Citgo Petroleum Corporation

135th Street & New Avenue

Lemont, IL 60439

INSTRUMENT SPECIFICATIONFlange-type Restrictive Orifices

ALL ITEMS SHALL COMPLY WITH GENERAL SPECIFICATION SHEETS

Installation notes:
1. Orifice dia. As
specified to suit
required conditions.
2. Gaskets
furnished by vendor.

MATERIAL: Monel

UPSTREAM
PIPE SIZE ORIFICE FLOW QUANTITY DP M S TEMP. FLANGE
ITEM

REV. QTY. TAG. NO. SCH. PRESSURE SERVICE

(IN.) (IN.) (SCFH) (PSI) W G (F) RATING
(PSIG)

1 2 1 20FO-057 4/2 80 0.084 250 60 57 a 17.00 100 300 Pilot gas to acid relief header.

10
1. The actual flow of 20FO-057 is about 110 SCFH for a bore diameter of 0.084.

1 of 25 360767842.xls/Current Flange Spec Sheet_Monel

 Citgo Petroleum Corporation
135th Street & New Avenue
Lemont, IL 60439

INSTRUMENT Union Restrictive Orifices

SPECIFICATION
ALL ITEMS SHALL COMPLY WITH GENERAL SPECIFICATION SHEETS

Installation notes:
1. Unless otherwise specified, the only markings on the orifice tab shall be the orfice diameter
indicated by a decimal fraction as shown on the drawing with 1/16-in. figure stamping hand dies.
2. Where lines are to be insulated, the insulated material covering the union shall be applied in such
a
manner that the markings on the tab will be fully exposed.
MATERIAL: 316SS 3. No asbestos-bearing material is acceptable; vendor to provide TFE gaskets.

UPSTREAM
PIPE SIZE ORIFICE FLOW QUANTITY DP M S TEMP. FLANGE
ITEM

REV. QTY. TAG. NO. SCH. PRESSURE SERVICE

(IN.) (IN.) (SCFH) (PSI) W G (F) RATING
(PSIG)

1 1 1 20FO-184 1-1/2 80 0.285 60 57 a 0.586 100 3000 Acid pump vent header purge.

10
1. Item 1 is made of monel.

2 of 25 360767842.xls/Current Union Spec Sheet

 Citgo Petroleum Corporation
135th Street & New Avenue
Lemont, IL 60439

INSTRUMENT SPECIFICATION Flange-type Restrictive Orifices

ALL ITEMS SHALL COMPLY WITH GENERAL SPECIFICATION SHEETS

Installation notes:
1. Orifice dia. As
specified to suit
required conditions.
2. Gaskets
furnished by vendor.

MATERIAL: 316SS

UPSTREAM
PIPE SIZE ORIFICE FLOW QUANTITY DP M S TEMP. FLANGE
ITEM

REV. QTY. TAG. NO. SCH. PRESSURE SERVICE

(IN.) (IN.) (SCFH) (PSI) W G (F) RATING
(PSIG)

1 1 1 20FO-175 4/2 80 0.135 60 55 a 17.00 100 150 Pilot gas to 20F-527.

10

3 of 25 360767842.xls/Current Flange Spec Sh_SS

 Citgo Petroleum Corporation
135th Street & New Avenue
Lemont, IL 60439

INSTRUMENT Union Restrictive Orifices

SPECIFICATION
ALL ITEMS SHALL COMPLY WITH GENERAL SPECIFICATION SHEETS

Installation notes:
1. Unless otherwise specified, the only markings on the orifice tab shall be the orfice diameter
indicated by a decimal fraction as shown on the drawing with 1/16-in. figure stamping hand dies.
2. Where lines are to be insulated, the insulated material covering the union shall be applied in such
a
manner that the markings on the tab will be fully exposed.
MATERIAL: 316SS 3. No asbestos-bearing material is acceptable; vendor to provide TFE gaskets.

UPSTREAM
PIPE SIZE ORIFICE FLOW QUANTITY DP M S TEMP. FLANGE
ITEM

REV. QTY. TAG. NO. SCH. PRESSURE SERVICE

(IN.) (IN.) (SCFH) (PSI) W G (F) RATING
(PSIG)

1 1 1 4/2 80 a 100

10

4 of 25 360767842.xls/New Union Spec Sheet

Yellow is an input cell: Green is a calculation:
P1: 60 psig W= 11.12 PPH

Underline is value actually used: Green in grey is a look-up value:

0.603 tp = 2.50
0.607

White in black is a final answer:

D2 = 0.106 in.

Important reference information about a cell is in violet:

From Fluor table

Cell for iteration with goal seek: Target (To) cell for goal seek: Changing cell for goal seek:
[1st Cell] [2nd Cell] [3rd Cell]
4.87 4.93 0.084
ell for goal seek:
 Citgo Petroleum Corporation
135th Street & New Avenue
Lemont, IL 60439

INSTRUMENT SPECIFICATION Flange-type Restrictive Orifices

ALL ITEMS SHALL COMPLY WITH GENERAL SPECIFICATION SHEETS

Installation notes:
1. Orifice dia. As
specified to suit
required conditions.
2. Gaskets
furnished by vendor.

MATERIAL: 316SS

UPSTREAM
PIPE SIZE ORIFICE FLOW QUANTITY DP M S TEMP. FLANGE
ITEM

REV. QTY. TAG. NO. SCH. PRESSURE SERVICE

(IN.) (IN.) (SCFH) (PSI) W G (F) RATING
(PSIG)

1 1 1 4/2 80 a 100

10

7 of 25 360767842.xls/New Flange Spec Sheet_SS

 Citgo Petroleum Corporation
135th Street & New Avenue
Lemont, IL 60439

INSTRUMENT SPECIFICATIONFlange-type Restrictive Orifices

ALL ITEMS SHALL COMPLY WITH GENERAL SPECIFICATION SHEETS

Installation notes:
1. Orifice dia. As
specified to suit
required conditions.
2. Gaskets
furnished by vendor.

MATERIAL: Monel

UPSTREAM
PIPE SIZE ORIFICE FLOW QUANTITY DP M S TEMP. FLANGE
ITEM

REV. QTY. TAG. NO. SCH. PRESSURE SERVICE

(IN.) (IN.) (SCFH) (PSI) W G (F) RATING
(PSIG)

1 1 1 4/2 80 a 100

10

8 of 25 360767842.xls/New Flange Spec Sheet_Monel

Caution: this sheet calculates properties based on yellow-highlighted cells. The viscosities will change and
pressure and temperature, however, the NIST values for pure components will change so if T or P change
NIST.
Gas Properties
Vc,
Properties using cm3/mol-
coresponding states y Tc, K Pc, atm 1 Zc w
Hydrogen 0 33.20 12.80 65.00 0.31 -0.22
Methane 0.94 190.60 45.40 99.00 0.29 0.01
Ethane 0.05 305.40 48.17 148.00 0.29 0.10
Propane 0.01 369.80 41.95 203.00 0.28 0.15
Propylene 0 365.00 45.60 181.00 0.28 0.15
Butane
Average, Mixture: 1.0000 198.13 45.65 102.49 0.29 0.01
k=

R, atm-cm^3/(K-gmole): 8.21E+01
Temperature, F: 100 311
Pressure, psig.: 90 Use initial (1) properties.
Viscosity, cP: 0.01151 From VISC Sheet - manual entry-- use NIST website for
individual m, then use Wilke's method in spreadsheet to calc
mixture m.
m, cP @ 78 psig m, cP @ 90 psig
100 120 100 120
Methane 0.011661 0.012008 0.011659 0.012006
Ethane 0.00986 0.010179 0.009882 0.010201
Propane 0.00853 0.008836 0.008547 0.008853
Propylene 0.009013 0.009347 0.009039 0.009372
Butane 0.009254 0.012779
 iscosities will change and are a function of
hange so if T or P change update with

Cpo,
cal/gmol-
K M m, cP
6.91 2.02 0.00919
8.66 16.04 0.01167
12.98 30.07 0.00988
18.30 44.10 0.00855
15.78 42.08 0.00904

8.98 17.02
1.28

- use NIST website for

hod in spreadsheet to calculate
 Thin plate orifice
RESTRICTIVE ORIFICE ---- Method 1 Low-Moderate DP
Rough method provided originally in an article in Chemical Engineering magazine tb/bore diameter = 0.93
P2/P1 = 0.05 Thin plate, no choked flow.
Calculation not applicable: refer to Kirk-Cunningham method.

P1: Method assumes, implicitly, that gas is ideal gas mixture or perfect gas.
7 Qg/SQRT( DP(P1 +P2)/(2SgT1) 1/5 Flow through a thin plate is never choked flow. For this to apply, the ratio of tb/bore
D = X X (tp/0.125) diameter must be < 6. (Reference: pg. 13.22, Richard Miller's "Flow Measurement
8
5440 Engineering Handbook," 3rd ed., McGraw Hill, 1996. Page 13-22 refers to the work
of Cunningham (1951) and Ward-Smith (1979).
Kirk-Cunningham applies when P2<0.63P1. Cunningham showed that choked flow
(critical, i.e., M =1 @ throat) does not occur for thin orifice plates.

D, inches; Qg, gas flow in SCFH (60 F, 1 atm); DP, P1, P2, psia; Sg = Mg/Mair Line Size tp,mm
T1, R; tp, plate thickness. 0.5 1.5
0.75 1.5
Qg: 250 SCFH @ 60 F, 1 atm Complete Property Sheet 1 1.5
DP = 57.00 Tr = 2.51 from sheet 1.5 2
P1: 60 psig Pr = 0.11 2 2.5
P2: 3 psi Using initial properties @ 3 3
Mw: 17 P1, T1 4 3 Using table from
Sg = 0.59 manual allowed 6 3 Fluor specification:
T: 100 deg. F k = 1.28 8 6 "Flange Type
Plate Rate 300 300, 600# ANSI 10 6 Restrictive Orifice"
tp = 2.50 mm From Fluor table 12 6
Z: 1.00 0.98 Calculated using virial equations 14 9
D1, nom: 2.00 in. Sch.: 80 16 9
18 12
Sat. Curve Test: 0.749 Test: OK Abbott Equations are acceptable 20 12
Hot Gas Test: 0.433 Saturated Area 24 16
B1 = 0.135 Pr/Tr = 0.044 Z = 1.00
B0 = -0.014

11 of 25 360767842.xls/RO1
Lemont, Illinois
 Pcf = 40.98 psig Choked Flow - for thick plate D2 = 0.106 in. Beta = 0.055

12 of 25 360767842.xls/RO1
Lemont, Illinois
 Thick plate orifice or flow
RESTRICTIVE ORIFICE ---- Method 2 nozzle, Choked Flow
tb/db = 7.41 Thick plate method applies: choked flow. Min. Pressure is: 40.98 psig
Choked Flow: eq. 4-40, pg. 100, Daniel Crowl, Joseph Louvar, "Chemical Process Safety Fundamentals with Applications,
Prentice-Hall, 1990.

4-40
P1: W Crowl & Louvar assume a thick orifice plate, or flow nozzle, not a thin plate.
A =
Co P1 k gc M (k+1)/(k-1)
2 Also found in Perry's 6th edition of "Chemical Engineering Handbook," pg. 5-14, equation 5.27.
RT1 X
k+1 Assumes Beta < 0.2. (Ideal gas also assumed and implicite in solution using isentropic
expansion).

A: throat cross-sectional area, sq. ft; W: #/s; Co = 0.72; P1: inlet pressure, psf; gc = 32.174
T1: inlet temperature, F; R = 1545.3 ft-#f/#mole-R. This sheet is most useful in estimating flow from nozzles and holes in vessels or
pipe.
Qg: 250 SCFH @ 60 F, 1 atm St. T = 60 F
W= 11.22 PPH 14.696 psia
r= 0.04 lbs./cf Co: 0.72 Crowl/Louvar recommends 1.0 for Co with sharp-edged orifices
D1: 1.939 in. with Re1 >30,000; seldom does this occur.
P1: 60 psig k = 1.28 Property Sheet
exp. = 8.03
Mw: 17.02 Property Sheet
Pcf = 40.98 psig Choked Flow
T: 100 deg. F

A= 0.004 sq. in. Complete Property Sheet

Tr = 2.51 Using initial properties @ P1, T1
D= 0.067 in. Pr = 0.11
Beta = 0.0348 Sat. Curve Test: 0.749 Below: use charts
tp = 0.50 in. Hot Gas Test: 0.433 Saturated Area
Test: OK Abbott Equations are acceptable
B1 = 0.135
B0 = -0.014
Pr/Tr = 0.044

13 of 25 360767842.xls/RO2
Lemont, Illinois
 Z = 1.00

14 of 25 360767842.xls/RO2
Lemont, Illinois
 07/17/2017 Calculation for North American Mfg. Co. Combustion Air FE

ORIFICE DATA SHEET

Type of Orifice Plate: Standard

Drain Hole (for Condensate): None
MAXIMUM (URV-Ranged) DIFFERENTIAL PRESSURE = 40 IWC Pipe Diameter?
MAXIMUM FLOW RATE REQUIRED = 10,000 PPH
131,510 SCFH
DP (Required ) AT REQUIRED MAX. FLOW RATE = 29.78 IWC Y-Equation?
CALCULATED MAXIMUM FLOW RATE (At URV) = 11,589 PPH hw-O.K. Turndown O.K 0.895
152,400 SCFH Y-O.K.
PERMANENT PRESSURE LOSS AT MAX. RATE (At URV) = 1.35 PSIG
37.53 IWC
ORIFICE INLET MAX. CALC. REYNOLDS NUMBER = 1,050,626
Orifice Re?
NOMINAL DIFFERENTIAL PRESSURE = 7.45 IWC Re--tubulent--O.K.
NOMINAL FLOW RATE = 5,000 PPH Safe Min. Rate?
65,750 SCFH Min.---O.K.
MINIMUM DIFFERENTIAL PRESSURE = 0.30 IWC
MINIMUM (Practical) FLOW RATE = 1,000 PPH Mach No. OK?
13,150 SCFH Gas Orifice velocity is O.K.
MINIMUM ORIFICE INLET REYNOLDS NUMBER = 10,000
Change in Physical Properties?
FLUID: Change in properties --O.K

INITIAL GAS TEMPERATURE = 70 F

INITIAL GAS PRESSURE = 30 psig
GAS COMPRESSIBILITY COEFFICIENT, Z, = 1.000
GAS SPECIFIC HEAT RATIO, k, = 1.3981784205
GAS VISCOSITY @ FLOW CONDITIONS = 0.0163455501 cP

BASE TEMPERATURE = 60 F
BASE PRESSURE = 14.696 psig
BASE COMPRESSIBILITY FACTOR, Z, = 1.000

NOMINAL PIPE DIAMETER, INCHES = 24" CS Pipe

PIPE INTERNAL DIAMETER, INCHES = 23.5 Inches
FLANGE ORIFICE DIAMETER, do, INCHES , = 4.2622252739 Inches

ORIFICE BETA = 0.1814

PLATE MATERIAL = SS
PLATE BASE THERMAL EXPANSION = 0.0000097 1/F
PLATE THERMAL EXPANSION = 0.0000089 1/F

CHANGE IN GAS DENSITY OVER PLATE = -0.94%

CHANGE IN GAS TEMPERATURE = -4.9 F
DISCHARGE MACH NO., M=1 IS CRITICAL, = 0.126

For Maximum Flow Calculation

C' (PPH) = 274.091 K = 0.5972 Y1 = 0.9905
Ftb = 1.003 C' (SCFH) = 3604.474 Fpv = 1.0000
Fm = 1.000 FG = 0.99857 FPb = 1.0000
Fa = 1.000 FTf = 0.9896 Fl = 0.9998
Flowing conditions were used to calculate the discharge rate of the orifice.

D. Willard International Steel Services, Inc. 360767842.xls

 07/17/2017 Calculation for FE-344
'A' Reactor Toluene Atomizing Nitrogen

ORIFICE DATA SHEET

Type of Orifice Plate: Integral

Drain Hole (for Condensate): None
MAXIMUM (URV-Ranged) DIFFERENTIAL PRESSURE = 60.2 IWC Pipe Diameter?
MAXIMUM FLOW RATE REQUIRED = 172 PPH
2,320 SCFH
DP (Required ) AT REQUIRED MAX. FLOW RATE = 60.20 IWC Y-Equation?
CALCULATED MAXIMUM FLOW RATE (At URV) = 171 PPH hw-O.K. Turndown O.K 0.416
2,320 SCFH Y-O.K.
PERMANENT PRESSURE LOSS AT MAX. RATE (At URV) = 1.56 PSIG
43.30 IWC
ORIFICE INLET MAX. CALC. REYNOLDS NUMBER = 176,990
Orifice Re?
NOMINAL DIFFERENTIAL PRESSURE = 15.03 IWC Re--tubulent--O.K.
NOMINAL FLOW RATE = 86 PPH Safe Min. Rate?
1,160 SCFH Min.---O.K.
MINIMUM DIFFERENTIAL PRESSURE = 0.60 IWC
MINIMUM (Practical) FLOW RATE = 17 PPH Mach No. OK?
230 SCFH Gas Orifice velocity is O.K.
MINIMUM ORIFICE INLET REYNOLDS NUMBER = 10,000
Change in Physical Properties?
FLUID: Change in properties --O.K

INITIAL GAS TEMPERATURE = 70 F

INITIAL GAS PRESSURE = 130 psig
GAS COMPRESSIBILITY COEFFICIENT, Z, = 1.000
GAS SPECIFIC HEAT RATIO, k, = 1.3
GAS VISCOSITY @ FLOW CONDITIONS = 0.018 cP

BASE TEMPERATURE = 60 F
BASE PRESSURE = 14.696 psig
BASE COMPRESSIBILITY FACTOR, Z, = 1.000

NOMINAL PIPE DIAMETER, INCHES = 1/2" Sch-40 CS

PIPE INTERNAL DIAMETER, INCHES = 0.664 Inches
FLANGE ORIFICE DIAMETER, do, INCHES , = 0.34 Inches

ORIFICE BETA = 0.5120

PLATE MATERIAL = SS
PLATE BASE THERMAL EXPANSION = 0.0000097 1/F
PLATE THERMAL EXPANSION = 0.0000089 1/F

CHANGE IN GAS DENSITY OVER PLATE = -0.35%

CHANGE IN GAS TEMPERATURE = -1.8 F
DISCHARGE MACH NO., M=1 IS CRITICAL, = 0.096

D. Willard
 This method is more general.

Thin plate orifice

RESTRICTIVE ORIFICE ---- Method 3 All flow conditions
Crane TP 410, "Flow of Fluids Through Valves, Fittings, and Pipe," 23rd printing. tb/bore diameter = 0.67
P2/P1 = 0.016667 Thin plate, no choked flow.
ASME calculation not practical --- P2/P1 too low ---Kirk-Cunningham
method.

P1: Flow through a thin plate is never choked flow. For this to apply, the ratio of tb/bore diameter must be < 6.
2 DP r (Reference: pg. 13.22, Richard Miller's "Flow Measurement Engineering Handbook," 3rd ed., McGraw Hill, 1996.
W = 1891 Y C d Page 13-22 refers to the work of Cunningham (1951) and Ward-Smith (1979). In 2005, Kirk explored the limits of
0
Cunningham's work. He found that ASME formulas worked fine with adjustment of Y; C could be defined using ASME
Equation 2-24, Crane TP 410, and other methods.
adapted on 3.24 of text.
Kirk-Cunningham applies when P2<0.63P1. Cunningham showed that choked flow (critical, i.e., M =1 @ throat) does
not occur for thin orifice plates.

W: lbs./hr; Y: dimensionless; C: 1/ft; do: inches; DP: psi; r: #mass/cf

Standard Conditions: P, psia = 14.696 T, F = 60
Complete Property Sheet
Flange taps Tr = 1.43 from sheet
Qg: 86 SCFH Y= 0.72 Kirk-Cunningham Pr = 0.11
@ 14.696
r, #/cf = 0.06 psia & 1 atm. k= 1.28 Using initial properties @
DP = 59.00 P1, T1
P1: 60 psig 0.607 ASME, Crane 410 Sat. Curve Test: 0.749 Test:
C, ft-1 =
P2: 1 psi 0.607 Cunningham Hot Gas Test: 0.433 OK
Mw: 24 0.607 manual allowed Pr/Tr = 0.078 Saturated
r, #/cf = 0.01 manual allowed B1 = 0.100 Area
T: 120 deg. F B0 = -0.156
Plate Rate 300 300, 600# ANSI Abbott Equations are acceptable
tp = 1.50 mm From Fluor table Z = 0.99
Z: 0.99 manual allowed
D1, nom: 0.75 in. Sch.: 160
mg, cP= 0.01151 manual allowed Re1 = 4,874

DPp = 56 psig

Wd = 5.44 PPH Wcalc = 5.47 PPH Problem solved with goal seek
Match Qg: 4.93 PPH
Pcf = 40.98 psig Choked Flow - for thick plate Do = 0.088 in. Beta = 0.144

17 of 25 360767842.xls/RO3
Lemont, Illinois
 This method is more general.

Thin plate orifice

RESTRICTIVE ORIFICE ---- Method 4 All flow conditions
Crane TP 410, "Flow of Fluids Through Valves, Fittings, and Pipe," 23rd printing. tb/bore diameter = 1.82
P2/P1 = 0.033333 Thin plate, no choked flow.
ASME calculation not practical --- P2/P1 too low ---Kirk-Cunningham
method.

Flow through a thin plate is never choked flow. For this to apply, the ratio of tb/bore diameter must be < 6.
P1: P2: W = 338.178 rb K d2 Y1 FPb FTb FTf1 FPvGr FGr Dh Pf1 (Reference: pg. 13.22, Richard Miller's "Flow Measurement Engineering Handbook," 3rd ed., McGraw Hill, 1996.
Page 13-22 refers to the work of Cunningham (1951) and Ward-Smith (1979). In 2005, Kirk explored the limits of
Adapted from equation 9.68, "The AGA equation," in Richard Miller's Flow Cunningham's work. He found that ASME formulas worked fine with adjustment of Y; C could be defined using ASME
and other methods.
Measurement Engineering Handbook, 3rd ed., McGraw Hill , CR 1996 Kirk-Cunningham applies when P2<0.63P1. Cunningham showed that choked flow (critical, i.e., M =1 @ throat) does
(This equation was adapted originally from equation 2-24, Crane TP 410.)
not occur for thin orifice plates.

Complete Property Sheet

W: lbs./hr; Y: dimensionless; C: 1/ft; do: inches; DP: psi; r: #mass/cf Estimated Compressibility Factor (Z) for Base and Inlet Conditions
Standard Conditions: P, psia = 14.696 T, F = 60 For (b): Trb = 1.46 Sat. Curve Test: 0.714 Test:
Choose Cunningham (1),Miller (2), or Fluor (3) for Y1: Prb = 0.04 Hot Gas Test: 0.400 OK
Flange taps 1 Cunningham Pr/Tr = 0.030 Saturated Area
Qg: 250 SCFH Y1 = 0.66 Cunningham recommended OK Zb = 0.980 B1 = 0.104
rb, #/cf = 0.05 k= 1.28 manual 0.980 B0 = -0.148
DP = 87.0 Abbott Equations are acceptable
P1: 90 psig 0.595 ASME, Crane 410 Zf = 0.980
C, ft-1 =
P2: 3 psi 0.607 Cunningham
Mw: 17 manual allowed For (1): Tr1 = 1.57 Sat. Curve Test= 0.772 Test:
r1, #/cf = 0.02 manual allowed Pr1 = 0.16 Hot Gas Test= 0.455 OK
T: 100 deg. F Pr/Tr = 0.100
Saturated Area
Plate Rate 300 300, 600# ANSI B1 = 0.113
tp = 2.50 mm From Fluor table B0 = -0.122
Z1: 0.991 manual allowed Abbott Equations are acceptable
D1, nom: 2.00 in. Sch.: 80 Zf = 0.991
mg, cP= 0.01151 manual allowed Re1 = 3,233

DPp = 86 psig

Wd = 11.43 PPH Wcalc = 11.31 PPH Problem solved with goal seek
Match Qg: PPH Qcalc = 247 SCFH
Pcf = 57.43 psig Choked Flow - for thick plate Do = 0.054 in. Beta = 0.028

18 of 25 360767842.xls/R04
Lemont, Illinois
 VISC

GAS MIXTURE VI S CO S ITY

This sheet talks with the Properties Sheet.

Enter values in "Yellow." Manual input values are in "Green."

Temperature 38 C 100 F Calculated values in "Light Green".

Program assumes that gases are perfect and form an ideal vapor solution. Program will deviate slightly for high pressure (>150 psig & presence of wet gas.
Wilke method shows some deviations where molecular weights are significantly different, i.e., Mi>>Mj.

Wilke Gas Mixture Viscosity Calculation for Ideal Gases or Real Gases @ Low-Moderate Pressures

Component yi Man Manual h i hi M F i1 F i2 F i3 F i4 F i5 F i6 F i7 F i8 F i9 F i10 Sum F ij Sum yih i N

Hydrogen 0.00 Yes 0.009189 - 2.02 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1
Methane 0.94 Yes 0.011672 0.0117 16.04 0.000 1.000 1.473 1.899 0.000 0.000 0.000 0.000 0.000 0.000 1.033 0.011 2
Ethane 0.05 Yes 0.009882 0.0099 30.07 0.000 0.665 1.000 1.300 0.000 0.000 0.000 0.000 0.000 0.000 0.689 0.001 3
Propane 0.01 Yes 0.008547 0.0085 44.10 0.506 0.506 0.766 1.000 0.000 0.000 0.000 0.000 0.000 0.000 0.524 0.000 4
Propylene 0.00 Yes 0.009039 - 42.08 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5
Gas 6 1.00 Yes 0.000000 - 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6
Gas 7 0.00 Yes 0.000000 - 0.00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7
Gas 8 0.00 Yes 0.000000 - 0.00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8
Gas 9 0.00 Yes 0.000000 - 0.00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 9
Gas 10 0.00 Yes 0.000000 - 0.00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10
Total 2.00 mm = 0.0115

m = a + b(T) + c(T)2 +d(T)3 Cp = a + b(T) + c(T)2 + d(T)3 + e(T)4 + f(T)5

Gas a b c Mwt. a b c d e f
AlCl2 97.89 9.04015 8.68E-03 ### 1.72E-09 ### 0
AlCl3 -0.0006 1.365E-05 -7.11E-10 133.34 ### 2.40E-02 ### 4.81E-08 ### 5.57E-15
Carbon Dioxide 0.00187 2.39E-05 -1.27E-09 44.009 6.21415 5.12E-03 ### 0 0 0
Carbon Monoxide 0.00628 2.16E-05 -1.70E-09 28.01 6.42043 8.88E-04 ### 0 0 0
Chlorine 0.00215 2.014E-05 2.33E-09 70.9 6.02127 6.56E-03 ### 3.01E-09 0.00000 0
Hydrogen Sulfide ### 2.40E-05 -3.40E-10 33.068 6.66150 2.85E-03 ### 0 0 0
Nitrogen 0.00344 4.28E-05 7.15E-09 28.013 6.89500 7.62E-04 ### 0 0 0
Oxygen 0.00624 2.59E-05 -2.71E-09 31.998 6.44284 1.25E-03 ### 0 0 0
HCl 0.00177 2.26E-05 3.95E-09 36.461 6.51457 ### 0 0 0 0
Sulfur Dioxide ### 2.12E-05 -1.44E-09 64.058 7.11595 5.93E-03 1.08E-06 0 0 0
TiCl4 0.0071 0.000073 1.157E-08 189.69 ### 2.92E-02 ### 1.32E-08 ### 2.62E-16
Water -0.00096 1.97E-05 -3.84E-09 18.015 7.08976 1.55E-03 0 0 0 0

Information Alligned for MBAL & VISC for auto entries. Cp = a + b(T) + c(T)2 + d(T)3 + e(T)4 + f(T)5
MAT-MATRIX a(m) b (m) c (m) Mwt a b c d e f
#N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A #N/A
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D. Willard 07/17/2017 Plant I RELSIZE.XLS(VISC)

 b .v.s. Q for sq.-edged orifice plates

0.1200
T1 = 100oF, DP = 87 psig, P1 = 90 psig, Using Cunningham
b, (bore dia./pipe ID)

0.1100 calculation for Y , as yielding the highest Q. The pressure drop

1
is not "hw;" the drop is the permanent pressure loss.
0.1000

0.0900

0.0800

0.0700

0.0600

0.0500

0.0400

0.0300
k = 1.2; M = 30
0.0200 k=1.3; M = 17
W = Q(PM/RT) = QM/408.67 k = 1.4; M = 2
PPH: pounds per hour
0.0100 Q = W(408.66/M)

0.0000
0 500 1,000 1,500 2,000 2,500 3,000 3,500
Q, SCFH (60 F, 14.7 psia)
T1 = 100oF, DP = 87 psig, P1 = 90 psig,
Using Cunningham

ko Q, SCFH b, 2" b, 1" M

1.2 50 0.0144 0.0144 30
1.2 250 0.0322 0.0322
1.2 500 0.0455 0.0455
1.2 1,000 0.0643 0.0643
1.2 1,500 0.0788 0.0788
1.2 2,000 0.0910 0.0910
1.2 3,000 0.1114 0.1114
1.2 4,000 0.1298 0.1298
1.2 5,000 0.1451 0.1451
1.3 50 0.0126 0.0126 17
1.3 250 0.0281 0.0281 0.0279
1.3 500 0.0397 0.0397
1.3 1,000 0.0561 0.0561
1.3 1,500 0.0688 0.0688
1.3 2,000 0.0794 0.0794
1.3 3,000 0.0973 0.0973
1.3 4,000 0.1317 0.1317
1.3 5,000 0.1472 0.1472
1.4 50 0.0072 0.0072 2
1.4 250 0.0163 0.0163
1.4 500 0.0230 0.0230
1.4 1,000 0.0325 0.0325
1.4 1,500 0.0398 0.0398
1.4 2,000 0.0460 0.0460
1.4 3,000 0.0563 0.0563
1.4 4,000 0.0660 0.0660
1.4 5,000 0.0737 0.0737