (;11., ... C(,H,
' I
':j
ll Ill
0

0 ..- N '(''ll .
.. . ),, .
,,
/
1:
'"'''
/'""'-...._

': ,, "
Cll:; C - - C6 H1,.
li
0 I\' v
"''h .:.h of \he ahvve undcl'f;'u
Wh och or bote kc.-LMes ra1111 o1 be
nitration reaction Limn
&ynthc-siud frum nCC!LOacet ic cswr :'
b<nwne '?

ai I and IV o nl,\

;b; fl sncJ fll (onl.

"'' rv :md V onl y

i<h l. IV Hfld V

I J:l ... A I

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95. Which of till' followil'Jg nre the t:hurnti<'ri HtJCS
of t:hemi!iOf'l)Uon ?

rv. Tulue!W
i Sele-ct t b:- anS\\',,r \.ht' code
\Vhat Jf lhc correc t i'r<icr u( rnttJ or!: l?iV(!O :
montJmlnltion ?

0
tAj 1 "'ld 2 unJy
ial !V > I > II > nl
ih.i 3 cnly
rb; Ill , n, 1, rv
u.;; 2 ;!mi 3 o nly

;: (iJ l. :! and
;d ; 1 ,. rv , lf1 ,. 11

UM. Thl! nf an nmdic.o )s

:"H) Hr '1 M11 1 ;,tt a
l )f O(H M tht.> mnximum
ir;
HI JO.;; Ms"1 Wba!. i; vr.hH! I'Jf the
Mid1;1tHs cr:mfi1:Hnt, l\(n
, . I
S
... ......................
+
(aj UOl M
,
s .j. Q ... 'l +
\)0 l M
The l.imt! ti.)f (.'f.ll)t.'l!fl \,r(>lddn (jf s .... ,
$ M
i.<> f'all l.o l/i1 ()( ini liul voh J<.' JS gi vcll by

.!
:d. ' M
I
''''""
l<,+k. k Cl i QI
-- __,...__
If'

99. \\1oat product rurnl.,d tin rou.ction of

-1-nitroanilint wi'th triOuOTOJ"'roXyHrel i< add ?
k(. k . .,. k
" n

: ::
1A-:Hnttrnhe1u.eoo
kl ,. k. . ...
............................... ! '4-dj n
k r k ,, 1q1

fJDTOKEJG 31 A

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 ,

97. <HHfli'IOI f'll>ifb!ftla -ti *- <\ t ?

l. 1. :l'r:Z 3!fu!ftNVI J;UJl
ll. 2. ::K:Af!154Uft<l<ll
IlL 3. fi!if,qoj >.'iri
IV. U.WI ;% 'Ill! WG ll>l !ro)r, Jn{ '

(a) 1JlR2
!a IV "' 1 "' H > Ill
I3ftn
0
(bJ

lb lll .> II > I > IV {(:j ilxffi23il<3

1<:1 II " Ill ,, IV "' l ( d) l. 2 3il< 3
ir.l: 1 > IV :. til : 11
!18. l?ll5 \!9ll1'\l'l 3l'l!fu! :)lfl:ll(t,<;l .$) i!{ fJU lO" Mn" 1
t '3ftf iU; !\ll<lJtJt< OO1 M t om :.lllflimfll
1 0 10"3
i
lr>T11l'T 1M '1\ ?
kr
\
S "-) s.,.. + l )\1
. k.
s --.......... s,, + ::Jil:,"T tal OOl M

ib> 001. M - l
s + Q _ ..k.!!....., !';,, Q .. ::l;'l'ill
lei 002 M
S' <fiT w-i:tl1 tfi'ti!R' 'IR ;m 1/c #! $
1m' 3l!iml'i5 "M"q fim:m'; '(:m :lll\?l11 ?

I
ta l t : ---- ----- ---- ...--:
k r ,. k 1< k IQI
99. r& 3lTl'f 111

<11'2! tl iRll 1

(di -r :
k, It .,tQI rdi
' '

N-DTCI<: EJG I 35 - A I

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l(JO. ln which of thu f(Jll()wit1.M, l'eAc:t.iJnti of 10:-J. An cn!HJ)(}Und lH..t\ing molc-t.."\\lar
!\IUlihelW!U<S, wi!l l.ht pwclu<:t bt Ill\ !(lrt!lUb. c.!HSO IP"C !(>JifJwing l!pt)dntl dnt.!l :

UV - \Vtak abs<trptlrJn at 1,m u.:t 29-5 nm

_PhN'HNH.. Ilei..,. y
............-..---:..... X .............
IR - \'
i.f L0 e m' i..sllunt))
0
znt,\cOH
- -- ---. Produci NM H - i> 2.4 <.qua J"lN, Zl-l );

') ..stn
nol.e,.,
' jU
n 't; anc'
6
2 fJr t ;-Q.l (triplN. 3H i
Alrlohel<OS<' -----"-+ X
What c.:>mpoun<l. ?
.
.....:.1:_ -.o- Produrt
<ni CII 3Cii 2CH 2CHO
?..

HCN !. ) cncHo
- -- X -----=-
2. Jlt!:I0.1
y C!l-,'

_!\i(t I..........,.. Product
0
I H;/ > . Pyrid ine , ,
Altio.\h .. .. -...- .......... X __,..............--. l I i dl CH,. GH CH C.Hi)H

I _
1._
_
_.................. Prod11ct
!: I 01. C\'m!;id(!r fnU<;wing .st.aWttH.mt)}

'l!. i trangf;,>muliiJn oi' )c "'0 to ) C ll:<

I m n hy
1()1. Whkh """ " f '" fm m 's
uf nnd fnt.H '>
\V l'JUl ... Kishnt.>r
i
Which uf
CILpH

I
i l tr'll,v
CH:1CH 20 H :h ; 2 UHJ}'
; t.: Bnd , 1 u.rh:i
102. C"HtSH1 l"r SUi tcrnt!nU. :
i d 5 l Jl( H' 2
L ,; .nltro,Jhent)! and can be
distinguished by II'< KP<1ttrn. Hl5. t.hc (oJiowi.J\g St..atemenl8 :
'l. nnd ..2nnc- can t. Bt.,nrenc c.Hion
disbnguiahed by t.hiJir OV .'\1-S;-; reactioP.
.,.
'I I t -d ichlorooth u no <llld
1.2-dichloroethnne can be distinguished
by Lhe<.r PMH 8fJC'CLNI .
, 2: ihdphonh: ,..,(1(1
a$. well ss ArS.. I Ar..:;,,
"'
Vrnid: uf <13t<'ments given io<'ore
Wh1ch of the state nenl:ll ubtW<' nl't' ! evrrl'Ct '!
? l
a j ! :l ,,nty
ib : :.! nd\'
it;,; 't. and unly
k ; I a.nd 3 <mly
i d > l. 2- tln<l :!

fHHC.H< .. EJG A

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100. Which one of tho f<>llnwing lOll. Prcll:l.lll NMR .Sp,letro,;wor>Y cat\ bi' applied t<l
t:ivom a$ RS :wtat:i()n fc.r tt>JI tmcl Dl>t t<>m ehirn.l dt<H:t which l>f tlw fullowirg 'I
n:'Sj>'l<:tl: vly ?
1. Armnnt1ci1:y
II ....-l....... . Br 2. fl -lxonding
H .. -1--
CH;B r
flr a.
4.
ds and
S truct.ura.l
tr01ts

is-omers

Setoet the- correct tJnswcY uaion the ("(Jt.1CJ

g;..-en bekw:

Ia) ! an:i 2 unly

!b i 2, 3 a nd 4 only

<c) l, :1 and .j <>nly

CH:P
Br - 1--- H (Q) !, 2, :> and 4

Br ....+. - H 109. How m:tny N'MR \\."tHdl:f bo by

in the c,f a l>f
CH.1Cl a<.id

Br ...... L.:.... ll :!
H ........
i d.l t it >
Br
' ! h 1
i<:j 5

ld:; i.)

n 0. the, following .

t. NaCl
2.

3.

What i< :he ord <!r nf "lliciency qf

nbovf' s alts low oonccn lr.JLiunl lh
,;o! ?
(a 1 I > ">3

'l > 3 >

{d :l > 2

ttl)

.,
idi >
"2

N OTOK E-JG 38 .. A I

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 .,
Ill. t"hr: ( l\ WHV<.:. is wh&.m it
z
mt)ie-(:Ult!/itHl fiuito, 3nd cur;t.ir:HJtHl.S.

1,)f foBc,rwing is an
: 1 Hfl
function '!
l!.p.!
;c t so1
i t! ! !>:rr
'.!

fc: t;s ; sin x

112. wh;ch doo:IS no/ oonl,un II ' is
!d ;;1 =tun r
i s) Lu.hi<>m hydrido>

!hi S<o<Jium hyd l'idt:

:c; Cail:<u:n hydridrt

rdJ

113. C;,l., hit5 ru<.>tllllic It is {'Xpluirmd b)

lt ns

Lnj But.h tJw an indivi<lu11lly

artd n is
nf St:ll.t:mt'!nt. f

lll. ,\11 ,,f whith of fultowittg ll.rc: rb! Both Me i ndhi:hmlly

'\Vh!t.(! '!
t r-w;, II i::o not

'1.. Pbilh ic!

J is inn.\, but. St.tiUmtuJt. Jl 1ii

:l. Znill i
!di I is false. but Stal.t'n1('n! II
4 M n\ 1.1:

::;.,;,'<', the nn.SW(r t.he <'Odl'

betow :
116 . Stalument J : The quantum );dd of Hl Clz
"''fiction IS l o - I o6
S:.c-cunwr.t .If : r""l uo r<\1.S.cenc-e i.$ n
"" :J >lnd 4 <ml,v
Cll'l i&'{lOn

N-OTO Kf:JG I 110 Al

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111. 1lit 3!WJI!'IR' 1Nl1 1m? Wlftlfit <JW c2 t ? m>. !!a> ow tt>l'R '" (!r<a -t,. o{(
h1. ) HzO <inn ! 4 "fl oN'! m I!W
ibj
.arf.IIT!f 'i'R71 'f>R"' li\ ?

lei so!.! 1 : ex
raJ
!d) No -
2
(bi 1P , e-'5

112. '1tl all=r 1'1$$5 H- 3IW'I

!cJ ., : sin x
t. ?

!a l N\ilsil I d)

tbl
/ c)
id) -aftfffqq
f.rht , f4AffiRJJa <ifa 15J w.rmt 4' ifil!R tl.

113. C ei2 Q< !J!a; <111<11 tir<l\ t I i'llmtl1 i52r-t l 3lk W'<R 1l 1 p #ff mw.:fl mr
l\m:! tr <lit '5'IRil it ? mo:w,.n:<k w8"" i#tf.'irr! Jth PF Q; .rm-
:fti! 1T1! we ai) Ne:rmu :fl '?Jf!rrr .
!vl 2 1

(8) ilm'f aWC<r: <1'<'<1 t. 3ih: <'!'WJ"l II.

ilS'.!r.t I lfii :ffii\ I
I 14. i! 'if alR ;n t . 3ll<ffil$l:
m t? (b ) ;:)'.:/i 1!i1!l<l <f'rQ fcl;:g 'itl:!r-1 n.
;;5\!f-'1 ! il>S <'J'tl if>'{l'l "'1ff I
l. AI< !IIi
2.
3.
Phlll!
Znilh

<1. Mnfll i

f?.'C! llt' lf't a51 1l'lirrl << rr81 Jm :

1J6. iBPR 1 : C l2 'iJ'ili <liflDVI
l <li 1 ;m
!04 - 106 I
r b; 1. 2 ffi1l s

N-OTO -K-EJG I 41 A I

_______________
.........................- - -- ...........................,
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 nwm-tnt.

i.hnn
l,i,ut.ron1:'.
SUlUHU.m.t .'l : 'rlw popui!ltion or ;t;kt'\\'
il . Unlike.! nr.l\Jt r QPYl. .;low cunf0t'tluition

neuuons nrt! nut repelled b) 1.2du:hlorm.:hlmc

< nocll-.car Lar;:et with in

118. Statem.,,t I: lrons- 1.2d imcc.hyl cyclohcxnut.' l 20. Stuti:'IIWll i: Ly.,philic colloidt< are enure
is murc lh.nn
U!-di1nethyl cydohe>'llnl!.
Slol.e!H<' "I iT: Jn fyt! phubi(: til.:
S!o/.cmcnl II : l n trnns .. l .'t..

br..,th methyl thun in

pt.u;:it ron l ti

d .....
(ll\ly ttnu methyl gn'HlP \'!an
m .

42 A. i

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 "''"'"[

117, i1i1R I : 'rf.'ll S'f 119. ifj:fJ;T I:

1,2l!TMt'T):(\ei1,"! 051 3lltJ:Ilf 1IJIT >'i
t1 3!fba; w"\rr5) Qll)t<l t 1

i1i1R u, a; 'lR i1W-r JJ : ! $
tl ufflaslifu '1iff
1

1.20. BR I : mlw, t:.<riax1t1! lllll'i'i$!11

118. ififF7/ :
3lft:T<5 r
1/llfW J.2 ssifilR * 1JRF1 l J : <i:! il Qffl'<I!'Q'I <1m. w.<Jl'lr it:!
3lftR!; I
it qffl'Cl'<f a;ujj tl lifflrn<n4'1ftilif
i1iWr 11 : la!78f 1,251$4im1 'f!l$<tM'It<R'!"l it, 't.i! t l
M itf1rn 3ltl'l'lfuo
aRt! ,'!l?lfct.;
i'i -ltfim ''Wl li!lfi
1?l!i :llWiffln lfR .rmm

NDTOKEJG I 43 " A I

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_..
 SPACE FOR ROUGH WOU.K
q;tt) '(fjJ"q a; 311! {:{

_______ ___
....__ .............
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.. ............ .
 -

SPACE FOR ROUGH WORK

atilt(

NOTOKEJG ! 45 - A I

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SPACE FOR ROUGH WORK
<5"J11-a; fffi!

I 4!) A )

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 SPACE FOR ROUGH WORK
(f)'*' (JjpJ ""''((

N-OTO-J<-EJG l 47 A i

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'<<tiltl"1-fa$1H
300
. == ======= ==
"''== = == ........,.

t. 3UII tRtaJUr 3!liW"Q !rR '11!\l fa=n 'O'l'l. -.m
"l:ll 'P 'l"'5 3ltla1 3I1ft I llfHffi t. <!r tR\IifUI ofllm'f I

<R\at01 I
2. Jm'tr,Q ; 11 3fljill"' A. B. C 'tlT 1R I)

:t &t! 'lflaw. tR tt m1 1111 11 Jl'Ml 1 -

Jljll>"lil!l lffis-n f. I <R\t:l'll <R 3/h' JIB 'f l ' - -..,.....,-, -- --,...- - . , - - -- -'

'i1 120 I II!R) 1W, 't ! 111"l<fi 3J'R 3i1);;i\ 8'11 I ii 11<inl;
4. <RlalUl
r3<Rllml. 'l'ft?. ; *- 1% .m <fl fl f.m'l 311'l.:nR lll!m tR :Jlflffi! <IWl1 1 wa
l l'11'"
WI lli; 1!<11 J'!ftJm ;{: Rl all . I cr.R :m 3lltTcll'l nil I md'i
-&; fffi! e<JJ ttl WMT '
5. 3I1'I<N 3lv.:t ri lr"!'R 3f<'fll t f<n! ::Jmtrim t.'< i!t J;f;,o ? 1 ll f?m 'l!t! f.!rn 1

II. $ 3fcl> i
7. nffi rn; 3l!Q <rt'tlli'IJ $ $ lll'qt'R :rm1ffo5 IR 3ifaia t!i\-IT Vj<' ctR, 3llfl<!l: fiw
lll!!Oltr. t$ '!IT2I J9lh'it if> 3r1ffi' f mm.r J<R<m ; ;
8. .3ll'1 3ftl'i!{ 'fl"i\ Ut?!Tro 1li\ .q iJl 1!1\: Cl'll! <rthm tJ; 'fi'I'IQ"' <R lWFI :Jm tmlf :\!Utl!it!'i Wl
t Jlm'i1 J11P. WI 'lfur<lil ;% <5I 3o'i<fJ! 't i
!l. col l!iT'Cf a? <r.!'ili alm a-; 3i't! /j "<f I

I0. 'lffif '3<l'd ll'1l '

d<'!jP-!"0 1i Julli!dN l:TU fm! tru' 'lll'flt J'ffi1 ffin! h I

; ; -; ll?.!a; lli m< ii<r,fi!llm ::rff{ f. 1 !I'R fcw m.> Ill! ea; 'lffil J'1'fl: lli
f-rmr !'$!! Jiali lilT ga;.f.'l!:rt !03!11 ;!,; '{\! il ;mr 'Jilt!'ln 1
\ill o1?: a:.'lt ea> 'll 3lftr-:5 3l'R i1'l 'lll'flt :nR llT::n ?latQ fu! 'ri! '3ffi'\ il t'<fi
J"(f{ mi\ tmn .{: ;ro W'! ij; ir.l!r tf\ J<l'i lfqt 1111 :il11?'l1 I

\ i;;; m'lt ;np "'lff f<r.r.rr :'i!t<n t

liHT iiT'l Y<R :;f. fhn ;;nor 't!. <to J<1
a; fml 1S"ir 'fi!l Sl'w.lll I

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I