Professional Documents
Culture Documents
.
ii
.. 2558
(Power Plant Engineering)
E-book 4 e-mail
e-mail
2558
(1)
(2) (3) 13
13 4
4
e-mail: somchart@engr.tu.ac.th
2558
iii
iv
1 1
1.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.4 . . . . . . . . . . . . . . . . . . . 5
2 9
2.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
2.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
2.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
3 27
3.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
3.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
3.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
3.4 . . . . . . . . . . . . . . . . . 38
4 41
4.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.2 . . . . . . . . . . . . . . . . . . . . . 43
4.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
4.4 . . . . . . . . . . . . . . . . . . . . . . . . 49
4.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
4.6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
4.7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
5 67
5.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
5.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
5.3 . . . . . . . . . . . . . . . . . . 72
v
vi
5.4 . . . . . . . . . . . . . . . . . . 82
5.5 . . . . . . . . . . . . . . . . . . . . 83
5.6 . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
5.7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
6 95
6.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
6.2 . . . . . . . . . . . . . . . . . . . . . 96
6.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97
6.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99
6.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
6.6 . . . . . . . . . . . . . . . . . 103
6.7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
6.8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
6.9 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
6.10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
6.11 . . . . . . . . . . . . . . . . . . . . . . 113
7 121
7.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
7.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
7.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124
7.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126
7.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
7.6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
7.7 . . . . . . . . . . . . . . . . . . . . . . . . 139
7.8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
7.9 . . . . . . . . . . . . . . . . . . . . . . . . . . 143
7.10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
8 151
8.1 . . . . . . . . . . . . . . . . . . 151
8.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
8.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
8.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 158
8.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162
9 167
9.1 . . . . . . . . . . . . . . . . . . . . 167
9.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
vii
9.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
9.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
9.5 . . . . . . . . . . . . . . . . . . . . . . . . . 189
9.6 . . . . . . . . . . . . . . . . . . . . . . 189
9.7 . . . . . . . . . . . . . . . . . . . . . . . 192
10 195
10.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
10.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201
10.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
10.4 . . . . . . . . . . . . . . . . . . . . . . . 215
11 221
11.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221
11.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222
11.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
11.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225
11.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
11.6 . . . . . . . . . . . . . . . . . . . . . . . . . . 233
12 237
12.1 . . . . . . . . . . . . . . . . . . . . . . . . 237
12.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238
12.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239
12.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240
12.5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
12.6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244
12.7 . . . . . . . . . . . . . . . . . . . . . 246
12.8 . . . . . . . . . . . . . . . . . . . . . . . . 247
12.9 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251
12.10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253
12.11 . . . . . . . . . . . . . . . . . . . . . 254
12.12 . . . . . . . . . . . . . . . . . . . . . . 256
13 261
13.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 261
13.2 . . . . . . . . . . . . . . . . . . . . . . . 265
13.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 269
13.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273
viii
13.5 . . . . . . . . . . . . . . . . . . . . . . . 276
13.6 . . . . . . . . . . . . . . . . . . . . . . 278
1
1.1
1.1
.. 2555 2557
(power generation system)
(power transmission system)
(substation)
2 1.
1.1: .. 2548
(W/)
1683
1114
804
774
622
581
458
377
286
225
147
131
75
52
39
28
(2) (.)
.
1.2. 3
(3) (.)
. .
.
1.2
(thermal power plant)
(gas turbine power plant)
(combined-cycle power plant)
(nuclear power plant)
(hydroelectric power plant)
(diesel power plant)
(renewable energy)
4 1.
1.3
MW
MW 1.2 ..
2558
1.2: .. 2558
(MW) (%)
23313 53.5
8176 18.7
3406 7.8
8741 20.0
(1) . (2)
(independent power producer) IPP (3) (small power producer)
SPP
.
.
IPP
SPP
IPP . .
IPP (1)
(2)
. (3) .
(4)
SPP .
90 MW SPP
1.4. 5
(cogeneration)
10%
45%
1.3 ..
2557 IPP
1.3: .. 2557
(MW) (%)
. 15482 45
13167 38
3615 10
() 2404 7
1.4
6 1.
1.4. 7
1.
2.
3.
4.
5.
6.
7.
8.
9. (IPP) (SPP)
10. EIA
8 1.
2
2.1
(discount
rate) (future value)
(present value)
P V = fP V F V (2.1)
P V , F V n
1
fP V =
(1 + i)n
(2.2)
1 3
1.1
P V = 1000000 F V = 1100000
PV
fP V =
FV
= 0.909
1
=
(1 + i)3
10 2.
i = 0.0323
(series payment)
(2.1) (2.2)
500000 600000 5%
700000 4.5%
P V = P V0 + P V1 + P V2
P V0 = 500000
600000
P V1 =
(1 + 0.05)
= 471729
700000
P V2 =
(1 + 0.045)2
= 641011
= P V = 1612740
n
F Vk k
F Vk+1 = (1 + r)F Vk
[ ( ) ]
F V1 1+r n
PV =
ir
1
1+i
(2.3)
r = i (2.3) P V
nF V1
PV =
1+i
(2.4)
2.1. 11
1000000
5% 5
7%
F V1 = 1000000 , r = 0.05 i = 0.07
[ ( ) ]
1000000 1.05 5
PV = 1
0.07 0.05 1.07
= 4501444
(optimization
process)
(levelized value)
(annual value)
n
(fP V 1 , fP V 2 , ..., fP V n ) (2.2)
(P V1 , P V2 , ..., P Vn ) (2.1) AV
P V1 + P V2 + + P Vn
AV =
fP V 1 + fP V 2 + + fP V n
(2.5)
50 /GJ 2-5
5% 5
4.5%
(2.1)
12 2.
FV fP V i P Vi
1 50.00 0.9569 47.85
2 52.50 0.9157 48.07
3 55.13 0.8763 48.31
4 57.88 0.8386 48.54
5 60.78 0.8025 48.78
P Vi fP V i (i = 1, 2, 3, 4, 5) (2.5)
47.85 + 48.07 + 48.31 + 48.54 + 48.78
AV =
0.9569 + 0.9157 + 0.8763 + 0.8386 + 0.8025
= 55.02 /GJ
(net present value) (internal
rate of return)
1500
150 20
8%
1500 (P Vout )
1500 20 (P Vin )
(2.3) r = 0
[ ( ) ]
150 1 + 0 20
P Vin = 1
i0 1+i
i = 0.08 1500
2.2. 13
2.2
(load curve)
2.1
2.1
(load) 2.1
(load curve) 1
1 1
2.1: 12
14 2.
(peak load)
(load factor)
2.2
(blackout)
15-20%
2.2:
2.1 93 MW 7
2.1
.. 2548-2557
kW kW.h 1
(average load)
(Pave ) (Pmax ) (LF)
Pave
LF =
Pmax
(2.6)
2.2. 15
2.1: .. 2548-2557
.. (MW) (MW)
2548 20538 26450
2549 21064 27106
2550 22586 28530
2551 22568 29892
2552 22045 29212
2553 24010 30920
2554 23900 31447
2555 26121 32600
2556 26598 33681
2557 26942 34668
2.1
2.1
2.1
(rated capacity)
(capacity factor)
Pave
CF =
Prated
(2.7)
Pave (2.7)
Prated Pmax (2.6)
Pave (2.6)
(2.7)
LF.Pmax
CF =
P
(2.8)
rated
16 2.
.
.
100 MW
.
70 MW 70 MW 24
30 MW 70 MW
2.3
30 6 + 70 4 + 90 2 + 60 4 + 100 4 + 80 2 + 60 2
Pave =
24
= 65 MW
65
LF = 100 = 0.65
2.3:
CF = LF Pave
Prated = Pmax = 100 MW
2.3
2.3. 17
30 6 + 70 6 + 60 4 + 70 6 + 60 2
Pave,1 =
24
= 57.5 MW
57.5
CF1 = = 0.82
70
70 MW 24 h
20 2 + 30 4 + 10 2
Pave,2 =
24
= 7.5 MW
7.5
CF2 = = 0.25
30
2.3
(variable cost) (xed cost)
2.4
(fuel cost) (operation and maintenance cost)
(construction cost)
2.3.1
18 2.
2.4:
(cf ) (Cf )
(E ) E kJ cf (kW.h) cf
3600Cf
cf =
E
(2.9)
E = .Q (2.10)
Q
(HHV) kJ/kg (mf ) /kg
Q = mf .HHV (2.11)
(Ff )
Cf = mf .Ff (2.12)
E Cf (2.9)
3600Ff
cf =
.HHV
(2.13)
4 -
1000, 1500, 1300 1100
4 20, 22, 18 15 MJ/kg
2.3. 19
(2.12) cf
Ff /HHV Ff /HHV 4
Ff (/kg) HHV (MJ/kg) Ff /HHV (/MJ)
1.0 20 0.050
1.5 22 0.068
1.3 18 0.072
1.1 15 0.073
800 MW 38%
82% 20000 kJ/kg 0.5
Ff (2.13)
cf ..HHV
Ff =
3600
0.5 0.38 20000
=
3600
= 1.06 /kg
2.3.2
Com
com =
E
(2.14)
20 2.
Com E
8760
E = 8760Pave (2.15)
Pave (2.7)
(2.14)
Com
com =
8760.CF.Prated
(2.16)
600 MW 500
35%
500 106
com =
8760 0.35 600 103
= 0.27 /kW.h
2.3.3
(depreciation)
30-40
(salvage value)
(A) (G) (D)
N
(staight-line method)
AG
D=
N
(2.17)
2.3. 21
(sinking-fund method)
(A G)i
D=
(1 + i)N 1
(2.18)
i
(xed-charge rate)
Cc I
ICc
cc =
8760.CF.Prated
(2.19)
Cc = Fc Prated (2.20)
Fc Fc
65 15
5% 5
A = 65 G = 5 N = 15
65 5
D=
15
= 4
150 MW
20000 /kW 10%
120 MW 50%
22 2.
20000 150 103 = 3000 I = 0.1 (2.8)
0.5 120
CF =
150
= 0.4
2.3.4
2.5 1
1
2
2
3
3
1 ()
2 (
) 3
()
2.1 %
(load distribution curve)
2.6
(base load) (intermediate load)
(peak load)
2.6
1
2.5 1
2
3
1, 2 3
2.3. 23
2.5:
2.6:
24 2.
2.3.5
(http://www.mea.or.th)
(http://www.pea.or.th)
(time of use TOU)
26 2.
1. 3
2.
3.
4.
5.
6.
7.
8. TOU
9. 50 /GJ 5%
2 5 5% 5
10. 6000 500
30
(internal return rate)
11. 800 MW
(peak load) 750 MW 8760
5 (capacity factor)
12. 42% 22000 kJ/kg
1500
13. 0.31
700 MW 8600 45%
14. 800 20
4% (salvage value) 60
(sinking-fund method)
15. 450 MW 18000 /kW
24 365 9%
37%
3
3.1
(coal)
(biomass)
3.1.1
4 (Anthracite)
(Bituminous) (Sub-bituminous) (Lignite)
(proximate analysis) (ultimate analysis)
4
(moisture) (volatile matter) (ash) (free carbon)
3.1
28 3.
(mi )
(mM )
(coke)
(mV M )
mA (mF C )
mF C m m m
xF C =
mi
; xV M = V M ; xM = M ; xA = A
mi mi mi
(3.1)
50%
(bound water)
(free water)
(uniform burning)
(tempering process)
3.1
954 C
CH4 CO2
3.1:
3.1. 29
(spontaneous combustion)
Al2 O3 , Fe2 O3 , CaO, P2 O5
(ash fusion temperature)
(slag)
3.1 4
3.1:
(%) (%) (%) (%)
4.3 9.6 5.1 81.0
8.5 10.8 36.4 44.3
22.2 4.3 33.2 40.3
36.8 5.9 27.8 29.5
m = mF C + mV M (3.2)
30 3.
5
mC m m m m
xC =
m
; xH = H ; xO = O ; xN = N ; xS = S
m m m m
(3.3)
5 1
(3.1) mi
(as-received coal) mi m
mi m = mM + mA (3.4)
m = mi (1 xM xA ) (3.5)
C, H, O, N, S (3.3)
(3.1) C, H, O, N, S
xC,ar = xC (1 xM xA ) (3.6)
mC
xC,ar =
mi
(3.7)
xH,ar , xO,ar , xN,ar xS,ar
C 39.58%, H 2.57%, O 9.70%, N
0.67%, S 0.49%, 33.54% 13.46% C, H, O, N, S
xH,ar , xO,ar , xN,ar xS,ar (3.6)
xC,ar
xC =
(1 xM xA )
0.3958
=
(1 0.3354 0.1346)
= 0.7468
(calorimeter)
(grindability)
(Hardgrove machine)
(Hardgrove index)
(abrasivity)
(carbon steel)
(swelling index)
(stationary grate)
32 3.
800 C
1 9
0
3.1.2
3.2 (
)
3.2:
(%) (%) (%) (%) (kJ/kg)
12.00 12.65 56.46 18.88 14,755
10.00 10.39 60.70 18.90 13,650
50.73 1.43 41.98 5.86 9,243
40.00 0.90 45.42 13.68 11,298
59.40 1.50 31.00 8.10 7,451
3.2. 33
3.2
C 84-89%, H 12-14%, O 2-3% N 0-1%
S 0-3%
(fractional distillation process)
(liquidied petroleum
gas LPG) (gasoline) (kerosene) (diesel)
(fuel oil)
3.2.1
40705 45520
kJ/kg 1, 2, 4,
5 6 ( 3 )
3.2.2
80% 20%
(emulsied diesel)
34 3.
3.2.3
(specic gravity)
15.6 C
s=
15.6 C
API (American Petroleum Insti-
tute) API s API
141.5
s=
131.5 + API
(viscosity)
ASTM Standard D445 (centis-
toke)
(viscometer)
(pour point)
3.3. 35
(ash point)
4-5 C
6
1% 3-4% 2%
SO3
(steam coil)
(1)
(2) (3)
3.3
(natural gas) (synthetic gas) (biogas)
3.3.1
(CH4 )
CO2
36 3.
(H2 S)
CO2
-
(methyl alcohol)
(ethyl alcohol)
(propylene)
(polypropylene)
(liqueed petroleum gas LPG)
LPG
LPG
(natural gasoline NGL) -
5 NGL
NGL
100%
(ideal gas)
Mi V
yi = = i
M V
Mi Vi i M V
3.3. 37
MBtu (1 Btu = 1.055 kJ)
3.3.2
(coal gasication) (coke-oven gas) (pro-
ducer gas) (water gas) (synthetic natural gas SNG)
(coke)
+ + +
H2 CH4
(exothermic)
+ CO + N2 +
CO N2 CO
CO H2
(endothermic)
+ + CO + H2
SNG N2 CO
CO + H2 O CO2 + H2
SNG SNG H2
CO CH4
CO + 3H2 CH4 + H2 O
(catalyst)
(blast-furnace gas) CO2
(sewer gas) CH4
38 3.
3.3.3
(biogas) (anaerobic diges-
tion) 5 C, H,
O, N S
Ca Hb Oc Ne Se
( )
b c 3d e
Ca Hb Oc Nd Se + a 4 2 + 4 + 2 H2 O
( ) ( )
a b c 3d e a b c 3d e
+
2 8 2 8
4
CH4 + 2 8 + 4 + 8 + 4 CO2
+ dNH3 + eH2 S
CO2 , NH3 H2 S
BOD (biochemical
oxygen demand) COD (chemical oxygen demand) BOD
80% COD BOD COD
3.4
7
(proven reserve) (probable
reserve) (possible reserve)
3.3
(
)
3.4. 39
3.3:
()
P1 P1+P2 P1+P2+P3 P1 P1+P2 P1+P2+P3
223 553 741 4 11 15
()
LPG 182 411 476 5 12 14
()
7752 15560 18885 6 13 16
()
1181 2007 2007 18 65 111
()
P1
P2
P3
3.4
20
70%
40 3.
1.
2. 4
3.
4.
5.
6. (coke)
7. (ultimate analysis)
8.
9.
10. (water gas)
11. (biogas)
12.
13.
14.
15. (proximate analysis) 15%
5% (dry, ash-free basis)
(ultimate analysis) H 3% H
(as-received coal)
4
4.1
(ue gas)
3
C + O2 CO2 (4.1)
H2 + 12 O2 H2 O (4.2)
S + O2 SO2 (4.3)
(CH4 )
O2
N2 , O2 , Ar CO2
42 4.
4.1:
(%)
N2 78.084 79
O2 20.946 21
Ar 0.934 0
CO2 0.036 0
(complete combustion)
(stoichiometric combustion)
C, H, S CO
(incomplete combustion)
O2 O2
(stoichiometric air) (theoreti-
cal air) H2 O, CO2 N2
O2
(Cm Hn )
Cm Hn + (m + n4 )(O2 + 3.76N2 ) mCO2 + n2 H2 O + 3.76(m + n4 )N2 (4.5)
CO CO
CO + 12 (O2 + 3.76N2 ) CO2 + 1.88N2 (4.6)
CO
CO
4.2. 43
4 (1) (2)
(3) (4)
(excess air)
4.2
(theoret-
ical air-fuel ratio) AF RT
AF RT kgair /kgfuel
molair /molfuel
= 28.84
Mf uel
(4.7)
28.84 Mf uel
C, H S (4.1)-(4.3)
O N
Ca Hb Sc Od Ne
C
( )
b d
Ca Hb Sc Od Ne +
a+ +c
4 2
(O2 + 3.76N2 )
[ ( ) ]
b b d e
aCO2 + H2 O + cSO2 + 3.76 a + + c + N2 (4.8)
2 4 2 2
(4.8)
( )
b d
AF RT = 4.76 a + + c
4 2
molair /molfuel (4.9)
4.2 AF RT (4.9)
N, O2 CO2 AF RT
AF RT
k y1 , y2 , ..., yk
AF RT AF RT,1 , AF RT,2 , ..., AF RT,k AF RT
4.2: AF RT
AF RT (molair /molfuel )
C 4.76
H 1.19
S 4.76
CH4 9.52
C2 H6 16.66
C3 H8 23.8
CO 2.38
AF RT
(4.9)
(4.7)
( )
28.84 4.76 b d
AF RT =
Mf uel
a+ +c
4 2
kgair /kgfuel (4.11)
4.2. 45
Ca Hb Sc Od Ne
Mf uel = 12a + b + 32c + 16d + 14e (4.12)
C, H, S O
12a
xC =
Mf uel
(4.13)
b
xH =
Mf uel
(4.14)
32c
xS =
Mf uel
(4.15)
16d
xO =
Mf uel
(4.16)
xC , xH , xS xO a, b, c d (4.11)
AF RT = 11.44xC + 34.32xH + 4.29xS 4.29xO kgair /kgfuel (4.17)
xM
xA
AF RT = (11.44xC + 34.32xH + 4.29xS 4.29xO )(1 xM xA ) (4.18)
xC , xH , xS xO
(3.6) (4.18)
AF RT = 11.44xC,ar + 34.32xH,ar + 4.29xS,ar 4.29xO,ar (4.19)
xC,ar , xH.ar , xS,ar xO,ar
4% 5%
C 83.1%, H 5.5%, O
7.4%, N 2.1% S 1.9% AF RT
(4.18) AF RT
AF RT = (11.44 0.831 + 34.32 0.055 + 4.29 0.019 4.29 0.074)
(1 0.04 0.05)
= 10.2 kgair /kgfuel
46 4.
4.3
(formation enthalpy)
(adiabatic ame
temperature)
(heating value)
1 kg 1 m3 (bomb
calorimeter)
(higher heating value)
(lower heating value)
4.3 C
4.3: C H S
HHV (kJ/kg)
C C + O2 CO2 33700
H H + 0.25O2 0.5H2 O 144200
S S + O2 SO2 9300
S 4.3 H
1 kg O 8 kg
( x )
HHV = 33700xC + 144200 xH O + 9300xS
8
(4.20)
(Dulongs formula) (4.20)
( x )
HHV = (33700xC + 144200 xH O + 9300xS )(1 xM xA )
8
(4.21)
4.3. 47
( xO,ar )
HHV = 33700xC,ar + 144200 xH,ar
8
+ 9300xS,ar (4.22)
4.3 C S H
9 kg 1 kg H
9
25 C 2442 kJ/kg
LHV = HHV 2442(9xH,ar + xM ) (4.23)
Cm Hn Cm Hn , CO H2
4.4
4.4:
HHV (kJ/m3 ) HHV (kJ/kg)
CH4 CH4 + 2O2 CO2 + 2H2 O 39700 55600
C2 H6 C2 H6 + 72 O2 2CO2 + 3H2 O 69600 52000
C3 H8 C3 H8 + 5O2 3CO2 + 4H2 O 99100 50500
H2 H2 + 2 O2 H2 O
1 12700 142200
CO CO + 12 O2 CO2 12600 10100
k y1 , y2 , ..., yk
HHV1 , HHV2 , ..., HHVk
k x1 , x2 , ..., xk
HHV1 , HHV2 , ..., HHVk
4.4
CO Vi i 1
m3 1 m3 k
V = y1 V1 + y2 V2 + ... + yk Vk (4.26)
25 C 1962 kJ/m3
(4.20) xM = 0
4 100%
xC,ar
= 0.70, xH,ar = 0.05, xO,ar = 0.04, xS,ar = 0.01, xM = 0.10 xA = 0.10
(4.22)
HHV = 33700(0.7) + 144200(0.05 0.04/8) + 9300(0.01)
= 30172 kJ/kg
(4.23)
LHV = 30172 2440(9 0.05 + 0.1)
= 28828 kJ/kg
(4.24) 4.4
HHV = 39700(0.8) + 12700(0.15) + 12600(0.05)
4.4. 49
= 34295 kJ/m3
1 m3 (4.26) 4.4
V = 2 0.8 + 1 0.15
= 1.75 m3
(4.27)
LHV = 34295 1960 1.75
= 30865 kJ/m3
4.4
2
(Orsat apparatus)
CO2 , CO O2
(CO2 , CO, O2 N2 )
N2
yN2 = 1 yCO2 yCO yO2 (4.28)
(AF RA )
4.4.1
AF RA
AF RA
AF RA =
(
)
=
1 N 2
0.767
50 4.
( )
=
1 N2 N2
0.767
(
)
1 28( N2 )
= xN,ar (4.29)
0.767
xN N C CO CO2
xcb C 1 kg
CO CO2
xcb =
12()(yCO + yCO2 )
=
12(yCO + yCO2 )()
= = (4.30)
xcb
xcb C (4.30)
(4.29)
( )
1 28xcb yN2
AF RA =
0.767 12(yCO + yCO2 )
xN,ar (4.31)
xcb
xcb
(xA )
(refuse)
(xcr ) xcb
= 1 x
cr
= x
A
= xA
(1 xcr ) ( )
=
xcr xA
=
1 xcr
xcb =
4.4. 51
xcr xA
xcb = xC,ar
1 xcr
(4.32)
4.4.2
Ca Hb Sc Od (4.8)
( )
b d
Ca Hb Sc Od +
a+ +c
4 2
(O2 + 3.76N2 )
( )
b b d
aCO2 + H2 O + cSO2 + 3.76 a + + c N2 (4.33)
2 4 2
O2
CO
( )
b d
Ca Hb Sc Od + a + 4 + c 2 (O2 + 3.76N2 ) (a )CO2 + CO +
[ ( ) ]
b b d
2
H2 O + cSO2 + ( 1) a + 4 + c 2 + 2 O2 +
52 4.
( )
b d
3.76 a + + c
4 2
N2 (4.34)
(air ratio) AF RA AF RT
O2 , CO N2 (4.29)
( 1)(a + b/4 + c d/2) + /2
yO2 =
Ntotal
(4.35)
yCO =
Ntotal
(4.36)
3.76(a + b/4 + c d/2)
yN2 =
Ntotal
(4.37)
Ntotal (4.30) (4.31)
1 ( 1)(a + b/4 + c d/2)
yO2 yCO =
2 Ntotal
(4.38)
(4.32) (4.33)
yN2 3.76
=
yO2 0.5yCO ( 1)
yN2
=
yN2 3.76(yO2 0.5yCO )
(4.39)
AF RA
AF RA = AF RT (4.40)
C3 H8 CO2 , O2
CO 11.5%, 2.7% 0.7%
AF RT C3 H8 23.8 / (4.31)
N2
yN2 = 1 yCO2 yO2 yCO
= 0.851
N (e = 0)
0.851/(0.027 007/2)
=
0.851/(0.027 007/2) 3.76
= 1.116
= AF RA = 1.116 23.8 = 26.56 molair /molfuel
4.5. 53
4.5
(lean mixture) (rich mix-
ture)
20% 20%
(e)
( )
AF RA AF RT
e=
AF RT
100 (4.41)
N2 O2
(burner)
15-30% 5-10%
3-15%
O2 CO2
Cm Hn O2
( n) [ ( n )]
Cm Hn + m+
4
(O2 + 3.76N2 ) mCO2 + ( 1) m +
4 )
O2
n ( n
+ H2 O + 3.76 m + N2 (4.42)
2 4
O2 , CO2
[( 1)(m + n/4)
yO2 =
4.76(m + n/4) n/4
m
yCO2 =
4.76(m + n/4) n/4
e = 100( 1)
yO2 yCO2 e
0.01e
yO2 =
4.76(1 + 0.01e) n/(4m + n)
54 4.
4m/(4m + n)
yCO2 =
4.76(1 + 0.01e) n/(4m + n)
O2 CO2 O2
O2
CO2
CO2 O2 CO2
O2
CO2 O2 CO2
4.2 CO2 , O2 CO
CO2
O2
O2
O2
4.6. 55
4.2: O2 CO2 CO
O2 O2
O2
CO
O2 CO
O2
CO CO
4.6
SO2
S + O2 SO2
SO2 O2 SO3
SO2 + 12 O2 SO3
SO3 (sulfuric acid)
SO3 + H2 O H2 SO4
56 4.
SO2
SO2
(p) 1 atm
(partial pressure) (pH2 O )
pH2 O = yH2 O p
yH2 O
1 atm (dew-
point temperature) pH2 O
4.7
1. (ignition temperature)
4.5
4.5:
( C)
C 700
S 243
H2 500
CO 609
CH4 580
C2 H6 515
C3 H8 480
4.7. 57
2.
3.
(furnace)
(1) (2)
(3)
4.7.1
(burner)
4.3
4.3
4.3:
11 kV (pilot ame)
58 4.
(main ame)
(turndown ratio)
(atomizer)
(1) (2)
(3)
4.7.2
H2 , CH4 CO
(mechanical stoker)
(pulverizer-burner system) (uidized bed combustion system)
(grate)
4.7. 59
(spreader)
(arch)
4.4 (spreader
stoker)
4.4:
(pulverizer)
3
26 112
60 4.
4.3
4 (1)
(2) (3)
(ashback)
(4)
4.5
4.5:
32 mm
0.6-4.6 m/s
4.7. 61
(CaCO3 )
MgCO3 CaCO3 CaO CO2
CaCO3 CaO + CO2
CaO SO2 O2
CaO + SO2 + 0.5O2 CaSO4
SO2 815 C 870 C
CaSO4
900 C
NOx
(bubbling uidized bed combustion) (bub-
bling uidized bed combustion) 4.6
4.7
62 4.
4.6:
(SH) (RH)
(Eco) (AH)
4.7:
SO2
4.7. 63
64 4.
1.
2. (stoichiometric combustion)
(complete combustion)
3.
4. H xH O xO
(free hydrogen)
5. (air ratio)
6. Orsat apparatus
7.
8.
9.
10. O2
11. CO2 O2
12.
13.
14.
15.
16. (uidized-bed combustion system)
17. (uidized bed) SO2
18. NOx
19. (HHV) C4 H10 128400 kJ/m3
1960 kJ/m3 (LHV) C4 H10
4.7. 65
5.1
5.1
(compressed liquid
subcooled liquid)
(saturated liquid)
(saturated vapor) (superheated vapor)
5.1:
68 5.
5.1 5.2
(saturated liquid
line) (saturated vapor line)
374 C 22 MPa
(vapor dome)
5.2
5.2:
(T ) (p) (v) (h) (s)
(steam table) (steam chart)
5.3 h-p
(steam quality)
5.1. 69
5.3: h-p
x x = 1 x = 0
5.3
70 5.
5.4:
5.2
(Carnot cycle) 5.4
1-2 (boiler)
2-3 (turbine)
3-4 (condenser)
4-1 (compressor)
1-2 3-4
1-2
3-4
T4
=1
T1
(5.1)
5.2. 71
(Rankine cy-
cle) 5.5
5.5:
1-2
2-3
3-4
4-1
T-s 5.4 5.5
4-1
wnet
=
qin
(5.2)
wnet = (h2 h3 ) (h1 h4 ) (5.3)
qin = h2 h1 (5.4)
72 5.
5.3
5.5
(5.1)
5 (1)
(2) (3)
(4) (5)
5.3.1
5.6
T-s
( 5.6)
(heat sink)
15%
5.6:
5.3.2
1-2 5.5 (superheater)
(superheated steam) 5.7
5.3. 73
5.5
650 C
5.7:
5.3.3
5.8 T-s
( )
(22.1 MPa)
5.9
(supercritical Rankine cycle)
74 5.
5.8:
5.9:
5.3.4
3
(reheat)
5.10
(reheater)
20%
5.3. 75
5.10:
850 K 15 MPa 0.01 MPa
0.9
5.11:
5.11 T-s
6 h6 = 192 kJ/kg
p6 p1 h1 = h6
2 h2 = 3510 kJ/kg.K
5 0.01 MPa 0.9 h5 = 2340 kJ/kg.K 5.11 s4 =
s5 T4 = T2 (s4 T4 )
4 h4 3620 kJ/kg p4 = 3.5 MPa
76 5.
3 p3 =
p4 s3 = s2 h3 = 3090 kJ/kg
wnet = wt
= h2 h3 + h4 h5
= 1700 kJ/kg
qin = h2 h1 + h4 h3
= 3848 kJ/kg
1700
= = 0.44
3848
5 s5 = s2
p5 = 0.01 MPa h5 = 2100 kJ/kg
wnet = h2 h5
= 1410 kJ/kg
qin = h2 h1
= 3318 kJ/kg
1410
= = 0.42
3318
5.3.5
(feed
water)
5.12
(regeneration)
(1-2-3-4-5-1) (1-2-3 -4 -
1)
5.3. 77
5.12:
(feed water
heater)
2 (1) (open feed water
heater) (2) (closed feed water heater )
5.13
5.14 T-s
5.13:
(5.2)
5.14
78 5.
5.14:
wnet
=
qin
(5.5)
wnet qin
wnet = h1 h2 + (1 m)(h2 h3 ) (1 m)(h5 h4 ) (h7 h6 ) (5.6)
qin = h1 h7 (5.7)
m
1 kg/s m
h6 h1
m=
h2 h5
(5.8)
(shell-and-tube
heat exchanger)
5.15
(drain)
TTD (terminal temperature difference)
5.16
()
5.3. 79
5.15:
(throttle valve)
()
5.16: ()
()
5.17 T-s
(5.5) wnet , qin m
wnet = h1 h2 + (1 m)(h2 h3 ) (h7 h4 ) (5.9)
qin = h1 h8 (5.10)
h8 h7
m=
h2 h5
(5.11)
TTD T8
T8 = Tsat TTD (5.12)
Tsat p2
5.17:
5.18 T-s
5.14 5.14
(feed water pump) 5.16
5.14 (5.5) wnet
qin
5.18:
70 bar 540 C
7 bar 0.07 bar TTD = 3 C
5.18
h1 = 3500 kJ/kg
h2 = 2860 kJ/kg
h3 = 2150 kJ/kg
h4 = 163 kJ/kg
h5 = h4
h6 = 697 kJ/kg
h8 = h6
7 h7 p7 T7 5.18 p7 = p1 = 70
bar T7 (5.17) 7 bar Tsat = 165 C
T7 = 162 C
h7 162 C
h7 = 684 kJ/kg
82 5.
m (5.15)
684 163
m=
2860 697 + 684 163
= 0.194 kg
5.4
(pump efciency, p ) (turbine ef-
ciency, t )
wps
p =
wp
wt
t =
wts
wps wp wps
(isentropic process)
wp wt wts
5.5. 83
5.19 T-s
h1s h4
p =
h1 h4
h2 h3
t =
h2 h3s
5.5
5.20
(o )
Pe
o =
m .HV
(5.18)
f
Pe , mf HV (heating value)
HV (HHV ) (LHV )
HV HV
o = b ..g (5.19)
84 5.
5.20:
b (boiler efciency)
ms (hout hin )
b =
mf .HV
(5.20)
ms , hin
hout
(Pnet ) (Qin )
Pnet
=
Qin
(5.21)
Qin (5.20)
g (Pe )
Pe
g =
Pnet
(5.22)
1 kW.h
(heat rate)
mf .HV
HR =
Pe t
(5.23)
5.6. 85
t mf
HR kJ/kW.h HR o
3600
HR =
o
(5.24)
5.6
5.21
(5.20)
(input-output method)
(heat-loss method) (5.20)
(Ql )
Ql
b = 1
mf .HV
(5.25)
5.21
6
Ql,i
Li =
mf .HV
(5.26)
b = 1 (L1 + L2 + L3 + L4 + L5 + L6 ) (5.27)
6
86 5.
5.21:
1.
Ta Tg
xdg .cpg (Tg Ta )
L1 =
HHV
(5.28)
xdg
Tg
Ta
CO2 , CO, O2
N2 NCO2 , NCO , NO2 NN2
mdg = 44NCO2 + 28NCO + 32NO2 + 28NN2 (5.29)
(4.30)
12(yCO + yCO2 )Ndg
mf =
xcb
(5.30)
2.
H
O
(xM + 9xH,ar )[2442 + cpv (Tg Ta )]
L2 =
HHV
(5.32)
L3
L2
L3 -
L3 = 0
4.
(refuse)
xuc .HHVC
L4 =
HHV
(5.34)
xuc HHVC
(32800 kJ/kg)
5. CO
L5 =
CO CO
=
CO
C
C
88 5.
CO
MCO yCO xcb HHVCO
=
MC (yCO + yCO2 )HHV
(5.35)
xcb CO
(MCO ) 28 C (MC ) 12 CO (HHVCO )
10100 kJ/kg
6.
1%
L6
1232 kg/h 0.143 1232 = 176 kg/h
(xuc ) 0.01 (xcb ) 0.72
N2 1 - 0.1365 - 0.0047 - 0.0518 = 0.807
(5.31)
[11(0.1365) + 7(0.0047) + 8(0.0518) + 7(0.807)] 0.72
xdg =
3(0.0047 + 0.1365)
= 12.9
(5.28)
12.9 1.0 (167 27)
L1 =
30369
= 0.0595
(5.32)
(0.06 + 9 0.05)[2442 + 1.9(167 27)]
L2 =
30369
= 0.0455
L3 = 0
0.01
(5.34)
0.01 32800
L4 =
30369
= 0.0108
CO (5.35)
28 0.47 0.72 10100
L5 =
12(0.47 + 13.65) 30369
= 0.0186
L1 L5 L6 (5.27)
b = 1 0.0595 0.0455 0 0.0108 0.0186 0.0050
= 0.861
90 5.
(4.23) HV
(5.20) (5.25) LHV
(L2 )
HHV
b = 1 (L1 + L3 + L4 + L5 + L6 )
LHV
(5.36)
(4.23)
b = 30369 2442(9(0.05) + 0.06)
= 29124
0.861 30369
b = = 0.898
29124
5.7
(cogeneration)
(bot-
toming system) (topping system) 5.22
(absorption chiller)
(trigeneration)
5.7. 91
5.22: () ()
5.23:
5.23
92 5.
(back-pressure turbine)
5.24
(extraction turbine)
5.24:
5.7. 93
1.
2.
3.
4.
5.
6. (
, , )
7.
8.
9. T-s -
10.
11. T-s
12.
13. 6 MPa 850 K
14. 900 K 12 MPa
TTD 5 K
15.
10 MPa 700 K 3 MPa
0.01 MPa (
)
94 5.
16.
8 MPa
850 K 0.8 MPa
0.01 MPa (drain cooler) TTD
5 C ()
17. 9000 kJ/kW.h
18. 180 ton/h 4 MPa
800 K 450 K
15000 kJ/kg 10 kg/s
19. 70%
CO2 10%, O2 5% SO2 1% CO 0.5% N2 83.5%
1 kg
20.
19600 kJ/kg
CO ( HHV CO 10080 kJ/kg)
6
6.1
(process boiler)
(utility boiler)
2
(re-tube boiler) (water-tube boiler)
18 bar
6.2 kg/s
(boiler shell)
(tensile stress)
pD
=
2t
(6.1)
96 6.
p D t
(D )
6.2
(steam generator)
(drum-type steam generator)
(once-through steam generator) 6.1
(furnace) (evaporator) (drum)
(superheater) (reheater) (economizer)
(air heater)
22.1 bar
( 5.11)
6.3. 97
6.1:
6.1
(steam separator)
6.3
(refractory)
98 6.
6.2:
6.3
(convection)
(bubbly
ow)
(slug ow)
(annular ow)
(mist ow) 6.3
(h) h
h
h
h
h
6.4. 99
6.3:
6.4
(pressure vessel)
(6.1) 30
m 4.5 m 30
(riser) (downcomer)
6.4
100 6.
6.4:
6.5 (bafe)
(screen)
(cyclone separator)
(d ) (r )
(p) p (H )
d r
(natural circulation)
d r
H r
d
6.5. 101
6.5:
H r
d
d r
180 bar
(forced circulation)
H
6.5
(total dis-
solved solid, TDS)
ppm (part per million)
102 6.
(blowdown)
( )
xw xs
mb = ms
xd xw
(6.2)
(xs = 0) (6.2)
( )
xw
mb = ms
xd xw
(6.3)
6.6:
mb d
(t)
xd1 xd2 xd2 xd1
6.7
ms (xw xs )(d + t)
mb =
[0.5(xd1 + xd2 ) xw ]d
(6.4)
6.6. 103
6.7:
6.6
100 MW
(radiant superheater)
(convec-
tive superheater)
104 6.
6.8
(parallel ow)
(counter-ow)
6.8
6.8:
(6.1)
6.7. 105
20-30 C
(soot
blower)
6.7
5 C
4
(attemperation)
(gas recirculation)
1.
106 6.
6.9
6.9:
2. (attemperator)
6.10
(mw )
ms hs1 + mw hw = (ms + mw )hs2
3.
6.11 (Q)
(Qa ) (Qg )
(Qr )
6.7. 107
6.10:
6.11:
4.
108 6.
6.12
6.12:
6.8
-
(thermal stress)
30 C
6.9. 109
10-12 m/s
6.9
110 C 4%
280 C 11%
150-420 C
280-400 C
135-180 C
(recuperator)
(regenerator)
6.13
6.13()
6.13()
(hopper) -
30-60 W/m2 . C
50-65
mm
110 6.
6.13: () ()
(matrix)
6.14 -
(Ljungstrom regenerator) -
(Rothemuhle regenerator)
-
(effectiveness)
-
(self-cleaning)
6.10. 111
6.14: () ()
120 MW
10 m 0.5-3 rpm
6.10
112 6.
(soot blower)
6.15:
6.11. 113
6.16
50 cm
6.16:
6.11
(draft)
2 (natural
draft) (mechanical draft)
6.11.1
(stack) 6.17
114 6.
H (p) H
6.17:
6.11.2
mf .AF RA .va .p
PF D =
F D
(6.5)
va F D
(PID ) p
mf (1 + AF RA )vg .p
PID =
ID
vg ID
(balanced draft)
6.11.3
(axial type) (centrifugal type)
(single-stage axial fan) (two-
stage axial fan)
116 6.
(forward-curved)
(at) (backward-
curved) 6.18
6.1
6.18: ,
(characteristic curve)
(system resistance curve)
6.19
6.11. 117
6.1:
78-83% 84-91% 70-72%
6.19:
(inlet vane
control) 6.20
sp1 sp2
sp2 sp3 p1 p2
118 6.
p2 p3
a b b c
a p1 b p2
b p2 c p3
6.20:
(variable-speed
control) sp1 p1 sp2 p2
sp3 p3
6.21:
6.11. 119
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
120 6.
7
7.1
(radial-ow turbine) (axial-ow turbine)
(stator) (rotor) 7.1
122 7.
7.1:
7.2
(stage)
7.2 4
(impulse stage)
(reaction stage)
7.2: 5
7.2. 123
7.2.1
7.3
7.3:
(pressure compound
stage) 7.4
7.4
(velocity compound stage) 7.5
7.2.2
124 7.
7.4:
(reaction degree)
hr
R=
hs + hr
(7.1)
hs hr
0 1 50%
7.6
50%
(air foil)
7.3
(nozzle)
7.3. 125
7.5:
7.6: 50%
(nozzle efciency)
126 7.
(isentropic ow)
h
N =
hs
(7.2)
(h0 ) (V0 ) (h1 )
(V1 )
V02 V2
h0 + = h1 + 1
2 2
V12 V2
= h = h0 h1 = 0
2 2
V0 V1
V12
h =
2
(7.3)
V1 = 2h (7.4)
0.4 MPa
0.1 MPa 90%
0.4 MPa h0 = 2740 kJ/kg
0.1 MPa s1s = s0 h1s = 2500 kJ/kg h (7.2)
h = 0.90(2740 2500) 103
= 2.16 105 J/kg
h (7.4)
V1 = 2 2.16 105
= 657 m/s
7.4
(velocity triangle)
7.4. 127
V
(absolute velocity) U W
=W
V +U
(7.5)
7.7
V1 (nozzle angle)
(1 ) (2 )
7.7: () ()
U = r (7.6)
rad/s r
N rpm
2N
=
60
(7.7)
128 7.
[ )]
1( 2
P = m h1 h2 +
2
V1 V22 (7.10)
W1 W2
[ )]
1( 2 2
0 = m h1 h2 + W1 W2
2
1( 2 )
= h1 h2 =
2
W1 W22 (7.11)
h1 h2 (7.10)
m [( 2 ) ( )]
P =
2
V1 V22 W12 W22 (7.12)
(7.12)
V12 = W12 + U 2 + 2W1 U cos 1
V22 = W22 + U 2 2W2 U cos 2
(7.12)
P = mU (W1 cos 1 + W2 cos 2 ) (7.13)
7.4. 129
7.7
(7.9) (7.13)
(vertex)
7.8 50%
1 = 2
50%
50%
1 = 2 2 = 1 W1 = V2 W2 = V1
7.8: () 50% ()
(blade efciency)
P
B =
mh
(7.14)
h (7.3)
(7.14)
P
B = 1 2
(7.15)
2 mV1
h (h0 h1 )
(h1 h2 ) V12 /2 (7.3)
h1 h2 (7.11)
1 2
h = [V + (W22 W12 )]
2 1
(7.16)
P
B = (7.17)
1 m[V 2
2 1 + (W22 W12 )]
130 7.
3000 rpm
600 mm 800 mm
(rm ) (600+800)/2 = 700 mm
(7.6) (7.7)
2N rm
U=
60
2 3000 0.7
= = 220 m/s
60
50% 20 C
50 m/s 30 m/s
8 kg/s
(1 ) (1 )
W1 sin 1 = V1 sin 1
W1 cos 1 = V1 cos 1 U
[ ]
V1 sin 1
1 = tan1
V1 cos 1 U
[ ]
50 sin 20
= tan1
50 cos 20 30
= 45.2
W1
V1 sin 1
W1 =
sin 1
50 sin 20
=
sin 45.2
= 24.1 m/s
P (7.11) B (7.15)
50% (2 = 1 W2 = V1 )
P = 8 30(24.1 sin 45.2 + 50 sin 20 )
= 15.4 kW
7.5. 131
1.54 104
B = 1
2 8[502 + (502 24.12 )]
= 0.87
7.5
Pact
P (7.10)
7.5.1
(1 = 2 )
(W1 = W2 ) V2
(2 = 90 )
7.9 (Uopt )
Uopt = W2 cos 2
V1 cos 1
Uopt =
2
(7.18)
Uopt (7.1)
m
Pmax =
2
(V1 cos 1 )2 (7.19)
Pmax (7.13)
B,max = cos2 1 (7.20)
132 7.
(7.16) 1 1 = 0
1 0
7.10
(Uopt )
Uopt = W4 cos 2
(W3 = W4 )
V3 cos 2 = 2Uopt (7.21)
7.5 V2 V3
(V2 = V3 )
V2 cos 2 = 2Uopt (7.22)
7.9:
7.5. 133
7.10:
Uopt W2
W2 cos 1 = V2 cos 2 + Uopt
= 3Uopt
(W1 = W2 )
V1 cos 1 = 4Uopt (7.23)
V1 cos 1
Uopt =
4
n
V1 cos 1
Uopt =
2n
(7.24)
134 7.
(P1 ) (P2 ) (7.7)
P1 = mUopt (V1 cos 1 + V2 cos 2 )
P2 = mUopt (V3 cos 2 )
3
5 : 3 : 1 2
h n
h/n
2h
V1 =
n
(7.27)
(7.16) Uopt n
7.4
7.5.2
50%
7.11
Uopt = V1 cos 1 (7.28)
7.5. 135
Uopt 2 = 90 (7.11)
Pmax = m (V1 cos 1 )2 (7.29)
Pmax (7.27) (7.15)
2 cos2 1
B,max =
1 + cos2 1
(7.30)
7.11: 50%
W2 = kW1 k < 1
1
136 7.
7.13
V1 cos 1 = W1 cos 1 + Uopt
Uopt = W2 cos 2 = kW1 cos 1
Uopt
V1 cos 1 = + Uopt
(k )
k
= Uopt = V1 cos 1
k+1
7.12:
(7.7) (7.13)
P = mUopt (V1 cos 1 )
( )
k
= m (V1 cos 1 )2
k+1
( )
k
B = 2 cos2 1
k+1
7.6
mhs hs
1. (tur-
bulence) mhs
2.
7.6. 137
3. 7.7
(PS ) P (7.7) (7.11)
4.
5.
7.12
(W )
(Wm )
PS P
7.13:
(stage efciency)
PS
S =
mhs
(7.31)
(7.29)
( ) ( ) ( )
h P PS
S = . .
hs mh P
1
138 7.
2 3-5
PS
P
= 1 fL (7.32)
S N , B fL
hs () ( ) PS /m
PS
m
= (7.34)
S =
hs
(7.35)
0.7 MPa h0 = 3540 kJ/kg
0.1 MPa s1s = s0 h1s = 3340 kJ/kg
hs = (3540 3340) 105 = 2.00 105 J/kg
(N ) rpm
2N
= = 157 rad/s
60
(7.33)
1000 157
S = = 0.785
2.00 105
7.7. 139
7.7
PT
PT
n=
PS
(7.36)
S 4
7.14 1 2s, 3ss, 4ss
5ss 1 2, 3, 4 5
PT
T =
m(h1 h5ss )
(7.37)
PT 4
PT = PS1 + PS2 + PS3 + PS4
S
PT = mS [(h1 h2s ) + (h2 h3s ) + (h3 h4s ) + (h4 h5s )]
PT (7.35)
[ ]
(h1 h2s ) + (h2 h3s ) + (h3 h4s ) + (h4 h5s )
T = S
h1 h5ss
7.14
(h1 h2s ) + (h2 h3s ) + (h3 h4s ) + (h4 h5s ) > h1 h5ss
T S
T = fR S (7.38)
fR (reheat factor) 1
140 7.
7.14: 4
2 2
50% 2
(1 )
h(1) 2
h(1) /2 (7.4)
V1 = h(1)
(7.16)
2U
V1 =
cos 1
( )2
U
= h(1) =4
cos 1
h(2)
(7.4)
V1 = 2h(2)
7.7. 141
(7.22)
4U
V1 =
cos 1
( )2
U
= h(2) = 8
cos 1
h(3)
h(3) /2 50%
h(3)
V1 =
2
(7.23)
U
V1 =
cos 1
( )2
U
= h(3) =2
cos 1
7.15
7.15
142 7.
7.15:
7.8
P F
(axial thrust)
A (7.31)
7.3 p1 p2
7.9. 143
7.6 p1
p2
7.16
7.16:
7.9
(high-pressure sec-
tion) (low-pressure sec-
tion) 7.17
7.17
144 7.
7.17:
(back-pressure turbine)
7.18
(hp turbine)
(ip turbine)
(lp turbine)
7.19
7.17 (double-ow
turbine)
7.9. 145
7.18:
7.20
7.20
3000 rpm
(tandem-compound turbine)
3000 rpm
1500 rpm
7.21 (cross-compound turbine)
146 7.
7.21:
7.10
50% (7.29) U
7.10. 147
(Uopt = V1 cos 1 )
(governor)
7.22 (yball
governor) (sleeve)
7.22:
10% 3000 rpm
3300 rpm
148 7.
1.
2.
3.
4. 50%
5.
6. 50%
7.
V1 1
8.
9.
10.
11.
12.
13.
14.
15. 3100 kJ/kg
3000 kJ/kg
16. 500 mm
3600 rpm
17. 900 m/s 20
300 m/s
7.10. 149
8.1
(cooling tower)
8.1
8.2
(shell-and-tube heat exchanger)
(one-pass)
(two-pass) 8.2
U (four-pass)
8.3
152 8.
8.1:
8.2:
8.2. 153
Q = U ATlm (8.1)
Tlm =
ITD TTD (8.2)
ln(ITD/TTD)
ITD TTD
U A
(8.1)
ITD TTD
Q
8.3:
8.1
(admilralty copper) 304 (304 stainless steel)
(fouling)
90-10
154 8.
4
8.4
8.4:
1.8
3 m/s
8.3. 155
(vacuum pump) (ejector)
8.3
8.3.1
-
(deaerator)
O2 CO2
O2 CO2
8.5
(heater) (vent condenser) (storage tank)
(trays)
156 8.
8.5:
8.3.2
(LP heater) (HP heater)
(desuperheater) (condensing section)
(drain cooler)
8.6
8.3. 157
8.7
8.6:
8.7:
158 8.
8.3.3
8.1
200 MW 3 8
200 MW
8.1:
(MW)
0 50 3 5
50 100 5 6
100 200 5 7
200 6 8
8.4
(once-through system)
(thermal pollution)
(closed-loop system)
(cooling tower)
8.4. 159
2
(wet cooling tower) (dry cooling tower)
8.4.1
(approach) (range)
(wet-bulb temperature)
(natural draft) (mechanical
draft)
(i ) (o ) H (p)
p = (o i )gH (8.3)
p
(hyperbola)
8.8
150 m 2.5-5
160 8.
8.8:
(forced draft)
(induced
draft)
(counter-ow) 8.9
(cross-ow) 8.10
8.8-8.10
(ll)
(packing)
(makeup water)
1-
1.5%
8.4. 161
8.9:
8.10:
(drift) (drift elim-
inator)
162 8.
0.03% (bafe)
(blowdown)
1-1.5%
(recirculation)
(interference)
8.4.2
8.11
8.12
8.5
(blowdown)
(makeup
8.5. 163
8.11:
8.12:
water) 1.5-2%
-
3 Ca+ , Mg2+ , Na+
3 HCO3 , Cl , SO2
4
164 8.
(scale)
CO2 O2
(sedimentation)
(coagulation)
(internal treatment)
(external treatment)
(ion
exchange process) (cation resin) (anion
resin) ( Ca+ , Mg2+ , Na+ ) ( HCO3 , Cl , SO2 4 )
R H+ + C+ R C+ + H+
2R H+ + C2+ R
2C
2+
+ 2H+
R+ OH + A R+ A + OH
2R+ OH + A2 R+
2A
2
+ 2OH
R
C Ca+ , Mg2+ , Na+
A HCO3 , Cl , SO2
4
H+ OH (H2 O)
8.5. 165
-
(regeneration)
2R C+ + H2 SO4 2R H+ + C+
2 SO4
2
R+ A + NaOH R+ OH + Na+ A
R+2 A2 + 2NaOH 2R+ OH + Na+2 A2
166 8.
1.
2.
3.
4.
5.
6.
7.
8. -
9.
10.
11.
12.
13.
14.
15.
9
9.1
-
(open-loop control)
(closed-loop control) 9.1
(output) (input) (set point)
(controller) (control element)
(process equipment)
168 9.
(sensor)
(feedback)
9.1:
9.2:
9.3:
9.2
170 9.
9.2.1
(manometer) (Bourdon gauge) (bellows
gauge) (diaphragm gauge)
(strain gauge)
9.4
p1
p2 p2
h p1
p2
p1 p2 = gh (9.1)
9.4:
p2 p1 p2
9.5
9.2. 171
9.5:
9.6
9.6:
9.7
9.8
172 9.
9.7:
9.8:
(differential pressure transmitter)
(block valve)
(equalizing valve) 9.9
9.2.2
(level gauge)
9.2. 173
9.9: (DPT)
9.10:
9.11
9.12
174 9.
9.11:
(9.1) (h)
DPT
9.12:
9.2.3
(bimetallic thermometer)
(lled-bulb thermometer) (resis-
9.2. 175
9.13:
9.14
(bellows)
RTD
RTD
-
176 9.
9.14:
(Seebeck effect)
9.15
9.16
V1 V2 V1 1 V2
2 2 0 C 2
V2 V1
1 2
2
1 0 C RTD
2 V2
V1 1
9.15:
9.2. 177
9.16:
9.17:
(thermowell) 9.17
9.2.4
178 9.
(pressure-difference ow meter)
(velocity-based ow meter)
(positive-displacement ow meter)
(DPT)
(orice meter) (Venturi tube) (ow nozzle) 90
(elbow meter) (Pitot tube) (averaging Pitot tube)
(Annubar)
9.18
9.19
9.20
(9.2)
p1 p2
Q=k
(9.2)
k
(d)
(D) ( = d/D)
9.21
(throat)
(9.2) k
9.22
90 9.23
9.2. 179
9.18:
9.19:
9.24
90 (p1 )
(total pressure)
1
p2 = p1 + V 2
2
(9.3)
180 9.
9.20:
9.21:
9.22:
V
2(p2 p1 )
Q=A
(9.4)
9.2. 181
9.23: 90
9.24:
9.25
90
9.26
182 9.
9.25:
9.26:
9.27:
9.28:
9.29
(1)
(2) (3)
184 9.
9.29:
9.30:
9.3
9.3. 185
50 Hz
50 Hz
50 Hz
(load demand signal)
(boiler-
following control) (turbine-following control)
(coordinated control)
9.31
(EC) (load set point)
(ET)
EC
(PC)
(pressure set point)
PC
(PT)
9.31:
186 9.
PT
PC
9.32 EC
PC
9.32:
9.33 -
EC
9.4
9.4. 187
9.33:
9.34
9.34
(cross-limited control) 9.35
(FT)
(FC)
(low select)
(high select)
188 9.
9.34:
9.35:
9.34
9.5. 189
9.34
9.5
9.36
(PT) (PC)
PC
PC
9.36
9.6
190 9.
9.36:
(single-element con-
trol) 9.37 (LT)
(LC)
(two-element control) 9.38
FT
9.6. 191
9.37:
9.38:
192 9.
9.39:
9.7
6
9.40
(primary superheater) -
(secondary superheater)
9.7. 193
(attempetor)
-
1 ( TT1)
2 (TT2) -
1 (TC1) TT1
2 (TC2) TC2 TT2
TC2
9.40:
194 9.
1.
2.
10 cm
3.
4.
5.
6.
7.
8.
9.
10. RTD
11.
12.
13.
14. (total pressure)
(static pressure) (dynamic pressure)
15.
16.
17.
18.
19.
20.
10
10.1
(gas turbine cycle)
10.1 (compressor)
(combustor)
(gas turbine)
10.1:
(open Brayton cycle) 10.2
(heater)
196 10.
10.2:
10.3 (closed Brayton cycle)
(cooler)
T1
(ideal gas)
T-s 10.3 4
1-2
2-3
3-4
4-1
(wnet ) (qin )
wnet = cp (T3 T4 ) cp (T2 T1 ) (10.1)
qin = cp (T3 T2 ) (10.2)
cp (B )
T4 T1
B = 1
T3 T2
10.1. 197
10.3:
T1 (T4 /T1 1)
=1
T2 (T3 /T2 1)
1-2 3-4
2-3 4-1
T2 T3
T
= rp
(k1)/k
=
T
(10.3)
1 4
k = cp /cv rp = p2 /p1
T1
B = 1
T2
1
=1 (k1)/k
(10.4)
rp
(10.4) k k
He Ar k 1.67
k 1.4
(T3 ) (T1 ) rp
rp
( )k/(k1)
T3
rp.max =
T1
(10.5)
T3 T1
(10.3) (10.1)
[ ( ) ]
1 ( )
wnet = cp T3 1 (k1)/k
T1
(k1)/k
rp 1 (10.6)
rp
198 10.
rp wnet (10.6)
( )k/2(k1)
T3
rp,opt =
T1
(10.7)
( )2
T1
wmax = cp T3 1
T3
(10.8)
10.4
1-2 3-4
T2s T1
c =
T2 T1
(10.9)
T3 T4
t =
T3 T4s
(10.10)
100%
10.4:
10.1. 199
-
(regenerator)
10.5
T-s
10.5:
10.5 -
(Tx ) (T4 )
Tx T4
(regenerator effectiveness, )
Tx T2
=
T4 T2
(10.11)
T4
T2
T4 T2 (reheating)
(intercooling) 10.6
(LC)
(HC) (LT)
200 10.
(HT)
10.6:
10.5 1 atm
15.6 C 1093.3 C 4
= 1366.3(4)0.4/1.4 = 919 K
T3 T4
= t = 0.88
T3 T4s
= T4 = 973 K
Tx T2
= = 0.7
T4 T2
= Tx = 817 K
wc = cp (T2 T1 )
= 166 kJ/kg
wt = cp (T3 T4 )
= 395 kJ/kg
qin = cp (T3 Tx )
= 552 kJ/kg
395 166
= = 41.5%
552
10.2
10.7
(heat recovery steam
generator HRSG)
wB + wR
cc =
qin
(10.12)
wB wR qin
(B )
(R )
wB = B qin
wR = R (1 B )qin
wB wR (10.12)
cc = R + B R B (10.13)
202 10.
-
R = 0.33 B = 0.26 0.5
cc 0.38 0.42
10.7:
HRSG
10.8
q1
q2
wB = B q1
wR = R [(1 B )q1 + q2 ]
wB + wR
cc =
q1 + q2
B q1 + R [(1 B )q1 + q2 ]
= cc =
q1 + q2
(10.14)
q2
x=
q1 + q2
= q2 = x(q1 + q2 )
10.2. 203
q2 (10.14)
cc = B + R B R xB (1 R ) (10.15)
10.8: HRSG
(10.13)
(10.12) wB , wR qin
wB = mg cpg (T3 T4 T2 + T1 ) (10.16)
wR = ms (ha hb hd + hc ) (10.17)
qin = mg cpg (T3 T2 ) (10.18)
mg ms
cpg mg ms
HRSG HRSG
10.7
7.5 15 C
750 C 100 C
50 bar 500 C
0.1 bar 200 MW
cpg = 1.1 kJ/kg.K k = 1.4
( )(k1)/k
p2
T2 = T1
p1
= 288 (7.5)0.4/1.4 = 512.2 K
( )(k1)/k
p4
T4 = T3
p3
= 1023 (7.5)0.4/1.4 = 620.5 K
wB (10.16)
wB = 196.1mg (10.20)
qin (10.18)
qin = 561.9mg (10.21)
ha = 3670 kJ/kg
hb = 2305 kJ/kg
hc = 192 kJ/kg = hd
wR (10.17)
wR = 1365ms (10.22)
(wB + wR )
196.1mg + 1365ms = 200 103 (10.23)
10.3. 205
MW wB (10.20) wR
(10.22) kW kW
(10.19)
ms
mg
= 0.0712 (10.24)
(10.23) (10.24) mg ms
mg = 681.9 kg/s
ms = 48.6 kg/s
mg , ms (10.20)-(10.22) (10.12)
wB = 133.8 MW
qin = 383.2 MW
wR = 66.3 MW
cc = 0.52
10.3
10.3.1
(aeroderivative gas turbine)
(industrial gas turbine)
206 10.
10.1
10.1:
30 16
50 MW 300 MW
10.3.2
(compres-
sor) (combustor) (turbine) (casing)
10.9
(positive displacement)
(centrifugal ) (axial)
10.10 (lift)
() ()
10.3. 207
10.9:
(W ) (chord line) ()
10.11
(guide vane)
7
10.10:
(stall)
10.12
208 10.
10.11:
(V ) ()
(variable-angle guide vane)
10.12:
(low-
pressure compressor) (high-pressure compressor)
(low-pressure turbine)
(high-pressure turbine)
10.13
10.3. 209
10.13:
(compressor wash)
(, SNG) ( , , 2)
3 (tubular) (tuboannular)
(annular) 10.14
(ame tube)
10.15
(recirculation zone)
(burning zone)
(dilution zone)
NOx NOx
NOx
210 10.
10.14:
10.15:
(single-shaft gas turbine)
10.16 (two-shaft gas turbine)
10.3. 211
10.16:
(creep)
(Larson-Miller parameter)
LM LM ( K)
( )
LM T1 = 900 K T2 = 890
K (10.1) t1 = 25000 T2 = 47000
10 K
10.17
212 10.
10.17:
10.3.3
ISO 15 C
60% 1 atm
1 atm
10.3. 213
NOx
100%
10.3.4
15 C
10.18
10.18:
(fogging system)
(absorption cooling system)
(vapor compression system)
10.19
(steam injection cycle)
10.1
10.19:
10.4. 215
10.20:
10.4
HRSG
HRSG
10.21
Ty Tx (pinch point)
HRSG Tx Ty
HRSG HRSG
5-30 C
HRSG (horizontal) (vertical)
(once-through) 10.22 HRSG
HRSG
HRSG
216 10.
10.21: HRSG
10.23 HRSG
HRSG
HRSG
HRSG HRSG HRSG
HRSG
10.22:
10.4. 217
10.23:
10.24
HRSG HRSG
HRSG (triple-
pressure HRSG)
10.24: HRSG
HRSG
HRSG
HRSG
218 10.
HRSG
HRSG
HRSG
HRSG
10.4. 219
1.
2.
3.
4. T-s
5.
6. B R
7.
8.
9.
10.
11.
12.
13. NOx
14.
15.
16. ISO
17.
18.
19.
20.
220 10.
21.
22.
23.
24. 50% 300 C
200 C 100 C
25. 30 C 2000 C
4
26. 50%
( k = 1.4, cp = 1.005 kJ/kg.K)
27. 300 K 1 atm
80% 8 atm
( k = 1.4)
28. 1300 K 8 atm
80%
1 atm ( k = 1.4)
29.
2
300 K 1300 K
0.8 ( cp = 1.005
kJ/kg.K k = 1.4)
30. 200 MW 7.5
15 C 750 C
750 C HRSG
50 bar 600 C
0.1 bar ( cp = 1.11 kJ/kg.K, k =
1.33 )
11
11.1
(hydroelectric power plant)
100 kW 30 MW
(1) (run-of-river plant)
(2)
(impoundment plant)
(3) (pumped-
storage plant)
11.1 (dam)
(penstock)
(hydraulic turbine)
222 11.
(generator)
11.1:
H Q
gQH 75%
= p .t .g (11.1)
p
t
g
11.2
11.2. 223
(rock-lled dam) (earth dam)
(gravity
dam) (arc dam) (buttress dam)
(buttress)
20-30%
11.1
(spillway)
224 11.
11.1:
(m3 ) (MW)
13462 731
17745 720
9510 500
8860 300
3057 240
1420 72
2263 55
1967 36
(service spillway)
(emergency spillway)
11.3
(low-pressure conduit)
(screen)
,
(surge tank)
(penstock)
PVC (polyethelene)
(expansion joint)
p1 1 p
+ V12 + L = gH
2
(11.2)
H p1
pL (pressure loss) V1
11.4. 225
pL
p = 1
gH
(11.3)
p 1
(water hammer)
11.4
11.2:
p1 1 p2 1
+ V12 =
2
+ V22 + E
2
(11.4)
p1 p2 1( 2 )
E=
+
2
V1 V22 (11.5)
Eact
t =
E
(11.6)
Eact
11.3:
11.4.1
(11.5)
(reaction degree)
(p1 p2 )/
R=
E
(11.7)
11.4. 227
R (impulse turbine) R
(reaction turbine) R
(Pelton turbine)
11.4
(nozzle)
(needle valve)
(deector)
11.4:
11.5
= 180
(V2 = 0)
180
170 1
(V2 > 0)
228 11.
11.5:
(casing)
(Francis turbine)
(Kaplan turbine)
11.6
(1) (2) (guide vane) (wicket
gate)
(3)
(runner blade)
(propeller) 4
8 11.7
(servo-motor)
11.6:
11.7:
V1 E p2 V2
p1 1
Emax =
+ V12
2
(11.8)
p2 = 0 V2 = 0 p2
V2
E Emax
E Emax
11.5
11.4.2
-
-
230 11.
(head) (specic
speed)
( 60 m) (60-
350 m) ( 350 m)
(H ) (P ) (N )
N P
Ns = 5/4 (11.9)
H
N (rpm) P kW H m
4 1100
11.8
11.8:
100%
11.9
(propeller) (xed-blade)
11.5. 231
11.9:
11.4.3
(runaway speed)
11.10 (tur-
bine governing system)
(speed gov-
ernor) (electro-hydraulic governor)
(speed sensor)
(actuator)
() ()
(runner)
11.5
(11.5)
E Emax (11.8)
p2 V2
11.11
232 11.
11.10:
z 1 2
3
1 3
p1 p3 1( 2 )
E=
+
2
V1 V32 (11.10)
p3 = 0
(V3 0) E Emax
E z
11.11:
2 3
p2 V2 V2
+ 2 + gz = 3
2 2
11.6. 233
[ ]
1 ( )
p2 = gz + V22 V32
2
(11.11)
(11.11) p2 z V2 V3
E p2 p2
(cavitation)
(vapor pressure)
(101.3 kPa) 100 C
27 C
3.54 kPa
27 C
7000 atm
p2
pv patm pv patm (11.11)
p2
11.6
11.12
234 11.
100%
11.12
(pump-turbine)
(motor-generator)
11.12:
(centrifugal pump)
620-660 m
350 m
250 MW 4
11.6. 235
1.
2.
3. 100 m
3.6 105 kg/h
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14. 60 m
15.
16.
17.
18.
19.
20.
236 11.
12
12.1
(nucleus)
(nucleon)
(mn ) 1.008665 amu
(mp ) 1.007277 amu (me ) 0.0005486 amu amu
atomic mass unit 1.66 1027 kg
H 1 He 2
C 12 (atomic number Z ) -
(mass number A)
(AZ ) (nuclear symbol) AZ X X
11 H 42 He
126 C
10 e -1
10 n
1
(neutrino) 00
(isotope)
(11 H) 1 (21 H)
(tritium) (31 H)
1 2
X-Z X
238 12.
(periodical table)
He-3 32 He U-235 235 92 U
D T
U-235, U-238 U-234
99.282%, 0.712% 0.006%
3 U-227 U-240
(H2 O)
(D2 O) 1 3200
0.03%
H2 O D2 O
D2 O
H2 O
12.2
C + O2 CO2
C O2
(valence electron)
A1Z1 K Z2 L Z3 M Z4 N
A2 A3 A4
A1
Z1 K +A2
Z2 L Z3 M +Z4 N
A3 A4
Z1 + Z2 = Z3 + Z4
A1 + A2 = A3 + A4
12.3. 239
X
27
13 Al + 42 He 30
14 Si + Z X
A
13 + 2 = 14 + Z
Z=1
27 + 4 = 30 + A
A=1
1 1 11 H
1 H 1 p
1 1
12.3
(mass defect) AZ X
m = (A Z)mn + Z(mp + me ) mX (12.1)
(Einsteins law)
E = mc2 (12.2)
m kg c 3.00 108 m/s
E (binding energy)
1 amu = 1.66 1027 kg
1 amu 1.494 1011 J 931 MeV
42 He -
4.00277 amu m 0.03037 amu E = 27.1 MeV
42 He 4 6.78 MeV
12.1
40
Fe, Co Ni
240 12.
12.1:
7.5 MeV
7.5 MeV
1 H 1 H
1 1
2 He (fusion)
4
11 H
(ssion)
12.4
(radioactive matter) -
1. (gamma ray)
12.4. 241
(excited state) (ground
state)
( )
A
Z X A
Z X+
2. (beta ray)
1
60
27 28 Ni +1 e + +
Co 60 0
3. (alpha ray)
239
94 Pu 235
92 U +42 He +
N (t) t
dN
dt
= N (12.3)
12.1:
(MeV)
C-14 5715 0.156
N-16 7.13 , 4.24 (), 6.129 ()
P-32 14.28 1.170
K-40 1.25 10 9 1.312
Co-60 5.271 , 0.315 (), 1.332 ()
Sr-90 29.1 0.546
I-131 8.021 , 0.606 (), 0.364 ()
Xe-135 9.10 , 0.910 (), 0.250 ()
Cs-137 30.2 , 0.514 (), 0.662 ()
Rn-222 3.823 , 5.490 (), 0.510 ()
U-235 7.40 108 4.152
U-238 4.47 10 9 4.040
Pu-239 2.41 10 4 5.055
0.6931
= t1/2 =
(12.5)
t1/2 12.1
Co-60 3 1000
12.1 t1/2 Co-60 5.271 (12.5)
0.6931
=
t1/2
(12.4)
( )
0.6931t
N (t) = N (0) exp
t1/2
( )
0.6931 3
= 1000 exp
5.271
= 674
12.5. 243
12.5
U-235, U-238, Pu-239 Th-232
2-3 (ssion)
A
Z X + 10 n A1
F
Z1 1 + A2
F
Z2 2 + m10 n
AZ X AZ11 F1 AZ22 F2 m
23592 U U-235 U-
235
U-235
235
92 U + 10 n 140
54 Xe + 94
38 Sr + 20 n
1
U-235 75 160
(delay process)
U-235
U-236 U-236
235
92 U + 10 n 236
92 U
U-236
2.34 107 U-236
14% 86%
235
92 U + 10 n 137
56 Ba + 97
36 Kr + 20 n
1
12.2: U-235
(MeV)
166
14
10
5
5
200
U-235 1 MW
1 U-235 0.86 0.14
1 U-235
E = 0.86 190 1.60 1013
= 2.61 1011 J
1
E= 6.02 1023 E
235
= 6.69 1010 J
86400 U-235 1 g
6.69 1010
P = = 0.774 MW
86400
1 MW U-235 1.3 g
12.6
U-235
12.6. 245
(chain reaction)
2-3
12.2
U-235
U-235
U-235 U-236
U-235
U-235
U-235
86% U-235
(slow neutron)
(thermal neutron)
(fast neutron)
(prompt neutron)
U-235
(En2 )
(En1 ) A
( )2
En2 A1
En1
=
A+1
(12.6)
2% U-238
246 12.
28% C-12
12.7
(1) (fuel core) (2)
(coolant) (3) (moderator) (4) (control rod) (5)
(reactor vessel)
(UO2 )
(UC) (cladding ma-
terial) Al, Mg, Zr,
3
(shim rod) (regulating rod)
(safety rod)
(boron steel)
12.8. 247
1.8 m
12.8
(1)
(pressurized water reactor, PWR) (2) (boiling water reactor,
BWR) (3) (advanced gas-cooled reactor, AGR) (4)
(pressurized heavy water reactor, PHWR) (5) RBMK
( Reaktor Bolshoy Moshchnosti Kanalniy High
Power Channel Reactor)
12.8.1
200-300
150-250
(zircaloy) 12.2
PWR 12.2
(primary loop)
(secondary loop)
325 C
150 (pressurizer)
PWR
PWR 374 C
374 C
230
248 12.
12.2:
12.8.2
U-235 -
1.9-2.6 % 750 90-100
12.3
PWR
75
285 C
12.3
BWR
PWR BWR
PWR
12.8. 249
12.3:
12.8.3
PHWR CANDU (Canadian Deuterium)
CANDU PWR
PWR
12.4
(Calandria)
12-13 CANDU
(zircaloy)
300 C
CANDU
CANDU
CANDU
1 3200
250 12.
12.4: CANDU
12.8.4
12.5
U-235 2.5-3.5%
CO2
CO2
650 C
AGR PWR BWR AGR PWR BWR
12.8.5 RBMK
RBMK 12.6
290 C BWR -
.. 2529 RBMK
12.9. 251
12.5:
12.6: RBMK
12.9
252 12.
(U3 O8 )
3.3
(27%)
(17%) (15%) (11%) (8%) (7%) (5%)
(4%) (4%) (leaching)
(yellow cake)
1000 MW 200
U3 O8 (UF6 )
U-235 1% 4% U-238
85%
(depleted uranium) U-235
(0.7%) (gas centrifuge)
(gas diffusion)
12.7
UF6 238 92 UF6 92 UF6
235
235 UF 235 UF UF
92 6 92 6 6
235 UF UF 235 UF UF
92 6 6 92 6 6
U-235
UF6
UF6
UF6 (UO2 )
1 cm 2 cm
12.10. 253
12.7:
12.8:
(fuel pellet)
60 cm 4 m
12.10
-
(1) (low-level waste)
(2) (intermediate-level waste)
(3) (high-level waste)
254 12.
5-10
(borosilicate glass)
500
U-235 1% U-238 93%
Pu-239 0.5% 5.5%
U-235,
U-238 Pu-239 U-235
Pu-239 U-235
Pu-239 U-235
Pu-239
12.11
H+
OH
(somatic
effect) (genetic effect)
-
(cosmic ray)
12.11. 255
(radiation dose) SI
(Gy) 1 Gy 1 J 1 kg
(equivalent radiation dose) (quality factor)
(Sv) 12.3
12.3:
, , 1
2
10
10
20
20
-
1
4 Sv
2-6 mSv
1 kg 4 103 J
256 12.
12.12
(International Atomic Energy Agency) IAEA
IAEA 3
U-235 95%
U-235 2-3%
(reactor meltdown)
26 .. 2529 (Chernobyl)
() RBMK
31 203
11 .. 2554 8.9
10
(Fukushima) (Fukushima Daiichi)
BWR 6
14
4
258 12.
1.
2. 239
94 Pu
3.
4.
5.
6. 90
38 39 Y
Sr 90
7. 360 2
6
8.
9.
10.
11.
12.
13.
14.
15.
16. RBMK
17.
18. (U3 O8 )
19.
20.
12.12. 259
21.
22.
23.
24. 1.007277 amu 1.008665 amu
168 O 15.99491 amu 168 O (1 amu = 1.66 1027 kg,
1 eV = 1.6 1019 J c = 3.0 108 m/s)
25. U-235 200 MeV 1 20000 kJ
1 g U-235 (1 eV = 1.6
1019 J 6.022 1023 1 mol U-235)
260 12.
13
13.1
13.1.1
N2 79% O2 21%
(particulate)
(NOx ) (SO2 )
(NO) (NO2 )
NO
262 13.
NO2
NOx
-
SO2 SO2 (sulfuric
acid) SO2
13.1
13.1:
SO2 NOx
(ppm) (ppm) (mg/m3 )
1.
1.1 700 400 320
1.2 950 200 240
1.3 60 200 60
1.4 60 200 320
2.
2.1
(1) 300 MW 640 350 120
(2) 300 - 500 MW 450 350 120
(3) 500 MW 320 350 120
2.2
(1) 300 MW 640 180 120
(2) 300 - 500 MW 450 180 120
(3) 500 MW 320 180 120
2.3 20 120 60
2.4 60 200 120
AW + BX + CY + DZ
13.1. 263
A
B
C
D
W
X
Y
Z
13.1
13.1:
13.1.2
264 13.
(cooling tower)
-
1. (pH) 5 9
2. 40 C
3. 3000 mg/L
4. 50 mg/L
5. BOD 20 mg/L
6. COD 120 mg/L
7.
13.2. 265
13.1.3
(stabilization)
13.2
NOx NOx
(combustion control) NOx
NOx (post-combustion control) NOx
NOx (NH3 )
NOx NOx NOx
NOx SCR (selective catalytic reduction) NOx
SCNR (selective non-catalytic reduction)
13.2.1
NOx
NOx
(ue gas recirculation)
NOx
NOx
266 13.
NOx NOx (low NOx burner)
(air staging) (fuel
staging) NOx
13.2
13.2: NOx
(exothermic)
(160 350 C)
NOx SCR 95%
SCR
13.2. 267
3 4
SCR
SCR NOx
(ammonia slip)
SO2 SO2 SO3
SO + 12 O2 SO3
NH3 + SO3 + H2 O NH4 HSO2
1
2NH3 + 2SO3 + H2 O + O2 2NH4 SO4
2
SCR
900 1050 C
SNCR NO2 NOx
NO 95% NO2 5% SNCR NOx
70 80% SCR SNCR
SCR SNCR SCR
4NH3 + 5O2 4NO + 6H2 O
4NH3 + 3O2 2N2 + 6H2 O
2NH3 + 2O2 N2 O + 3H2 O
NO (nitrous oxide, N2 O)
N2 O
NOx SNCR
NOx
SNCR NOx
(computational uid dynamics)
SNCR
13.3. 269
13.3
(bottom ash)
(y ash)
13.2
13.2:
(%) (%) (%)
60-80 0-5 20-40
10-30 0-10 70-90
5-90 0-5 10-95
(cyclone separator)
(electrostatic precipitator) (fabric lter)
13.3.1
(emitting electrode)
(grounded collecting plate)
30 80 kV
13.4
270 13.
13.4:
(ash hopper)
13.5
13.5:
(elec-
13.3. 271
13.3.2
(lter bag)
125 300 mm
12.5 m
(cell plate)
(reverse gas fabric lter) 13.6
272 13.
13.6:
13.7:
13.4. 273
13.3.3
13.8
13.8:
13.4
(extrinsic ash)
(intrinsic ash)
(silicon) (aluminum) (alkali)
(bottom ash)
274 13.
(y ash)
(mechanical stoker) 60 80% 20 40%
(pulverized coal) 10 30%
70 90%
13.4.1
(hopper)
13.9 (silo)
13.9:
(pneumatic)
13.4. 275
(Bernoulli equation)
(uidization)
60
13.4.2
276 13.
13.5
(SO2 ) -
S + O2 SO2
SO2 (sulfuric acid, H2 SO4 )
SO2
SO2
SO2
70%
SO2
SO2 SO2 (ue gas desulfurization)
SO2 (sulfurous acid, H2 SO3 )
(H+ ) (HSO3 )
H+ (SO2 3 )
SO2 + H2 O H2 SO3
H2 SO3 H+ + HSO3
H+ + HSO3 SO23 + 2H
+
SO2
SO2 (limestone)
13.5.1 SO2
SO2 (CaCO3 )
SO2 95 - 98% 13.10
SO2
SO2 (CaSO4 )
(CaSO3 ) -
13.10: SO2
SO2
(saturated)
278 13.
(mist eliminator)
(hydrocyclone)
SO2
13.5.2 SO2
pH 8 CO2 3 HCO3
SO2 SO2
13.11
SO2
SO2 + CO2
3 SO3 + CO2
2
SO2
3 HSO3 O2
1
SO2
3 + 2 O2 SO4
2
HSO3 + 12 O2 HSO4
pH 6 7 pH pH
13.6
(continuous emis-
sion monitoring, CEM)
13.6. 279
13.11: SO2
CEM
NO, NO2 SO2
13.6.1
2 (in-
situ method) (extractive method)
(point
analysis) (path analysis)
13.12
(single-pass)
280 13.
13.13 (double-pass)
NOx , SO2
13.12:
13.13:
13.6. 281
(dry extractive)
(wet extractive)
(dilution extractive)
(lter)
(membrane)
SO2
NOx
NOx
NOx SO2
50:1 250:1
13.3 NOx SO2
13.6.2
(light extinction)
282 13.
13.12 13.13
(beta ray
attenuation) C-14
(probe electrication)
(ground state)
NO NO2
NO2 NO
284 13.
1. NOx
2.
3. NOx SCR
4. NOx SCR
5. NOx SNCR
6.
7.
8.
9.
10.
11. SO2
12.
13.
14. CEM
15.
16.
17. SO2 SO2
18. NOx NOx
19.
20.
21.
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